Geochemistry Geophysics Geosystems最新文献

To date, the most complete paleolake-level reconstructions for the late Pleistocene water bodies that once occupied the Dead Sea depression have been based on the combination of dating of lake sediments and terrestrial materials. However, despite these major accomplishments, there is still limited spatial control regarding the water levels, suggesting some degree of uncertainty concerning the magnitude and rate of lake-level changes. Here, we re-examine the late Pleistocene lake-level changes in the Dead Sea during the transition from paleolake Lisan to the present-day Dead Sea. We rely on systematic dating of fossil stromatolites including 84 radiocarbon and 15 U-series ages, stable-isotope measurements, paleobiology, high-resolution topography, and numerical modeling to assess lake-level changes. Our results indicate that the highstand of paleolake Lisan was of shorter duration and the transition between Lake Lisan and the Dead Sea occurred at least 5 Kyrs earlier than previously indicated. By refining the timeline and accuracy of lake-level positions during the transition paleolake Lisan—Dead Sea, our study offers new insights into the regional and local paleo-climatic conditions during the last glacial period in this region.

Subduction zones serve as carbon recycling centers, where vast amassments of geologic carbon accrete or subduct through thermogenic gas windows over millions of years. We focus on New Zealand's Chatham Rise, a fossilized accretionary wedge remnant of the ∼400 Myr-active East Gondwanan margin. We undertake an amplitude-variation-with-offset (AVO)-based seismic analysis of the abiogenic Mesozoic sedimentary sequence (MES) and overlying Sequence Y chalk interval, which span the Chatham Rise's northwestern slope. Two-term AVO attribute analysis resulted in the interpretation of distinct AVO Class III–IV reflection anomalies, which demarcate the siliciclastic MES from overlying Sequence Y chalks. Unified through their strong negative intercept amplitudes, Class III anomalies increase in absolute amplitude with angle, while Class IV anomalies decrease in absolute amplitude with angle of incidence. Simultaneous AVO inversion of seismic data highlighted the presence of P-impedance anomalies, which directly underlie the regionally occurring Sequence Y chalk interval. Class III anomalies are modeled and interpreted as the result of a previously undefined coarse-grained lithofacies, bearing low saturations (2%–10%) of free gas. Co-occurring ClassIV AVO anomalies are modeled to provide evidence for a fine-grained upper MES, bearing similarly low saturations of free-gas in pore space. We speculate on the gas' origin, which could be from the Hikurangi subduction margin, in situ ancient microbial activity, or a new undetermined source related to the ancient East Gondwanan subduction margin and accretionary wedge.

Based on U-Pb dating of zircon crystals and petrographic analysis, this study provides new insights into the paleogeographic and accretion evolution along SW Japan. Our data are consistent with an older submarine fan identified from drilling in the Shikoku Basin (Kyushu Fan ∼14.7–12.2 Ma), having a mixed sand provenance from the paleo-Yangtze/Yellow rivers and the Shimanto Belt, and the younger Zenisu Fan (∼9.2–7.6 Ma), which is mainly sourced from the Shimanto Belt and the Izu-Bonin/Honshu arc collision. Our results are in agreement with the hypothesis of very oblique subduction or strike-slip motion between the northern Shikoku Basin and mainland Honshu from ∼12.2 to 9.2 Ma, after which essentially orthogonal subduction occurred after ∼8 Ma. The two main sandbodies drilled at IODP Site C0002 within the inner Nankai Accretionary Prism have similar petrographic signatures to those of the Zenisu and Kyushu submarine fans in the Shikoku Basin. The incorporation of the Shikoku Basin deposits most likely resulted from the seaward propagation of in-sequence thrusts forming an outer accretionary wedge. The incorporation of the Kyushu Fan into the inner accretionary prism implies that the décollement was located in the hemipelagic interval beneath the Kyushu Fan at least until ∼2 Ma, whereas it is now located in the hemipelagic intervals below the Zenisu Fan. Such shifts in décollement location are most likely related to changes in physical properties of the hemipelagic interval due to significant compaction and diagenesis during subduction.

Micromagnetic modeling allows the systematic study of the effects of particle size and shape on the first-order reversal curve (FORC) magnetic hysteresis response for magnetite particles in the single-domain (SD) and pseudo-single domain (PSD) particle size range. The interpretation of FORCs, though widely used, has been highly subjective. Here, we use micromagnetics to model randomly oriented distributions of particles to allow more physically meaningful interpretations. We show that one commonly found type of PSD particle—namely the single vortex (SV) particle—has far more complex signals than SD particles, with multiple peaks and troughs in the FORC distribution, where the peaks have higher switching fields for larger SV particles. Particles in the SD to SV transition zone have the lowest switching fields. Symmetrical and prolate particles display similar behavior, with distinctive peaks forming near the vertical axis of the FORC diagram. In contrast, highly oblate particles produce “butterfly” structures, suggesting that these are potentially diagnostic of particle morphology. We also consider FORC diagrams for distributions of particle sizes and shapes and produce an online application that users can use to build their own FORC distributions. There is good agreement between the model predictions for distributions of particle sizes and shapes, and the published experimental literature.

The Pleiades Volcanic Field is made up of some 20 monogenetic, partly overlapping scoria and spatter cones, erupted in the last 900 ka, cropping out from the ice close to the head of the Mariner Glacier in northern Victoria Land, Antarctica. Erupted products vary from hawaiite to trachyte, defining a complete mild Na-alkaline differentiation trend. Mafic samples are characterized by multi-elemental patterns typical of OIB magmas, moderately low ⁸⁷Sr/⁸⁶Sr (0.7037) and high ¹⁴³Nd/¹⁴⁴Nd (0.51284), with a clear within-plate affinity, indicating a subcontinental lithospheric source. With increasing SiO₂, ⁸⁷Sr/⁸⁶Sr ratios increase up to 0.7052 and ¹⁴³Nd/¹⁴⁴Nd decrease to 0.51277, supporting the hypothesis of open-system evolution, with significant crustal assimilation during fractional crystallization. The erupted volume of most evolved products (∼7 km³), according to fractionation models, suggests that primitive magmas should have been more than 10 times larger, indicating the occurrence of a large magma plumbing system, unexpected for a volcanic field of monogenetic scoria cones. The occurrence of a complete fractionation trend with large magma chambers and large assimilation rate is unusual, if not unique, among the alkali basaltic volcanic fields and it is matched by a climax of activity during the last glacial maximum (30 ka), as indicated by new ⁴⁰Ar-³⁹Ar ages (30 ± 3 ka and 25 ± 2 ka) for samples from the two most prominent edifices. Therefore, we hypothesize a role of a thick ice cap in suppressing eruptions and ultimately leading to prolonged magma residence time in the subsurface, favoring significant fractionation coupled with unusual high rates of crustal assimilation.

Zircon grains from the metasedimentary lower crust of the Rio Grande Rift, New Mexico, preserve a metamorphic record of the transition from Laramide compression to Eocene extension. Zircon U-Pb isotopes and trace-element concentrations from five two-pyroxene metaigneous granulite xenoliths define discrete populations: older zircon cores (∼15–50 Ma) that are depleted in heavy rare-earth elements (HREE) but Ti-rich, and younger zircon rims (∼3–15 Ma) with elevated HREE and lower Ti concentrations. Coupled phase equilibria and garnet-melt-zircon trace-element partitioning calculations show that the older zircon cores equilibrated in thick (>40 km), hot (800–900°C), garnet-bearing lower crust during the cessation of compression at the end of the Laramide orogeny. Zircon rim domains equilibrated at lower pressures, consistent with >9 km of thinning of the lower crust. Thermal-kinematic calculations show that these pressure-temperature-time constraints require thinning of the lithospheric mantle prior to and during regional Cenozoic extension. Convective erosion of the mantle lithosphere over tens of millions of years, possibly facilitated by dynamics of the Farallon slab, provides a mechanism to facilitate lower crustal heating and extension.

Ratios of glycerol dialkyl glycerol tetraethers (GDGT), which are membrane lipids of bacteria and archaea, are at the base of several paleoenvironmental proxies. They are frequently applied to soils as well as lake- and marine sediments to generate records of past temperature and soil pH. To derive meaningful environmental information from these reconstructions, high analytical reproducibility is required. Based on submitted results by 39 laboratories from across the world, which employ a diverse range of analytical and quantification methods, we explored the reproducibility of brGDGT-based proxies (MBT′_5ME, IR, and #rings_tetra) measured on four soil samples and four soil lipid extracts. Correct identification and integration of 5- and 6-methyl brGDGTs is a prerequisite for the robust calculation of proxy values, but this can be challenging as indicated by the large inter-interlaboratory variation. The exclusion of statistical outliers improves the reproducibility, where the remaining uncertainty translates into a temperature offset from median proxy values of 0.3–0.9°C and a pH offset of 0.05–0.3. There is no apparent systematic impact of the extraction method and sample preparation steps on the brGDGT ratios. Although reported GDGT concentrations are generally consistent within laboratories, they vary greatly between laboratories. This large variability in brGDGT quantification may relate to variations in ionization efficiency or specific mass spectrometer settings possibly impacting the response of brGDGTs masses relative to that of the internal standard used. While ratio values of GDGT are generally comparable, quantities can currently not be compared between laboratories.

We document an apparent downward displacement of the Matuyama-Brunhes magnetic reversal by ∼20 m at Scotia Sea International Ocean Discovery Program Site U1538 (Pirie Basin) by comparison with the well-defined paleomagnetic record at nearby Site U1537 (Dove Basin). Detailed stratigraphic correlation between the two sites is possible due to similar lithologic variations. However, the two sites have distinctly different porewater geochemistry. Notably, Site U1538 indicates a greater demand for electron acceptors to oxidize organic carbon and Fe²⁺ enrichment below the depth of SO₄²⁻ depletion. Magnetic parameters indicate enrichment of an authigenic magnetic mineral with strong remanence properties around the depth of SO₄²⁻ depletion (∼46 m at Site U1538) relative to magnetic parameters at correlative depths at Site U1537. Fe²⁺ enrichment below the depth of SO₄²⁻ depletion is not predicted based on the energetically favorable order of electron acceptors for microbial respiration but is documented here and in other depositional settings. This indicates Fe²⁺ production exceeds the production of H₂S by SO₄²⁻ reduction, providing a geochemical environment that favors the production and preservation of ferrimagnetic remanence-bearing iron sulfides over paramagnetic pyrite and, thus, a mechanism for deep chemical remanent magnetization acquisition at depths of tens of meters. The influence of authigenic ferrimagnetic iron sulfides on paleomagnetic signals can be difficult to demonstrate with magnetic properties alone; therefore, this finding has implications for evaluating the fidelity of magnetostratigraphic records with complementary geochemical data. Such situations should be considered in other depositional environments with similar porewater Fe²⁺ accumulation below the SO₄²⁻ reduction depth.

The amalgamation of Laurentia was initiated along the western margin of the Rae craton. However, the tectonic setting that generated magmatic rocks along this margin has long been debated, with the Thelon tectonic zone in the north having formed in an arc setting, and the Taltson magmatic zone in the south variably attributed to either continental arc or intracratonic magmatism. The magmatic rocks of the Great Slave Lake shear zone (GSLsz) lie between these two tectonic belts and, thus, may be critical to the interpretation of the evolution of the western Rae margin. To understand the origin of the rocks in the GSLsz, we have applied U-Pb geochronology, trace-element geochemistry, and O and Hf isotope analyses to zircons from a suite of samples that transect the La Loche River fault (LRf)—a major structure that bisects the GSLsz. Samples collected to the north of the LRf are Neoarchean in age, have mantle-like δ¹⁸O (4.7–5.8‰) and chondritic to juvenile εHf values (0–4.5), whereas those to the south are exclusively Paleoproterozoic in age and have more elevated δ¹⁸O (6.3–7‰) and much more evolved εHf values (−12 to −6); these results indicate that the LRf marks a crustal-scale suture between the Slave craton and the Taltson magmatic zone. Our isotopic data, together with other regional constraints from the area, are most consistent with the Taltson magmatic zone having formed in a continental arc setting emplaced into ca. 2.3 Ga juvenile basement crust.

Investigating rock-uplift variations in time and space provides insights into the processes driving mountain-belt evolution. The Apennine Mountains of Italy underwent substantial Quaternary rock uplift that shaped the present-day topography. Here, we present linear river-profile inversions for 28 catchments draining the eastern flank of the Northern-Central Apennines to reconstruct rock-uplift histories. We calibrated these results by estimating an erodibility coefficient (K) from incision rates and catchment-averaged erosion rates obtained from cosmogenic-nuclide data, and we tested whether a uniform or variable K produces a rock-uplift model that satisfactorily fits independent geochronological constraints. We employ a landscape-evolution model to demonstrate that our inversion results are reliable despite substantial seaward lengthening of the catchments during uplift. Our findings suggest that a rock-uplift pulse started around 3.0–2.5 Ma, coinciding with the onset of extension in the Apennines, and migrated southward at a rate of ∼90 km/Myr. The highest reconstructed rock-uplift rates (>1 km/Myr) occur in the region encompassing the highest Apennine massifs. These results are consistent with numerical models and field evidence from other regions exhibiting rapid rock-uplift pulses and uplift migration related to slab break-off. Our results support the hypothesis of break-off of the Adria slab under the central Apennines and its southward propagation during the Quaternary. Moreover, the results suggest a renewed increase in rock-uplift rates after the Middle Pleistocene along the Adriatic coast, coeval with recent uplift acceleration along the eastern coast of southern Italy in the Apulian foreland.