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Evaluation of Stainless Steels Welds Produced by Gas Tungsten Arc Welding With High Silicon Containing Solid Welding Filler Rod to Omit Back Shielding 高硅固体焊条省略后屏蔽的不锈钢气体钨极电弧焊焊缝评价
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-80246
A. Takahashi
Where single-sided welding is applied to fabrication and erection of piping made of low alloy steels, stainless steels (SS) and nonferrous alloys, back shielding by inert gas and its maintenance for the first few layers is required to obtain good weldability and to prevent oxidation of welds. In order to save consumption of inert gas, isolations to make a chamber for inert gas purging are placed inside piping for the joint and the adjacent areas to be welded, instead of inert gas purging for the whole piping length. However, placing the isolations before welding and removal of them after welding are sometimes impractical due to piping layout and construction sequence such as closure joints. To solve this issue, practices for omission of back shielding, such as use of flux cored welding filler rods for gas tungsten arc welding (GTAW) or high silicon welding wires for gas metal arc welding in modified wave short circuit mode (GMAW-S), had been developed and achieved the objective. These practices, however, require special training and qualifications for welders, close dimensional tolerance for fit-up, and special welding power source equipped with electrical waveform control. Also, welding quality such as remaining slag or spatters on piping internal is sometimes an issue. To make up for these shortcomings, high silicon solid welding filler rod was introduced to stainless steel welding by GTAW to eliminate back shielding, and mock-up tests were conducted. The properties of the welds were studied by comparison to the welds produced by the other welding processes such as GTAW with back shielding, GTAW with flux cored filler rod without back shielding, and GMAW-S using high silicon solid wire without back shielding. This paper discusses and evaluates the potential of the GTAW with high silicon solid filler rod which can eliminate the inert gas back shielding.
如果单面焊接应用于低合金钢、不锈钢(SS)和有色合金制成的管道的制造和安装,则需要用惰性气体进行背面保护,并对前几层进行维护,以获得良好的可焊性并防止焊缝氧化。为了节省惰性气体的消耗,在接头和相邻待焊区域的管道内放置隔离装置以形成惰性气体净化室,而不是在整个管道长度上放置惰性气体净化。然而,由于管道布局和施工顺序(如封闭接头)的原因,在焊接前放置隔离层并在焊接后拆除隔离层有时是不切实际的。为了解决这一问题,开发了省略背屏蔽的做法,如在钨气弧焊(GTAW)中使用药芯焊丝或在改进波短路模式(GMAW-S)下使用高硅焊丝进行金属气弧焊。然而,这些做法需要对焊工进行特殊培训和资格认证,安装时的尺寸公差要严格,并配备有电气波形控制的特殊焊接电源。此外,焊接质量,如残余渣或飞溅在管道内部有时是一个问题。为了弥补这些不足,将高硅固体焊料棒引入到不锈钢焊接中,消除背屏蔽,并进行了实物试验。通过与有反屏蔽的GTAW、无反屏蔽的GTAW和无反屏蔽的高硅实心焊丝的GMAW-S焊接工艺的焊缝性能进行对比研究。讨论并评价了高硅固体填料棒消除惰性气体反屏蔽的潜力。
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引用次数: 0
Metallurgical Characterization of a 114,000-Hour Service-Aged Forge 91-Pipe 91 Steel Header Weldment 114000小时使用时效锻造91管91钢头焊件的冶金特性
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-85319
Yiyu Wang, Wei Zhang, Yanli Wang, Zhili Feng, J. Siefert, Alex Bridges, S. Kung
In this work, multi-scale metallurgical characterizations with advanced microscopy techniques were conducted on an ex-service girth weld between a SA-182 forge 91 (F91) steel reducer to a SA335 pipe 91 (P91) steel header after 141,000 hours (16 years) service at a coal-red power plant between 1991 and 2015. Multiple metallurgical factors, including compositions, inclusions, precipitates, and hardness, were analyzed in comparison for the F91 and P91 steels. The results not only gain an in-depth understanding of creep deformation mechanisms in 9Cr steel welds, but also provide baseline information for remaining lifetime assessments of those service-aged steam components. The results show highly nonuniform creep degradation and damages were observed on the F91 and P91 sides. Base metal and heat affected zone (HAZ) on the F91 steel side experienced a higher degree of microstructure degradation with lower hardness and a higher fraction of creep cavities. Softened zones with lower hardness values were identified in both HAZs of F91 side and P91 side. However, the most creep damaged zones (CDZ) with the highest number density of cavities are not the identified softened zones. In the CDZ, creep cavities are always associated with coarse precipitates (Laves phase, Z phase) and large inclusions (Al oxides, AlN, MnS). A higher fraction of inclusions, coarser precipitates, and larger grain size in F91 steel put itself and its HAZ more vulnerable to creep damages, especially the infamous Type IV cracking.
在这项工作中,使用先进的显微技术对1991年至2015年在一家煤红色发电厂服役141,000小时(16年)后的SA-182锻造91 (F91)钢减速器与SA335管91 (P91)钢集箱之间的退役环焊缝进行了多尺度冶金表征。对F91和P91钢的成分、夹杂物、析出相和硬度等多种冶金因素进行了比较分析。研究结果不仅深入了解了9Cr钢焊缝的蠕变变形机制,而且为这些服役年龄的蒸汽部件的剩余寿命评估提供了基线信息。结果表明:F91和P91两侧均出现了高度不均匀的蠕变退化和损伤;F91钢侧母材和热影响区(HAZ)的显微组织退化程度较高,硬度较低,蠕变空洞比例较高。F91侧和P91侧的haz均存在硬度值较低的软化区。然而,蠕变损伤区(CDZ)最多,空洞数密度最高,并不是确定的软化区。在CDZ中,蠕变空洞总是伴随着粗相(Laves相、Z相)和大夹杂物(Al氧化物、AlN、MnS)。F91钢中较高的夹杂物、较粗的析出相和较大的晶粒尺寸使其本身及其热影响区更容易发生蠕变损伤,尤其是臭名昭著的IV型开裂。
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引用次数: 0
Investigation on Mechanical Properties of X80 Pipeline Girth Weld Welded by Semi-Automatic and Automatic Welding X80管道环焊缝半自动与自动焊接力学性能研究
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-83663
W. Ren, J. Shuai
The traditional manual welding in pipeline construction is being gradually replaced by semi-automatic and automatic welding in China. Semi-automatic welding is especially applied to X80 pipeline girth weld welding widely. Compared with semi-automatic welding, automatic welding has features of more efficiency, better quality and higher reliability. As the strength of pipeline steel increasing and the length, diameter as well as wall thickness of pipeline enlarging, automatic welding becomes the main trend at the development of the pipeline welding technology in the foreseeable future. Grasping the mechanical properties of X80 pipeline girth weld is crucial to ensuring the safety of pipeline operation. In order to determine the mechanical properties of X80 pipeline girth weld welded by semi-automatic and automatic welding, the experimental specimens were extracted from X80 pipeline girth weld welded by semi-automatic and automatic welding respectively to carry out the uniaxial tensile tests, fracture toughness tests and Charpy impact tests. In the tensile tests, the ultimate tensile strength of X80 pipeline girth weld welded by automatic welding (GWA) was higher than that of X80 pipeline girth weld welded by semi-automatic welding (GWSA) and the former had smaller dispersions. The fracture toughness tests showed that the fracture toughness of GWA was higher than that of GWSA. The Charpy impact tests results revealed that the impact energy of GWA was higher than that of GWSA. From the overall point of view, the mechanical properties of GWA are better than that of GWSA. The automatic welding technique is recommended for the welding of X80 pipeline, which is vitally important to maintain the structural integrity of X80 pipeline.
在中国,管道施工中传统的手工焊接正在逐渐被半自动和自动焊接所取代。半自动焊接尤其广泛应用于X80管道环焊缝的焊接。与半自动焊接相比,自动焊接具有效率高、质量好、可靠性高等特点。随着管道钢强度的不断提高,管道长度、直径和壁厚的不断增大,自动焊接成为可预见未来管道焊接技术发展的主要趋势。掌握X80管道环焊缝的力学性能是保证管道运行安全的关键。为确定X80管道半自动和自动焊接环焊缝的力学性能,分别从X80管道半自动和自动焊接环焊缝中提取实验试样,进行单轴拉伸试验、断裂韧性试验和夏比冲击试验。在拉伸试验中,自动焊接(GWA)焊接的X80管道环焊缝的极限抗拉强度高于半自动焊接(GWSA)焊接的X80管道环焊缝,且前者的弥散较小。断裂韧性试验表明,gwwa的断裂韧性高于GWSA。Charpy冲击试验结果表明,gwwa的冲击能高于GWSA。从整体上看,gwwa的力学性能优于GWSA。X80管道的焊接建议采用自动焊接技术,这对保持X80管道的结构完整性至关重要。
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引用次数: 1
New Strength Theory and Its Application to Determine Burst Pressure of Thick-Wall Pressure Vessels 新强度理论及其在厚壁压力容器爆破压力确定中的应用
Pub Date : 2022-07-17 DOI: 10.1115/pvp2022-84902
Xian-Kui Zhu, B. Wiersma, R. Sindelar, W. R. Johnson
The classical Tresca and von Mises strength theories have been utilized extensively for pressure vessel and pipeline design. For pressure vessel design, ASME B&PV code was developed using both Tresca and von Mises strength theories, where the yield strength (YS) was used for an elastic design and the ultimate tensile strength (UTS) was used for an elastic-plastic design. For pipeline design, ASME B31.3, B31G, or other codes were developed using the Tresca strength theory coupled with the YS or a flow stress. The flow stress was introduced to reduce over conservatism from the YS and avoid overestimation from the UTS for many steels. It has been widely accepted that the burst strength of pipelines depends on the UTS and strain hardening rate, n, of the ductile steel. The average shear stress yield theory was thus developed, and the associated burst pressure solution was obtained as a function of UTS and n. Experiments showed that the Zhu-Leis solution provides a reliable prediction of the burst pressure for defect-free thin-wall pipes. In order to extend the Zhu-Leis solution to thick-wall pressure vessels, this work modified the traditional strength theories and obtained new burst pressure solutions for thick-wall pressure vessels. Three new flow stresses were proposed to describe the tensile strength and plastic flow response for a strain hardening material. The associated strength theories were then developed in terms of the Tresca, von Mises and Zhu-Leis yield criteria. From these new strength theories, three burst pressure solutions were obtained for thick-wall cylinders, where the von Mises solution is an upper bound prediction, Tresca solution is a lower bound prediction, and the Zhu-Leis solution is an averaged prediction of burst pressure for thick-wall vessels. Subsequently, the proposed burst solutions were validated by a large dataset of full-scale burst tests.
经典的Tresca和von Mises强度理论在压力容器和管道设计中得到了广泛应用。对于压力容器的设计,ASME B&PV规范是使用Tresca和von Mises强度理论开发的,其中屈服强度(YS)用于弹性设计,极限拉伸强度(UTS)用于弹塑性设计。对于管道设计,ASME B31.3, B31G或其他规范是使用Tresca强度理论与YS或流动应力相结合而开发的。对于许多钢,引入流动应力是为了减少来自YS的过度保守性和避免来自UTS的过高估计。人们普遍认为管道的破裂强度取决于韧性钢的应变硬化率和应变硬化率n。由此建立了平均剪切应力屈服理论,并得到了相关的破裂压力解作为UTS和n的函数。实验表明,Zhu-Leis解可以可靠地预测无缺陷薄壁管的破裂压力。为了将朱磊解推广到厚壁压力容器,本文对传统的强度理论进行了修正,得到了新的厚壁压力容器破裂压力解。提出了三个新的流动应力来描述应变硬化材料的拉伸强度和塑性流动响应。相关的强度理论随后根据Tresca, von Mises和Zhu-Leis屈服准则发展起来。根据这些新的强度理论,得到了厚壁容器破裂压力的三种解,其中von Mises解为上限预测,Tresca解为下限预测,chu - leis解为厚壁容器破裂压力的平均预测。随后,提出的爆破解决方案通过大型全尺寸爆破测试数据集进行了验证。
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引用次数: 2
Compatibility of Medium Density Polyethylene (MDPE) for Distribution of Gaseous Hydrogen 中密度聚乙烯(MDPE)与气态氢分布的相容性
Pub Date : 2022-07-01 DOI: 10.1115/pvp2022-84791
R. Shrestha, J. Ronevich, Lisa D. Fring, K. Simmons, N. Meeks, Zachary E. Lowe, Timothy J. Harris, C. San Marchi
Numerous projects are looking into distributing blends of natural gas and different amounts of gaseous hydrogen through the existing natural gas distribution system, which is widely composed of medium density polyethylene (MDPE) line pipes. The mechanical behavior of MDPE with hydrogen is not well understood; therefore, the effect of gaseous H2 on the mechanical properties of MDPE needs to be examined. In the current study, we investigate the effects of gaseous H2 on fatigue life and fracture resistance of MDPE in the presence of 3.4 MPa gaseous H2. Fatigue life tests were also conducted at a pressure of 21 MPa to investigate the effect of gas pressure on the fatigue behavior of MDPE. Results showed that the presence of gaseous H2 did not degrade the fatigue life nor the fracture resistance of MDPE. Additionally, based on the value of fracture resistance calculated, a failure assessment diagram was constructed to determine the applicability of using MDPE pipeline for distribution of gaseous H2. Even in the presence of a large internal crack, the failure assessment evaluation indicated that the MDPE pipes lie within the safe region under typical service conditions of natural gas distribution pipeline system.
许多项目正在研究通过现有的天然气分配系统分配天然气和不同数量的气态氢的混合物,该系统广泛由中密度聚乙烯(MDPE)管线组成。MDPE与氢的力学行为尚不清楚;因此,需要研究气态H2对MDPE力学性能的影响。在本研究中,我们研究了3.4 MPa气体H2对MDPE疲劳寿命和抗断裂性能的影响。在21 MPa压力下进行了疲劳寿命试验,研究了气体压力对MDPE疲劳行为的影响。结果表明,气体H2的存在并没有降低MDPE的疲劳寿命和抗断裂性能。此外,根据计算出的断裂阻力值,构建了失效评估图,以确定采用MDPE管道进行气态H2分布的适用性。在天然气配气管道系统典型使用工况下,即使存在较大的内裂纹,其失效评价结果也表明MDPE管道处于安全范围内。
{"title":"Compatibility of Medium Density Polyethylene (MDPE) for Distribution of Gaseous Hydrogen","authors":"R. Shrestha, J. Ronevich, Lisa D. Fring, K. Simmons, N. Meeks, Zachary E. Lowe, Timothy J. Harris, C. San Marchi","doi":"10.1115/pvp2022-84791","DOIUrl":"https://doi.org/10.1115/pvp2022-84791","url":null,"abstract":"\u0000 Numerous projects are looking into distributing blends of natural gas and different amounts of gaseous hydrogen through the existing natural gas distribution system, which is widely composed of medium density polyethylene (MDPE) line pipes. The mechanical behavior of MDPE with hydrogen is not well understood; therefore, the effect of gaseous H2 on the mechanical properties of MDPE needs to be examined. In the current study, we investigate the effects of gaseous H2 on fatigue life and fracture resistance of MDPE in the presence of 3.4 MPa gaseous H2. Fatigue life tests were also conducted at a pressure of 21 MPa to investigate the effect of gas pressure on the fatigue behavior of MDPE. Results showed that the presence of gaseous H2 did not degrade the fatigue life nor the fracture resistance of MDPE. Additionally, based on the value of fracture resistance calculated, a failure assessment diagram was constructed to determine the applicability of using MDPE pipeline for distribution of gaseous H2. Even in the presence of a large internal crack, the failure assessment evaluation indicated that the MDPE pipes lie within the safe region under typical service conditions of natural gas distribution pipeline system.","PeriodicalId":434862,"journal":{"name":"Volume 4B: Materials and Fabrication","volume":"102 4","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114023247","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Investigating the Role of Ferritic Steel Microstructure and Strength in Fracture Resistance in High-Pressure Hydrogen Gas 铁素体钢组织和强度在高压氢气中抗断裂性能中的作用研究
Pub Date : 2022-06-01 DOI: 10.1115/pvp2022-83915
J. Ronevich, B. Kagay, C. San Marchi, Yiyu Wang, Zhili Feng, Yanli Wang, K. Findley
Despite their susceptibility to hydrogen-assisted fracture, ferritic steels make up a large portion of the hydrogen infrastructure. It is impractical and too costly to build large scale components such as pipelines and pressure vessels out of more hydrogen-resistant materials such as austenitic stainless steels. Therefore, it is necessary to understand the fracture behavior of ferritic steels in high-pressure hydrogen environments to manage design margins and reduce costs. Quenched and tempered (Q&T) martensite is the predominant microstructure of high-pressure hydrogen pressure vessels, and higher strength grades of this steel type are more susceptible to hydrogen degradation than lower strength grades. In this study, a single heat of 4340 alloy was heat treated to develop alternative microstructures for evaluation of fracture resistance in hydrogen gas. Fracture tests of several microstructures, such as lower bainite and upper bainite with similar strength to the baseline Q&T martensite, were tested at 21 and 105 MPa H2. Despite a higher MnS inclusion content in the tested 4340 alloy which reduced the fracture toughness in air, the fracture behavior in hydrogen gas fit a similar trend to other previously tested Q&T martensitic steels. The lower bainite microstructure performed similar to the Q&T martensite, whereas the upper bainite microstructure performed slightly worse. In this paper, we extend the range of high-strength microstructures evaluated for hydrogen-assisted fracture beyond conventional Q&T martensitic steels.
尽管铁素体钢易受氢辅助断裂的影响,但它们仍然是氢基础结构的重要组成部分。用奥氏体不锈钢等耐氢材料制造管道和压力容器等大型部件是不切实际的,而且成本太高。因此,有必要了解铁素体钢在高压氢环境中的断裂行为,以管理设计余量并降低成本。淬火回火(Q&T)马氏体是高压氢压力容器的主要组织,高强度等级的这种钢比低强度等级的钢更容易受到氢降解的影响。在本研究中,对4340合金的单热进行热处理,形成替代组织,以评估其在氢气中的抗断裂性。在21和105 MPa H2条件下,对强度与基准Q&T马氏体相近的下贝氏体和上贝氏体进行了断裂试验。尽管测试的4340合金中MnS夹杂物含量较高,降低了空气中的断裂韧性,但在氢气中的断裂行为与之前测试的其他Q&T马氏体钢相似。下贝氏体组织表现与Q&T马氏体相似,而上贝氏体组织表现略差。在本文中,我们扩展了氢辅助断裂的高强度显微组织评估范围,超出了传统的Q&T马氏体钢。
{"title":"Investigating the Role of Ferritic Steel Microstructure and Strength in Fracture Resistance in High-Pressure Hydrogen Gas","authors":"J. Ronevich, B. Kagay, C. San Marchi, Yiyu Wang, Zhili Feng, Yanli Wang, K. Findley","doi":"10.1115/pvp2022-83915","DOIUrl":"https://doi.org/10.1115/pvp2022-83915","url":null,"abstract":"\u0000 Despite their susceptibility to hydrogen-assisted fracture, ferritic steels make up a large portion of the hydrogen infrastructure. It is impractical and too costly to build large scale components such as pipelines and pressure vessels out of more hydrogen-resistant materials such as austenitic stainless steels. Therefore, it is necessary to understand the fracture behavior of ferritic steels in high-pressure hydrogen environments to manage design margins and reduce costs. Quenched and tempered (Q&T) martensite is the predominant microstructure of high-pressure hydrogen pressure vessels, and higher strength grades of this steel type are more susceptible to hydrogen degradation than lower strength grades. In this study, a single heat of 4340 alloy was heat treated to develop alternative microstructures for evaluation of fracture resistance in hydrogen gas. Fracture tests of several microstructures, such as lower bainite and upper bainite with similar strength to the baseline Q&T martensite, were tested at 21 and 105 MPa H2. Despite a higher MnS inclusion content in the tested 4340 alloy which reduced the fracture toughness in air, the fracture behavior in hydrogen gas fit a similar trend to other previously tested Q&T martensitic steels. The lower bainite microstructure performed similar to the Q&T martensite, whereas the upper bainite microstructure performed slightly worse. In this paper, we extend the range of high-strength microstructures evaluated for hydrogen-assisted fracture beyond conventional Q&T martensitic steels.","PeriodicalId":434862,"journal":{"name":"Volume 4B: Materials and Fabrication","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126086170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of High-Pressure Hydrogen Gas and Pre-Charged Hydrogen on Fatigue Crack Initiation and Fatigue Life of 255 Super Duplex Stainless Steel 高压氢气和预充氢对255超级双相不锈钢疲劳裂纹萌生和疲劳寿命的影响
Pub Date : 2022-06-01 DOI: 10.1115/pvp2022-84797
B. Kagay, J. Ronevich, C. San Marchi
High strength austenite-ferrite duplex stainless steels are a potential alternative to austenitic stainless steels for components in hydrogen gas storage systems. Since these components experience cyclic loading from frequent pressurization and depressurization, the effect of hydrogen on the fatigue behavior of duplex stainless steel must be understood. To determine the influence of hydrogen on fatigue crack initiation and fatigue life of a 255 super duplex stainless steel, circumferentially notched tensile (CNT) specimens were fatigue tested in the as-received condition in air, with pre-charged internal hydrogen in air, and in the as-received condition in high pressure hydrogen gas. The direct current potential difference (DCPD) method was used to detect crack initiation so that S-N curves could be produced for both (i) cycles to crack initiation and (ii) cycles to failure. An electropolished CNT specimen was also cycled in the as-received and hydrogen pre-charged conditions but interrupted just after crack initiation. The microstructural locations of small fatigue cracks were then identified with scanning electron microscopy and electron backscatter diffraction (EBSD). High pressure hydrogen gas and pre-charged hydrogen decreased the fatigue life of 255 duplex stainless steel by a nearly identical amount. The effects of hydrogen on fatigue crack initiation and fatigue life of 255 duplex stainless steel are discussed and compared to austenitic stainless steels.
高强度奥氏体-铁素体双相不锈钢是氢气储存系统中奥氏体不锈钢的潜在替代品。由于这些部件经历了频繁加压和减压的循环加载,因此必须了解氢对双相不锈钢疲劳行为的影响。为确定氢对255超级双相不锈钢疲劳裂纹萌生和疲劳寿命的影响,对环形缺口拉伸(CNT)试样在空气中、空气中预充氢和高压氢气中进行了疲劳试验。采用直流电位差(direct current potential difference, DCPD)方法检测裂纹起裂,从而得到裂纹起裂周期和失效周期的S-N曲线。电抛光碳纳米管样品也在接收和氢气预充条件下循环,但在裂纹萌生后中断。然后利用扫描电镜和电子背散射衍射(EBSD)确定了小疲劳裂纹的显微组织位置。高压氢气和预充氢对255双相不锈钢疲劳寿命的影响几乎相同。讨论了氢对255双相不锈钢疲劳裂纹萌生和疲劳寿命的影响,并与奥氏体不锈钢进行了比较。
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引用次数: 0
Fatigue and Fracture of Pipeline Steels in High-Pressure Hydrogen Gas 管道钢在高压氢气中的疲劳与断裂
Pub Date : 2022-04-01 DOI: 10.1115/pvp2022-84757
Christopher San Marchi, J. Ronevich
Decarbonizing natural gas networks is a challenging enterprise. Replacing natural gas with renewable hydrogen is one option under global consideration to decarbonize heating, power and residential uses of natural gas. Hydrogen is known to degrade fatigue and fracture properties of structural steels, including pipeline steels. In this study, we describe environmental testing strategies aimed at generating baseline fatigue and fracture trends with efficient use of testing resources. For example, by controlling the stress intensity factor (K) in both K-increasing and K-decreasing modes, fatigue crack growth can be measured for multiple load ratios with a single specimen. Additionally, tests can be designed such that fracture tests can be performed at the conclusion of the fatigue crack growth test, further reducing the resources needed to evaluate the fracture mechanics parameters utilized in design. These testing strategies are employed to establish the fatigue crack growth behavior and fracture resistance of API grade steels in gaseous hydrogen environments. In particular, we explore the effects of load ratio and hydrogen partial pressure on the baseline fatigue and fracture trends of line pipe steels in gaseous hydrogen. These data are then used to test the applicability of a simple, universal fatigue crack growth model that accounts for both load ratio and hydrogen partial pressure. The appropriateness of this model for use as an upper bound fatigue crack growth is discussed.
使天然气网络脱碳是一项具有挑战性的事业。用可再生氢气替代天然气是全球考虑的一种选择,以使供暖、电力和住宅使用天然气脱碳。众所周知,氢会降低结构钢(包括管道钢)的疲劳和断裂性能。在这项研究中,我们描述了环境测试策略,旨在有效利用测试资源,产生基线疲劳和断裂趋势。例如,通过控制应力强度因子(K)在K增加和K减少两种模式下,可以测量单一试样在多种载荷比下的疲劳裂纹扩展。此外,测试可以设计为在疲劳裂纹扩展试验结束时进行断裂试验,进一步减少了评估设计中使用的断裂力学参数所需的资源。采用这些试验策略建立了API级钢在气态氢环境下的疲劳裂纹扩展行为和抗断裂性能。特别地,我们探讨了载荷比和氢分压对管道钢在气态氢中的基线疲劳和断裂趋势的影响。然后使用这些数据来测试一个简单的通用疲劳裂纹扩展模型的适用性,该模型考虑了载荷比和氢分压。讨论了该模型作为上界疲劳裂纹扩展模型的适用性。
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引用次数: 0
Post-Irradiation Fracture Toughness Characterization of Generation II FeCrAl Alloys 第二代FeCrAl合金辐照后断裂韧性表征
Pub Date : 2019-10-01 DOI: 10.2172/1606843
Xiang Chen, K. Field, Dalong Zhang, C. Massey, J. Robertson, K. Linton, A. Nelson
FeCrAl alloys are promising candidate materials for the accident tolerant fuel (ATF) cladding application due to their exceptional resistance to oxidation in elevated temperature steam environments. Currently, limited fracture toughness data are available for the FeCrAl alloys, including the FeCrAl alloys newly developed at Oak Ridge National Laboratory (ORNL) under the U.S. Department of Energy’s Advanced Fuels Campaign (AFC) program. In this study, two Generation II candidate FeCrAl alloys, i.e., C06M (81.8Fe-10Cr-6Al-0.03Y-2Mo-0.2Si) and C36M (78.8Fe-13Cr-6Al-0.03Y-2Mo-0.2Si), were irradiated in the High Flux Isotope Reactor (HFIR) at ORNL to assess the fracture characteristics of these alloys after neutron irradiation. A total of six rabbit capsules were irradiated in HFIR at target temperatures of 200°C, 330°C, and 500°C up to target damage doses of 8 displacements per atom (dpa) and 16 dpa. Post-irradiation fracture toughness testing was performed following the Master Curve method in the ASTM E1921 standard. The main findings of this study are: 1) Both the C06M and C36M alloys exhibited a similar response to irradiation concerning irradiation hardening and embrittlement. 2) The irradiation temperature played different roles in terms of irradiation hardening and embrittlement for both C06M and C36M: after irradiation between 166°C and 204°C, both materials exhibited significant irradiation hardening and embrittlement; after irradiation between 315°C and 343°C, both materials showed small irradiation hardening without irradiation embrittlement. After irradiation between 501°C and 507°C, however, the irradiation softening without irradiation embrittlement was observed in both materials. 3) Comparing the microhardness and Master Curve reference temperature T0q before and after neutron irradiation, we did not observe a linear correlation between the two parameters for both C06M and C36M steels. This should be mainly due to a flat response of the Master Curve reference temperature T0q to the irradiations at 166–204°C and 315–343°C ranges 4) C06M showed a lower T0q, meaning better toughness, than C36M at the unirradiated condition, and such trend was kept even after neutron irradiation except for the 166–204°C irradiation after which both materials had similar T0q. 5) In terms of hardening and embrittlement, the irradiation effect on both C06M and C36M appeared to saturate after an irradiation dose of 7 dpa.
FeCrAl合金在高温蒸汽环境中具有优异的抗氧化性能,是耐事故燃料(ATF)包层应用的有前途的候选材料。目前,有限的断裂韧性数据可用于FeCrAl合金,包括美国能源部先进燃料运动(AFC)计划下橡树岭国家实验室(ORNL)新开发的FeCrAl合金。本研究将C06M (81.8Fe-10Cr-6Al-0.03Y-2Mo-0.2Si)和C36M (78.8Fe-13Cr-6Al-0.03Y-2Mo-0.2Si)两种第二代候选FeCrAl合金在ORNL的高通量同位素反应堆(HFIR)中辐照,评估这两种合金在中子辐照后的断裂特征。在HFIR中辐照6只兔胶囊,目标温度分别为200°C、330°C和500°C,目标损伤剂量分别为8位移/原子(dpa)和16 dpa。辐照后断裂韧性测试按照ASTM E1921标准中的主曲线法进行。主要研究结果如下:1)C06M和C36M合金在辐照硬化和脆化方面表现出相似的辐照响应。2)辐照温度对C06M和C36M的辐照硬化和辐照脆化作用不同:在166℃~ 204℃辐照后,两种材料均表现出明显的辐照硬化和辐照脆化;在315℃~ 343℃辐照后,两种材料均表现出较小的辐照硬化,无辐照脆化。在501℃~ 507℃之间辐照后,两种材料均出现了辐照软化现象,但未出现辐照脆化现象。3)对比中子辐照前后C06M和C36M钢的显微硬度和主曲线参考温度T0q,我们没有观察到这两个参数之间的线性相关。这主要是由于主曲线参考温度T0q在166-204℃和315-343℃范围内对辐照的平缓响应所致。4)C06M在未辐照条件下比C36M表现出更低的T0q,这意味着韧性更好,即使在中子辐照后也保持这种趋势,但在166-204℃辐照后,两种材料的T0q相似。5)在硬化脆化方面,辐照剂量为7 dpa时,C06M和C36M的辐照效应均趋于饱和。
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引用次数: 3
期刊
Volume 4B: Materials and Fabrication
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