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Intrinsic magnetic properties of Sm/sub 2/Fe/sub 17-x/M/sub x/N/sub y//C/sub y/ [M=Al, Ga, or Si] Sm/sub 2/Fe/sub 17-x/M/sub x/N/sub y/ C/sub y/ [M=Al, Ga, or Si]的本征磁性能
Pub Date : 1999-05-18 DOI: 10.1109/INTMAG.1999.837860
M. Kubiś, D. Eckert, A. Handstein, B. Gebel, K. Muller, L. Schultz
The partial substitution of Fe by AI, Ga or Si enhances the thermal stability of the interstitial Sm,Fe,,-carbides making possible the application of high temperature processes for the preparation of highly dense magnets [l-4]. The intrinsic magnetic properties of the compounds investigated in the present work play an important role for the assessment of their potential for possible applications. SmzFe,,.,M, samples with M = Al (x = I, 2, 31, M = Ga (x = 0.5, 1, 2), and M = Si (x = 0.25,0.5, I ) were prepared by arc melting, induction melting and homogenization treatment. The samples were pulverized by crushing and milling to mean particle sizes mainly below 10 pm and nitrogenated at 500OC for 6hrs in 800mbar N, or carhurized at 500°C for 16hrs in 600 mbar CH,. Alternatively, a melt-carburized Sm,Fe15Ga2C,.B sample was prepared. The powders were aligned in a magnetic field of 2 T, cold compacted with a pressure of about 500MPa and resin-bonded. The Curie temperatures were obtained fmm M’(T)-Plots of thermomagnetic measurements. Demagnetization curves were measured in a vibrating sample magnetometer. The saturation polarization I, and the anisotropy field Ha were determined by a numerical fining procedure of the demagnetization curves in the region of the reversible rotation magnetization processes [5]. The obtained values of Curie temperatures, saturation polarizations and anisotropy fields for the Sm2Fe,,.,M,N,/C, samples are given in Fig. I . For comparison, the intrinsic magnetic properties of Sm,Fe,,N,/C, taken from ref. [6] were added to the graphs. Curie temperature and saturation polari2ation decrease monotonically for increasing content of substitution M. The nonmagnetic dilution by the substitution atoms seems to be the dominating effect. The nitrides exhibit always larger values than the corresponding carbides. The drop of the saturation polarization 1, is very strong. For example. J, of Sm2Fe,,GazC, is only 0.81 T and with that much lower than the reported value of 1.05 T for melt-carburized Sm2Fe,,Ga2C, [2]. On the other hand, the I,-value of 1.0 T obtained for the melt-carburized Sm,Fe,,Ga2C18 sample corresponds very well with ref. [2]. It can he concluded, that the gas-carburization has an unfavourable effect on the saturation polarization compared to melt-carburization. The anisotropy fields increase significantly for small M contents x 4 1 (e.g. Sm,Fe165Ga, 5CyR”y with Ha = 25.0126.6 T compared to Ha = 16122 T for Sm,Fe,,CylN,). For M contents x 2 1 the anisotropy fields start to decrease. The decrease of H, for the carbides is weaker than that for the nitrides, leading finally to comparahle or even higher Ha values for ‘the carbides (e.g. Sm,Fe,,AI,C/”, with Ha= 17.3115.2 T). The gas-carburized SmzFe,,Ga,C, sample shows a much higher H,value (17.8 T) than the melt-carburized Sm2FelrGa2CiR y n p l e (Ha= 10.1 T, which corresponds well with the reported Ha-value for melt-carburized Sm2Fe,,GazC2 of 13 T [2]). In this case, a favoura
AI、Ga或Si对Fe的部分取代增强了间隙Sm、Fe、-碳化物的热稳定性,使得高温工艺在高密度磁体制备中的应用成为可能[l-4]。本工作中所研究的化合物的本征磁性能对评估其潜在的应用潜力起着重要的作用。SmzFe,,。M = Al (x = 1, 2, 31), M = Ga (x = 0.5, 1, 2), M = Si (x = 0.25,0.5, 1),通过电弧熔化、感应熔化和均质化处理制备样品。通过粉碎和碾磨使样品的平均粒径主要小于10 pm,并在800mbar N下在500℃下氮化6小时,或在600 mbar CH下在500℃下碳化16小时。或者,熔体渗碳Sm,Fe15Ga2C,。制备B样品。粉末在2 T的磁场中排列,在约500MPa的压力下冷压,树脂粘接。居里温度为fmm M′(T)-热磁测量图。用振动样品磁强计测量了消磁曲线。饱和极化I和各向异性场Ha是通过对可逆旋转磁化过程区域的退磁曲线进行数值细化来确定的[5]。得到了Sm2Fe的居里温度、饱和极化场和各向异性场的值。,M,N,/C,试样如图1所示。为了比较,我们将参考文献[6]中的Sm,Fe, N,/C的本征磁性加入图中。随着取代m含量的增加,居里温度和饱和极化单调降低,取代原子的非磁性稀释似乎是主要作用。氮化物总是比相应的碳化物表现出更大的值。饱和极化的下降非常强。为例。Sm2Fe,,GazC的J值仅为0.81 T,远低于熔融渗碳Sm2Fe,,Ga2C的1.05 T,[2]。另一方面,熔体渗碳Sm,Fe,,Ga2C18样品的I,-值为1.0 T,与文献[2]非常吻合。与熔融渗碳相比,气体渗碳对饱和极化的影响是不利的。当M含量较少时,各向异性场显著增加(例如Sm,Fe165Ga, 5CyR ' y, Ha = 25.0126.6 T,而Sm,Fe, CylN, Ha = 16122 T)。当M含量为x21时,各向异性场开始减小。碳化物的H值下降比氮化物的要弱,最终导致碳化物的Ha值相当甚至更高(例如Sm,Fe,,AI,C/”,Ha= 17.3115.2 T),气体渗碳的SmzFe,,Ga,C样品的H值(17.8 T)远高于熔融渗碳的Sm2FelrGa2CiR y, p / e样品(Ha= 10.1 T),这与报道的熔融渗碳Sm2Fe,,GazC2的Ha值(13 T)相吻合[2])。在这种情况下,气体渗碳比熔融渗碳对各向异性场的影响更大。对于所研究化合物(x t O)的本征磁性,添加少量ga的样品显示出永磁体应用的最大潜力。
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引用次数: 0
The effect of concentration and valency of iron sulphate media on the bio-magnetic iron sulphides produced through continuous culture 硫酸铁培养基的浓度和价对连续培养产生的生物磁性硫化铁的影响
Pub Date : 1999-05-18 DOI: 10.1109/INTMAG.1999.837700
A. Bahaj
Biologically produced iron sulphide (FeS) is of great interest in the area of bioremedation as it posses adsorbing properties surpassing those produced by chemical means. This paper reports on the effect of varying the relative concentrations of Fe(II) and Fe(III) sulphates in the culture medium of a sulphate reducing bacteria chemostat on the magnetic properties of the iron sulphide produced. An optimum Fe(II):Fe(III) ratio is determined to maximise the magnetic susceptibility of the microbial sulphide produced. This will result in a reduction of the magnetic field intensity used in magnetically separating heavy metals in hioremediation applications. The paper details the economics of the separation and proposes a magnetically and cost optimised process for such applications.
生物产生的硫化铁(FeS)由于其吸附性能优于化学方法产生的硫化铁,在生物修复领域具有很大的兴趣。本文报道了硫酸盐还原菌恒化菌培养基中Fe(II)和Fe(III)硫酸盐相对浓度的变化对所产硫化铁磁性能的影响。确定了铁(II):铁(III)的最佳比例,以最大限度地提高微生物硫化物的磁化率。这将导致磁场强度的降低,用于磁分离重金属在高修复应用。本文详细介绍了分离的经济性,并为此类应用提出了一种磁力和成本优化的工艺。
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引用次数: 0
Magnetoelastic waves in ferri- and antiferromagnetic crystals near spin reorientaional phase transission 铁磁和反铁磁晶体在自旋重定向相传输附近的磁弹性波
Pub Date : 1999-05-18 DOI: 10.1109/INTMAG.1999.837950
I. Dikshtein, Sung-Ho S. Salk
Anomalous decrease of the sound velocity and the important role that nonlinear processes play near the spin-reorientational phase transitions (OPT) in the limited ferrimagnetic (FM) and antifemmagnetic (AF) crystals make such o~ystals promising materials for use in electronic devices [I]. The e5ciency of such devices can be raised considerably by using surface waves, since the energy of such waves is concenmted within a thin surface layer. The study of the spectra of magnetoelasic (ME) waves in limited specimens of FM and AF makes it possible to determine the type of sofl mode involved in OPT. It is usually assumed that the h e energy depends only fiom the symmetric part of the distortion tensor, u,,=aU/& i.e. on the strain tensor ek=(aU/3xk+aU&,)I2, where U is a displacement vector. However, within this approach the h e energy is invariant with respect to translation of the volume elements of the crystal, but it is not invariant with respeci to a local rotation of such elements. When sound propagates in magnetic material, the volume elements of the medium hun locally together with the magnetic anisotropy axes, which increases the cnergy of the crystal. Examining this problem in a rigorous setting requires building a consistent translationand rotation-invariant theory that should also allow for the dependence of energy on the antisymetric pan of the distortion tensor r~y=(aU&~-aUJ&,)I2 related to the rotation of small volume elements with nspect to each other upon an inhomogeneous deformation of the crystal [2]. In this case the presence of a magnetic field endows thin plates with a mmsvetse rigidity and leads to transformation of the dispersion law of a flexural wave into a linear (sonic) law 131. Here we use a rigorous rotationand translation-invariant theory to study the Lamb and Raylei& waves propagation near an OPT induced by temperature in orthorhombic AF and FM bounded by planes-l, and placed in a magnetic field HIlx. For example, the dispersion laws for the Rayleigh, flexural and transverse Lamb waves with NIX in a plate of an easy-plane AF with weak ferromagnetism and low magnetic anisotropy in a basal plane xy (H&
在有限铁磁(FM)和反铁磁(AF)晶体中,声速的异常降低和非线性过程在自旋取向相变(OPT)附近发挥的重要作用使这类o~晶体成为电子器件中有前途的材料[1]。由于表面波的能量集中在一个薄的表面层内,因此使用表面波可以大大提高这种装置的效率。在有限的FM和AF试样中对磁弹性(ME)波的谱进行研究,可以确定OPT中涉及的sofl模态类型。通常假设能量仅取决于畸变张量u,,=aU/&的对称部分,即取决于应变张量ek=(aU/3xk+aU&,)I2,其中u为位移矢量。然而,在这种方法中,能量对于晶体的体积元素的平移是不变的,但是对于这些元素的局部旋转却不是不变的。当声音在磁性材料中传播时,介质的体积元与磁各向异性轴局部结合,使晶体的能量增加。在严格的环境中检查这个问题需要建立一个一致的平移和旋转不变理论,该理论还应该允许能量依赖于畸变张量r~y=(aU&~-aUJ&,)I2的反对称平移,这与小体积元素在晶体[2]的非均匀变形上的相互旋转有关。在这种情况下,磁场的存在使薄板具有毫微米级的刚性,并导致弯曲波的色散定律转变为线性(声波)定律131。本文采用严格的旋转和平移不变理论,研究了以平面为界的正交AF和FM中温度诱导的OPT附近的Lamb和Raylei&波传播,并将其放置在磁场HIlx中。例如,具有弱铁磁性和低磁各向异性的易平面AF板在基面xy (H&
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引用次数: 0
Multiresolution algorithm for integral and boundary element equations in magnetic field computations 磁场计算中积分和边界元方程的多分辨率算法
Pub Date : 1999-05-18 DOI: 10.1109/INTMAG.1999.837673
J.C. Yang, K. Shao, H. Yu, J. Lavers
Wavelet algorithm far integral equations was first studied in [I] . In magwetic field computations, previously plblished p a p utilized the standard scheme to gel a dense ma& and then applied the fast wavelet vansfonii to appvimate it to a sparse one. Therefore, one have to allccate extra metnon for the transformed matrix. Mnmver, the t r d d mabix did not appear to have beuer condition number lhan the original one. In this paper, we use wavelet functions as bath basis functions and weight funnions. It is a reasonable trade-olf between tbe entire domain and subsstiM basis functions. The whole dornais may be divided iiib several subsections, while in each subsection the higher resolution basis is incorporated, whsch preserve the merits of entire domain basis functions. A sparse matrix thus is derived
对积分方程的小波算法进行了研究[1]。在磁场计算中,前人采用标准格式对密集磁场进行压缩,然后采用快速小波变换对稀疏磁场进行压缩。因此,我们必须为变换后的矩阵分配额外的量。然而,第一个模型的条件号似乎并没有比原始模型的条件号更低。本文采用小波函数作为基函数和权函数。它是整个定义域和子基函数之间的一种合理的折衷。将整个域基函数划分为若干小节,在每个小节中加入高分辨率基函数,从而保留了整个域基函数的优点。由此导出了一个稀疏矩阵
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引用次数: 0
The calculation of magnetostatic wave devices amplitude- and phase-frequency characteristics by partial wave beams method 用部分波束法计算静磁波器件的幅频和相频特性
Pub Date : 1999-05-18 DOI: 10.1109/INTMAG.1999.837215
V. Shcheglov, V. Zubkov
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引用次数: 0
Modeling and experimental investigation of thermal interaction in the head-disk interface of mr head based recording systems 磁流变磁头记录系统磁头-磁盘界面热相互作用的建模与实验研究
Pub Date : 1999-05-18 DOI: 10.1109/INTMAG.1999.837107
Qingfang Leng, Bo Liu, Gongye Zhou, Wei Zhang, A. Mydeen, T. Yamamoto
I Intmduetion The read-back signal thermally induced from the head-disk interface is one of the most serious concern in the engineering integration of the MR head based rewrding systems. especially when technology moves to sub-micro-inch beaddisk spacing and 40 Gb/in2 mal densities [l][2]. This paper presents the results of thermal signal modehng, beating and cooling process simulation, and experimental analysis. An analytical model is proposed which takes the headdisk spacing into account and can be used for quantitative analysis of the head-disk systems. Results of the transient process study show that a submicron lateral resolution c m be achieved for characterizing the disk surface. Experimental inveslipations, supported by the analytical model, indicate thhd the air thermal conductivity inside the laser bump hole is smaller than that of outside the bump hole. Satisfyiog agreement between estimated bump shape and the bump shape measured by AFM is achieved when proper thermal conductiviv ratio is used. Experimental results also suggest that the MR thermal signal can be used for in-situ monitoring of the headdisk spacing variation, with the relationship provided by the proposed analytical model.
磁头-磁盘接口热诱导的回读信号是基于磁磁共振磁头的奖励系统工程集成中最严重的问题之一。特别是当技术发展到亚微英寸的硬盘间距和40 Gb/in2的密度时[1][2]。本文给出了热信号建模、加热和冷却过程仿真以及实验分析的结果。提出了一种考虑磁碟间距的分析模型,可用于磁碟系统的定量分析。瞬态过程研究的结果表明,对圆盘表面的表征达到了亚微米的横向分辨率。在分析模型的支持下,实验研究表明,激光碰撞孔内的空气导热系数小于碰撞孔外的空气导热系数。当采用适当的导热系数时,估计的凸点形状与原子力显微镜测量的凸点形状吻合较好。实验结果还表明,磁流变热信号可以用于现场监测头盘间距变化,并与所提出的分析模型提供的关系相吻合。
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引用次数: 1
The permeability of ferrite plated films 铁氧体镀膜的磁导率
Pub Date : 1999-05-18 DOI: 10.1109/INTMAG.1999.837745
P. J. van der Zaag, P. Lubitz, Y. Kitamoto, M. Abe
Recently, there has been a growing interest in the fabrication of ferrite films, especially by pulsed laser deposition (PLD), e.g [I], but also by sputtering, see for instance [Z]. Owing to their insulating character ferrite films could be applied for integrated inductors 111 or to improve the efficiency of thin film recording heads 131. Most of the studies of the growth of ferrite films, thus far, only report the saturation magnetization value, Ms, or the coercivity, He. However, in mast applicatons the permeability of the ferrite films is the key parameter, which unfortunately is rarely reported [2]. A disadvantage of the films grown by PLD or sputtering is that they require a high deposition temperature of typically around 650 'C, which is too high for most application in devices which involve other thin layers. Ferrite films grown by ferrite plating offer a much more favourable depostion temperature of only 80 'C [4]. We will discuss the characterization of the magnetic properties, notably permeability's of NiZn-ferrite plated films. The approx. 1 pm thick NiZn-ferrite films studied had a Ms % 520 kA/m which is comparable to bulk values for NiZn-ferrite. As can be seen from Fig. 1, the NiZn-ferrite films grown by ferrite plating on a glass substrate have a p = 28 f 3 (open balls). This value can be increased to p= 60 *5 hy an anneal step at T 2 325 OC, which in addition increases
最近,人们对铁氧体薄膜的制造越来越感兴趣,特别是通过脉冲激光沉积(PLD),例如[I],但也可以通过溅射,例如[Z]。由于其绝缘特性,铁氧体薄膜可用于集成电感111或提高薄膜记录磁头131的效率。到目前为止,大多数关于铁氧体薄膜生长的研究只报道了饱和磁化值Ms或矫顽力He。然而,在大多数应用中,铁氧体薄膜的磁导率是关键参数,不幸的是很少有报道[2]。PLD或溅射生长的薄膜的缺点是它们需要很高的沉积温度,通常在650℃左右,这对于大多数涉及其他薄层的设备的应用来说太高了。通过铁氧体电镀生长的铁氧体薄膜提供了更有利的沉积温度,仅为80℃[4]。我们将讨论磁性能的表征,特别是氮化氮铁氧体镀膜的磁导率。约。所研究的1 pm厚的nizn -铁氧体薄膜的Ms % 520 kA/m与nizn -铁氧体的体积值相当。从图1可以看出,在玻璃基板上镀铁氧体生长的nizn -铁氧体薄膜具有p = 28 f3(开球)。在温度为2525℃时,该值可增加到每退火一步p= 60 *5 h,并进一步增加
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引用次数: 0
45/spl deg/ torque method for containing anisotropy constant 45/spl度/扭矩法含各向异性常数
Pub Date : 1999-05-18 DOI: 10.1109/INTMAG.1999.837498
Y. Uesaka, Y. Nakatani, N. Hayashi, H. Fukushima, N. Inaba
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引用次数: 0
Design opmization of a moving magnet disk drive actuator with minimized detrimental electromagnetic forces 以最小的有害电磁力为目标的移动磁碟驱动器优化设计
Pub Date : 1999-05-18 DOI: 10.1109/INTMAG.1999.837615
S.X. Chen, Y. Mah, Q. Li, H. Lin
Introduction Advances in map ti^ recording head and media over the last decade hate pushed recording rlen,tiy up io a poml uhcre funher improvement i s Itkcl) to hc impeded h) mechanical constrainti l'mently. the WYO bandwidth of most cnnvcnlional head positioning ,)stem i s lirmtcd by thr In-plane rcronance modes of the actuator mechanism For a typrcal 3 5-inch drive actuator, the lowest t n p l ~ ~ monance. referred a.. the QR mode (quai-rigid body mude). (X'CUIS between 3 10 5 MIL. This IS due to the ela5ticity of the pirot h n g and Ibe mass of the moving pans of the actuator Moi l IlDD today UVP a moiinp voicciod inutur IO drive he actuatnr arm carrying the readlwnte heads. Howcvcr. the driving lurcc produced b) the conventional moving voice coil motor has a large tn.planc component In the seek direction. This creates rubstanual reaction furcc at thr pivot k m n g which cm pnlcnually cxcitcs the QR mode of the actuator Ihe Q K made, i f exited. causes undesirable vibration of the arm in the data track acehng diwcuun. Thir csuccs difficulty in head positioning Juring mck following and l irmta the bandwidth of the servo system T h i r paper prrscnls a novel moving -et dctyillor which substantially solres the abow described d i s h a n t a g , and provides w improve actuator mechamism for high density recording rn hard disk dnves
在过去的十年里,地图记录头和媒体的进步推动了记录技术的发展,使其达到了一个新的高度,在此基础上,进一步的改进使其在很大程度上克服了机械限制。对于一个典型的3 - 5英寸驱动执行机构,其最低的WYO带宽为1 / 2 ~ 1 / 2。被称为一个. .QR模式(准刚体模式)。(X'CUIS在3 - 10 - 5 MIL之间,这是由于轴的弹性和执行器的运动盘的质量,今天的UVP是一个运动的周期,用于驱动执行器手臂携带readlwnheads。Howcvcr。b)传统的动音圈电机在寻向上有较大的平面分量。这在支点处产生了非稳态反应,该反应在支点处产生,该支点在支点处产生,该支点每月激发执行器的QR模式。在数据轨道上产生不期望的振动。他们成功地解决了磁头定位困难、轨迹跟踪和伺服系统带宽限制等问题,提出了一种新型的移动伺服电机,该电机基本上解决了上述问题,并为高密度记录硬盘驱动器提供了一种改进的执行机构
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引用次数: 0
A remote query glucose dosimeter based -on magnetostatic coupling 一种基于静磁耦合的远程查询葡萄糖剂量计
Pub Date : 1999-05-18 DOI: 10.1109/INTMAG.1999.837359
Y. Liu, C. Tong, P. Stoyanov, K. Loiselle, C. Grimes
Magnetically soft tbin film elements, see Figure 1, are bonded to a polymer layer that is made to swell in response to glucose concentration. The dosimeter design consists of four triangles, initidly spaced 50 )un apart, arranged tn form a 12 mm x 12 mm square with the triangle tips centered at a common origin. As the polymer size changes so does the distance between the magnetic elements and hence tbe magnetic domain structure per magnetostatic coupling. The sensor is placed within a lime varying magnetic field of an intensity sufficient to switch the magnetization vector of the collective magnetic elements comprising the dosimeter. The magnetic flux changes generated by the periodic magnetization reversals can be detected as a series of voltage spikes in suitably lofated detecting coils. Concentration levels of the chemical anal@ can be related to the ampliok of the d e w voltage spike that the time varying flux generates [l]. Figure 2 shows the voltage spike amplitude as afunction of element spacing for tbe 'split square' design shown in Fig. I ; window pane smctures have also been used with success. The sensing principle is general and can be adapted to sense a variety of analytes by appropriate polymer design. Since the sensor is monitored through changes in magneoc flux no physical connections are needed to obtain sensor information.
磁性软薄膜元件(见图1)与聚合物层结合,聚合物层会随着葡萄糖浓度的变化而膨胀。剂量计的设计由四个三角形组成,最初间隔50毫米,排列成一个12毫米x 12毫米的正方形,三角形尖端以一个共同原点为中心。随着聚合物尺寸的变化,磁性元件之间的距离也随之变化,因此静磁耦合的磁畴结构也随之变化。所述传感器放置在强度足以切换构成剂量计的集体磁性元件的磁化矢量的可变磁场内。周期性磁化反转产生的磁通量变化可以在适当位置的检测线圈中以一系列电压尖峰的形式检测到。化学分析液的浓度水平可以与时变磁通产生的电压尖峰的振幅有关[1]。图2显示了图1所示的“分裂方形”设计的电压尖峰幅度与元件间距的关系;窗玻璃结构的应用也很成功。传感原理是通用的,并且可以通过适当的聚合物设计来适应传感各种分析物。由于传感器是通过磁通的变化来监测的,因此不需要物理连接来获取传感器信息。
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引用次数: 0
期刊
IEEE International Magnetics Conference
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