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Temperature distribution in a new composite material for hydrogen storage – Design study of different cooling concepts 一种新型储氢复合材料的温度分布——不同冷却概念的设计研究
Lars Baetcke, M. Kaltschmitt
A newly developed composite material has been explored based on metal hydrides in combination with polymers enriched with highly porous carbon. As metal hydride, a RHC (reactive hydride composite) was chosen (e.g., MgH2 + 2 LiBH4). The hydride is infiltrated into the pores of the porous carbon suppressing the long-range phase separation of the two different hydrides by nano-confinement. The aim is to maintain fast kinetics and achieve cycle stability of the RHC (reactive hydride composite). The combination of RHC and porous carbon is then integrated into a polymer film to allow an easy and safe handling of the material. To produce a storage system out of such a film, the thin material is rolled in the same style like a rolled membrane module; i.e., it is rolled together with a thin spacer (e.g., steel mesh) allowing an easy hydrogen access to all parts of the membrane. The last step is the implementation of the rolled storage module into the tank shell. To analyze different design concepts and the behavior of this newly developed composite storage material, extensive FEM-simulations have been realized for different cooling structures. The latter is necessary to fulfil the thermodynamic requirements and to maximize the speed of hydrogen storage. Therefore, the temperature development within the storage during hydrogen feeding are investigated. Beside this, the hydrogen flow as well as the kinetics of the chemical reaction are analyzed. Based on such extensive simulations of different design concepts, the most promising overall storage systems are developed and systematically optimized. Finally, the total hydrogen content of the overall storage system is calculated and compared between different design concepts. Based on this, conclusions are drawn about robust criteria how to construct a cooling and heating device for this new storage material.
以金属氢化物与富含高多孔碳的聚合物相结合,开发了一种新型复合材料。作为金属氢化物,选择了RHC(活性氢化物复合材料)(如MgH2 + 2 LiBH4)。氢化物渗透到多孔碳的孔隙中,通过纳米约束抑制了两种不同氢化物的远距离相分离。目的是保持快速动力学和实现RHC(活性氢化物复合材料)的循环稳定性。然后将RHC和多孔碳的组合集成到聚合物薄膜中,从而可以轻松安全地处理材料。为了从这种薄膜中生产存储系统,将薄材料以与卷膜模块相同的方式轧制;也就是说,它与一个薄间隔(例如,钢网)滚在一起,允许氢气容易进入膜的所有部分。最后一步是实现储罐模块滚入罐壳。为了分析不同的设计理念和这种新开发的复合存储材料的性能,对不同的冷却结构进行了广泛的有限元模拟。后者对于满足热力学要求和最大限度地提高储氢速度是必要的。因此,研究了加氢过程中储存库内的温度变化。除此之外,还分析了氢的流动和化学反应的动力学。基于对不同设计概念的广泛模拟,开发并系统优化了最有前途的整体存储系统。最后,计算并比较了不同设计理念下整个储氢系统的总含氢量。在此基础上,得出了构建这种新型存储材料的冷却和加热装置的可靠准则。
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引用次数: 0
Techno-economic Evaluation Of A Modular Compressed Air Energy Storage To Support Integration Of Wind Generation On El Hierro 支持耶罗岛风力发电一体化的模块化压缩空气储能系统技术经济评价
Eva Schischke, Annedore Kanngießer, Markus Hadam, M. Budt
In order to reduce the dependence on fuel imports as well as CO2-emissions, islands are switching from diesel to renewable generation. Energy storage systems are used to avoid curtailment of the renewable generation as well as to reduce cycling of the diesel generator. This paper evaluates the operation of a modular, low temperature adiabatic compressed air system (KompEx LTA-CAES ®) on El Hierro using mixedinteger linear programming. Optimal dimensions for charging power and storage capacity are determined and a sensitivity analysis concerning fuel prices and storage efficiency is presented. The economic situation is assessed for the KompEx LTA-CAES as well as for the existing pumped hydro storage.
为了减少对燃料进口的依赖以及二氧化碳的排放,岛屿正在从柴油发电转向可再生能源发电。储能系统用于避免可再生能源发电的削减,以及减少柴油发电机的循环。本文使用混合整数线性规划评估了El耶罗岛上的模块化低温绝热压缩空气系统(KompEx LTA-CAES®)的运行。确定了充电功率和存储容量的最优尺寸,并对燃料价格和存储效率进行了敏感性分析。对KompEx LTA-CAES以及现有抽水蓄能电站的经济状况进行了评估。
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引用次数: 1
Power Quality in Smart Distribution Systems with Electric Battery, Large Loads and PV Generation. 电池、大负荷和光伏发电智能配电系统的电能质量。
M. Ortiz, Idar Petersen, R. Mikut, Henrik Landsverk, S. Simonsen
A change in the electricity consumption is taking place, where one of the main reasons is the large increase in Distributed Generation, as photovoltaic (PV) systems and electric batteries in the low voltage (LV) distribution grid. This could translate in specific cases into a situation of increased peak load and bigger voltage fluctuation. Therefore, an effective control of the grid voltage is necessary to achieve a stable energy supply from renewable sources. What services can a battery provide? The authors present an analysis of voltage control and other battery services in a LV grid. A flexible model based on Python is developed and used to solve a multi-period optimal power flow problem. They propose an optimised distributed voltage regulation. The power flow equations are linearised around a stable operation point, which allows high feasibility and computation speed. Then a receding horizon framework is described, including 24h and 1h updated forecasts. The analysis is performed on a LV network with large loads of a stadium, large PV generation (690kWp) and with a 1MWh battery. The new method provides an optimization of the grid operation (reduced voltage variation and cost of energy imported from the grid) under different seasonal weeks.
电力消费正在发生变化,其中一个主要原因是分布式发电的大量增加,如光伏(PV)系统和低压(LV)配电网中的电池。在特定情况下,这可能会导致峰值负载增加和电压波动更大。因此,有效控制电网电压是实现可再生能源稳定供电的必要条件。电池能提供什么服务?作者对低压电网中的电压控制和其他电池服务进行了分析。基于Python开发了一个灵活的模型,并将其用于求解多周期最优潮流问题。他们提出了一种优化的分布式电压调节。功率流方程在稳定运行点附近线性化,具有较高的可行性和计算速度。然后描述了一个后退地平线框架,包括24h和1h更新的预测。该分析是在一个低压网络上进行的,该网络具有体育场的大负载,大型光伏发电(690kWp)和1MWh电池。该方法在不同的季节周提供了电网运行的优化(减少电压变化和从电网进口的能源成本)。
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引用次数: 1
Experimental Characterization of Magnetite Under Thermal Cycling For Thermocline Energy Storage 温跃层储能磁铁矿热循环实验表征
Y. F. Baba, A. A. Mers, H. Ajdad, Yaroslav Grosu, A. Faik
the present paper investigates the effect of thermal cycling on magnetite thermo physical characteristics particularly density, heat capacity, thermal diffusivity and thermal conductivity. The purpose was to evaluate the stability of the TESM and to emphasize its suitability for thermocline energy storage for medium temperature. Cycled magnetite was characterized and then compared to raw magnetite. Obtained results have shown that magnetite is a stable filler material, convenient for thermal energy storage. More important, thermal cycling impacts positively the studied material, it permits to get rid for the impurities present in the raw material. Furthermore, thermophysical properties of magnetite increase by applying thermal cycling. Keywords—magnetite; thermocline energy storage; thermal energy storage material; characterization; thermal cycling.
本文研究了热循环对磁铁矿热物理特性的影响,特别是对磁铁矿密度、热容量、热扩散系数和导热系数的影响。目的是评价TESM的稳定性,并强调其适合于中温的温跃层储能。对循环磁铁矿进行了表征,并与原磁铁矿进行了比较。研究结果表明,磁铁矿是一种稳定的填充材料,便于储热。更重要的是,热循环对所研究的材料有积极的影响,它允许去除原料中存在的杂质。此外,热循环可以提高磁铁矿的热物性。Keywords-magnetite;温跃层储能;蓄热材料;描述;热循环。
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引用次数: 0
Business Models and Grid Impact of Energy Storages and Controllable Loads for PV-Self-Consumption at Prosumer Level 产消级光伏自用储能和可控负荷的商业模式和电网影响
B. Idlbi, D. Stakic, Matthias Casel, D. Graeber, G. Heilscher, Martin Fiedler
Many countries are experiencing rapidly increasing distributed generation (DG) of renewable energy sources (RES). Electricity self-consumption is currently replacing feed-in-tariffs (FIT) as one main driver of this development. A prosumer, who is a consumer and producer of energy through his own DG, like photovoltaic (PV), can save costs through the self-consumption of his PV energy. The attractiveness of this business case is mainly based on the decreasing levelized cost of energy (LCOE) of PV systems as well as the difference between the decreasing FIT and the increasing costs of electricity consumption from the public grid. Utilizing local energy storages like batteries or power-to-heat (PtH) can increase both self-consumption and earnings. Noticing this tendency, electricity suppliers and industrial manufacturers offer new business models, in which small local storages of prosumers can be substituted with district storages or even virtual storages. This contribution presents an economic comparison and grid impact analysis of different self-consumption business models (i.e. home storages, PtH, district storages, virtual storages), considering the perspectives of prosumers as well as electricity suppliers. For realistic results, assumptions have been made based on the data of a real grid area near the city of Ulm. The results show that home storages, district storages as well as PtH systems are currently significantly less profitable for prosumers compared to pure PV-systems, if only selfconsumption is targeted as a business case. District storages are not attractive as a business model as well, whereas cloud storages can yield a quite good return at least for the electricity suppliers. However, an analysis of a future scenario indicates a better economic potential for storage business models. The grid impact analysis demonstrates a possible reduction of load and voltage through storages. Yet, for an efficient use of storage systems in regard to the electricity grid, financial incentives are necessary to support a grid-friendly operation of storages. Keywords—Home Battery Storage, District Battery Storage, Power-to-Heat, Self-Consumption, Business Models, Grid Impact
许多国家正在经历可再生能源(RES)分布式发电(DG)的快速增长。电力自用目前正在取代上网电价(FIT),成为这一发展的主要推动力。一个产消者,通过他自己的DG(如光伏),既是能源的消费者又是能源的生产者,他可以通过自己消费他的光伏能源来节省成本。这个商业案例的吸引力主要是基于光伏系统的平均能源成本(LCOE)的下降,以及FIT的下降和公共电网电力消耗成本的增加之间的差异。利用电池或电热(PtH)等本地能源存储可以增加自我消耗和收入。注意到这一趋势,电力供应商和工业制造商提供了新的商业模式,在这种模式中,生产消费者的小型本地存储可以被区域存储甚至虚拟存储所取代。这篇文章从产消者和电力供应商的角度出发,对不同的自用商业模式(即家庭储能、PtH、区域储能、虚拟储能)进行了经济比较和电网影响分析。为了使结果更逼真,我们基于乌尔姆市附近的一个真实网格区域的数据进行了假设。结果表明,如果仅将自我消费作为商业案例,那么家庭存储,区域存储以及PtH系统目前对产消者来说,与纯pv系统相比,利润明显较低。区域存储作为一种商业模式也没有吸引力,而云存储可以产生相当不错的回报,至少对电力供应商来说是这样。然而,对未来情景的分析表明,存储业务模式具有更好的经济潜力。电网影响分析表明,通过存储可以降低负荷和电压。然而,为了有效地利用电网方面的储能系统,财政激励是必要的,以支持电网友好的储能操作。关键词:家用电池储能,区域电池储能,电换热,自用,商业模式,电网影响
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引用次数: 1
Provision of cooling in Oman - a linear optimisation problem with special consideration of different storage options 提供冷却在阿曼-一个线性优化问题,特别考虑不同的存储选项
S. Köhler, Franziska Pleißner, H. Francke, Jann Launer, Christoph Pels Leusden
The work analyses thermal and electrical solar cooling systems regarding the influence of energy storages using the open source tool open energy modelling framework (oemof). The systems are optimised with respect to lowest cost, considering various storage configurations and boundary conditions such as a required solar fraction. The results illustrate the importance of the different storage options on the size of the system components and the solar fraction. Optimal solar electrical cooling achieves solar fractions above 65%, optimal solar thermal cooling solar fractions above 87%, with a clear economic advantage for solar electrical cooling. Electrical energy storage suffers from high investment cost (compared to other storage options) and is not part of the cost optimal solutions. A sensitivity analysis shows, that even 50% decreased storage costs and increased electricity prices don’t allow a profitable use of large electrical storages. To increase the solar fraction of solar electrical cooling to more than 65 % it is mandatory to use electricity storage. For both concepts, higher than cost optimal solar fractions can be achieved by increasing the respective storage sizes. Solar fractions of up to 95% are still economically reasonable. However, solar fractions above 98% result in an extreme cost increase.
这项工作使用开源工具开放能源建模框架(oemof)分析了热能和电力太阳能冷却系统对储能的影响。考虑到各种存储配置和边界条件,例如所需的太阳能分数,系统在最低成本方面进行了优化。结果说明了不同的存储选项对系统组件的大小和太阳能比例的重要性。最佳太阳能电冷却系统的太阳能分数达到65%以上,最佳太阳能热冷却系统的太阳能分数达到87%以上,太阳能电冷却具有明显的经济优势。电能存储的投资成本高(与其他存储选项相比),并且不是成本最优解决方案的一部分。一项敏感性分析表明,即使降低50%的存储成本和提高电价,也不允许大规模电力存储的盈利使用。为了将太阳能电冷却的太阳能比例提高到65%以上,必须使用电力存储。对于这两个概念,可以通过增加各自的存储尺寸来实现高于成本的最佳太阳能分数。高达95%的太阳能比例在经济上仍然是合理的。然而,超过98%的太阳能比例会导致成本急剧增加。
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引用次数: 1
Energy system design for deep decarbonization of a sunbelt city by using a hybrid storage approach 利用混合储能方法实现阳光带城市深度脱碳的能源系统设计
O. Walter, M. Huber, M. Kueppers, A. Tremel, Stefan Becker
With continuously falling cost of renewable power generation and ambitious decarbonization targets, renewable sources are about to rival fossil fuels for energy supply. For a high share of fluctuating renewable generation, large-scale energy storage is likely to be required. In addition to selling electricity, the reliable supply of heat and cold is a further interesting revenue pool, which makes hybrid storage technologies an interesting option. The main feature of hybrid energy storage – as defined here is to offer charging and especially discharging in different forms of energy by combining different charging, discharging and storage devices. They can address various demands (e.g. electricity and cold) simultaneously. Two hybrid storages, pumped thermal energy storage (PTES) and power-to-heat-to-x (x: heat and/or electricity) energy storage (PHXES), are investigated based on a technoeconomic analysis within this work. Both hybrid storage technologies are charged with electricity and can supply heat and electricity during discharging. They are implemented into a simplified energy system model of a prototype city in the earth’s sunbelt in the year 2030 to find a cost-optimal configuration. Different cases are evaluated: a power-to-power case (P2P), where only an electric demand must be addressed and a power-topower-and-cooling (P2P&C) case, where the electric demand from the P2P case is divided into a residual electric demand and a cooling demand. For both cases, a natural gas-based benchmark scenario and a decarbonized, renewable-based scenario including the hybrid energy storage technologies are calculated. Both, total expenditures and CO2 emissions are lower in the P2P&C scenarios compared to P2P scenarios. PHXES plays a major role in both cases. PTES is part of the costoptimal solution in the P2P&C decarb scenario, only if its specific cost are further decreased. Keywords—Hybrid energy storage, Energy system modeling, Decarbonization
随着可再生能源发电成本的不断下降和雄心勃勃的脱碳目标,可再生能源即将与化石燃料竞争能源供应。对于波动的可再生能源发电的高份额,可能需要大规模的能源储存。除了出售电力,可靠的冷热供应是另一个有趣的收入来源,这使得混合存储技术成为一个有趣的选择。混合储能的主要特点是通过组合不同的充电、放电和存储设备,提供不同形式的能量的充电,特别是放电。它们可以同时满足各种需求(如电和冷)。本研究基于技术经济分析,研究了两种混合储能技术,即泵送热能储能(PTES)和电-热-x (x:热/电)储能(PHXES)。这两种混合存储技术都是带电的,并且可以在放电时提供热量和电力。将它们应用到2030年地球阳光带的一个原型城市的简化能源系统模型中,以找到成本最优的配置。评估了不同的情况:电力对电力的情况(P2P),其中只需要解决电力需求,以及电力-电力-冷却(P2P&C)情况,其中P2P情况下的电力需求分为剩余电力需求和冷却需求。对于这两种情况,分别计算了基于天然气的基准情景和基于脱碳、可再生能源的情景,包括混合储能技术。与P2P模式相比,P2P模式下的总支出和二氧化碳排放量都较低。PHXES在这两种情况下都起着重要作用。在P2P&C脱碳方案中,PTES是成本最优解决方案的一部分,前提是其具体成本进一步降低。关键词:混合储能;能源系统建模;脱碳
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引用次数: 2
Decentralized city district hydrogen storage system based on the electrochemical reduction of carbon dioxide to formate 分散式城市区域储氢系统基于电化学还原二氧化碳生成甲酸
D. Lust, Paul Rößner, Marcus Brennenstuhl, E. Klemm, B. Plietker, U. Eicker
High fluctuations of renewable energy sources, such as wind and solar energy, require storage capacity to maintain supply reliability. For long term storage energy carriers to substitute fossil fuels must be found. The reduction of carbon dioxide to liquid substances such as formic acid or formate with electrons from renewable energy sources seem to be a promising approach. This paper tries to find answers for the following question: Under which conditions is it possible to use electrochemical carbon dioxide reduction to formate as urban seasonal energy storage?
风能和太阳能等可再生能源波动很大,需要储存能力来维持供应的可靠性。为了长期储存能源,必须找到替代化石燃料的载体。利用来自可再生能源的电子将二氧化碳还原为液态物质,如甲酸或甲酸盐,似乎是一种很有前途的方法。本文试图寻找以下问题的答案:在什么条件下可以利用电化学二氧化碳还原生成作为城市季节性储能?
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引用次数: 1
Optimization of Extended CHP Plants with Energy Storages — an Open-Source Approach 带储能的扩展热电联产电厂的优化——一种开源方法
Jakob Wolf, C. P. Leusden, S. Köhler, Jann Launer
An extended CHP system in a characteristic future market situation with a share of 50% electric energy provided by renewable energy sources is analysed using the open energy modelling framework oemof. Cost-optimal plant configurations are computed based upon assumptions for investments costs and energy prices. The results show that thermal storages are always integrated in the optimum plant layout with little sensitivity to all assumptions. A storage for electrical energy is only considered if sufficiently high price periods occur in the electric energy market. This result is highly sensitive to assumptions regarding storage cost and energy prices. The model is made available open-source for further use.
本文利用开放能源建模框架oemof分析了一个扩展的热电联产系统在未来市场的特点,其中50%的电力由可再生能源提供。成本最优工厂配置是基于投资成本和能源价格的假设计算的。结果表明,蓄热量总是被纳入到最优工厂布局中,对所有假设都不太敏感。只有当电力市场出现足够高的价格时,才会考虑电能的储存。这一结果对存储成本和能源价格的假设高度敏感。该模型是开源的,可以进一步使用。
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引用次数: 1
Numerical Assessement of Energy Storage Performances of Magnetite and Quartzite for CSP Storage Applications 磁铁矿和石英岩在光热储能应用中的储能性能数值评价
Y. F. Baba, A. A. Mers, H. Ajdad, Yaroslav Grosu, A. Faik
this paper pinpoints the thermal energy storage performances of two TESM, quartzite as classic thermal energy storage material commonly used in CSP and magnetite as emerged thermal energy storage filler material. The TES performances included charge, discharge and cycle efficiencies (utilization rate). In the first place, the developed numerical code for thermocline energy storage is presented and validated. Subsequently, and for both filler materials, the thermocline behavior and TES performances during charging and discharging process are examined. These performances are investigated for two potential scenarios: the first one considers the same storage tank size and the same discharge period. While, the second one, concerned sized storage tank for each combination HTF/TESM. Different heat transfer fluids are utilized involving natural oils, synthetic oils and molten salt. The obtained results showed that no significant difference of the zone thickness between the two materials. Moreover, we noted that quartzite presents slightly higher charge discharge and storage efficiencies. However, magnetite, for the same storage tank size and the same discharge time, magnetite is able to restore a great amount of energy. Furthermore, magnetite requires less storage tank volume. More important, we deduced that the TES performances are not impacted only by the TESM properties but they are also driven by the HTF nature and that molten salts are largely more efficient. Keywords—thermocline energy storage; TESM; HTF; magnetite; quartzite; thermocline behavior; charge efficiency; discharge efficiency; storage efficiency.
本文明确了两种TESM的储热性能,石英岩是CSP中常用的经典储热材料,磁铁矿是新兴的储热填充材料。TES的性能包括充电、放电和循环效率(利用率)。首先,提出并验证了开发的温跃层储能数值代码。随后,对两种填料在充放电过程中的温跃层行为和TES性能进行了研究。研究了两种可能的情况:第一种情况是考虑相同的储罐尺寸和相同的放电周期。第二种是HTF/TESM组合的储罐尺寸。不同的传热流体被使用,包括天然油、合成油和熔盐。结果表明,两种材料的区厚无显著差异。此外,我们注意到石英岩的充放电和储存效率略高。然而,对于相同的储罐尺寸和相同的放电时间,磁铁矿能够恢复大量的能量。此外,磁铁矿需要较少的储罐体积。更重要的是,我们推断出TES性能不仅受到TESM性能的影响,而且还受到HTF性质的驱动,并且熔盐在很大程度上效率更高。关键词:温跃层储能;TESM;公路信托基金;磁铁矿;石英岩;温跃层行为;充电效率;放电效率;存储效率。
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引用次数: 0
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Proceedings of the 13th International Renewable Energy Storage Conference 2019 (IRES 2019)
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