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Cu2O-Enhanced Back Surface Field Empowers Selenium-Based TiO2/Sb2Se3 Thin Film Solar Cells to Achieve Efficiency over 32% Cu2O 增强的背表面场使硒基 TiO2/Sb2Se3 薄膜太阳能电池的效率超过 32
IF 1.204 Q3 Energy Pub Date : 2024-03-23 DOI: 10.3103/S0003701X23601515
Basra Sultana, A. T. M. Saiful Islam, Md. Dulal Haque, Abdul Kuddus

Antimony (Sb) chalcogenides, particularly antimony selenide (Sb2Se3), have gained attention as promising semiconductor materials in order to creat and advancement of competitive solar cells. These materials exhibit a range of desirable qualities, such as excellent absorption rate, ability to modify band gap, and plentiful in the crust of the earth. This article describes an antimony selenide (Sb2Se3) absorber based high-efficient thin film solar cell (TFSC) with copper oxide (Cu2O) as as back surface field (BSF) by dint of Al/ITO/TiO2/Sb2Se3/Cu2O/Ni heterostructure using SCAPS-1D Simulator. This research entails an in-depth assessment of various physical and electrical characteristics of every solar active semiconductorof TiO2,Sb2Se3, and Cu2O covering the thickness of each layer, concentration of carrier doping, defect density in the bulk and at the interface, carrier generation rate together with recombination. Initially, the variation in photovoltaic parameters of open circuit voltage (Voc), short-circuit current density (Jsc), fill factor (FF), power conversion efficiency (PCE), and quantum efficiency (QE) investigated without the BSF layer, followed by a comprehensive analysis on the role of Cu2O BSF layer for enhancing cell’s performance explored systematically. The proposed heterostructure shows improved PCE of over 32% (which was 21% without BSF) with JSC of 37.492 mA/cm2, VOC of 1.024 V, and FF of 83.595%. Thus, the utilisation of a heterostructure comprising Sb2Se3 absorber and copper oxide Cu2O BSF layer demonstrates significant promise in the development and production the high-efficiency greenery thin-film solar cells (TFSCs).

摘要锑(Sb)瑀,特别是硒化锑(Sb2Se3),作为一种有前途的半导体材料,在创造和发展有竞争力的太阳能电池方面受到了关注。这些材料表现出一系列令人满意的特性,如出色的吸收率、改变带隙的能力以及在地壳中含量丰富。本文利用 SCAPS-1D 模拟器,通过 Al/ITO/TiO2/Sb2Se3/Cu2O/Ni 异质结构,描述了一种基于硒化锑(Sb2Se3)吸收剂的高效薄膜太阳能电池(TFSC),并以氧化铜(Cu2O)作为背表面场(BSF)。这项研究需要深入评估 TiO2、Sb2Se3 和 Cu2O 等每种太阳能活性半导体的各种物理和电气特性,包括每层的厚度、载流子掺杂浓度、块体和界面上的缺陷密度、载流子生成率和重组。首先,研究了无 BSF 层时开路电压 (Voc)、短路电流密度 (Jsc)、填充因子 (FF)、功率转换效率 (PCE) 和量子效率 (QE) 等光伏参数的变化,然后系统地分析了 Cu2O BSF 层对提高电池性能的作用。所提出的异质结构将 PCE 提高了 32%(无 BSF 时为 21%),JSC 为 37.492 mA/cm2,VOC 为 1.024 V,FF 为 83.595%。因此,利用由 Sb2Se3 吸收体和氧化铜 Cu2O BSF 层组成的异质结构,在开发和生产高效绿色薄膜太阳能电池(TFSCs)方面大有可为。
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引用次数: 0
Heterojunction-with-Intrinsic-Thin-Layer Photovoltaic Panels Operation—Numerical Simulation and Outdoor Tests in Moscow 带有本征薄层的异质结光伏电池板的运行--数值模拟和莫斯科户外测试
IF 1.204 Q3 Energy Pub Date : 2024-03-23 DOI: 10.3103/S0003701X2360193X
Yaroslav A. Menshikov, Oleg S. Popel, Alexey B. Tarasenko

The research has been devoted to benefits for heterojunction silicon PV panels application evaluation. Evaluation has been conducted through numerical simulation and field tests in Moscow conditions. During simulation PV array year energy yields for HJT monocrystalline Si panels have been derived for 2013–2018 years using NASA Power initial satellite data on solar radiation daily sums. Experimental investigation has been realized through multicrystalline and HJT panel comparative test using test bed, simulating small off-grid power unit. Specific energy yield of panel (ratio of energy yield for given period of time to the panel peak power) has been chosen as a criterion for panels operation comparison in both cases. The research novelty is concerned with attempt to estimate additional energy, produced due to amorphous silicon layer presence by means of field tests in different weather conditions. Calculation showed no benefits for HJT PV panels. Experimental research showed that up to 5–6 kWh/m2/day solar radiation sum value HJT panel provides 1–20% power output gain relatively multicrystalline panel with maximum gain of 14–16% in range of 2–2.5 kWh/m2/day solar radiation sum values.

摘要 该研究致力于对异质结硅光伏电池板的应用效益进行评估。评估通过数值模拟和莫斯科条件下的现场测试进行。在模拟过程中,利用美国国家航空航天局(NASA)电力卫星关于太阳辐射日总和的初始数据,得出了 2013-2018 年 HJT 单晶硅电池板的光伏阵列年发电量。通过使用试验台进行多晶和 HJT 面板比较试验,模拟小型离网发电装置,实现了实验研究。面板的比能量产量(给定时间内的能量产量与面板峰值功率之比)被选为两种情况下面板运行比较的标准。研究的新颖之处在于通过在不同天气条件下进行实地测试,估算非晶硅层的存在所产生的额外能量。计算结果表明,HJT 光伏电池板没有任何优势。实验研究表明,在 5-6 千瓦时/平方米/天的太阳辐射总和值范围内,HJT 面板的功率输出增益为多晶硅面板的 1-20%,在 2-2.5 千瓦时/平方米/天的太阳辐射总和值范围内,最大增益为 14-16%。
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引用次数: 0
Analysis of a Dual-Axis 20W-Rated Photovoltaic Solar Tracker 分析额定功率为 20W 的双轴光伏太阳能跟踪器
IF 1.204 Q3 Energy Pub Date : 2024-03-23 DOI: 10.3103/S0003701X23600960
Nashil Sowaruth, Raviduth Ramful

Solar energy is one of the most abundant forms of renewable energies for countries located in the tropics like Mauritius. Further interests and initiatives have been observed in recent years to harness solar energy in Mauritius. One way to maximize the capture of solar energy is by considering solar trackers which can be a fundamental part in modern photovoltaic (PV) setups. The aim of this study was to investigate the efficiency of a low-cost solar tracker fitted with an innovative tracking mechanism to harness solar energy in Mauritius. In this study, a low-cost system was designed to harness solar energy efficiently by virtue of a tracking mechanism based on a novel ball-joint system to provide charging power to portable devices even in remote places. An intelligent charging circuitry was incorporated not only to provide power for any connected devices but also to keep the system running in conditions of low sunlight. The efficiency assessment of the solar tracker was conducted on a real scale prototype, which was constructed by considering off-the-shelf materials to keep an overall low manufacturing cost. Test results showed that the innovative tracking mechanism could successfully track the sun path. This contributed to an overall increase in the nominal power generation of the solar tracker, which was found to be around 15 W in contrast to the static panel which was around 10 W. Moreover, the charging duration of the portable devices from the charging unit in the solar tracker was found to be similar when compared to the one corresponding to direct charge from the mains. The developed and tested prototype in this study has shown the benefits of using a solar tracking device to capture and generate solar energy and clean power respectively which could be further developed and refined on a larger scale for mass commercialization as portable power-generating devices.

摘要太阳能是毛里求斯等热带国家最丰富的可再生能源之一。近年来,人们对在毛里求斯利用太阳能产生了更多兴趣并采取了更多举措。最大限度地利用太阳能的一种方法是考虑使用太阳能跟踪器,它是现代光伏(PV)装置的基本组成部分。本研究的目的是调查配备创新跟踪机制的低成本太阳能跟踪器在毛里求斯利用太阳能的效率。在这项研究中,设计了一种低成本系统,通过基于新型球形接头系统的跟踪机制有效利用太阳能,即使在偏远地区也能为便携式设备提供充电电源。该系统采用了智能充电电路,不仅能为任何连接设备供电,还能在日照不足的条件下保持系统运行。太阳能跟踪器的效率评估是在一个实际规模的原型上进行的,该原型由现成材料制成,以保持较低的总体制造成本。测试结果表明,创新的跟踪机制能够成功地跟踪太阳轨迹。此外,通过太阳能跟踪器的充电装置为便携式设备充电的持续时间与通过电源直接充电的持续时间相近。本研究中开发和测试的原型显示了使用太阳能跟踪装置分别捕获和产生太阳能和清洁电力的好处,可以进一步开发和改进,使其成为大规模商业化的便携式发电装置。
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引用次数: 0
Design and Realization of a Photovoltaic Tracer using DC/DC Converter 利用 DC/DC 转换器设计和实现光伏跟踪器
IF 1.204 Q3 Energy Pub Date : 2024-03-23 DOI: 10.3103/S0003701X23601321
Abdelilah Khlifi, Yamina Khlifi, Mohamed Larbi Elhafyani

This article deals with the characterization of photovoltaic (PV) panels using current-voltage (I–V) tracers. It focuses on the realization of a low cost and real-time I–V tracer that uses an inexpensive DC/DC converter, a fixed load and sensors for measuring current and voltage of the PV Panel. Additionally, a data acquisition interface (DAI) is developed to collect real-time PV data under different weather conditions. The developed tracer reduces testing time for PV panel characterization compared with classical methods. In order to evaluate the performance of the developed tracer, we analyze the electrical parameters to which the electronic equipment is exposed and contrasts the advantages of the suggested technique and disadvantages of the classical method of measurement (i.e., using multimers), taking a variety of criteria including accuracy into account. For further validation, we compare the experimental PV characteristics to the simulated PV curves obtained using a single diode model.

摘要 本文论述了使用电流-电压(I-V)跟踪器对光伏(PV)面板进行表征的问题。文章重点介绍了如何利用廉价的 DC/DC 转换器、固定负载和用于测量光伏板电流和电压的传感器,实现低成本和实时的 I-V 示踪器。此外,还开发了一个数据采集接口(DAI),用于收集不同天气条件下的实时光伏数据。与传统方法相比,所开发的跟踪器缩短了光伏电池板鉴定的测试时间。为了评估所开发示踪器的性能,我们分析了电子设备所面临的电气参数,并对比了所建议技术的优点和传统测量方法(即使用多聚物)的缺点,同时考虑了包括精度在内的各种标准。为了进一步验证,我们将实验光电特性与使用单二极管模型获得的模拟光电曲线进行了比较。
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引用次数: 0
The Role of Specific Interactions in the Formation of Perovskite Structures 特定相互作用在形成包晶结构中的作用
IF 1.204 Q3 Energy Pub Date : 2024-03-05 DOI: 10.3103/S0003701X23601746
I. N. Nurgaliev, M. B. Marasulov, N. R. Ashurov

Using methylammonium lead iodide (MAPbI3) as an example, the process of complexation of molecular particles from solution at the initial stage of crystallization was studied using calculations based on the density functional theory (DFT). The calculations were carried out taking into account solvents widely used in experiments: dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF) and N-methyl-2-pyrrolidone (N-MP) to analyze the structure and energy of iodoplumbate complexes in the form of simple complex [PbImXn]2 – m and polymeric iodoplumbates ([PbImXn]2 – m)x. Reaction schemes for the formation of MAPbI3 in DMSO and DMF solvents, as well as in DMF–DMSO and DMF–N–MP binary solvents, are proposed based on the calculated energies. Calculations showed the important role of NH–O hydrogen bonds in the formation of iodoplumbate monomers, as well as the imbalance of the energies of the complexes at several elementary stages of the reaction in various solvents (the formation of [PbI4Xn]2– is favorable; the formation of [PbI5Xn]3– is slowed down. Mixing a small amount of DMSO with DMF results in a better energy balance and, therefore, potentially better equilibrium in the overall crystallization process, and thus a better quality of the perovskite crystal structure.

摘要 以甲基碘化铅铵(MAPbI3)为例,使用基于密度泛函理论(DFT)的计算方法研究了结晶初期分子颗粒从溶液中络合的过程。计算考虑了实验中广泛使用的溶剂:二甲基亚砜(DMSO)、N,N-二甲基甲酰胺(DMF)和 N-甲基-2-吡咯烷酮(N-MP),分析了简单复合物 [PbImXn]2 - m 和聚合碘铂酸盐([PbImXn]2 - m)x 形式的碘铂酸盐复合物的结构和能量。根据计算得出的能量,提出了在 DMSO 和 DMF 溶剂中,以及在 DMF-DMSO 和 DMF-N-MP 二元溶剂中形成 MAPbI3 的反应方案。计算结果表明,NH-O 氢键在碘铂酸盐单体的形成过程中起着重要作用,而且在各种溶剂中,复合物在反应的几个基本阶段的能量不平衡([PbI4Xn]2- 的形成有利;[PbI5Xn]3- 的形成缓慢。将少量二甲基亚砜与 DMF 混合会导致更好的能量平衡,因此,整个结晶过程可能会达到更好的平衡,从而提高包晶晶体结构的质量。
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引用次数: 0
Studies of Degradation Silicon Heterojunction Solar Cells by 1 MeV Electrons Irradiation 1 MeV 电子辐照下硅异质结太阳能电池的降解研究
IF 1.204 Q3 Energy Pub Date : 2024-03-05 DOI: 10.3103/S0003701X23600984
V. S. Kalinovskii, E. I. Terukov, S. N. Abolmasov, K. K. Prudchenko, E. V. Kontrosh, I. A. Tolkachev, A. V. Kochergin, A. S. Titov, O. K. Ataboev

This article attempts to assess the radiation resistance of heterostructure silicon solar cells to the effects of 1 MeV electrons and discusses their prospects for power supply of the global low-orbit satellite communication system. The data obtained from this study allow us to identify the most promising types of heterostructure silicon solar cells for use in low-orbit spacecraft. These are n-α-Si:H-(p)c-Si:Ga-p-α-Si:H and n-µc-Si:H-(p)c-Si:Ga-p-α-Si:H solar cells. The degradation in efficiency of these structures was less than 30% by 1 × 1015 cm–2 fluence of 1 MeV electrons.

摘要 本文试图评估异质结构硅太阳能电池对 1 MeV 电子影响的抗辐射能力,并讨论其为全球低轨道卫星通信系统供电的前景。通过这项研究获得的数据,我们确定了最有希望用于低轨道航天器的异质结构硅太阳能电池类型。它们是 n-α-Si:H-(p)c-Si:Ga-p-α-Si:H 和 n-µc-Si:H-(p)c-Si:Ga-p-α-Si:H 太阳能电池。在 1 × 1015 cm-2 的 1 MeV 电子通量作用下,这些结构的效率降低不到 30%。
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引用次数: 0
Biogas Production based on Thermophilic Methanogenic Fermentation of Chicken Manure 基于鸡粪嗜热甲烷发酵的沼气生产
IF 1.204 Q3 Energy Pub Date : 2024-03-05 DOI: 10.3103/S0003701X23601874
A. A. Makhsumkhanov, O. M. Pulatova, B. Kh. Alimova, Sh. T. Sadullaev, Sh. A. Tashbaev, A. R. Sarynsakhodzhaev, M. K. Karimov, M. K. Kurbanov, D. Sh. Saidov, U. B. Sharopov, K. Yu. Rashidov, A. Yu. Usmanov, Zh. Z. Shermatov, M. S. Payzullakhanov

The paper presents data on the study of the kinetics of gas formation from chicken manure under thermophilic conditions. It was shown that the volume of biogas for 30 days in the control variant did not exceed 85 dm3, whereas with the addition of 10 and 20% of the balanced thermophilic methanogenic association as an inoculate was 150 and 180 dm3, respectively, and the methane content in the biogas composition reached up to 70 and 65%, respectively. It was shown that bacteria belonging to the Enterobacteriacea family, as well as some pathogenic bacteria and helminths, were not found in the fermentation system under thermophilic conditions.

摘要 本文介绍了在嗜热条件下鸡粪形成气体的动力学研究数据。结果表明,对照变体 30 天的沼气量不超过 85 立方米,而加入 10% 和 20% 的平衡嗜热产甲烷联合体作为接种物后,沼气量分别为 150 立方米和 180 立方米,沼气成分中的甲烷含量分别达到 70% 和 65%。研究表明,在嗜热条件下的发酵系统中没有发现肠杆菌科细菌以及一些病原菌和蠕虫。
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引用次数: 0
Investigating the Performance of Graded Index Nanocomposite-Perovskite Solar Cells 研究分级指数纳米复合材料--Perovskite 太阳能电池的性能
IF 1.204 Q3 Energy Pub Date : 2024-03-05 DOI: 10.3103/S0003701X23600893
Hala J. El-Khozondar, Mohammed M. Shabat

This study presents a novel four-layer solar cell design, composed of NiOx embedded in glass on top of a perovskite layer and SnO2 substrate. Incident light enters through the glass layer and exits through the substrate into the surrounding air. A novel graded index of the composite layer is proposed where the refractive index varies with the vertical distance from the glass interface. Using the Maple program, we calculate the transmittance, reflectance, and absorbance powers of the proposed solar cells, while examining the influence of different parameters on these powers. Our findings indicate that the transmittance, reflection, and absorption powers are sensitive to changes in layer thickness. Specifically, we observe that the absorbance power approaches unity for longer wavelengths while remaining above 0.7 for shorter wavelengths. Furthermore, we propose integrating this cell into a tandem solar cell configuration, where it can complement another cell by providing support in longer wavelengths and high absorbance in shorter wavelengths.

摘要 本研究提出了一种新颖的四层太阳能电池设计,由嵌在玻璃中的 NiOx、过氧化物层和二氧化锡衬底组成。入射光从玻璃层进入,再从衬底射入周围的空气中。我们提出了一种新颖的复合层分级折射率,即折射率随玻璃界面垂直距离的变化而变化。我们使用 Maple 程序计算了拟议太阳能电池的透射率、反射率和吸收率,同时研究了不同参数对这些功率的影响。我们的研究结果表明,透射、反射和吸收功率对层厚度的变化非常敏感。具体来说,我们观察到,在较长的波长下,吸收功率接近于 1,而在较短的波长下,吸收功率保持在 0.7 以上。此外,我们还建议将这种电池集成到串联太阳能电池配置中,通过在较长的波长上提供支持和在较短的波长上提供高吸收率来补充另一种电池。
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引用次数: 0
Critical Review on Various Solar Drying Technologies: Direct and Indirect Solar Dryer Systems 对各种太阳能干燥技术的严格审查:直接和间接太阳能干燥系统
IF 1.204 Q3 Energy Pub Date : 2024-03-05 DOI: 10.3103/S0003701X2360073X
C. N. Deepak, Aruna Kumar Behura

Food industry being one of the world’s largest energy intensive industries, lack of proper preservation and storage techniques have led to huge amount of food losses and wastage. Dehydration of food and vegetables has been an effective technique of preservation as this reduces post-harvest losses, make them easier to transport, store and can prevent the growth of microbes. Abundant solar energy being available for free of cost, solar drying is desirable in terms of environment friendliness, economic benefits and is compatible for remote locations. Solar dryers optimize this process with efficient utilization of solar energy and provides higher quality products. Different configurations of solar dryers with diverse configurations and applications have been designed and implemented over the years. Based on the difference in supply and utilization of solar energy, the most prominent solar dryer configurations are direct and indirect solar dryers. This work intends to review the features, design and performance of existing direct and indirect solar dryers. Major challenges such as intermittency and unsteady availability of solar energy has been addressed through thermal energy storage by many research studies, which has also been effectively reviewed. Materials used for construction, design constraints, thermal energy storage integration and experimental results have been discussed and tabulated. The review revealed highly efficient solar collectors such as tube type absorber and evacuated tube collectors, solar concentrators employed dryers capable of achieving elevated temperatures, greenhouse and solar tent dryers with huge capacity and novel dryer and collector designs of superior performance. Various integration techniques of different thermal energy storage materials and their enhancement in performance were eminently observed in the review. As a source of technological attributes and constructional features, this review paper intends to aid the development of solar dryers and food preservation employing renewable energy.

摘要 食品工业是世界上最大的能源密集型产业之一,缺乏适当的保存和储存技术导致了大量的食品损失和浪费。食品和蔬菜的脱水是一种有效的保存技术,因为它可以减少收获后的损失,使其更易于运输和储存,并能防止微生物的生长。丰富的太阳能可以免费获得,太阳能干燥从环境友好、经济效益和适用于偏远地区的角度来看都是可取的。太阳能干燥器通过有效利用太阳能优化了这一过程,并提供了更高质量的产品。多年来,人们设计并实施了不同配置和应用的太阳能干燥机。根据太阳能供应和利用的不同,最主要的太阳能干燥机配置是直接和间接太阳能干燥机。这项工作旨在回顾现有直接和间接太阳能干燥器的特点、设计和性能。许多研究已通过热能储存解决了太阳能间歇性和不稳定性等主要挑战,本研究也对这些挑战进行了有效审查。研究还讨论了建筑材料、设计限制、热能储存集成和实验结果,并将其列表。综述揭示了高效太阳能集热器(如管式吸收器和真空管集热器)、采用太阳能聚光器的能达到高温的干燥器、容量巨大的温室和太阳能帐篷干燥器以及性能优越的新型干燥器和集热器设计。综述中还详细介绍了不同热能储存材料的各种集成技术及其性能的提高。作为技术属性和结构特征的来源,本综述论文旨在帮助开发太阳能干燥器和利用可再生能源保存食物。
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引用次数: 0
Analysis of Degradation and Performance Changes of the Pap-Namangan Solar Photovoltaic Plant Pap-Namangan 太阳能光伏发电厂的退化和性能变化分析
IF 1.204 Q3 Energy Pub Date : 2024-03-05 DOI: 10.3103/S0003701X23601497
U. O. Odamov, M. M. Kamilov, Sh. K. Niyazov, A. Kutlimratov

This article presents the results of degradation studies and performance changes (for 7 years) of solar panels of a solar photovoltaic plant located in the Pap district of the Namangan region of Uzbekistan using the IEC 61724 standard. The solar photovoltaic plant is located in a zone of sharp continental climate, built from polycrystalline photovoltaic panels and has a power of 130 kW. The analysis of monitoring system data showed that the average degradation rate of solar panels is 0.224%/year, which is comparable to the values obtained by the same method for other power plants with similar characteristics. The degradation value is determined from the slope of the annual temperature-adjusted productivity factor. The annual productivity ratio varies from 75.89 to 93.54%, depending on the season, i.e., the value is higher in spring and summer, lower in autumn and winter, with an average value of 87.22%. The average annual changes in the reference and final generation are 4.12 and 3.67 h, respectively.

摘要 本文介绍了采用 IEC 61724 标准对位于乌兹别克斯坦纳曼干州帕普区的太阳能光伏电站的太阳能电池板进行降解研究和性能变化(7 年)的结果。该太阳能光伏发电站位于大陆性气候区,由多晶硅光伏板建成,功率为 130 千瓦。对监测系统数据的分析表明,太阳能电池板的平均衰减率为 0.224%/年,与其他具有类似特性的发电厂通过相同方法获得的数值相当。衰减值是根据年温度调整生产率系数的斜率确定的。年生产率从 75.89% 到 93.54% 不等,取决于季节,即春夏季较高,秋冬季较低,平均值为 87.22%。参考世代和最终世代的年平均变化时间分别为 4.12 和 3.67 h。
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引用次数: 0
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Applied Solar Energy
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