Laser-induced fluorescence spectroscopy was used to determine the concentration of cobalt ions in aqueous solution, in which CH-90 resin was used to chelate the ions to transform the liquid samples into solid ones. The experimental results showed that the fluorescence emission of the ions was significantly enhanced after excited by a low-power semiconductor laser at the wavelength of 447 nm. The limit of detection of 1.0 ng/L was achieved, which was 10,000 times lower than the permissible Co(Ⅱ) content of 0.01 mg/L in drinking water. The fluorescence intensity was proportional to the concentration of cobalt ions with a linear correlation coefficient of R2 = 0. 998. The method greatly improved the sensitivity of detection for cobalt element in aqueous solutions.
{"title":"Highly sensitive detection of cobalt ions in aqueous solutions by laser induced fluorescence spectroscopy","authors":"Lanxin Shi, Jinan Xia, Dongqing Qiao, Junjie Pan, Huimiao Cheng, Zixuan Wang","doi":"10.1007/s00340-025-08561-5","DOIUrl":"10.1007/s00340-025-08561-5","url":null,"abstract":"<div><p>Laser-induced fluorescence spectroscopy was used to determine the concentration of cobalt ions in aqueous solution, in which CH-90 resin was used to chelate the ions to transform the liquid samples into solid ones. The experimental results showed that the fluorescence emission of the ions was significantly enhanced after excited by a low-power semiconductor laser at the wavelength of 447 nm. The limit of detection of 1.0 ng/L was achieved, which was 10,000 times lower than the permissible Co(Ⅱ) content of 0.01 mg/L in drinking water. The fluorescence intensity was proportional to the concentration of cobalt ions with a linear correlation coefficient of R<sup>2</sup> = 0. 998. The method greatly improved the sensitivity of detection for cobalt element in aqueous solutions.</p></div>","PeriodicalId":474,"journal":{"name":"Applied Physics B","volume":"131 11","pages":""},"PeriodicalIF":2.0,"publicationDate":"2025-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145315828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-13DOI: 10.1007/s00340-025-08541-9
Fengshan Liu, Timothy A. Sipkens, Joel C. Corbin
Ultrafine soot particles emitted from combustion devices and biomass burning are a major particulate pollutant for human health and a major climate forcer. Unprecedented efforts have been made to understand the mechanism of soot formation and the physical, chemical, and optical properties of soot particles at different stages of maturity. Pulsed laser-induced incandescence (pLII) has become a powerful tool for in-situ measurements of soot volume fraction and primary particle size and to investigate the effects of pulsed laser irradiation on soot absorption properties. Experimental studies have confirmed that a high-power laser pulse can enhance the absorption of young soot particles through laser-induced annealing. Previous studies have ascribed the observed changes in soot absorption by pulsed laser irradiation to thermal annealing. In this study, a numerical study was conducted to model the effect of pulsed laser irradiation on the absorption efficiency of soot of different maturities to reproduce the results of a recent double-pulse pLII experiment. The numerical results based on thermal annealing models proposed in the literature failed to capture the enhanced peak LII signals of laser-heated young soot compared to those of un-preheated soot. By assuming the laser-induced annealing of soot particle is attributed to both thermal and photon mechanisms, the modified LII model can reproduce the experimentally observed enhancement in the peak LII signal of laser irradiated soot of different maturities. The findings of this study serve as indirect evidence to support the conjecture that the photon mechanism plays an important role in laser-induced annealing of young soot.
{"title":"On the mechanism of laser-induced annealing of soot","authors":"Fengshan Liu, Timothy A. Sipkens, Joel C. Corbin","doi":"10.1007/s00340-025-08541-9","DOIUrl":"10.1007/s00340-025-08541-9","url":null,"abstract":"<div><p>Ultrafine soot particles emitted from combustion devices and biomass burning are a major particulate pollutant for human health and a major climate forcer. Unprecedented efforts have been made to understand the mechanism of soot formation and the physical, chemical, and optical properties of soot particles at different stages of maturity. Pulsed laser-induced incandescence (pLII) has become a powerful tool for in-situ measurements of soot volume fraction and primary particle size and to investigate the effects of pulsed laser irradiation on soot absorption properties. Experimental studies have confirmed that a high-power laser pulse can enhance the absorption of young soot particles through laser-induced annealing. Previous studies have ascribed the observed changes in soot absorption by pulsed laser irradiation to thermal annealing. In this study, a numerical study was conducted to model the effect of pulsed laser irradiation on the absorption efficiency of soot of different maturities to reproduce the results of a recent double-pulse pLII experiment. The numerical results based on thermal annealing models proposed in the literature failed to capture the enhanced peak LII signals of laser-heated young soot compared to those of un-preheated soot. By assuming the laser-induced annealing of soot particle is attributed to both thermal and photon mechanisms, the modified LII model can reproduce the experimentally observed enhancement in the peak LII signal of laser irradiated soot of different maturities. The findings of this study serve as indirect evidence to support the conjecture that the photon mechanism plays an important role in laser-induced annealing of young soot.</p></div>","PeriodicalId":474,"journal":{"name":"Applied Physics B","volume":"131 11","pages":""},"PeriodicalIF":2.0,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00340-025-08541-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145316128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-13DOI: 10.1007/s00340-025-08572-2
Boxuan Chen, Tianbo He, Liang Chen, Zhigang Hu, Jingsong Li
In this paper, a self-calibration photoacoustic (PA) spectroscopy analysis technique based on the idle transmitted light intensity was proposed to resolve the key influence of incident light power on PA signal. To demonstrate this proposed gas sensing technique, methane (CH4) was selected as the target gas, a photoacoustic spectroscopy (PAS) gas sensor system based on near-infrared distributed feedback (DFB) diode laser emitting at 1653 nm was developed by combining wavelength modulation spectroscopy (WMS) with second harmonic (2 F) signal detection method. Instead of the expensive optical power meter, a low-cost photodetector (PD) is used to measure the transmitted light signal and serves as the reference signal for the normalization of the PA signal. The experimental results show that the measured WMS-PA-2 F/PD signals have a good immune to the large dynamic fluctuations of the incident light power. The Allan-Werle deviation analysis indicated that a detection limit of 42.1 ppb can be achieved with an average time of 244 s, corresponding to the corresponding normalized noise equivalent absorption coefficient (NNEA) of 3.63 × 10− 9({text{c}text{m}}^{-1}text{W}/text{H}text{z}).
{"title":"Self-calibration photoacoustic spectroscopy for trace gas detection","authors":"Boxuan Chen, Tianbo He, Liang Chen, Zhigang Hu, Jingsong Li","doi":"10.1007/s00340-025-08572-2","DOIUrl":"10.1007/s00340-025-08572-2","url":null,"abstract":"<div><p>In this paper, a self-calibration photoacoustic (PA) spectroscopy analysis technique based on the idle transmitted light intensity was proposed to resolve the key influence of incident light power on PA signal. To demonstrate this proposed gas sensing technique, methane (CH<sub>4</sub>) was selected as the target gas, a photoacoustic spectroscopy (PAS) gas sensor system based on near-infrared distributed feedback (DFB) diode laser emitting at 1653 nm was developed by combining wavelength modulation spectroscopy (WMS) with second harmonic (2 F) signal detection method. Instead of the expensive optical power meter, a low-cost photodetector (PD) is used to measure the transmitted light signal and serves as the reference signal for the normalization of the PA signal. The experimental results show that the measured WMS-PA-2 F/PD signals have a good immune to the large dynamic fluctuations of the incident light power. The Allan-Werle deviation analysis indicated that a detection limit of 42.1 ppb can be achieved with an average time of 244 s, corresponding to the corresponding normalized noise equivalent absorption coefficient (NNEA) of 3.63 × 10<sup>− 9</sup> <span>({text{c}text{m}}^{-1}text{W}/text{H}text{z})</span>.</p></div>","PeriodicalId":474,"journal":{"name":"Applied Physics B","volume":"131 11","pages":""},"PeriodicalIF":2.0,"publicationDate":"2025-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145316087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}