Applied Petrochemical Research最新文献

About half of the product from iron-based high-temperature Fischer–Tropsch synthesis is an aqueous product containing dissolved oxygenates. Volatile oxygenates can be recovered by distillation, but the bulk of the carboxylic acids remain in the water, which is called acid water. Fractional freezing was explored as a process for producing a more concentrated carboxylic acid solution from which the carboxylic acids could be recovered as petrochemical products, while concomitantly producing a cleaner wastewater. Solid–liquid equilibrium data were collected for aqueous solutions of acetic acid, propionic acid, and butyric acid. A synthetic Fischer–Tropsch acid water mixture (0.70?wt% acetic acid, 0.15?wt% propionic acid, and 0.15?wt% butyric acid) was prepared and the liquid phase concentrations of the acid species at solid–liquid equilibrium were determined. Control experiments with material balance closure on each of the carboxylic acid species were performed at selected conditions. Having more than one carboxylic acid species present in the mixture meaningfully changed the solid–liquid equilibrium versus temperature of the system. The carboxylic acids partitioned between the solid phase and the liquid phase and a practical design would require multiple duty-controlled solid–liquid equilibrium stages, with most of the separation taking place in the temperature range 0 to ??5?°C.

In this paper, the photochemical conversion process of aromatic hydrocarbons in Balakhani oil well (BO) as a case study was investigated. To study the composition of BO, first, it has been separated into the first, second, third, and fourth groups of aromatics using chromatography absorption column. It has been established that the composition of the separated groups is mainly composed of mono-, tri-, and tetracyclic aromatic hydrocarbons. It has been shown that the optical densities of the absorption bands corresponding to bi-, tri-, and polycyclic aromatic hydrocarbons decrease with increasing the photo-irradiation period, hence their maximum absorption band undergoes the hypsochromatic shift, which is characteristic for electron donor substances. It has been determined that the photochemical conversion process in the sample oil (BO) occurs with radical-chain and molecular mechanisms. As a result of the photochemical conversion process of arene-type aromatic hydrocarbons, the first difference during the photooxidation of endoperoxides, hydroxynones, quinones, and phenes is the formation of cyclic peroxides and quinones.

In this study, deep eutectic solvents (DESs) were prepared using choline chloride as hydrogen bond acceptor (HBA) and ethylene glycol (EG) or glycerol (GLY) or urea (U) as hydrogen bond donor (HBD) and were evaluated as solvents in the extraction of benzene from n-hexane. Six of such solvents were prepared using different molar ratios of HBA: HBD and code named DES1, DES2, DES3, DES4, DES5 and DES6. Liquid–liquid equilibria (LLE) data for the ternary systems of n-hexane-benzene-DESs were measured at 303?K and 101.3?kPa. Solubility data and mutual solubilities between n-hexane and DES were measured using the traditional cloud point method. The tie lines were obtained using titration and refractive index measurements on both phases (n-hexane phase and DES-phases). The ternary systems exhibit type-1 phase behavior. The Othmer-Tobias and Hands equations were applied to examine the reliability of the LLE data. The tie-line data were correlated using the nonrandom two-liquid (NRTL) and universal quasichemical (UNIQUAC) thermodynamic models, and their corresponding binary interaction parameters were determined. The results show that the maximum separation factors were 31.24, 462.00, 15.24, 37.83, 174.60 and 126.00 for DES1, DES2, DES3, DES4, DES5 and DES6, respectively. The glycerol based DES (DES2 and DES5) show the highest separation factors and thus considered the most suitable for separating benzene from hexane. The regression coefficient for both Othmer-Tobias and Hand equations are higher than 0.99 for all DESs, indicating the reliability and consistency of the data. Both NRTL and UNIQUAC models adequately capture the experimental data.

In this work, we prepared different alkyl acrylates by esterifying acrylic acid with different alcohols (decanol, dodecanol, hexadecanol and octadecanol). Anilimide was then produced by the reaction of aniline with maleic anhydride. Different teropolymers were prepared by polymerization reaction of anilimide, different alkyl acrylate esters and olefins in different ratios. The thermal stability of the prepared terpolymers was measured by thermal gravimetric analysis which demonstrated a high thermal stability. The polymers were degraded above 500?°C. The rheology behavior shows shear-thinning, it approaches the ideal Newtonian behavior in case of polymer (C). The prepared terpolymers succeeded in raising the viscosity index of oil to 118 in case of polymer (C) and decreasing the pour point of oil to -12 in case of polymer (E).

Determining the solubility of gases in solvents and considering non-idealities at different operating conditions are essential to design a cost-effective and energy-efficient absorption process. In this work, using a lab-made set-up, solubility of ethylene in N-methyl-2-pyrrolidone (NMP) was measured at different temperatures (278.15, 298.15, and 328.15?K) and pressures up to 14?bar, and the kinetic and equilibrium data were obtained. Accordingly, Henry’s law constants are calculated at various temperatures. Then, thermodynamic modeling was accomplished by applying Peng-Robinson equation of state (PR-EOS) and Wilson activity coefficient model, and the binary interaction parameters were estimated. By the thermodynamic modeling, positive deviation from ideal behavior was apparently observed. Due to low absolute average deviation of?<?7.7%, the correlated model was able to predict the ethylene solubility in NMP with a reliable accuracy.

For the proper working of the internal combustion engine, engine oil plays a significant role. The performance of the engine is greatly affected by oil that has degenerated. In order to determine the optimal gap between oil changes, it is crucial to measure the deterioration in the engine oil. Multiple parameters like oxidation, nitration, viscosity and so on are brought into use. One of the methods used to quantify the deterioration in the engine oil is the Fourier Transform Infrared (FTIR) spectroscopy. The main parameters of the engine oil are distinguished by this method by utilizing Infrared (IR) absorption at different bandwidths. The two significant parameters in engine oil deterioration are oxidation and nitration. However, the limitation of the FTIR method is that it is more expensive and since it uses huge machinery, it requires a lot of area. Hence, the use of this method is not possible in the field area due to the need for space. It is this major limitation that is the motivation for proposing an inexpensive, yet handy system, using an IR sensor set up, in this paper. This system is used for measuring the transmittance of engine oil that has degenerated. For this paper, we collected random samples at various times from service stations that were specifically authorized. These samples were used in experiments based on the FTIR spectroscopy and UV spectrophotometer and the results were compared using the IR sensor setup. Investigation of the experimental results showed that monitoring oil transmittance using an IR sensor setup is possible, and a robust relationship between oxidation and nitration and the transmittance of the oil was observed. Moreover, a pattern of deterioration for a specific engine oil (SAE 5W30) which is utilized for passenger cars and light duty vehicles was also established.

Three valsartan metal (tin, nickel, and magnesium) complexes were examined as capture and storage media for methane under high temperature (323?K) and pressure (50?bar) conditions. The surface morphology of the complexes were examined using Field emission scanning electron microscopy and displayed porous structures comprising particles of different shapes and sizes. The narrow pore-size distribution of metal complexes makes them suitable materials for methane capture. The methane adsorption–desorption isotherms of the metal complexes were reversible. The tin(IV) and nickel(II) complexes exhibited type-III physisorption isotherms, while the magnesium(II) complex displayed a type-IV physisorption isotherm. Both types of isotherms are typical for mesoporous materials. The magnesium(II) complex was more efficient compared with the tin(IV) and nickel(II) complexes. It exhibited a remarkable methane uptake capacity of 71.68?cm³/g under optimized conditions.

This work reports the synthesis of mesoporous Ce_1-x-Zr_xO_2-δ (x?=?0.5 and 0.8) mixed oxides with distinct Ce/Zr mole ratio by inverse micelle template method and their catalytic exploration for epoxidation of styrene in isopropanol solvent using TBHP as the oxidant. Among various catalysts investigated, the Ce_0.8Zr_0.2O₂ combination catalyst exhibited best catalytic activity with?~?98% conversion and?~?90% selectivity to styrene epoxide. The synthesized Ce–Zr mixed oxide catalysts were characterized by various state-of-the-art techniques. Characterization studies revealed that Ce/Zr mole ratio has an imperative influence on the physicochemical properties such as surface area, oxygen vacancy concentration, and redox nature. Interestingly, catalytic efficiency was significantly improved with the increase of Ce and decrease of Zr content in the Ce–Zr mixed oxides. Catalytic efficiency and distribution of the products for styrene oxidation under various conditions such as reaction time, solvent, temperature, and styrene to TBHP mole ratio were also evaluated. Reusability of the highly active Ce_0.8Zr_0.2O₂ mixed oxide catalyst was also demonstrated.

Light alkane aromatization for aromatic compound production, used in petrochemical industries is an attractive area of research. The effect of second metal co-impregnation was investigated in stabilizing zinc on ZSM-5 in aromatization of propane. HZSM-5 was modified with zinc and iron metal by co wet-impregnation and characterized using XRF, XRD, BET, N₂-adsorption, FTIR, FTIR-Pyridine, SEM, TEM, H₂-TPR and XPS. The effect of different loadings of Iron on Zn/ZSM-5 was investigated on acidity, aromatic yield, product distribution and aromatization performance. Performance test was conducted in a fixed bed reactor at 540?°C, one atmosphere. GHSV of 1200?mL/g-h. Co-impregnation of Zn with Fe improved the catalytic activity and aromatic yield for 10?h time on stream as compared to parent HZSM-5 and Zn/ZSM-5 of very low aromatic yield and propane conversion. Impregnation of Zn as the dehydrogenating metal on HZSM-5 steadily increased aromatic yield from 5% on HZSM-5 to 25% and was steadily dropped to 20% after 10?h TOS. The co-impregnation of iron of 1–3?wt% loading as the second metal for zinc stability with 2?wt% Zn on ZSM-5 improved propane conversion and aromatic yield to 55% for the 10?h TOS. This further enhanced aromatic product distribution and minimized light gases.