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Nd Isotopic Equilibration During Channelized Melt Transport Through the Lithosphere: A Feasibility Study Using Idealized Numerical Models 通过岩石圈的通道化熔融迁移过程中的钕同位素平衡:使用理想化数值模型的可行性研究
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-30 DOI: 10.1029/2024GC011593
Mousumi Roy, G. Lang Farmer, Kellen Malone
<p>This study is motivated by the observed variability in trace element isotopic and chemical compositions of primitive (Si<span></span><math> <semantics> <mrow> <msub> <mi>O</mi> <mn>2</mn> </msub> <mo><</mo> </mrow> <annotation> ${mathrm{O}}_{2}< $</annotation> </semantics></math>52 wt %) basalts in southwest North America (SWNA) during the Cenozoic transition from subduction to extension. Specifically, we focus on processes that may explain the enigmatic observation that in some localities, basalts with low Ta/Th, consistent with parental melts in a subduction setting, have <span></span><math> <semantics> <mrow> <msub> <mi>ε</mi> <mrow> <mi>N</mi> <mi>d</mi> </mrow> </msub> </mrow> <annotation> ${varepsilon }_{Nd}$</annotation> </semantics></math> signatures consistent with continental lithospheric mantle (CLM). In locations with the oldest CLM (Proterozoic and Archean), Cenozoic basalts with low Ta/Th have <span></span><math> <semantics> <mrow> <msub> <mi>ε</mi> <mrow> <mi>N</mi> <mi>d</mi> </mrow> </msub> </mrow> <annotation> ${varepsilon }_{Nd}$</annotation> </semantics></math> well below zero. We model channelized magma transport through the CLM using simple 1D transport models to explore the extent to which diffusive and reactive mass exchange can modify Nd isotopic compositions via open system melt-wallrock interactions. For geologically reasonable channel spacings and volume fractions, we quantify the reactive assimilation rates required for incoming melt with a different <span></span><math> <semantics> <mrow> <msub> <mi>ε</mi> <mrow> <mi>N</mi> <mi>d</mi> </mrow> </msub> </mrow> <annotation> ${varepsilon }_{Nd}$</annotation> </semantics></math> than the wall-rock to undergo a substantial isotopic shift during <span></span><math> <semantics> <mrow> <mo>≈</mo> </mrow> <annotation> ${approx} $</annotation> </semantics></math>10 km channelized melt transport. In the presence of grain boundaries, e
在新生代从俯冲向伸展的转变过程中,北美西南部(SWNA)的原始玄武岩(Si O 2 < ${mathrm{O}}_{2}< $ 52 wt %)的痕量元素同位素和化学成分发生了变化。具体来说,我们重点研究了一些过程,这些过程可能解释了这样一个令人费解的现象:在一些地方,Ta/Th含量低的玄武岩与俯冲环境中的母熔体一致,而ε N d ${varepsilon }_{Nd}$特征与大陆岩石圈地幔(CLM)一致。在具有最古老CLM的地区(新元古代和奥陶纪),具有低Ta/Th的新生代玄武岩的ε N d ${varepsilon }_{Nd}$远低于零。我们使用简单的一维输运模型来模拟岩浆在CLM中的通道化输运,以探索扩散和反应质量交换通过开放系统熔体-壁岩相互作用改变Nd同位素组成的程度。对于地质上合理的通道间距和体积分数,我们量化了与壁岩不同的ε N d ${varepsilon }_{Nd}$流入熔体在≈ ${approx} $ 10 km通道化熔体运移过程中发生重大同位素转变所需的反应同化率。在存在晶界的情况下,富熔体通道与贫熔体围岩之间的扩散增强有助于同位素平衡,但这种效应不足以解释观测结果;我们的模型表明,壁岩的反应性同化也有很大的贡献。此外,我们的模型还支持这样一种观点,即在新生代玄武岩中观测到的Ta/Th和ε N d ${varepsilon }_{Nd}$的共变性不能仅仅归因于运移,还必须反映出西南地区与俯冲有关的母熔体向与延伸有关的母熔体的转变。
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引用次数: 0
Paleomagnetic Constraints on the Rapid Plate Shift of North China Block During the Jurassic From ∼155 Ma Dykes and Sills 从∼155 Ma岩体和岩屑看侏罗纪时期华北地块快速板块移动的古地磁制约因素
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-28 DOI: 10.1029/2024GC011671
Pengfei Wang, Zhiyu Yi, Joseph G. Meert, Yu-Shu Liu, Silin Yang, Fei Wang, Zaijun Li, Baochun Huang

A large-scale apparent polar wander occurred during the Jurassic interval, which is interpreted as true polar wander (TPW). As the motion is nearly orthogonal to the TPW axis, the North China Block (NCB) experienced the largest latitudinal and environmental changes and provides unique constraints on Jurassic TPW. However, due to the lack and uneven quality of paleomagnetic data, TPW records in North China are controversial. Here, we report a new paleomagnetic pole (80.8°N, 13.0°E, A95 = 7.4°) from the late Jurassic sills and dykes that intrude the Nandaling and Xiahuayuan formations in the NCB. The new pole places the NCB at 36.8° ± 7.4°N at 155 ± 3.4 Ma, using Beijing as the reference site. Combined with the reliable Jurassic poles, our study reveals a large, steady southward shift of 37.3° ± 7.2° for the NCB during the Middle and Late Jurassic, and reflects a component of TPW. The position of ∼155 Ma pole also supports significant TPW prior to ∼160 Ma and agrees with proposals attributing the diachronous 165–155 Ma aridification across the Eastern Asian blocks.

侏罗纪时期发生了大规模的明显极地漂移,被解释为真正的极地漂移(TPW)。由于其运动几乎与TPW轴正交,华北地块(NCB)经历了最大的纬度和环境变化,为侏罗纪TPW提供了独特的约束条件。然而,由于古地磁数据缺乏且质量参差不齐,华北地区的TPW记录存在争议。在此,我们报告了一个新的古地磁极(80.8°N, 13.0°E, A95 = 7.4°),它来自侵入北华北界南大岭地层和下花园地层的晚侏罗世岩屑和岩体。以北京为参照地,新的极点将北西伯利亚大陆置于北纬 36.8° ± 7.4°,年代为 155 ± 3.4 Ma。结合可靠的侏罗纪极点,我们的研究揭示了中侏罗世和晚侏罗世期间北大西洋边界37.3° ± 7.2°的大幅度稳定南移,反映了TPW的一个组成部分。∼155Ma极点的位置也支持在∼160Ma之前的显著TPW,并与东亚地块165-155Ma的非同步干旱化的提议相一致。
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引用次数: 0
Miocene Alkaline Basaltic Magmatism in Northeastern Tibetan Plateau: Implications for Mantle Evolution and Plateau Outward Growth 青藏高原东北部中新世碱性玄武岩岩浆活动:对地幔演化和高原向外生长的影响
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-27 DOI: 10.1029/2024GC011601
Yue Che, Dong Liu, Zhidan Zhao, Yaoling Niu, Fang-Zhen Teng, Donald J. DePaolo, Xuehui Yu, Di-Cheng Zhu, Ningyuan Qi, Xuanxue Mo

The widespread Cenozoic alkaline magmatism within and around the Tibetan Plateau offers a prime opportunity to probe the nature of the mantle at the depths where basalt magmas originate. The close temporal and spatial relationship between volcanism and regional strike-slip fault systems also helps better understand the geodynamics of outward growth of the plateau in response to the continued India-Asia convergence. We present a comprehensive study of the deeply sourced alkaline basalts formed along the Kunlun strike-slip fault with the aim of understanding their petrogenesis and the composition of mantle sources beneath the northeastern Tibetan Plateau. High Nb/U and Ce/Pb ratios and relatively depleted bulk-rock Sr-Nd-Pb isotope compositions corroborate the mantle origin of these alkaline basalts. Homogeneous and low 87Sr/86Sr of clinopyroxene indicates negligible crustal contamination during magmatic evolution. Low δ26Mg in the alkaline basalts and positive correlations with Hf/Sm and Ti/Ti* indicate that the basalts were derived from mantle that was metasomatized by melts derived from sedimentary carbonates during the Paleo-Tethyan seafloor subduction. Based on 40Ar/39Ar dating results, it appears that the alkaline basaltic magmatism in the northeastern Tibetan Plateau occurred simultaneously with Kunlun strike-slip faulting. These observations suggest that the India-Asia convergence must have reactivated ancient subduction plate boundaries and resulted in strike-slip faulting along these suture zones within and around the Tibetan Plateau. The eruption of low-volume and deeply rooted alkaline basalts may have been controlled by fractures associated with the strike-slip fault systems.

青藏高原内部和周围广泛存在的新生代碱性岩浆活动为探测玄武岩岩浆发源地深处的地幔性质提供了一个绝佳的机会。火山活动与区域性走向滑动断层系统之间密切的时空关系也有助于更好地理解高原在印度-亚洲持续汇聚作用下向外生长的地球动力学。我们对沿昆仑走向滑动断层形成的深源碱性玄武岩进行了全面研究,旨在了解其岩石成因和青藏高原东北部地下地幔源的组成。高Nb/U和Ce/Pb比值以及相对贫化的大块岩石Sr-Nd-Pb同位素组成证实了这些碱性玄武岩的地幔来源。霞石的87Sr/86Sr均一且较低,表明岩浆演化过程中地壳的污染可以忽略不计。碱性玄武岩中的δ26Mg含量较低,且与Hf/Sm和Ti/Ti*呈正相关,表明这些玄武岩来源于地幔,而地幔在古泰西期海底俯冲过程中被沉积碳酸盐岩的熔融物变质。根据 40Ar/39Ar 测定结果,青藏高原东北部的碱性玄武岩岩浆活动似乎与昆仑走向滑动断层同时发生。这些观察结果表明,印度-亚洲辐合一定重新激活了古代俯冲板块边界,并导致青藏高原内部和周围沿这些缝合带的走向滑动断层。火山喷发量小、根深蒂固的碱性玄武岩可能受到了与走向滑动断层系统相关的断裂的控制。
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引用次数: 0
Dependence of Simulated Fault Gouge Frictional Behavior on Mineral Surface Chemistry Quantified by Cation Exchange Capacity 通过阳离子交换容量量化模拟断层冲沟摩擦行为与矿物表面化学性质的关系
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-21 DOI: 10.1029/2024GC011678
Matt J. Ikari, Marianne Conin

The slip behavior of crustal faults is known to be controlled by the composition of the fault gouge, but the exact mechanisms, especially considering the role of water-rock interactions, are still under investigation. Here, we use a geochemical approach measuring the cation exchange capacity (CEC) of several phyllosilicate minerals and non-clays, using CEC as a proxy for the ability to bind water to the mineral surfaces and/or develop electrostatic forces between particles. Laboratory shearing experiments show that low CEC materials (<3 mEq/100 g) tend to exhibit high friction, low cohesion, and velocity-weakening frictional behavior. Phyllosilicate minerals exhibit CEC values up to 78 mEq/100 g and correspondingly lower friction coefficients, higher cohesion, and a tendency for velocity-strengthening friction. Zeolite behavior is atypical, exhibiting a high CEC value typical of phyllosilicates but the strength and frictional characteristics of a non-clay with low CEC. This suggests that the structure of the mineral is important for non-phyllosilicates. For phyllosilicates, our results can be explained by water bound to mineral surfaces, creating bridges of hydrogen or van der Waals bonds between particles. The enhanced particle bonding for high CEC materials is consistent with high cohesion under zero effective stress conditions, and lowered friction by trapping bound water between the mineral surfaces under normal load. Bound water may explain the tendency for velocity-strengthening friction in high CEC materials by hindering a Dieterich-type time-dependent frictional strengthening mechanism.

众所周知,地壳断层的滑移行为受断层冲沟成分的控制,但其确切机制,特别是考虑到水与岩石相互作用的作用,仍在研究之中。在此,我们采用地球化学方法测量了几种植物硅酸盐矿物和非粘土的阳离子交换容量(CEC),用CEC来表示水与矿物表面结合的能力和/或颗粒间产生静电力的能力。实验室剪切实验表明,低 CEC 材料(<3 mEq/100 g)往往表现出高摩擦力、低内聚力和速度减弱摩擦行为。叶硅酸盐矿物的 CEC 值高达 78 mEq/100 g,因此摩擦系数较低、内聚力较高,并倾向于速度增强摩擦。沸石的行为并不典型,它表现出典型的植硅酸盐的高 CEC 值,但却具有低 CEC 的非粘土的强度和摩擦特性。这表明矿物结构对非叶硅酸盐非常重要。就植硅酸盐而言,我们的结果可以解释为水与矿物表面结合,在颗粒之间形成氢桥或范德华键。高 CEC 材料的颗粒结合力增强,这与零有效应力条件下的高内聚力以及在法向载荷作用下通过在矿物表面之间捕获结合水而降低摩擦力是一致的。结合水可能会阻碍迪特里希类型的时间依赖性摩擦强化机制,从而解释高 CEC 材料中速度强化摩擦的趋势。
{"title":"Dependence of Simulated Fault Gouge Frictional Behavior on Mineral Surface Chemistry Quantified by Cation Exchange Capacity","authors":"Matt J. Ikari,&nbsp;Marianne Conin","doi":"10.1029/2024GC011678","DOIUrl":"https://doi.org/10.1029/2024GC011678","url":null,"abstract":"<p>The slip behavior of crustal faults is known to be controlled by the composition of the fault gouge, but the exact mechanisms, especially considering the role of water-rock interactions, are still under investigation. Here, we use a geochemical approach measuring the cation exchange capacity (CEC) of several phyllosilicate minerals and non-clays, using CEC as a proxy for the ability to bind water to the mineral surfaces and/or develop electrostatic forces between particles. Laboratory shearing experiments show that low CEC materials (&lt;3 mEq/100 g) tend to exhibit high friction, low cohesion, and velocity-weakening frictional behavior. Phyllosilicate minerals exhibit CEC values up to 78 mEq/100 g and correspondingly lower friction coefficients, higher cohesion, and a tendency for velocity-strengthening friction. Zeolite behavior is atypical, exhibiting a high CEC value typical of phyllosilicates but the strength and frictional characteristics of a non-clay with low CEC. This suggests that the structure of the mineral is important for non-phyllosilicates. For phyllosilicates, our results can be explained by water bound to mineral surfaces, creating bridges of hydrogen or van der Waals bonds between particles. The enhanced particle bonding for high CEC materials is consistent with high cohesion under zero effective stress conditions, and lowered friction by trapping bound water between the mineral surfaces under normal load. Bound water may explain the tendency for velocity-strengthening friction in high CEC materials by hindering a Dieterich-type time-dependent frictional strengthening mechanism.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"25 9","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011678","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142276554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Paleomagnetism-Based Chronology of Holocene Lava Flows at Mt Ruapehu, Aotearoa New Zealand 基于古地磁学的新西兰奥特亚罗瓦鲁佩胡山全新世熔岩流年表
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-19 DOI: 10.1029/2024GC011745
Pedro Doll, Gillian M. Turner, Ben M. Kennedy, Alexander R. L. Nichols, Annika Greve, Jim W. Cole, Shaun R. Eaves, Dougal B. Townsend, Graham S. Leonard, Chris E. Conway

Dating young lava flows is essential for understanding volcano's eruption frequency, yet challenging due to methodological limitations of commonly used dating techniques. Ruapehu (Aotearoa New Zealand) produced many lava flows during the Holocene, but constraints on the timing of these eruptions are scarce. Here, we use paleomagnetic dating to deliver new eruption ages of 18 lava flows with uncertainties ranging between 500 and 2,700 years (at the 95% confidence level). Comparison between lava flows' paleomagnetic directions and a local paleosecular variation record indicates that the large lava flow field located on the Whakapapa area was emplaced during at least three distinct eruptive episodes between 10600 and 7400 BP. Two of these episodes closely followed a large collapse event that affected Ruapehu's northern area and generated large volumes of lava between 10600 and 8800 BP, with the third episode producing less voluminous lava flows between 8100 and 7400 BP. Following a smaller collapse of the southeastern sector of the edifice at ca. 5300 BP, several low-volume lava flows were emplaced during at least two distinct eruptive episodes prior to ca. 1000 BP, which supplied the Whangaehu valley with lava. The youngest age inferred from our data represents the youngest eruption age provided for a lava flow outside Ruapehu's summit region. This research provides greater detail to the Holocene effusive chronology at Ruapehu, shedding light on partial cone reconstructions after edifice collapses during the Holocene, and the time relationships between trends observed in its effusive and explosive activity.

对年轻的熔岩流进行测年对于了解火山的喷发频率至关重要,但由于常用测年技术在方法上的局限性,对其进行测年具有挑战性。鲁阿佩胡火山(新西兰奥特亚罗瓦)在全新世期间产生了许多熔岩流,但对这些火山喷发时间的限制却很少。在这里,我们利用古地磁测年法给出了 18 个熔岩流的新喷发年龄,其不确定性在 500 年到 2700 年之间(95% 置信度)。熔岩流的古地磁方向与当地古地磁变化记录的比较表明,位于Whakapapa地区的大型熔岩流场至少是在公元前10600年到公元前7400年之间的三次不同的喷发过程中喷发的。其中两次紧随影响鲁阿佩胡北部地区的大型塌陷事件之后,在公元前 10600 年至 8800 年期间产生了大量熔岩,第三次在公元前 8100 年至 7400 年期间产生的熔岩流量较少。大约在公元前 5300 年,火山口的东南部发生了一次规模较小的坍塌。在大约公元前 5300 年,至少有两次不同的喷发期产生了几股低容量的熔岩流,这些熔岩流为旺海湖山谷提供了熔岩。从我们的数据中推断出的最年轻年龄代表了鲁阿佩胡山顶地区以外熔岩流的最年轻喷发年龄。这项研究为鲁阿佩胡全新世的喷出年代学提供了更多细节,揭示了全新世期间建筑物坍塌后部分火山锥的重建情况,以及在其喷出和爆炸活动中观察到的趋势之间的时间关系。
{"title":"Paleomagnetism-Based Chronology of Holocene Lava Flows at Mt Ruapehu, Aotearoa New Zealand","authors":"Pedro Doll,&nbsp;Gillian M. Turner,&nbsp;Ben M. Kennedy,&nbsp;Alexander R. L. Nichols,&nbsp;Annika Greve,&nbsp;Jim W. Cole,&nbsp;Shaun R. Eaves,&nbsp;Dougal B. Townsend,&nbsp;Graham S. Leonard,&nbsp;Chris E. Conway","doi":"10.1029/2024GC011745","DOIUrl":"https://doi.org/10.1029/2024GC011745","url":null,"abstract":"<p>Dating young lava flows is essential for understanding volcano's eruption frequency, yet challenging due to methodological limitations of commonly used dating techniques. Ruapehu (Aotearoa New Zealand) produced many lava flows during the Holocene, but constraints on the timing of these eruptions are scarce. Here, we use paleomagnetic dating to deliver new eruption ages of 18 lava flows with uncertainties ranging between 500 and 2,700 years (at the 95% confidence level). Comparison between lava flows' paleomagnetic directions and a local paleosecular variation record indicates that the large lava flow field located on the Whakapapa area was emplaced during at least three distinct eruptive episodes between 10600 and 7400 BP. Two of these episodes closely followed a large collapse event that affected Ruapehu's northern area and generated large volumes of lava between 10600 and 8800 BP, with the third episode producing less voluminous lava flows between 8100 and 7400 BP. Following a smaller collapse of the southeastern sector of the edifice at ca. 5300 BP, several low-volume lava flows were emplaced during at least two distinct eruptive episodes prior to ca. 1000 BP, which supplied the Whangaehu valley with lava. The youngest age inferred from our data represents the youngest eruption age provided for a lava flow outside Ruapehu's summit region. This research provides greater detail to the Holocene effusive chronology at Ruapehu, shedding light on partial cone reconstructions after edifice collapses during the Holocene, and the time relationships between trends observed in its effusive and explosive activity.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"25 9","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011745","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142275091","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Core-Top Calibrations for Element-To-Calcium Proxies of Seawater Properties in Bamboo Corals (Keratoisididae) From the South China Sea 南中国海竹珊瑚(Keratoisididae)海水性质的元素-钙代用指标的核顶校准
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-18 DOI: 10.1029/2024GC011677
Xiaoli Zhou, Haozhuang Wang, Yuhan Zhu, Yue Wang, Les Watling, Zhimin Jian, Peijun Qiao

Bamboo corals are promising archives of paleoceanographic conditions. Existing calibrations for element-to-calcium ratio (El/Ca) proxies of bamboo corals, however, are not necessarily calibrated to contemporaneous environmental parameters, thus weakening the reliability of the proxies. Here, we aim at calibrating the proxies by comparing El/Ca in the outermost surface of the calcareous skeletons of live-collected bamboo corals from the South China Sea (SCS) with modern environmental records. Statistical analysis suggests that Mg/Ca and Ba/Ca can be expressed as a function of in situ seawater temperature and silicate concentration, respectively, that is, Mg/Ca (mmol/mol) = 2.17 ± 0.51 * T (°C) + 74.90 ± 2.66 and Ba/Ca (μmol/mol) = 0.070 ± 0.020 * Silicate (μmol/kg) + 7.27 ± 2.42. The slope of the Mg/Ca-T equation from this study is slightly different from that in a previous study on bamboo corals, likely due to taxonomic and/or geographic differences of the corals and/or differences in sampling strategy and pre-treatment method. Intra- and inter-coral variations have small effects on Mg/Ca, yielding an uncertainty of 2.04 mmol/mol in Mg/Ca (95% confidence interval), equivalent to 0.94°C in estimated temperature. The slope of the Ba/Ca-silicate equation is the same as that in a previous study, suggesting little effect of geographic difference on Ba/Ca. Intra- and inter-coral variations in Ba/Ca are larger than those in Mg/Ca, possibly reflecting incorporation of multiple Ba-rich particulate phases and/or highly variable nutrient concentrations in the micro-environment near corals. These new calibrations allow reconstructions of paleo-temperature and nutrient concentration in the SCS on decadal and longer timescales.

竹珊瑚是很有希望的古海洋条件档案。然而,现有的竹珊瑚元素钙比(El/Ca)代用指标并不一定与当时的环境参数进行校准,从而削弱了代用指标的可靠性。在此,我们通过比较从中国南海(SCS)活体采集的竹珊瑚钙质骨骼最外层的钙镁比值(El/Ca)与现代环境记录来校准代用指标。统计分析表明,Mg/Ca和Ba/Ca可分别表示为原位海水温度和硅酸盐浓度的函数,即Mg/Ca(mmol/mol)= 2.17 ± 0.51 * T(℃)+ 74.90 ± 2.66,Ba/Ca(μmol/mol)= 0.070 ± 0.020 * 硅酸盐(μmol/kg)+ 7.27 ± 2.42。本研究中 Mg/Ca-T 等式的斜率与之前对竹节珊瑚的研究略有不同,这可能是由于珊瑚的分类和/或地理差异和/或取样策略和预处理方法的不同造成的。珊瑚内部和珊瑚之间的变化对 Mg/Ca 的影响较小,因此 Mg/Ca 的不确定性为 2.04 mmol/mol(95% 置信区间),相当于估计温度的 0.94°C。Ba/Ca-硅酸盐方程的斜率与之前的研究相同,表明地理差异对Ba/Ca的影响很小。珊瑚内部和珊瑚之间 Ba/Ca 的变化比 Mg/Ca 的变化要大,这可能反映了珊瑚附近微环境中多种富含 Ba 的颗粒相和/或营养浓度的高度变化。通过这些新的校准结果,可以重建南中国海的古温度和营养物质浓度的十年或更长的时间尺度。
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引用次数: 0
Dynamic Recrystallization of Olivine During Simple Shear: Evolution of Microstructure and Crystallographic Preferred Orientation From Full-Field Numerical Simulations 简单剪切过程中橄榄石的动态再结晶:从全场数值模拟看显微结构和晶体学优先取向的演变
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-18 DOI: 10.1029/2023GC011212
Y. Yu, A. Griera, E. Gomez-Rivas, P. D. Bons, D. García-Castellanos, B. Hao, R. A. Lebensohn, M.-G. Llorens

Upper mantle deformation is mainly controlled by the mechanical behavior of olivine. Crystallographic preferred orientations (CPOs) develop in olivine due to crystal-plastic deformation during mantle flow, where the a-axes of olivine polycrystalline aggregates are aligned with the flow direction. Therefore, the observed CPO in olivine-rich rocks is used as an indicator of the mantle flow direction. Experimental data show that olivine rheology is strongly controlled by the microstructure. While the influence of plastic deformation is in general well characterized, the role of dynamic recrystallization during deformation is not totally understood, limiting our ability to interpret the deformation history of naturally deformed rocks. This contribution presents microdynamic numerical simulations of olivine polycrystalline aggregates with different iron content (i.e., fayalite content) with the aim of exploring the CPO and grain size response to dynamic recrystallization. We use a full-field approach with an explicit simulation of viscoplastic deformation and dynamic recrystallization processes under simple shear boundary conditions up to high strain. The simulations show that the CPOs are similar and practically reach the same maximum regardless of the iron content. CPOs are characterized by a single cluster of a-axis and two-clusters of b-axis, reveling a joint activity of the easy glide [100](010) and the moderate strength [100](010) slip systems. High-strain domains of our models are consistent with experimental results, showing an A-type fabric with double maxima, and where the CPO is aligned with the shear direction. The model provides a deeper understanding of the dynamic recrystallization influence on olivine CPOs resulting from plastic deformation.

上地幔变形主要受橄榄石机械行为的控制。由于地幔流动过程中的晶体塑性变形,橄榄石中出现了晶体学优选取向(CPO),即橄榄石多晶聚集体的 a 轴与流动方向一致。因此,在富橄榄石岩石中观测到的 CPO 可作为地幔流动方向的指标。实验数据表明,橄榄石的流变性受到微观结构的强烈控制。虽然塑性变形的影响总体上已得到很好的描述,但对变形过程中动态再结晶的作用还不完全了解,这限制了我们解释天然变形岩石变形历史的能力。本文介绍了不同铁含量(即辉绿岩含量)橄榄石多晶聚集体的微观动态数值模拟,旨在探索动态再结晶对 CPO 和晶粒尺寸的响应。我们采用全场方法,明确模拟了简单剪切边界条件下的粘塑性变形和动态再结晶过程,直至高应变。模拟结果表明,无论铁含量多少,CPOs 都是相似的,并且实际上达到了相同的最大值。CPO 的特征是 a 轴有一个簇,b 轴有两个簇,揭示了易滑动 [100](010) 和中等强度 [100](010) 滑移系统的共同活动。模型的高应变域与实验结果一致,显示出具有双最大值的 A 型结构,其中 CPO 与剪切方向一致。该模型有助于深入理解塑性变形对橄榄石 CPO 的动态再结晶影响。
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引用次数: 0
Formation of a Large Cold Groundwater Mantle Helium Anomaly and High Temperature Geothermal Resources in Response to Bimodal Magmatism Near Roosevelt Hot Springs and Utah FORGE, Milford Valley, Southwest Utah 犹他州西南部米尔福德山谷罗斯福温泉和犹他州 FORGE 附近双峰岩浆作用形成的大型冷地下水地幔氦异常和高温地热资源
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-17 DOI: 10.1029/2024GC011539
Stuart F. Simmons, Stefan Kirby

A large mantle helium anomaly and separate domains of high heat flow are the predominant manifestations of bimodal magmatic activity in the Milford valley. The mantle helium anomaly (1.9–2.6 R/Ra) covers 270 km2 and is subdivided into two separated domains: a cold shallow groundwater regime and high temperature hydrothermal activity. The zone of anomalous heat flow covers >100 km2 and is also subdivided into two adjacent domains, comprising hydrothermal activity at Roosevelt Hot Springs (RHS) (3–7 W/m2) and conductive heat flow (100–180 mW/m2). While the transfer of heat and mantle helium at RHS are coupled, heat and helium transfer are decoupled in the adjacent cold groundwater regime to the west. Both the mantle helium and geothermal anomalies are attributed to recent mafic-felsic magmatic intrusions of >400 km3, however, the absence of volcanic eruptions <500,000 years indicates magmas stall before rising to shallow crustal level <10 km depth. Deep level magmatism produces a felsic composition melt, which is inferred to be responsible for the widespread and near uniform range of diluted mantle helium values. A thick and impermeable mass of crystalline granitic basement rock at the mid-crustal level divides the ascent of mantle helium into separate flow paths. It may also impede the rise of buoyant magma trapping thermal energy that facilitates partial melting, slow cooling, and development of a thick thermal aureole. Partitioning of convective and conductive thermal regimes and independent flow paths supplying deeply derived helium characterize the development of a large long-lived magma-related geothermal system.

米尔福德山谷的双峰岩浆活动主要表现为巨大的地幔氦异常和独立的高热流域。地幔氦异常(1.9-2.6 R/Ra)面积达 270 平方公里,细分为两个独立的区域:低温浅层地下水系统和高温热液活动。热流异常区面积为 100 平方公里,也被细分为两个相邻的区域,包括罗斯福温泉(RHS)的热液活动(3-7 W/m2)和传导热流(100-180 mW/m2)。热量和地幔氦在罗斯福温泉的传递是耦合的,而在西面相邻的冷地下水系统中,热量和氦的传递是分离的。地幔氦和地热异常都是由于近期400立方公里的岩浆侵入造成的,但是,50万年来没有火山喷发,这表明岩浆在上升到10公里深的地壳浅层之前就停滞了。深层岩浆活动产生了长石成分的熔体,据推断,这就是稀释地幔氦值范围广泛且近乎一致的原因。地壳中层厚而不透水的结晶花岗岩基底岩石将地幔氦的上升分为不同的流动路径。它还可能阻碍浮力岩浆的上升,捕获热能,促进部分熔化、缓慢冷却和形成厚厚的热晕。对流和传导热机制的分离以及提供深层衍生氦的独立流动路径是大型长寿命岩浆相关地热系统发展的特征。
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引用次数: 0
A REE Inverse Model From Bulk Distribution Coefficients and Boundary Conditions: Results for Shield and Rejuvenated Stage Hawaiian Volcanoes 根据块体分布系数和边界条件建立的 REE 反演模型:盾状火山和年轻化阶段夏威夷火山的研究结果
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-16 DOI: 10.1029/2024GC011651
M. J. Carr, M. D. Feigenson, E. Gazel
<p>A major challenge in mantle geochemistry is determining the source composition and melt fraction involved in melting. We provide a new Rare-Earth Element (REE) inverse model that provides source concentration, source and melt mineral modes, and melt fraction based on the difference between separate determinations of bulk distribution coefficients and constrained by boundary conditions. An analytical inverse of the batch melting equation provides expressions for source, <span></span><math> <semantics> <mrow> <msubsup> <mi>C</mi> <mi>o</mi> <mi>i</mi> </msubsup> </mrow> <annotation> ${C}_{o}^{i}$</annotation> </semantics></math>, and bulk distribution coefficient of the mantle, <span></span><math> <semantics> <mrow> <msubsup> <mi>D</mi> <mi>o</mi> <mi>i</mi> </msubsup> </mrow> <annotation> ${D}_{o}^{i}$</annotation> </semantics></math>, with two unknowns, the initial concentration of La in the mantle, <span></span><math> <semantics> <mrow> <msubsup> <mi>C</mi> <mi>o</mi> <mrow> <mi>L</mi> <mi>a</mi> </mrow> </msubsup> </mrow> <annotation> ${C}_{o}^{La}$</annotation> </semantics></math>, and <i>P</i><sup><i>i</i></sup>, the bulk distribution coefficient of the melt. We traverse through a range of <span></span><math> <semantics> <mrow> <msubsup> <mi>C</mi> <mi>o</mi> <mrow> <mi>L</mi> <mi>a</mi> </mrow> </msubsup> </mrow> <annotation> ${C}_{o}^{La}$</annotation> </semantics></math> steps and examine thousands of melt modes, <i>P</i><sup><i>i</i></sup>, at each step. Thousands of trial melt modes fail by generating <span></span><math> <semantics> <mrow> <msubsup> <mi>D</mi> <mi>o</mi> <mi>i</mi> </msubsup> </mrow> <annotation> ${D}_{o}^{i}$</annotation> </semantics></math> that are inconsistent with partition coefficients. Many surviving trials cannot be inverted to estimate a mantle mode. Other boundary conditions eliminate
地幔地球化学的一个主要挑战是确定熔融过程中涉及的源成分和熔体分数。我们提供了一种新的稀土元素(REE)反演模型,它可以提供源浓度、源和熔融矿物模式,以及基于单独测定的体分布系数和边界条件约束之间的差值的熔融分数。批量熔融方程的分析逆模型提供了源 C o i ${C}_{o}^{i}$ 和地幔体分布系数 D o i ${D}_{o}^{i}$ 的表达式,其中有两个未知数,即地幔中 La 的初始浓度 C o L a ${C}_{o}^{La}$ 和熔体的体分布系数 Pi。我们遍历了 C o L a ${C}_{o}^{La}$ 的一系列步骤,并在每个步骤中检验了数千种熔体模式 Pi。数以千计的试验熔融模式因产生与分区系数不一致的 D o i ${D}_{o}^{i}$ 而失败。许多幸存的试验无法反演以估计地幔模式。其他边界条件则会消除更多的试验。根据熔岩套件的 REE 数据计算出的 D o i ${D}_{o}^{i}$ 与根据分区系数和地幔模式计算出的 D c i ${D}_{c}^{i}$ 之间的差值,对存活的试验进行排序。我们选择最接近拟合且通过所有边界条件的解。我们用夏威夷的熔岩套件测试了我们的新模型,不同的证据表明它们熔化自不同的地幔源,莫纳凯亚代表屏蔽期熔岩,而海底基基代表再生期熔岩。我们对地幔成分和熔融参数的反向确定与早期基于 HREE 成分假设的模型是一致的。
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引用次数: 0
3D Shear Velocity Structure of the Caribbean—Northwestern South America Subduction Zone From Ambient Noise and Ballistic Rayleigh Wave Tomography 从环境噪声和弹道瑞雷波断层扫描看加勒比海-南美洲西北部俯冲带的三维剪切速度结构
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-12 DOI: 10.1029/2024GC011612
Wenpei Miao, John Cornthwaite, Alan Levander, Fenglin Niu, Michael Schmitz, Guoliang Li, Viviana Dionicio, German Prieto

The Caribbean-South America subduction zone is a flat subduction zone, with Laramide-style thick-skinned uplifts occurring in the Merida Andes, Sierra de Perija Range, and Santa Marta Massif. Geodetic measurements and historical seismicity show this region is storing strain energy and is capable of a mega-thrust earthquake (M ≥ 8.0). Previous seismic investigations of the lithosphere and upper mantle in this area are either very large scale, very local, or only peripheral to this area; therefore, details of the Caribbean plate subduction geometry beneath the Maracaibo block remain unclear. In this study, we used a new data set acquired by the Caribbean-Merida Andes seismic experiment (CARMA), which comprised 65 temporary broadband stations and 44 permanent stations from the Colombian and Venezuelan national seismic networks. We jointly inverted ambient noise Rayleigh wave Z/H ratios, phase velocities in the 8–30 s band and ballistic Rayleigh wave phase velocities in 30–80 s band to construct a 3-D S-wave velocity model in the area between 75°–65°W and 5°–12°N. The 3-D model reveals a general increase in crust thickness from the trench to the southeast. An anomalous area is the Lake Maracaibo, which is underlaid by the thinnest crystalline crust in the region. This observation may indicate that the Maracaibo block is experiencing a contortion deformation within the crust. We also identified a high velocity anomaly above the subducting Caribbean slab, likely representing a detached piece of eclogitized Caribbean large igneous province from the base of the Maracaibo block. Additionally, our Vs model clearly indicates a slab tear within the subducted Caribbean slab, approximately beneath the Oca-Ancon Fault.

加勒比-南美洲俯冲带是一个平坦的俯冲带,在梅里达安第斯山脉、Sierra de Perija 山脉和圣玛尔塔山丘出现拉拉姆式厚皮隆起。大地测量和历史地震活动表明,该地区正在储存应变能量,有可能发生特大推力地震(M ≥ 8.0)。以前对这一地区岩石圈和上地幔的地震调查要么规模很大,要么非常局部,要么只是在这一地区的外围;因此,马拉开波区块下加勒比板块俯冲几何形状的细节仍不清楚。在这项研究中,我们使用了加勒比海-梅里达安第斯地震实验(CARMA)获得的新数据集,其中包括来自哥伦比亚和委内瑞拉国家地震网络的 65 个临时宽带台站和 44 个永久台站。我们联合反演了环境噪声瑞雷波 Z/H 比值、8-30 s 波段的相位速度和 30-80 s 波段的弹道瑞雷波相位速度,构建了西经 75°-65° 和北纬 5°-12° 之间区域的三维 S 波速度模型。三维模型显示,地壳厚度从海沟向东南方向普遍增加。马拉开波湖是一个异常区域,该区域的结晶地壳厚度最薄。这一观察结果可能表明,马拉开波区块正在经历地壳内部的扭曲变形。我们还在俯冲的加勒比板块上方发现了一个高速异常点,它很可能代表从马拉开波区块底部分离出来的一块碎屑化加勒比大火成岩带。此外,我们的 Vs 模型清楚地表明,在俯冲的加勒比板块内部,大约在奥卡-安孔断层的下方,存在板块撕裂。
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引用次数: 0
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Geochemistry Geophysics Geosystems
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