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Laser ablation analysis of bivalve shells – archives of environmental information 双壳类动物的激光烧蚀分析——环境信息档案
Q2 Earth and Planetary Sciences Pub Date : 2008-07-01 DOI: 10.34194/geusb.v15.5052
M. Kluender, D. Hippler, R. Witbaard, D. Frei
Reconstructing past secular environmental variations is an important issue in palaeoclimate research. However, most key variables for palaeoclimate reconstructions cannot be measured directly, and reconstructions are therefore based on proxy data. Here, we demonstrate the potential of bivalve shells as an archive of environmental parameters. The Geo lo gical Survey of Denmark and Greenland (GEUS) has developed a fast and reliable method for chemical analyses of shell material by laser ablation - inductively coupled plasma - mass spectrometry (LA-ICP-MS), and here we present some ex amples of the use of this method. In tropical and subtropical waters, corals can provide century-long archives of past water chemistry with annual resolution. A comparable archive for temperate and Arctic waters would be highly useful in climate research, and therefore it has been examined whether this can be provided by bivalve shells (e.g. Schoene et al. 2005). Long-lived species may provide archives with annual resolution extending over several hundred years, whereas short-lived, fast-growing species can provide archives with a seasonal or in some cases daily resolution over a period of a few years. Most bivalves are sessile, and shells are commonly preserved as fossils. There are, however, a number of challenges related to the use of bivalves as proxy archives: (1) many proxies show species specific behaviour (Seed 1980); (2) only very few proxies are dependent on a single variable (Wefer et al. 1999); and (3) the effects of biology and ontogeny on the uptake of trace elements and stable isotope fractionation in shell carbonate are largely unknown and have to be evaluated empirically. Therefore, any potential proxy must be calibrated individually for each species of interest before it can be used. A large number of chemical analyses are needed to calibrate a proxy. These are commonly obtained by solution ICP-MS, in which sample preparation is time-consuming and labour-intensive. The use of LA-ICP-MS is therefore a considerable advance in bivalve shell proxy research, as it greatly reduces the effort needed for sample preparation. At the same time, the method requires less material for analysis, thus providing better spatial and hence temporal resolution. Proxies based on bivalve shell carbonate can be used in present-day environmental monitoring, and for environmental reconstructions from shells found as fossils. Shells from museum collections and shells found in archaeological middens can give information on historic and prehistoric environmental conditions (e.g. Carrell et al. 1987), and fossil shells can be used as archives of environmental parameters on geological timescales (e.g. Hendry et al. 2001).
重建过去的长期环境变化是古气候研究中的一个重要问题。然而,古气候重建的大多数关键变量不能直接测量,因此重建是基于代理数据的。在这里,我们展示了双壳类贝壳作为环境参数档案的潜力。丹麦和格陵兰地质调查局(GEUS)开发了一种快速可靠的方法,即激光烧蚀-电感耦合等离子体质谱法(LA-ICP-MS),用于壳材料的化学分析,在这里我们介绍了一些使用该方法的例子。在热带和亚热带水域,珊瑚可以提供长达一个世纪的过去的水化学档案,每年分辨率。温带和北极水域的可比档案将在气候研究中非常有用,因此已经研究了双壳类贝壳是否可以提供这种档案(例如Schoene et al. 2005)。寿命长的物种可以提供长达几百年的年度分辨率,而寿命短、生长迅速的物种可以提供季节性分辨率,在某些情况下可以提供几年的日常分辨率。大多数双壳类是无柄的,壳通常作为化石保存下来。然而,使用双壳类作为代理档案存在许多挑战:(1)许多代理显示物种特有的行为(Seed 1980);(2)只有极少数代理依赖于单一变量(Wefer et al. 1999);(3)生物和个体发育对贝壳碳酸盐中微量元素吸收和稳定同位素分馏的影响在很大程度上是未知的,需要进行经验评估。因此,任何潜在的代理都必须针对每个感兴趣的物种单独校准,然后才能使用。校准代理需要大量的化学分析。这些通常是通过溶液ICP-MS获得的,其中样品制备是耗时和劳动密集型的。因此,LA-ICP-MS的使用在双壳类代理研究中是一个相当大的进步,因为它大大减少了样品制备所需的工作量。同时,该方法需要较少的分析材料,从而提供更好的空间和时间分辨率。基于双壳类碳酸盐岩的代用物可用于当今的环境监测,也可用于化石壳的环境重建。博物馆收藏的贝壳和考古堆中发现的贝壳可以提供历史和史前环境条件的信息(例如Carrell et al. 1987),化石贝壳可以作为地质时间尺度上的环境参数档案(例如Hendry et al. 2001)。
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引用次数: 20
Provenance of Cretaceous and Paleocene sandstones in the West Greenland basins based on detrital zircon dating 基于碎屑锆石定年的西格陵兰盆地白垩纪和古新世砂岩物源
Q2 Earth and Planetary Sciences Pub Date : 2007-10-12 DOI: 10.34194/GEUSB.V13.4969
A. Schersten, M. Sønderholm
The extensive and very deep ?Jurassic/Cretaceous–Palaeogene sedimentary basins offshore West Greenland have a significant petroleum exploration potential. This is particularly true for the offshore region west of Disko and Nuussuaq where a live petroleum system has been documented for many years. At present, stratigraphic knowledge in this area is almost nonexistent and analogue studies from onshore areas and offshore exploration wells to the south are therefore crucial to understanding the distribution and quality of possible reservoir rocks in the Disko–Nuussuaq offshore area. One of the main risk parameters in petroleum exploration in this region is the presence of an adequate reservoir rock. Tectonostratigraphic considerations suggest that several sand-prone stratigraphic levels are probably present, but their provenance and reservoir quality are at present poorly known both onshore and offshore. A sediment provenance study including zircon provenance U-Pb dating and wholerock geochemical analysis was therefore initiated by the Geological Survey of Denmark and Greenland (GEUS) in preparation for the Disko West Licensing Round 2006 (Schersten et al. 2007). The main aims of this study were to: 1. Characterise the source areas and dispersal patterns for the various sandstone units of Cretaceous–Paleocene age in the Nuussuaq Basin and compare these with sandstone units in selected West Greenland offshore exploration wells (Figs 1, 2), employing advanced zircon provenance U-Pb dating using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS; cf. Frei et al. 2006). 2. Detect possible changes in sediment source with time, e.g. local versus regional sources. Zircon as a provenance tool is receiving increasing attention and has proven to be a powerful indicator of clastic sediment sources, a tracer of the Earth’s oldest materials, and a tracer of continental crust-forming processes (Froude et al. 1983; Williams & Claesson 1987; Dodson et al. 1988; Fedo et al. 2003; Hawkesworth & Kemp 2006). Zircon is common in continental rocks and it is assumed that its distribution in sediments will normally represent the source rocks. Although there are several complications, the sediment zircon U-Pb age frequency should in general terms mirror the relative proportions of different source materials. This assumption is particularly important if exotic components can be identified, as their frequency will provide an estimate of the exotic influx: it may also be essential in tracing sediment paths that affect the detrital compositions and subsequent diagenetic history of possible hydrocarbon reservoir rocks.
西格陵兰近海侏罗系/白垩系-古近系广泛而深的沉积盆地具有重要的油气勘探潜力。在Disko和Nuussuaq以西的近海地区尤其如此,在那里,多年来一直有油气系统的记录。目前,该地区的地层学知识几乎不存在,因此,从陆上和海上探井进行的模拟研究对于了解Disko-Nuussuaq海上地区可能的储层岩石的分布和质量至关重要。该地区油气勘探的主要风险参数之一是是否存在足够的储集岩。构造地层学方面的考虑表明,可能存在几个易砂地层,但它们的来源和储层质量目前在陆上和海上都知之甚少。因此,丹麦和格陵兰地质调查局(GEUS)启动了沉积物物源研究,包括锆石物源U-Pb测年和整体岩石地球化学分析,为2006年迪斯科西部许可轮做准备(Schersten et al. 2007)。本研究的主要目的是:1。利用先进的锆石物源U-Pb测年技术(激光烧蚀感应耦合等离子体质谱法(LA-ICP-MS)),对Nuussuaq盆地白垩纪-古新世不同砂岩单元的源区和扩散模式进行了表征,并与选定的西格陵兰海上探井的砂岩单元进行了比较(图1、2);参见Frei et al. 2006)。2. 探测沉积物来源随时间可能发生的变化,例如,本地来源与区域来源。锆石作为一种物源工具正受到越来越多的关注,并已被证明是碎屑沉积物来源的有力指示物,是地球最古老物质的示踪剂,也是大陆地壳形成过程的示踪剂(Froude et al. 1983;Williams & Claesson 1987;Dodson et al. 1988;Fedo et al. 2003;Hawkesworth & Kemp 2006)。锆石普遍存在于陆相岩石中,一般认为其在沉积物中的分布代表了烃源岩。虽然存在一些复杂因素,但沉积物锆石U-Pb年龄频率总体上反映了不同源物质的相对比例。如果能够识别出外来成分,这一假设就尤为重要,因为它们的频率将提供对外来流入的估计;对于追踪影响碎屑组成和随后可能的烃储集岩成岩历史的沉积物路径,这一假设也可能至关重要。
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引用次数: 12
Lithostratigraphy of the Palaeogene – Lower Neogene succession of the Danish North Sea 丹麦北海古近纪-下新近纪演替的岩石地层学
Q2 Earth and Planetary Sciences Pub Date : 2007-06-29 DOI: 10.34194/GEUSB.V12.5249
P. Schiøler, J. Andsbjerg, O. Clausen, G. Dam, K. Dybkjær, L. Hamberg, C. Heilmann-Clausen, E. Johannessen, Lars Kristensen, I. Prince, J. A. Rasmussen
As a result of a lithological, sedimentological and biostratigraphic study of well sections from the Danish sector of the North Sea, including some recently drilled exploration wells on the Ringkobing–Fyn High, the lithostratigraphic framework for the siliciclastic Palaeogene to Lower Neogene sediments of the Danish sector of the North Sea is revised. The sediment package from the top of the Chalk Group to the base of the Nordland Group is subdivided into seven formations containing eleven new members. The existing Vale, Lista, Sele, Fur, Balder, Horda and Lark Formations of previously published lithostratigraphic schemes are adequate for a subdivision of the Danish sector at formation level. Bor is a new sandstone member of the Vale Formation. The Lista Formation is subdivided into three new mudstone members: Vile, Ve and Bue, and three new sandstone members: Tyr, Idun and Rind. Kolga is a new sandstone member of the Sele Formation. Hefring is a new sandstone member of the Horda Formation. Freja and Dufa are two new sandstone members of the Lark Formation. Danish reference sections are established for the formations, and the descriptions of their lithology, biostratigraphy, age and palaeoenvironmental setting are updated.
通过对北海丹麦部分(包括最近在Ringkobing-Fyn高地钻探的一些探井)井段的岩性、沉积学和生物地层学研究,对北海丹麦部分古近纪至下新近纪的硅质碎屑沉积物的岩石地层格架进行了修订。从白垩组顶部到Nordland组底部的沉积物包被细分为包含11个新成员的7个地层。现有的Vale组、Lista组、Sele组、Fur组、Balder组、Horda组和Lark组的先前公布的岩石地层方案足以在地层水平上对丹麦部门进行细分。Bor是Vale组一个新的砂岩成员。Lista组划分为3个新泥岩段:Vile、Ve和Bue, 3个新砂岩段:Tyr、Idun和Rind。Kolga是Sele组一个新的砂岩成员。Hefring是Horda组一个新的砂岩成员。Freja和Dufa是云雀组的两个新砂岩成员。为这些地层建立了丹麦参考剖面,并更新了它们的岩性、生物地层学、年龄和古环境背景的描述。
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引用次数: 80
Magnetic anomalies and metamorphic boundaries in the southern Nagssugtoqidian orogen, West Greenland 西格陵兰南那格苏木托起甸造山带的磁异常与变质界
Q2 Earth and Planetary Sciences Pub Date : 2006-12-05 DOI: 10.34194/GEUSB.V11.4930
J. Korstgård, B. M. Stensgaard, T. Rasmussen
Within the southern Nagssugtoqidian orogen in West Greenland metamorphic terrains of both Archaean and Palaeoproterozoic ages occur with metamorphic grade varying from low amphibolite facies to granulite facies. The determination of the relative ages of the different metamorphic terrains is greatly aided by the intrusion of the 2 Ga Kangâmiut dyke swarm along a NNE trend. In Archaean areas dykes cross-cut gneiss structures, and the host gneisses are in amphibolite to granulite facies. Along Itilleq strong shearing in an E–W-oriented zone caused retrogression of surrounding gneisses to low amphibolite facies. Within this Itivdleq shear zone Kangâmiut dykes follow the E–W shear fabrics giving the impression that dykes were reoriented by the shearing. However, the dykes remain largely undeformed and unmetamorphosed, indicating that the shear zone was established prior to dyke emplacement and that the orientation of the dykes here was governed by the shear fabric. Metamorphism and deformation north of Itilleq involve both dykes and host gneisses, and the metamorphic grade is amphibolite facies increasing to granulite facies at the northern boundary of the southern Nagssugtoqidian orogen. Here a zone of strong deformation, the Ikertoq thrust zone, coincides roughly with the amphibolite–granulite facies transition. Total magnetic field intensity anomalies from aeromagnetic data coincide spectacularly with metamorphic boundaries and reflect changes in content of the magnetic minerals at facies transitions. Even the nature of facies transitions is apparent. Static metamorphic boundaries are gradual whereas dynamic boundaries along deformation zones are abrupt.
西格陵兰南那萨木托起甸造山带内发育太古宙和古元古代变质地,变质等级从低角闪岩相到麻粒岩相不等。2 Ga康- 米乌特岩脉群沿北北东向侵入对不同变质地形的相对年龄的确定有很大帮助。太古宙岩脉横切片麻岩构造,寄主片麻岩为角闪岩—麻粒岩相。沿Itilleq,东西向强烈剪切带使周围片麻岩向低角闪岩相退退。在Itivdleq剪切带内,康米乌特岩脉沿东西向剪切构造,给人以岩脉被剪切重新定向的印象。然而,岩脉基本保持未变形和未变质状态,表明剪切带在岩脉就位前就已形成,岩脉的走向受剪切构造支配。伊蒂勒克北部变质变形涉及岩脉和赋矿片麻岩,变质等级为角闪岩相,在南纳苏托起甸造山带北界向麻粒岩相过渡。这里有一个强烈的变形带,即伊克托克逆冲带,与角闪岩-麻粒岩相转变大致重合。航磁资料的总磁场强度异常与变质边界极为吻合,反映了相转变时期磁性矿物含量的变化。甚至连相转变的性质也很明显。静态变质边界是渐进性的,而沿变形带的动态边界是突发性的。
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引用次数: 3
Precambrian crustal evolution and Cretaceous–Palaeogene faulting in West Greenland: Structural analysis of the northern Nagssugtoqidian orogen, West Greenland: an example of complex tectonic patterns in reworked high-grade metamorphic terrains 西格陵兰前寒武纪地壳演化与白垩纪-古近纪断裂:西格陵兰纳格苏托奇甸造山带北部的构造分析:一个改造后的高级变质地的复杂构造模式的例子
Q2 Earth and Planetary Sciences Pub Date : 2006-12-01 DOI: 10.34194/GEUSB.V11.4929
S. Mazur, S. Piazolo, G. Ian Alsop
Structural analysis of the deeply eroded northern flank of the Palaeoproterozoic Nagssugtoqidian orogen shows marked regional variations in both the orientation and type of fabrics, as is characteristic of Precambrian high-grade terrains subjected to polyphase deformation. Here we investigate the relationship between strain, metamorphic grade, and the resulting structural patterns. The study area south of Aasiaat in West Greenland consists of amphiboliteto granulite-grade Archaean orthogneisses and relatively thin supracrustal units. The regional foliation displays a WSW–ENE to SW–NE strike associated with steep to moderate dips towards the WNW or SSE. Lineation trends are WSW–ENE and generally plunge gently towards the WSW. Mesoscopic fold hinges are usually colinear with the regional lineation. A systematic change in the plunge of lineations occurs across the south-western part of the study area. Towards the south, the lineation plunge progressively increases, despite the generally uniform strike of foliation. This southward increase of lineation pitch is typically associated with the transition from L > S or L = S shape fabrics in rocks characterised by a low pitch, to S > L or S fabrics in the zone of moderate to high pitch. The structural patterns point to subdivision of the study area into a southern domain mostly characterised by S or S > L shape fabrics and a moderate to high angle of lineation pitch, and a northern domain showing L > S or L = S fabrics and low angles of lineation pitch. This subdivision corresponds well with the map scale boundary between granulite facies rocks in the south and amphibolite facies rocks farther north. The observed structural pattern may be explained by two alternative tectonic models: (1) northward indentation of the previously cooled granulite block into the rheologically weaker amphibolite domain, and (2) strain partitioning within a mid-crustal transpression zone. In model 2 the northern domain represents a localised zone dominated by strike-slip kinematics, whereas the southern domain shows evidence of mostly coaxial shortening. Recent geochronology supports the indentator model in spite of limited available data. Despite the details and structural complexities of the two tectonic models, the granulite and amphibolite facies domains seem to form autochthonous segments of a crustal section linked by a transitional zone that was only reactivated and reworked during indentation or transpression. The Nagssugtoqidian compression was effectively transferred across this zone towards the northern amphibolite domain that suffered penetrative deformation during the Palaeoproterozoic event. The N–S shortening was accommodated through folding, indentation and/or strike-slip displacements, rather than by thrusting and folding as seen south of the study area.
对古元古代那杉托起甸造山带北翼深蚀构造的构造分析表明,构造的方位和类型具有明显的区域差异,是前寒武纪多期变形高等级地形的特征。在这里,我们研究了应变、变质等级和由此产生的结构模式之间的关系。亚洲以南西格陵兰研究区由角闪岩-麻粒岩级太古宙正长岩和相对较薄的上地壳单元组成。区域叶理作用表现为西东—东偏东至西东—北东向,并伴有向西西北或南西方向陡倾至中倾。线理趋势为WSW - ene,一般向WSW方向缓慢倾斜。介观褶皱铰链通常与区域线形共线。研究区的西南地区出现了线状突降的系统性变化。向南方向,尽管面理的走向大致一致,但线理突逐渐增大。这种向南的线理螺距增加,主要与低音高的岩石中的L > L或L = S型组布向中高音高区的S > L或S型组布过渡有关。构造模式表明研究区划分为南区以S或S > L型织物为主,线距角适中至较高,北区以L > S或L = S织物为主,线距角较低。这一划分与南部麻粒岩相岩和北部角闪岩相岩的地图尺度界线吻合较好。观察到的构造模式可以用两种不同的构造模式来解释:(1)先前冷却的麻粒岩块向北压入流变较弱的角闪岩域;(2)中地壳变形带内的应变分配。在模型2中,北部地区代表一个局部区域,主要是走滑运动,而南部地区则显示出主要是同轴缩短的证据。尽管现有资料有限,但最近的地质年代学支持压痕模型。尽管两种构造模式的细节和结构复杂,麻粒岩和角闪岩相域似乎形成了一个由过渡带连接的地壳剖面的原生片段,该过渡带仅在压陷或坳陷期间被重新激活和改造。在古元古代事件中,纳苏托祁甸挤压作用有效地转移到北角闪岩域,并发生了渗透变形。南北向缩短是通过褶皱、压痕和/或走滑位移来调节的,而不是像研究区南部那样通过逆冲和褶皱来调节的。
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引用次数: 9
Precambrian crustal evolution and Cretaceous–Palaeogene faulting in West Greenland: Evolution of Neoarchaean supracrustal belts at the northern margin of the North Atlantic Craton, West Greenland 西格陵兰前寒武纪地壳演化与白垩纪-古近纪断裂:西格陵兰北大西洋克拉通北缘新太古代表壳带演化
Q2 Earth and Planetary Sciences Pub Date : 2006-12-01 DOI: 10.34194/geusb.v11.4914
B. M. Stensgaard, M. Keiding, J. Hollis, J. V. Gool, A. Garde
The Archaean North Atlantic Craton of West Greenland collided at c. 1.9 Ga with a lesser-known Archaean craton to the north, to form the Nagssugtoqidian orogen. The Palaeoproterozoic metamorphic grade and strain intensity decrease northward through the orogen, allowing investigation of the reworked Archaean components in its northern part. Two Archaean supracrustal belts in this region – the Ikamiut and Kangilinaaq belts – are investigated here using field mapping, aeromagnetic data, zircon geochronology, and geochemistry. Both belts comprise quartzo-feldspathic and pelitic metasedimentary rocks, amphibolite, and minor calc-silicate rocks, anorthosite and ultramafic rocks. PbPb and U-Pb dating of detrital zircons and host orthogneisses suggest deposition at c. 2800 Ma (Kangilinaaq belt) and after 2740 Ma (Ikamiut belt); both belts have zircons with Neoarchaean metamorphic rims. Metasedimentary rocks and orthogneisses at Ikamiut share similar steep REE signatures with strong LREE enrichment, consistent with local derivation of the sediment and deposition directly onto or proximal to the regional orthogneiss precursors. Zircon age data from Kangilinaaq indicate both local and distal sources for the sediment there. Geochemical data for Kangilinaaq amphibolites indicate bimodal, mixed felsic–mafic source rocks with island-arc basaltic affinities, consistent with a shelf or arc setting. Both belts experienced a similar tectono-metamorphic history involving Neoarchaean amphibolite facies peak metamorphism at c. 2740–2700 Ma, possibly due to continued emplacement of tonalitic and granodioritic magmas. Nagssugtoqidian lower amphibolite facies metamorphism at c. 1850 Ma was associated with development of the large-scale F 2 folds and shear zones that control the present outcrop pattern. The observed differences in the sources of the Kangilinaaq and Ikamiut belts and their shared post-Archaean history suggest they were formed in different Neoarchaean environments proximal to and on a continental plate, and were amalgamated in a convergent margin setting shortly after their deposition.
西格陵兰岛的太古代北大西洋克拉通在约1.9 Ga与北部一个不太为人所知的太古代克拉通碰撞,形成了那苏木托起甸造山带。古元古代的变质等级和应变强度通过造山带向北降低,使其北部的太古代成分得以重新改造。本文利用野外填图、航磁资料、锆石年代学和地球化学等方法,对该地区两个太古宙上地壳带Ikamiut和Kangilinaaq进行了研究。这两个带包括石英长石和泥质变质沉积岩、角闪岩和少量钙硅酸盐岩石、斜长岩和超镁铁质岩石。碎屑锆石的PbPb和U-Pb定年和寄主正交性表明沉积时间约为2800 Ma (Kangilinaaq带)和2740 Ma (Ikamiut带)之后;两个带都有新太古代变质边缘的锆石。伊kamiut地区的变质沉积岩和正长岩具有相似的陡稀土特征,且LREE富集较强,这与沉积物的局部衍生和直接沉积在区域正长岩前体上或近端一致。康基利纳克的锆石年龄数据表明,那里的沉积物既有本地来源,也有远端来源。康基利纳克角闪岩地球化学资料显示双峰型、英基性混合烃源岩具有岛弧玄武岩亲缘关系,符合陆架或弧背景。两个带都经历了相似的构造变质史,包括在约2740-2700 Ma的新太古代角闪岩相变质高峰,可能是由于调性和花岗闪长岩岩浆的持续侵位。那苏托祁甸下角闪岩相变质作用与控制现今露头格局的大型f2褶皱和剪切带的发育有关。从观测到的Kangilinaaq带和Ikamiut带的物源差异以及它们共同的后太古代历史来看,它们形成于不同的新太古代环境,分别靠近大陆板块和在大陆板块上,并在沉积后不久融合在一个辐合边缘环境中。
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引用次数: 10
Stratigraphy and palaeoceanography of upper Maastrichtian chalks, southern Danish Central Graben 丹麦中央地堑南部上马斯特里赫特白垩岩的地层学和古海洋学
Q2 Earth and Planetary Sciences Pub Date : 2006-11-29 DOI: 10.34194/GEUSB.V10.4870
J. Ineson, B. Buchardt, S. Lassen, J. A. Rasmussen, P. Schiøler, N. Schovsbo, E. Sheldon, F. Surlyk
reservoirs in the Danish sector of the North Sea and have been intensively studied, yet their lithological uniformity can frustrate attempts to develop a high-resolution stratigraphic subdivision and a genetic understanding of the factors controlling production and sedimentation of the pelagic carbonate ooze. Recent research into these topics, supported by the Danish Energy Authority, was carried out by the Geological Survey of Denmark and Greenland (GEUS) in collaboration with the Geological Institute, University of Copenhagen by means of a multidisciplinary study involving quantitative/semiquantitative palynology, micropalaeontology (nannofossils, foraminifers) and isotope geochemistry, integrated with detailed sedimentology. Two key wells were selected, the M-10X well from the Dan Field and the E-5X well from the Tyra SE Field (Fig. 1), based on the extensive core coverage in these wells and on their position in the southern part of the Danish Central Graben where evidence of large-scale resedimentation (and consequent stratigraphic complexity) is uncommon within the Maastrichtian section. In focusing on such a pelagic carbonate system, the ultimate aim is a holistic understanding of the marine system including temperature variation, nutrient supply and distribution, salinity, watermass layering, circulation and oxygen distribution. All these factors influence organic productivity and thus the accumulation of biogenic sediment. This study concentrated on a number of palaeoceanographic signals that can be derived from the sedimentary record, summarised in Fig. 2. Planktonic organisms, both phytoplankton (e.g. coccolithophores, some dinoflagellates) and zooplankton (e.g. foraminifers) provide a record of conditions in the upper watermasses, largely within the photic zone, while bottom conditions are indicated by epifaunal/infaunal organisms (e.g. benthic foraminifers) and bioturbation, and by the sedimentological evidence of depositional processes at the sea floor. On a larger scale, the input of terrestrial organic material relative to the marine component can provide an indirect measure of shoreline migration and thus relative sea-level change, a factor that is also reflected in the δ13C isotopic composition of the seawater, as recorded by the biogenic carbonate ooze.
在北海丹麦部分的储层中,已经对其进行了深入的研究,然而,它们的岩性均匀性可能会阻碍开发高分辨率地层细分和对上层碳酸盐软泥的生产和沉积控制因素的遗传学理解。丹麦和格陵兰地质调查局(GEUS)与哥本哈根大学地质研究所合作,在丹麦能源局的支持下,对这些问题进行了最近的研究,通过一项涉及定量/半定量孢粉学、微体古生物学(纳米化石、有孔虫)和同位素地球化学的多学科研究,结合了详细的沉积学。选择了两个关键井,Dan油田的M-10X井和Tyra SE油田的E-5X井(图1),这是基于这些井的广泛岩心覆盖范围,以及它们位于丹麦中央地堑的南部,在马斯特里希特剖面中,大规模再沉积(及其导致的地层复杂性)的证据并不常见。关注这样一个远洋碳酸盐岩系统,最终目的是全面了解海洋系统,包括温度变化、营养供应和分布、盐度、水团分层、循环和氧气分布。所有这些因素都影响有机生产力,从而影响生物沉积物的积累。这项研究集中在一些可以从沉积记录中得到的古海洋学信号上,如图2所示。浮游生物,浮游植物(如球石藻,一些鞭毛藻)和浮游动物(如有孔虫)提供了上层水体条件的记录,主要是在光带内,而底部条件则由底栖/水生生物(如底栖有孔虫)和生物扰动以及海底沉积过程的沉积学证据表明。在更大的尺度上,陆相有机质相对于海洋组分的输入可以间接测量海岸线迁移,从而测量相对海平面变化,这一因素也反映在海水的δ13C同位素组成中,如生物成因碳酸盐软泥所记录的。
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引用次数: 5
Advanced in situ geochronological and trace element microanalysis by laser ablation techniques 采用激光烧蚀技术进行原位年代学和微量元素分析
Q2 Earth and Planetary Sciences Pub Date : 2006-11-29 DOI: 10.34194/GEUSB.V10.4884
D. Frei, J. Hollis, A. Gerdes, D. Harlov, Christine Karlsson, P. Vásquez, Ferhard Franz, L. Johansson, C. Knudsen
Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) was developed in 1985 and the first commercial laser ablation systems were introduced in the mid 1990s. Since then, LA-ICP-MS has become an important analytical tool in the earth sciences. Initially, the main interest for geologists was in its ability to quantitatively determine the contents of a wide range of elements in many minerals at very low concentrations (a few ppm and below) with relatively high spatial resolution (spot diameters of typically 30–100 μm). The potential of LA-ICP-MS for rapid in situ U–Th–Pb geochronology was already realised in the early to mid 1990s. However, the full potential of LA-ICP-MS as the low-cost alternative to ion-microprobe techniques for highly precise and accurate in situ U–Th–Pb age dating was not realised until the relatively recent advances in laser technologies and the introduction of magnetic sectorfield ICP-MS (SF-ICPMS) instruments. In March 2005, the Geological Survey of Denmark and Greenland (GEUS) commissioned a new laser ablation magnetic sectorfield inductively coupled plasma mass spectrometry (LA-SF-ICP-MS) facility employing a ThermoFinnigan Element2 high resolution magnetic sectorfield ICP-MS and a Merchantek New Wave 213 nm UV laser ablation system. The new GEUS LA-SF-ICP-MS facility is widely used on Survey research projects in Denmark and Greenland, as well as in collaborative research and contract projects conducted with partners from academia and industry worldwide. Here, we present examples from some of the these ongoing studies that highlight the application of the new facility for advanced geochronological and trace element in situ microanalysis of geomaterials. The application of LASF-ICP-MS based in situ zircon geochronology to regional studies addressing the Archaean geology of southern West Greenland is presented by Hollis et al. (2006, this volume).
激光烧蚀电感耦合等离子体质谱法(LA-ICP-MS)于1985年发展起来,第一个商用激光烧蚀系统在20世纪90年代中期推出。从那时起,LA-ICP-MS已成为地球科学中重要的分析工具。最初,地质学家的主要兴趣在于它能够以相对较高的空间分辨率(斑点直径通常为30-100 μm)在非常低的浓度(几ppm及以下)下定量确定许多矿物中各种元素的含量。LA-ICP-MS在快速原位U-Th-Pb地质年代学方面的潜力早在20世纪90年代初至中期就已实现。然而,LA-ICP-MS作为离子微探针技术的低成本替代品,用于高精度和准确的原位U-Th-Pb年龄测定的全部潜力直到激光技术的相对最新进展和磁场ICP-MS (SF-ICPMS)仪器的引入才得以实现。2005年3月,丹麦和格陵兰地质调查局(GEUS)委托了一个新的激光烧蚀磁场电感耦合等离子体质谱(LA-SF-ICP-MS)设备,该设备采用ThermoFinnigan Element2高分辨率磁场ICP-MS和mertek new Wave 213 nm紫外激光烧蚀系统。新的GEUS LA-SF-ICP-MS设备广泛用于丹麦和格陵兰岛的调查研究项目,以及与全球学术界和工业界合作伙伴进行的合作研究和合同项目。在这里,我们从这些正在进行的研究中举出一些例子,这些研究突出了新设备在地质材料的先进地质年代学和微量元素原位微分析中的应用。Hollis等人(2006年,本卷)介绍了基于原位锆石年代学的LASF-ICP-MS在西格陵兰岛南部太古宙地质区域研究中的应用。
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引用次数: 21
Review of Survey Activities 2005: Earthquake seismology in Greenland – improved data with multiple applications 2005年调查活动回顾:格陵兰地震地震学——改进的数据与多种应用
Q2 Earth and Planetary Sciences Pub Date : 2006-11-01 DOI: 10.34194/geusb.v10.4910
T. Larsen, T. Dahl-Jensen, P. Voss, T. Jørgensen, S. Gregersen, H. P. Rasmussen
Earthquake seismology is a rapidly evolving field that has provided a wealth of new information about deep geological structures on a regional scale over the last decade as well as information about dynamic processes in the Earth. A major leap forward was the development of portable digital broad band (BB) seismographs around 1990. Without any changes in configuration, these are able to record the signals from large distant earthquakes, as well as the signals from weak local events. BB seismographs typically cover a frequency range from 0.0083 Hz to 50 Hz, making them useful for studies ranging from the high frequency signals from explosions to the very low frequency oscillations following major earthquakes. The first seismological observatory in Greenland was established in 1907 in Qeqertarsuaq (GDH) and was in service for about five years (Hjelme 1996). Later, seismographs were established in Ivittut (1927) and Illoqqortoormiut (1928; SCO), and the network has been regularly upgraded and expanded ever since (Fig. 1). Prior to the development of BB seismographs, each station was equipped with a set of seismographs with different frequency sensitivities in an attempt to cover both distant and local earthquakes. Now just one small instrument is needed at each location. The Geological Survey of Denmark and Greenland (GEUS) operates four permanent BB seismographs in Greenland (Fig. 1), two of them in collaboration with foreign institutions. In addition to the permanent network, there are currently 13 temporary BB seismographs active in Greenland, of which eight are operated by GEUS. Three of the temporary seismograph stations were established as part of the Danish Continental Shelf Project (Marcussen et al. 2004), and the remainder in connection with research projects. Three temporary seismographs were deployed during 2005 as part of a research project aiming to resolve very deep regional structures in North Greenland: the Citronen Fjord station (CFJ, Continental Shelf Project), and the stations in Kullorsuaq (KUL) and Daneborg (DBG).
地震地震学是一个迅速发展的领域,在过去的十年中,它提供了丰富的关于区域范围内深部地质结构的新信息,以及关于地球动力学过程的信息。一个重大的飞跃是1990年左右便携式数字宽带(BB)地震仪的发展。在没有任何配置改变的情况下,这些仪器能够记录来自远距离大地震的信号,以及来自本地弱地震的信号。BB地震仪通常覆盖的频率范围从0.0083赫兹到50赫兹,这使得它们对从爆炸的高频信号到大地震后的低频振荡的研究都很有用。格陵兰的第一个地震观测站于1907年在Qeqertarsuaq (GDH)建立,并服务了大约5年(Hjelme 1996)。后来,在伊维图特(1927年)和伊洛科托米特(1928年)建立了地震仪;(图1)。在研制BB地震仪之前,每个台站都配备了一套不同频率灵敏度的地震仪,试图同时覆盖远震和局地地震。现在每个地点只需要一个小仪器。丹麦和格陵兰地质调查局(GEUS)在格陵兰运行着四台永久BB地震仪(图1),其中两台是与外国机构合作的。除了永久台网外,格陵兰岛目前有13个临时BB地震仪,其中8个由GEUS操作。其中三个临时地震仪站是作为丹麦大陆架项目(Marcussen et al. 2004)的一部分建立的,其余的与研究项目有关。2005年,作为旨在解决北格陵兰极深区域结构的研究项目的一部分,部署了三个临时地震仪:Citronen Fjord站(CFJ,大陆架项目)和Kullorsuaq站(KUL)和Daneborg站(DBG)。
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引用次数: 9
An integrative and quantitative assessment of the gold potential of the Nuuk region, West Greenland 西格陵兰努克地区黄金潜力的综合定量评估
Q2 Earth and Planetary Sciences Pub Date : 2006-11-01 DOI: 10.34194/GEUSB.V10.4902
B. M. Stensgaard, T. Rasmussen, A. Steenfelt
An integrative and quantitative assessment of the gold potential of the Nuuk region, West Greenland
西格陵兰努克地区黄金潜力的综合定量评估
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引用次数: 2
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Geological Survey of Denmark and Greenland Bulletin
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