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Use of Soil Amendments to Reduce Nitrogen, Phosphorus and Heavy Metal Availability 利用土壤改良剂降低氮、磷和重金属的有效性
Pub Date : 1998-03-01 DOI: 10.1080/10588339891334221
I. Phillips
The primary objectives of this study were to determine (1) the exchange characteristics of various soil amendments using a range of salt solutions, (2) the effect of selected soil amendments on heavy metal (Cu2+, Pb2+, and Zn2+) availability, and (3) the effect of selected soil amendments on NH4 + and P availability. The CEC of zeolite and red mud obtained using solutions of 0.1 M BaCl2 and 0.1 M BaCl2/NH4Cl were significantly lower than values obtained using 1 M KCl and 1 M NH4Cl. The higher CEC obtained with monovalent cations indicated that larger divalent cations could not enter the mineralogical framework of zeolite and red mud, and, consequently, a number of exchange sites were only accessible to the smaller monovalent cations. These findings suggest that 1 M KCl and 1 M NH4NO3 should be used as the extracting solutions to obtain the best estimation of CEC and ECEC of red mud and zeolite. The ability of red mud, zeolite, and calcium phosphate (Ca-P), mixed at rates of 0%, 5%, 10%, and 20% (w/w), to ...
本研究的主要目的是确定(1)使用一系列盐溶液的各种土壤改良剂的交换特性,(2)选定的土壤改良剂对重金属(Cu2+, Pb2+和Zn2+)有效性的影响,以及(3)选定的土壤改良剂对NH4 +和P有效性的影响。使用0.1 M BaCl2和0.1 M BaCl2/NH4Cl溶液得到的沸石和赤泥的CEC显著低于使用1 M KCl和1 M NH4Cl得到的值。一价阳离子获得的较高CEC表明,较大的二价阳离子不能进入沸石和赤泥的矿物框架,因此,一些交换位点只有较小的一价阳离子才能进入。以上结果表明,选用1 M KCl和1 M NH4NO3作为萃取溶液可获得赤泥和沸石的CEC和ECEC的最佳估计。赤泥、沸石和磷酸钙(Ca-P)以0%、5%、10%和20% (w/w)的比例混合,对…
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引用次数: 61
Characterization of Heavy Metals in Soil by High Gradient Magnetic Separation 高梯度磁选法测定土壤中重金属
Pub Date : 1998-03-01 DOI: 10.1080/10588339891334212
R. Rikers, P. Rem, W. Dalmijn, A. Honders
In recent years forecasting soil cleaning efficiencies of polluted soil, especially those contaminated with heavy metals, has become an important issue. Failure of the methods to predict the right efficiency has resulted in financial losses and penalties. This article describes an addition to the traditional characterization methods for soils contaminated by heavy metals, improving the quality of the basic decisions to be made. The method is based on magnetic separation using a Frantz Isodynamic Separator (FIS) for this study. The FIS isolates soil particles containing heavy metals so that these particles, which are relevant for soil cleaning, can be studied in more detail. Four contaminated soils were tested, for example, soils that were a problem for the soil-cleaning industry. The experiments indicate that each soil has its own magnetic properties that should be regarded as a fingerprint. Density measurements of two soils show that densities approach the quartz density separated at moderate and high ma...
近年来,污染土壤特别是重金属污染土壤的土壤净化效率预测已成为一个重要问题。这些方法未能正确预测效率,导致了经济损失和处罚。本文介绍了一种对重金属污染土壤的传统表征方法的补充,提高了所要做出的质量基本决策。该方法是基于磁分离,使用弗朗茨等动力分离器(FIS)进行本研究。FIS分离出含有重金属的土壤颗粒,以便对这些与土壤清洁有关的颗粒进行更详细的研究。例如,对四种污染土壤进行了测试,这些土壤对土壤清洁行业来说是一个问题。实验表明,每种土壤都有自己的磁性,可以看作是一种指纹。两种土壤的密度测量结果表明,密度接近于中、高压下分离的石英密度。
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引用次数: 9
Field Scale Variations in Soil Properties for Spatially Variable Control: A Review 空间变量控制土壤性质的田间尺度变化研究进展
Pub Date : 1998-03-01 DOI: 10.1080/10588339891334258
F. Goderya
This article reviews the widely scattered information on spatial variability of field-scale properties. It mainly addresses the variations in properties that influence nitrate accumulation and movement resulting from the agricultural activities in the root zone. The drive for this research comes from the perception and evidence of widespread contamination arising from production agriculture. The information is useful in the spatial management of soil for prevention of non-point source groundwater contamination from production practices. The review includes most of the static soil properties, one water transport property, some soil fertility variables, and crop yield. It examines various investigations and parameters identifying the magnitude of variability, and spatial correlation values for a given property are provided in a tabular form. Various sources of spatial variability, as well as methods of evaluating soil variability, are also discussed. For static soil properties, the range of coefficient of v...
本文综述了广泛分散的场尺度物性空间变异性信息。它主要研究影响根区农业活动导致的硝酸盐积累和运动的特性变化。这项研究的动力来自于对生产农业产生的广泛污染的认识和证据。这些资料有助于土壤空间管理,防止生产实践造成的非点源地下水污染。综述了大部分土壤静态特性、一个水分运输特性、一些土壤肥力变量和作物产量。它检查了各种调查和参数,确定了可变性的大小,并以表格形式提供了给定属性的空间相关值。本文还讨论了土壤空间变异性的各种来源以及评价土壤变异性的方法。对于静态土的性质,系数v…
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引用次数: 32
Effect of Flush Water Temperature and Type on Commercial Shoreline Cleaning Agent Efficiency 冲水温度和类型对商用海岸清洗剂效率的影响
Pub Date : 1998-03-01 DOI: 10.1080/10588339891334230
M. Tumeo, Amanda Cote
A research team at the University of Alaska Fairbanks Water and Environment Research Center conducted a series of column experiments to investigate the effect of flush water temperature and type (salt vs. fresh) on shoreline cleaning agent (SCA) efficiency. Results confirmed that the use of SCAs can enhance oil removal from porous media but showed that at the colder temperatures common in Alaska the efficiency of shoreline cleaners is significantly reduced. Using salt water also tends to decrease the efficiency of flushing. The data also show that the majority of the removal attributable to the shoreline cleaning agent occurs within the first one to three pore volume flushes. After that time, the effectiveness of the flushing procedure drops off to that of pure water for all three SCAs tested.
阿拉斯加费尔班克斯大学水与环境研究中心的一个研究小组进行了一系列的柱式实验,以调查冲洗水的温度和类型(盐与新鲜)对海岸线清洁剂(SCA)效率的影响。结果证实,SCAs的使用可以提高多孔介质中的除油效果,但在阿拉斯加常见的较冷温度下,海岸线清洁剂的效率显著降低。使用盐水也会降低冲洗效率。数据还表明,海岸线清洗剂的大部分去除作用发生在前一到三次孔隙体积冲洗中。在此之后,对于所有三种测试的sca,冲洗程序的有效性下降到纯水的有效性。
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引用次数: 7
Simulations of intrinsic biodegradation using a non‐linear modification of first‐order reaction kinetics 利用一阶反应动力学的非线性修正模拟内在生物降解
Pub Date : 1997-09-01 DOI: 10.1080/15320389709383582
J. Odermatt
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引用次数: 7
Feasibility study of surfactant use for remediation of organic and metal contaminated soils 表面活性剂用于有机和金属污染土壤修复的可行性研究
Pub Date : 1997-09-01 DOI: 10.1080/15320389709383585
Chih Huang, J. V. Benschoten, Tara C. Healy, M. E. Ryan
In this Investigation, four surfactants were examined in a laboratory study that included testing for naphthalene solubilization capacity, suriactant sorption to soil, and treat‐ability for a sandy soil artificially contaminated with lead and naphthalene. Of interest was an examination of surfactant performance characteristics under the acidic conditions that may be required for metal removal. Although pH is recognized as a critical factor in metal sorption to soils, it did not significantly impact the solubilization ability of any of the surfactants for naphthalene. The sorption of nonionic surfactants to the soil was not affected by pH, while sorption of anionic surfactants increased as the pH decreased. Although nonionic surfactants showed better solubility enhancement for naphthalene than anionic surfactants, the latter may enhance lead desorption from the soil, presumably due to interactions between the anionic head groups of the surfactant and the Pb2+ ion. A mass balance model was used to interpret...
在本研究中,对四种表面活性剂进行了实验室研究,包括测试萘的增溶能力、表面活性剂对土壤的吸附以及对被铅和萘人工污染的沙质土壤的处理能力。我们感兴趣的是在去除金属所需的酸性条件下对表面活性剂性能特征的研究。虽然pH被认为是金属吸附到土壤中的关键因素,但它对任何表面活性剂对萘的增溶能力都没有显著影响。非离子表面活性剂对土壤的吸附不受pH的影响,而阴离子表面活性剂的吸附随pH的降低而增加。虽然非离子表面活性剂对萘的溶解性比阴离子表面活性剂表现出更好的增强作用,但阴离子表面活性剂可能会促进土壤中铅的脱吸,这可能是由于表面活性剂的阴离子头基与Pb2+离子之间的相互作用。一个质量平衡模型被用来解释……
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引用次数: 18
Comparison of Two Soil Gas Methods Used during a Field Investigation 两种土壤气测法在野外调查中的比较
Pub Date : 1997-07-01 DOI: 10.1080/15320389709383571
T. L. Liikala, J. C. Evans
Soil gas surveys were employed to help determine the nature and extent of contamination resulting from the past operation of source area ST58, the Old Quartermaster Service Station, at Eielson Air Force Base, Alaska. Two Intrusive methods were used for comparison, active conventional gas extraction and the passive Petrex method. Results were comparable, with gasoline identified as the main subsurface contaminant In both surveys. Close spatial correlation was also achieved among screening instruments and laboratory analyses. Contaminant concentrations corresponded very well with unsealed blueprints showing the locations of the above‐ground storage tanks and associated piping, subsequent test pit soil samples, and excavation results. The contamination probably occurred as a result of surface spills and leaks from discontinuities and/or breaks in the underground piping. A finer grid was employed in the Petrex method survey and produced better‐resolved contours. The use of conventional gas extraction provided...
采用土壤气体调查来帮助确定过去在阿拉斯加艾尔森空军基地的ST58区(旧军需服务站)操作造成的污染的性质和程度。采用两种侵入法进行对比,即主动常规抽气法和被动Petrex法。结果具有可比性,在两次调查中,汽油被确定为主要的地下污染物。筛选仪器和实验室分析之间也实现了密切的空间相关性。污染物浓度与未密封的蓝图非常吻合,蓝图上显示了地上储罐和相关管道的位置、随后的测试坑土壤样本和挖掘结果。污染可能是由于地下管道的不连续性和/或断裂造成的表面泄漏和泄漏造成的。在Petrex方法测量中采用了更精细的网格,并产生了更高分辨率的等高线。使用传统的天然气开采提供了…
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引用次数: 1
Removal of chromium, nickel and cadmium from clays by in‐situ electrokinetic remediation 原位电动力修复法去除粘土中的铬、镍和镉
Pub Date : 1997-05-17 DOI: 10.1080/15320389709383574
K. Reddy, Usha S. Parupudi
This article presents the results of a research study that investigated the use of the in situ electrokinetic process for removing chromium, nickel, and cadmium from contaminated clays. For this study, electrokinetic experiments were conducted on two types of clays: kaolin, a commercial‐grade soil consisting mainly of kaolinite clay mineral, and glacial till, a field derived clay that possesses a complex mineralogical composition. Two sets of experiments were performed. The first set of experiments consisted of clays contaminated with both chromium in its hexavalent form, Cr(VI), and nickel, Ni(II). Each of these contaminants was in a concentration of 500 mg/kg. The second set of experiments consisted of clays contaminated with Cr(VI), Ni(II), and cadmium, Cd(II), In concentrations of 500 mg/kg, 500 mg/kg, and 250 mg/kg, respectively. These specific contaminants and contaminant concentration levels were selected to simulate typical electroplating waste conditions. In each test, the contaminated clay was s...
本文介绍了一项研究的结果,该研究调查了使用原位电动过程从受污染的粘土中去除铬、镍和镉。在这项研究中,对两种类型的粘土进行了电动实验:高岭土,一种主要由高岭石粘土矿物组成的商业级土壤,以及冰川土,一种具有复杂矿物组成的田间粘土。进行了两组实验。第一组实验包括被六价形式的铬(Cr(VI))和镍(Ni(II))污染的粘土。每一种污染物的浓度都是500毫克/公斤。第二组试验采用浓度分别为500 mg/kg、500 mg/kg和250 mg/kg的Cr(VI)、Ni(II)和镉、Cd(II)污染粘土。选择这些特定的污染物和污染物浓度水平来模拟典型的电镀废物条件。在每次试验中,被污染的粘土是…
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引用次数: 96
Dose assessment considerations for remedial action on plutonium‐contaminated soil 对钚污染土壤补救行动的剂量评估考虑
Pub Date : 1997-05-01 DOI: 10.1080/15320389709383564
B. Church
This article describes some of the dose assessment issues that should be considered when planning and executing a soil remedial activity. What is the proper dose scenario/ model? What are the appropriate cleanup criteria? How is the data gathered and analyzed (both before and after) cleanup? By describing the features and aspects of how these issues and others were considered or not considered in planning for the remedial action underway at Maralinga, Australia (former site of the Nuclear Weapons Testing Program of the United Kingdom) when compared with historical international experience of this type, the author attempts to illustrate that it is almost nonsensical to preselect a single soil value for Pu in soil (for national or international use), particulariy when expressed as a soil concentration (pCi/g or bq/g). This is especially so when the problem is Pu on the surface or near the surface of the soil. This is the situation common at nuclear test sites where “one point safe tests” were conducted. At ...
本文描述了在规划和执行土壤补救活动时应考虑的一些剂量评估问题。适当的剂量方案/模式是什么?什么是合适的清理标准?如何收集和分析数据(在清理之前和之后)?通过描述在规划澳大利亚马拉林加(联合王国核武器试验方案的前场址)正在进行的补救行动时如何考虑或不考虑这些问题和其他问题的特点和方面,并将其与此类历史国际经验进行比较,作者试图说明,为土壤中的钚预先选择一个土壤值(供国家或国际使用)几乎是荒谬的。特别是当以土壤浓度(pCi/g或bq/g)表示时。当问题是在土壤表面或接近土壤表面时尤其如此。这是在进行"一点安全试验"的核试验场常见的情况。在…
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引用次数: 3
Bioremediation: A perspective 生物修复:一个视角
Pub Date : 1997-05-01 DOI: 10.1080/15320389709383560
D. Errampalli, J. Trevors, Hung Lee, K. Leung, M. Cassidy, Kyle L. Knoke, T. Marwood, K. W. Shaw, M. Blears, E. Chung
In this opinion paper, we offer our perspective on our bioremediation research along with the methods to assess its effectiveness as a safe and beneficial technology to remediate selected soil sites. The isolation and characterization of bacterial isolates from chemically contaminated soils, their survival and catabolic activity in contaminated soil, toxicity testing in chemically contaminated soils, molecular‐based methods of detection such as the polymerase chain reaction (PCR) and DNA probing are discussed. By using numerous conventional microbiological, chemical techniques, and molecular based methods, bioremediation can be studied in a comprehensive manner and the technology transferred to the commercial sector.
在这篇观点论文中,我们提供了我们对生物修复研究的看法,以及评估其作为一种安全有益的技术修复选定土壤站点的有效性的方法。本文讨论了从化学污染土壤中分离的细菌的分离和特性,它们在污染土壤中的生存和分解代谢活性,化学污染土壤的毒性测试,基于分子的检测方法,如聚合酶链反应(PCR)和DNA探针。通过使用许多传统的微生物学、化学技术和基于分子的方法,可以全面研究生物修复,并将技术转移到商业部门。
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引用次数: 20
期刊
Journal of Soil Contamination
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