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Determination of HMF Value and Diastase Activities in Strained Honeys Sold in Markets 市售滤过蜂蜜HMF值及淀粉酶活性测定
Pub Date : 2023-10-15 DOI: 10.34248/bsengineering.1349150
Seda Dicle KORKMAZ
This study aimed to determine HMF values and diastase activities of the strained honeys collected from various markets in Türkiye and to evaluate their suitability to Turkish Food Codex, Directive on Honey. The samples were obtained with original package and their shelf lifes were remarked by companies. A total of 90 honey samples, 45 were flower honey and 45 were honeydew honey, were analysed for HMF using High Performance Liquid Chromatography and for diastase activity using UV spectrophotometer. According to the results, it was observed that the 35.5% of flower honey samples and the 20% of honeydew honey samples were not fulfilled the HMF value and/or diastase activity standards of the Turkish Food Codex. The highest HMF value of the samples was 119.8 mg/kg, while the lowest diastase activity of samples was 0.9. Furthermore, 15 of 45 flower honey and 8 of 45 honeydew honey samples were in critical limits for the mentioned standards. In conclusion, in strained honey offered for consumption, either heat treatment that is applied during the production or increasing HMF value and decreasing diastase activity depending on storage temperature limit the product's shelf life. HMF in honey is known to be a potential risk for food safety and public health. Appropriate production and storage conditions for honey should be ensured until it reaches the consumer, and all quality criteria, especially HMF and diastase, should be targeted to comply with the Turkish Food Codex Directive on Honey, until the end of the shelf life. Thus, it will be possible to ensure food safety by protecting both public health and producer rights. In addition, raising consumers' awareness on the subject will enable the development of internal control at both manufacturers and markets.
本研究旨在确定从土耳其不同市场收集的蜂蜜的HMF值和淀粉酶活性,并评估其对土耳其食品法典蜂蜜指令的适用性。样品采用原包装,并有公司注明保质期。采用高效液相色谱法和紫外分光光度计对90份蜂蜜样品进行了HMF和淀粉酶活性分析,其中45份为花蜜,45份为蜜露蜜。结果显示,35.5%的花蜜和20%的蜜露蜜不符合土耳其食品法典规定的HMF值和/或淀粉酶活性标准。样品HMF值最高为119.8 mg/kg,淀粉酶活性最低为0.9。45份花蜜样品中有15份和45份蜜露蜂蜜样品中有8份均在上述标准的临界范围内。总之,在供消费的过滤蜂蜜中,在生产过程中应用的热处理或根据储存温度增加HMF值和降低淀粉酶活性限制了产品的保质期。蜂蜜中的HMF已知对食品安全和公众健康构成潜在风险。在蜂蜜到达消费者手中之前,应确保蜂蜜的适当生产和储存条件,并且所有质量标准,特别是HMF和淀粉酶,都应符合土耳其食品法典关于蜂蜜的指令,直到保质期结束。因此,可以通过保护公众健康和生产者的权利来确保食品安全。此外,提高消费者对这一问题的认识将有助于在制造商和市场上发展内部控制。
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引用次数: 0
Investigation of Defects Occurring in the Foundry Process of Ceramic Sanitary Ware on the Final Product 陶瓷卫生洁具铸造过程中最终产品缺陷的研究
Pub Date : 2023-10-15 DOI: 10.34248/bsengineering.1347161
Nihal DERİN COŞKUN, Eray ÇAŞIN, Cumhur Eren IŞIK
When the export values of ceramic sanitaryware in Türkiye are analyzed, it is seen that the data for the year 2022 of ~660 million dollars continues to increase. In the sector, which reaches an annual average increase of 100 million dollars, the amount of production as well as the design demands change and shape the market. The most important difficulty factors in design are due to the fact that the products in the sector have large sizes, complex shapes and the most human-made production stages. When these factors are compared with other ceramic sectors, it is revealed that although industrialization has increased in the production of ceramic sanitaryware, the lack of production amount and the excess of faults are among the biggest problems. Glaze faults are the leading faults observed in the final product, and since this problem is not recyclable, it harms the ceramic sanitaryware industry in terms of cost. In this study, the glaze faults reflected in the final glazed products originating from the casting shop stage, which attracts attention in this field due to its large size and whiteness and there is not much data for the vitreous ware industry in the literature, have been studied. In the study, which was carried out with the aim of detecting and eliminating some faults in industrial production and creating data for the literature, faults arising from mechanical evenings used in classical and pressure casting benches and material residues used in retouching processes were determined. These faults were produced on the basis of the laboratory and the characterization of the glazed faulty products was made. It is concluded that production losses can be reduced by eliminating these problems, consequently increasing quality and productivity.
分析韩国陶瓷洁具的出口额,可以看出,2022年的数据约为6.6亿美元,继续增加。在平均每年增加1亿美元的行业中,生产数量和设计需求都在变化,并塑造着市场。设计中最重要的困难因素是由于该领域的产品尺寸大,形状复杂,生产阶段最人性化。当这些因素与其他陶瓷行业进行比较时,发现陶瓷洁具的生产虽然工业化程度有所提高,但产量不足和故障过多是其中最大的问题。釉面缺陷是最终产品中观察到的主要缺陷,由于这个问题是不可回收的,它在成本方面损害了陶瓷洁具行业。本研究对源自铸造车间阶段的最终釉面产品中所反映的釉面缺陷进行了研究,该缺陷因其尺寸大、白度高而受到该领域的关注,且文献中有关玻璃器皿行业的数据较少。在这项研究中,其目的是检测和消除工业生产中的一些故障,并为文献创造数据,确定了经典和压力铸造工作台中使用的机械夜晚和润饰过程中使用的材料残留物引起的故障。在实验室的基础上产生了这些缺陷,并对釉面缺陷产品进行了表征。通过消除这些问题,可以减少生产损失,从而提高质量和生产率。
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引用次数: 0
Neuroanatomy of Entrepreneurship and Bibliometric Analysis of Studies with Vosviewer 创业精神的神经解剖学和Vosviewer研究的文献计量学分析
Pub Date : 2023-10-15 DOI: 10.34248/bsengineering.1346685
Abdullah BALLI
Entrepreneurship has been at the focus of many scientists doing research in the field of social sciences. Studies have focused on entrepreneurial intention, entrepreneurial disposition and entrepreneurial behavior. Generally, empirical methods have been used in studies, but the neurophysiological, neuropsychological and psychoneuroendocrinological reasons behind the individual's entrepreneurship have been neglected. In short, genetic factors, hormones, behavioral genetic factors related to the individual's being an entrepreneur were not taken into account in the studies. However, with the use and development of neuroscience methods, tools and approaches in different fields, the opportunities offered by neuroscience in research on entrepreneurship in the field of Social Sciences have recently begun to be utilized. This has facilitated the neuroanatomical examination of entrepreneurial individuals. Entrepreneurship research focuses on the individual's family, environmental, social and educational interactions. In order for entrepreneurship to be understood in a multidimensional way, it is necessary to consider human behavior in terms of genetic transfers, hormones, behavioral genetics and the interactions of these factors with each other. For this reason, studies on the concepts of "entrepreneurship and neuroscience", "entrepreneurship and genetics", "entrepreneurship and biology" and "neuroentrepreneurship" gain importance. The aim of this study is to provide information about the neuroscience methods, tools and approaches used in entrepreneurship research, to make a detailed bibliometric analysis of the researches, to identify the trends and gaps related to the mentioned concepts and to bring them to the attention of researchers and to make suggestions about what should be done in future studies. Since a better understanding of entrepreneurial thought, intention and behavior will contribute to the development of entrepreneurship, mapping the studies in the literature in terms of the neuroanatomy of entrepreneurship and analyzing them within the scope of quantitative data makes the study unique. The study consists of five parts. In the first part of the study, studies carried out for a better understanding of entrepreneurship in terms of neurophysiology, hormones and genetics are given by making use of neuroscience methods, tools and approaches in the literature. In the second part, neuroscience tools, methods and approaches used in entrepreneurship research are explained. In the third part, the method of the research and in the fourth part, the bibliometric analysis findings are given. In the last part, the discussion and conclusion, the deficiencies identified in the field and recommendations for future studies are made. As the analysis unit, bibliometric data of different types of papers scanned in the Web of Science (WoS) database and published between 2006 and 2023 was taken as a basis. As a result of the research, 379 publications related to
企业家精神一直是许多从事社会科学研究的科学家关注的焦点。研究主要集中在创业意向、创业倾向和创业行为三个方面。研究中一般采用实证方法,但忽视了个体创业背后的神经生理学、神经心理学和精神神经内分泌学原因。简而言之,研究中没有考虑到与个体创业相关的遗传因素、激素、行为遗传因素。然而,随着神经科学方法、工具和方法在不同领域的应用和发展,神经科学为社会科学领域的创业研究提供的机会最近开始得到利用。这有助于对创业个体进行神经解剖学检查。创业研究侧重于个人的家庭、环境、社会和教育互动。为了从多维度上理解企业家精神,有必要从遗传转移、激素、行为遗传学以及这些因素相互作用的角度来考虑人类行为。因此,“企业家精神与神经科学”、“企业家精神与遗传学”、“企业家精神与生物学”、“神经企业家精神”等概念的研究变得尤为重要。本研究的目的是提供关于创业研究中使用的神经科学方法、工具和方法的信息,对研究进行详细的文献计量分析,确定与上述概念相关的趋势和差距,并提请研究人员注意,并就未来研究应做的工作提出建议。由于更好地理解创业思想、意图和行为将有助于创业精神的发展,因此从创业精神的神经解剖学角度对文献中的研究进行映射,并在定量数据的范围内对其进行分析,使该研究具有独特性。本研究共分为五个部分。在研究的第一部分,通过利用文献中的神经科学方法、工具和方法,从神经生理学、激素和遗传学的角度进行了更好地理解创业精神的研究。第二部分阐述了创业研究中使用的神经科学工具、方法和途径。第三部分给出了研究方法,第四部分给出了文献计量分析结果。最后是讨论和结论,指出了本领域存在的不足,并对今后的研究提出了建议。以Web of Science (WoS)数据库中扫描的2006 - 2023年间发表的不同类型论文的文献计量数据为分析单元。研究结果显示,与“创业”和“神经科学”相关的论文共有379篇,其中研究最多的论文有260篇是神经科学、神经学,53篇是商业经济学,47篇是数学计算生物学。目前已确定的关于“创业”和“遗传学”的出版物346篇,其中研究最多的146篇是基因遗传,44篇是生物化学、分子生物学,35篇是商业经济学。共发现183篇关于“创业”和“生物学”的论文,其中58篇是研究最多的多学科科学,55篇与基因遗传有关,44篇与商业有关。在研究范围内,仅在Web of Science (WoS)数据库中发现了9篇与“神经企业家精神”相关的出版物,这些出版物与企业家精神和神经科学直接相关。最后一部分是讨论和总结,提出创业研究需要做的事情和建议。
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引用次数: 0
Development of a Web Server-Based Remote Monitoring System for Environmental Conditions in Broiler Chicken Farming 基于Web服务器的肉鸡养殖环境状况远程监测系统的开发
Pub Date : 2023-10-15 DOI: 10.34248/bsengineering.1339165
Hayrettin KARADÖL, Ali ÇAYLI, Adil AKYÜZ, Serdar ÜÇOK
Etlik piliç yetiştiriciliği artan talep doğrultusunda giderek yaygınlaşan üretim kollarından biri haline gelmiştir. Kümes ortamında ortaya çıkan Karbondioksit, Amonyak, Hidrojen Sülfür gibi zararlı gazlar, atmosfer, kanatlı sağlığı ve dolayısıyla insan sağlığı açısından önemli etkilere sahiptir. Bu durum, etlik piliç yetiştiriciliğinde süreçlerinin hassas kontrolünü ön plana çıkarmaktadır. Bu çalışmada, etlik piliç üretimi yapan 2 katlı bir çiftliğe ait kümes içi ortam koşulları (sıcaklık, bağıl nem, karbondioksit ve amonyak,) 2 yetiştirme dönemi süresince sensörlerle okunmuştur. Daha sonra geliştirilen bir web server uygulaması ile uzak izleme sistemi oluşturulmuştur. 1. üretim döneminde kümes ortamının başlangıç sıcaklığı ortalama 34 °C, bağıl nem değerleri ise % 50 seviyelerinde gerçekleşmiştir. İlerleyen haftalarda sıcaklık değerinin kademeli olarak düştüğü ve üretim döneminin son günlerinde minumun sıcaklık değerinin 20 °C, bağıl nem değerinin ise %70 seviyelerine ulaştığı belirlenmiştir. 2. üretim dönemi süresince 9. günden itibaren yapılan ölçümlerde, ortalama sıcaklık değerinin 25 °C, bağıl nem değerleri ise % 50 seviyelerinde gerçekleşmiştir. İlerleyen haftalarda sıcaklık değerinin kademeli olarak düştüğü ve üretim döneminin son günlerinde minumun sıcaklık değerinin 14 °C, bağıl nem değerinin ise %70 seviyelerine ulaştığı belirlenmiştir. CO2 değeri ise 1. üretim döneminde her iki kat için genel olarak kabul edilebilir sınır değer olan 3000 ppm değerini sadece 1. katta 2-3 saat süre ile aştığı diğer zamanlarda kabul edilebilir sınırlar içerisinde olduğu görülmüştür. Ancak havaların soğumasıyla birlikte 2. üretim döneminde 10-15. günlerde civcivlerin zemin katta 12 saatten daha fazla süreyle 3000 ppm’in üzerinde CO2’e maruz kaldığı, 1. katta ise birkaç saat süre ile 5000 ppm seviyelerine kadar çıktığı görülmüştür. Her iki üretim dönemi için NH3 değerinin son hafta içerisinde artış gösterme eğiliminde olduğu ve bu artışın maksimum 8 ppm değerine ulaştığı belirlenmiştir.
随着需求的不断增长,肉鸡养殖已成为日益广泛的生产分支之一。禽舍环境中产生的二氧化碳、氨气、硫化氢等有害气体对大气、家禽健康以及人类健康都有重大影响。这种情况强调了对肉鸡饲养过程的精确控制。在这项研究中,传感器读取了一个两层肉鸡养殖场禽舍在两个生长期的环境条件(温度、相对湿度、二氧化碳和氨气)。然后,利用网络服务器应用程序创建了一个远程监控系统。在第一个生产期,禽舍的初始温度为 34 °C,相对湿度为 50 %。随后几周,温度值逐渐下降,在生产期的最后几天,最低温度值达到 20 °C,相对湿度值达到 70%。在第二个生产期,第 9 天的平均温度值为 25 °C,相对湿度值为 50 %。随后几周,温度值逐渐下降,在生产期的最后几天,最低温度值达到 14 °C,相对湿度值达到 70%。据观察,在第一个生产期,两层楼的二氧化碳值都超过了一般可接受的极限值 3000 ppm,只有 1 楼的二氧化碳值在 2-3 小时内超过了极限值,其他时间都在可接受范围内。然而,随着天气转凉,在第 2 个生产期的第 10-15 天,雏鸡在底层接触二氧化碳超过 3000 ppm 的时间超过了 12 小时,在 1 层的几个小时内,雏鸡接触的二氧化碳高达 5000 ppm。在两个生产期中,NH3 值在最后一周呈上升趋势,最高升至 8 ppm。
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引用次数: 0
A Parallel Algorithm for Designing Primer and Probe for Accurate Detection of Severe Acute Respiratory Syndrome Coronavirus 一种精确检测严重急性呼吸综合征冠状病毒的引物与探针并行设计算法
Pub Date : 2023-10-15 DOI: 10.34248/bsengineering.1324890
Hilal ARSLAN, Rıza DURMAZ
The spread of the SARS-CoV-2 in many countries has led to multiple SARS-CoV-2 variants, and this makes accurate detection of SARS-CoV-2 difficult. The reverse transcription real-time polymerase chain reaction (RT-PCR) is a widely used gold-standard method to detect SARS-CoV-2, and accurate designing of primers and probes is crucial to prevent false negative results, especially with the rise of new dangerous variants. Therefore, it is significant to determine primers and probes targeting conserved regions in the genome sequence to diagnose many variants of SARS-CoV-2. In this paper, we propose a novel and efficient method for identifying PCR primers and probe sequences by evaluating sequences belonging to SARS-CoV-2 variant of concern and variants of interest. We propose 13 primer and probe sets by analyzing 54,524 sequences in Alpha variant, 25,465 sequences in Beta variant, 53,501 sequences in Gamma variant, 46,225 sequences in Delta variant, and 43,682 sequences in Omicron variant from GISAID. Furthermore, we analyzed 1,008 sequences in Lambda variant as well as 5,844 sequences in Mu variant to extract primer and probe sets from GISAID. The proposed primer and probe sets were validated in 406,757 new SARS-CoV-2 unique genomes collected from NCBI. In silico evaluation presented that the proposed set of primers and probes are found inside about 99% of SARS-CoV-2 genome sequences. Designed primers present a higher potential to detect the main SARS-CoV-2 recent variant of concerns and the variants of interests. The superiority of the proposed method is also highlighted by comparing the state-of-the-art PCR primer and probe sets based on the number of mismatches for various types of SARS-CoV-2 genomes.
SARS-CoV-2在许多国家的传播导致了多种SARS-CoV-2变体,这使得准确检测SARS-CoV-2变得困难。逆转录实时聚合酶链反应(RT-PCR)是广泛使用的检测SARS-CoV-2的金标准方法,准确设计引物和探针对于防止假阴性结果至关重要,特别是随着新的危险变体的出现。因此,确定针对基因组序列保守区域的引物和探针对诊断SARS-CoV-2的多种变异具有重要意义。在本文中,我们提出了一种新的、高效的方法,通过评估SARS-CoV-2变体和感兴趣变体的序列来鉴定PCR引物和探针序列。通过对GISAID中Alpha变体的54,524个序列、Beta变体的25,465个序列、Gamma变体的53,501个序列、Delta变体的46,225个序列和Omicron变体的43,682个序列进行分析,我们提出了13个引物和探针组合。此外,我们分析了Lambda变体的1008个序列和Mu变体的5844个序列,从GISAID中提取引物和探针集。在NCBI收集的406,757个新的SARS-CoV-2独特基因组中验证了所提出的引物和探针集。计算机评估表明,所提出的引物和探针在约99%的SARS-CoV-2基因组序列中被发现。设计的引物在检测主要的SARS-CoV-2近期变体和兴趣变体方面具有更高的潜力。基于不同类型SARS-CoV-2基因组的错配数量,比较了最先进的PCR引物和探针集,也突出了所提出方法的优越性。
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引用次数: 0
Daylight Analysis in Terms of Building Direction and One-Way Roof 建筑朝向和单向屋顶的采光分析
Pub Date : 2023-10-15 DOI: 10.34248/bsengineering.1354194
Mehmet Sait CENGIZ
The location of the buildings in the residential area is very important in protecting or benefiting from sunlight. The dynamic structure of the sun, which constantly changes according to time and seasons, directly affects the building's architecture and urban formation. Ignoring the sun's use of the structures during the construction of the buildings can cause significant disturbances to the residents. Daylight strategies, which are also influenced by climate, depend on the availability of natural light, determined by the latitude of the building site and the instantaneous conditions around the building. High latitudes have different summer and winter conditions, with lower daylight levels in winter. At these latitudes, designers often aim to maximize daylight penetration in buildings. In the tropics, where daylight levels are high throughout the year, the design emphasis is often on preventing overheating by limiting the amount of sunlight entering the building. Daylight availability depends not only on latitude, but also on the orientation of a building, and each facade and material of the building requires a different design importance. Therefore, daylight and architectural design strategies are two inseparable phenomena. In this respect, examining traditional architecture and successful natural lighting designs in the past is very useful for understanding climate-balanced building design. For this purpose, determining the roof slope according to the sun angle in architectural structures by calculating according to the location provides efficiency in many issues from energy efficiency to human health.
建筑在居住区的位置对于保护或受益于阳光非常重要。太阳的动态结构根据时间和季节不断变化,直接影响着建筑的结构和城市形态。在建筑的建造过程中,忽视太阳对结构的使用会对居民造成严重的干扰。日照策略也受到气候的影响,取决于自然光的可用性,由建筑场地的纬度和建筑周围的瞬时条件决定。高纬度地区的夏季和冬季条件不同,冬季日照较低。在这些纬度地区,设计师们的目标往往是最大限度地提高建筑的日照穿透力。在热带地区,全年日照水平都很高,设计的重点往往是通过限制进入建筑物的阳光量来防止过热。日光的可用性不仅取决于纬度,还取决于建筑的朝向,建筑的每个立面和材料都需要不同的设计重要性。因此,日光与建筑设计策略是两个不可分割的现象。在这方面,研究传统建筑和过去成功的自然采光设计对于理解气候平衡的建筑设计非常有用。为此,在建筑结构中,根据太阳角度来确定屋顶的坡度,根据位置来计算,为从能源效率到人体健康的许多问题提供了效率。
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引用次数: 0
DC-DC Dönüştürücülerin Kapsamlı Analizi ve Değerlendirilmesi: Gelişmeler, Uygulamalar ve Zorluklar 直流-直流转换器的综合分析与评估:发展、应用和挑战
Pub Date : 2023-10-15 DOI: 10.34248/bsengineering.1357849
Fuad ALHAJ OMAR
Power electronics stand as the cornerstone of our electrified world, and versatile DC-DC converters are a key component of this technology. In this comprehensive analysis, we investigate deeply the realm of DC-DC converters, examining their pivotal role in modern power systems. From the evolution of converter topologies to their wide-ranging applications, we explore the advancements that propel this field forward. Whether maintaining continuous power in portable devices or facilitating renewable energy integration, DC-DC converters are the fundamental components. Yet, they face formidable challenges, from complex control strategies to voltage stress management. This study reveals the complex configuration of DC-DC converters, detailing a narrative of adaptability, resilience, and innovation in response to the increasing energy demands of our time.
电力电子是我们电气化世界的基石,多功能DC-DC转换器是这项技术的关键组成部分。在这个综合分析中,我们深入研究了DC-DC变换器领域,研究了它们在现代电力系统中的关键作用。从转换器拓扑的演变到其广泛的应用,我们探索了推动这一领域向前发展的进步。无论是在便携式设备中保持连续供电还是促进可再生能源的整合,DC-DC转换器都是基本组件。然而,他们面临着巨大的挑战,从复杂的控制策略到电压应力管理。本研究揭示了DC-DC转换器的复杂配置,详细描述了适应性、弹性和创新,以应对我们这个时代日益增长的能源需求。
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引用次数: 0
Comparing of CFD contours using image analysing method: a study on velocity distributions 用图像分析方法比较CFD轮廓:速度分布的研究
Pub Date : 2023-10-15 DOI: 10.34248/bsengineering.1310711
Ahmet ERDOĞAN, Mahmut DAŞKIN
Contour plotting, a widely utilized graphical technique for visualizing CFD (Computational Fluid Dynamics) outcomes, is highly valuable. It provides an effective and practical approach to analysing distributions of magnitudes belonging to fluid domains such as; velocity, temperature, pressure, volume fraction, etc. Nevertheless, when analysing multiple contours, especially showing similar distribution, identifying the ideal contour can be difficult and open to speculation. In this research, the issue was addressed by employing the Image Analysis Method for the classification of velocity distribution contours. This led to determining which picture has the best distribution among a few of the contour’s pictures. Firstly, velocity distribution contours downstream of the diffuser located in Air Handling Unit (AHU) unit were obtained by using CFD. The contour pictures were then transferred to MATLAB environment. With pixel analysis in MATLAB, the pictures were able to be classified based on which parameters had an effect on the velocity distribution. Variable parameters are the length of the fan channel (x) and the ratio of cross-sectional areas of the AHU (A/Ao). The results showed that x=250 mm and A/Ao=0.5 improved velocity distributions by 6% and 20%, respectively.
等值线图是一种广泛应用于CFD(计算流体动力学)结果可视化的图形技术,具有很高的价值。它提供了一种有效和实用的方法来分析属于流体域的震级分布,例如;速度、温度、压力、体积分数等。然而,当分析多个轮廓线时,特别是显示相似的分布时,确定理想的轮廓线可能是困难的,并且容易引起猜测。本研究采用图像分析方法对速度分布轮廓线进行分类,解决了这一问题。这就决定了在几个轮廓图中哪一张图的分布最好。首先,利用CFD计算得到了空气处理机组扩压器下游的速度分布轮廓。然后将轮廓图转移到MATLAB环境中。在MATLAB中进行像素分析,根据对速度分布有影响的参数对图像进行分类。可变参数为风机通道长度(x)和AHU的截面积比(A/Ao)。结果表明,x=250 mm和A/Ao=0.5分别改善了6%和20%的速度分布。
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引用次数: 1
The Angular Use of Light in Architecture and the Concept of Space 建筑中光线的角度运用与空间概念
Pub Date : 2023-10-15 DOI: 10.34248/bsengineering.1346534
Mehmet Sait CENGIZ
In this study, the analysis of the understanding of space under the influence of light was made. The content of the study touched on the effect of light and space on human perception, both architecturally and computationally. The identity that the light adds to the space, the interaction of the material with the light, and the illusory properties of the light are explained. While examining these abstract concepts, the illumination area of the light was calculated with a computational application. The fact that light is one of the most effective elements used in space has revealed the necessity of designing form, material, and lighting together. It is understood that the effect of basic elements that make up space, such as form and material color, can be increased with angular lighting. It has been understood that if a textured surface is illuminated with a directional light, the visual effect of the surface will increase. However, it has been understood that a material with a smooth structure and a material with a rough structure cannot be illuminated with the same lighting method, and this visual effect will create negativity. For original lighting designs, it is necessary to make accented or homogeneous lighting according to the need, and it is possible to provide this with designed-planned lighting.
在这项研究中,分析了在光的影响下对空间的理解。研究的内容涉及光和空间对人类感知的影响,包括建筑和计算。光为空间增加的身份,材料与光的相互作用,以及光的虚幻特性都得到了解释。在研究这些抽象概念的同时,通过计算应用程序计算了光的照明面积。光是空间中使用的最有效的元素之一,这一事实揭示了将形式、材料和照明设计在一起的必要性。据了解,构成空间的基本元素的效果,如形式和材料的颜色,可以增加角度照明。众所周知,如果用定向光照射纹理表面,表面的视觉效果将会增加。然而,人们已经了解到,结构光滑的材料和结构粗糙的材料不能用相同的照明方法进行照明,这种视觉效果会产生负性。对于原创性的照明设计,需要根据需要进行强调或均匀的照明,可以通过设计规划的照明来提供。
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引用次数: 0
A New Soluble Copper Phthalocyanine Derivative as a Smart Material 一种新型可溶酞菁铜衍生物作为智能材料
Pub Date : 2023-10-15 DOI: 10.34248/bsengineering.1341180
Fuat ERDEN, Ebru YABAŞ
Copper phthalocyanine (CuPc) and its derivatives are considered as candidate materials in many applications. Particularly, easy and sensitive film-forming ability, commercial availability, chemical stability, and ease in tailoring its molecular structure make CuPc a versatile material. On the other hand, main challenge that Pcs often exhibit is their poor solubility in organic solvents. In this sense, this work involves designing of new CuPc derivatives by introducing suitable substitutions to improve the solubility in organic solvents. Specifically, [2,9,16,23-tetra{(4,5-Diphenyl-1H-imidazole)-2-yl-thio}phthalocyaninato-copper(II)] (1) and [2,9,16,23-tetra{(4,5-Diphenyl-1-methyl-1H-imidazole)-2-yl-thio}phthalocyaninato-copper(II)] (2) were prepared. The results show that compound 1 is soluble in tetrahydrofuran (THF), dimethylformamide (DMF), and dimethyl sulfoxide (DMSO), and compound 2 is soluble in chloroform, acetone, methanol, THF, DMF, and DMSO. Optical and spectroscopic properties of the synthesized compounds were also investigated, and it was determined that the energy bang gaps of compounds 1 and 2 are 1.70 eV and 1.56 eV, respectively. Strikingly, we demonstrate that compound 1 is exhibiting a rapid and reversible color change behavior upon altering pH in the entire pH spectrum. As it is known, materials that respond reversibly to chemical and/or physical stimuli in a controllable fashion are regarded as smart materials. Hence, we report that compound 1 is actually a smart material that can be used as a simple yet efficient pH sensor.
酞菁铜(CuPc)及其衍生物被认为是许多应用领域的候选材料。特别是,容易和敏感的成膜能力、商业可用性、化学稳定性和易于定制的分子结构使CuPc成为一种多用途材料。另一方面,pc经常表现出的主要挑战是它们在有机溶剂中的溶解度差。从这个意义上说,本工作涉及通过引入合适的取代来设计新的CuPc衍生物,以提高其在有机溶剂中的溶解度。具体而言,制备了[2,9,16,23-四{(4,5-二苯基- 1h -咪唑)-2-基-硫}酞菁酸铜(II)](1)和[2,9,16,23-四{(4,5-二苯基-1-甲基- 1h -咪唑)-2-基-硫}酞菁酸铜(II)](2)。结果表明,化合物1可溶于四氢呋喃(THF)、二甲基甲酰胺(DMF)和二甲亚砜(DMSO),化合物2可溶于氯仿、丙酮、甲醇、四氢呋喃、DMF和DMSO。对合成化合物的光学和光谱性质进行了研究,确定化合物1和2的能隙分别为1.70 eV和1.56 eV。引人注目的是,我们证明了化合物1在整个pH谱中改变pH值时表现出快速可逆的颜色变化行为。众所周知,以可控方式对化学和/或物理刺激作出可逆反应的材料被视为智能材料。因此,我们报告化合物1实际上是一种智能材料,可以用作简单而高效的pH传感器。
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引用次数: 0
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Black sea journal of engineering and science
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