P. Zarębski, Dominik Katarzyński, Hanna Godlewska-Majkowska, A. Komor, A. Gawryluk
In this study, the potential impact of wind farm locations on the sustainable development of cities in Poland was evaluated, considering the availability of wind-generated electricity. We analyzed 37 cities in Poland with populations over 100,000. Research indicates that wind farms located 30–80 km from large cities perform best in terms of generating capacity, while greater distances increase transmission costs and energy losses. In Poland, wind farms are primarily situated in the northwestern regions, posing challenges for energy transmission to the southern cities, which are the main centers of energy consumption. The findings show that wind farms with the highest generating capacity are generally about 50 km from major cities. Key factors influencing wind farm locations include technical criteria, economic feasibility, environmental impact, public opinion, and the availability of transmission networks. Sustainable development of wind farms requires strategic cooperation between urban and rural municipalities, joint spatial planning, coordinated land acquisition, and the exchange of know-how.
{"title":"Wind Farms’ Location and Geographical Proximity as a Key Factor in Sustainable City Development: Evidence from Poland","authors":"P. Zarębski, Dominik Katarzyński, Hanna Godlewska-Majkowska, A. Komor, A. Gawryluk","doi":"10.3390/en17143447","DOIUrl":"https://doi.org/10.3390/en17143447","url":null,"abstract":"In this study, the potential impact of wind farm locations on the sustainable development of cities in Poland was evaluated, considering the availability of wind-generated electricity. We analyzed 37 cities in Poland with populations over 100,000. Research indicates that wind farms located 30–80 km from large cities perform best in terms of generating capacity, while greater distances increase transmission costs and energy losses. In Poland, wind farms are primarily situated in the northwestern regions, posing challenges for energy transmission to the southern cities, which are the main centers of energy consumption. The findings show that wind farms with the highest generating capacity are generally about 50 km from major cities. Key factors influencing wind farm locations include technical criteria, economic feasibility, environmental impact, public opinion, and the availability of transmission networks. Sustainable development of wind farms requires strategic cooperation between urban and rural municipalities, joint spatial planning, coordinated land acquisition, and the exchange of know-how.","PeriodicalId":504870,"journal":{"name":"Energies","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141651167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fujie Wang, Fanfan Li, Wei Sun, Xiaozhong Song, Huishan Lu
To address the high complexity and low accuracy issues of traditional methods in mixed coal vitrinite identification, this paper proposes a method based on an improved DeepLabv3+ network. First, MobileNetV2 is used as the backbone network to reduce the number of parameters. Second, an atrous convolution layer with a dilation rate of 24 is added to the ASPP (atrous spatial pyramid pooling) module to further increase the receptive field. Meanwhile, a CBAM (convolutional block attention module) attention mechanism with a channel multiplier of 8 is introduced at the output part of the ASPP module to better filter out important semantic features. Then, a corrective convolution module is added to the network’s output to ensure the consistency of each channel’s output feature map for each type of vitrinite. Finally, images of 14 single vitrinite components are used as training samples for network training, and a validation set is used for identification testing. The results show that the improved DeepLabv3+ achieves 6.14% and 3.68% improvements in MIOU (mean intersection over union) and MPA (mean pixel accuracy), respectively, compared to the original DeepLabv3+; 12% and 5.3% improvements compared to U-Net; 9.26% and 4.73% improvements compared to PSPNet with ResNet as the backbone; 5.4% and 9.34% improvements compared to PSPNet with MobileNetV2 as the backbone; and 6.46% and 9.05% improvements compared to HRNet. Additionally, the improved ASPP module increases MIOU and MPA by 3.23% and 1.93%, respectively, compared to the original module. The CBAM attention mechanism with a channel multiplier of 8 improves MIOU and MPA by 1.97% and 1.72%, respectively, compared to the original channel multiplier of 16. The data indicate that the proposed identification method significantly improves recognition accuracy and can be effectively applied to mixed coal vitrinite identification.
{"title":"An Identification Method for Mixed Coal Vitrinite Components Based on An Improved DeepLabv3+ Network","authors":"Fujie Wang, Fanfan Li, Wei Sun, Xiaozhong Song, Huishan Lu","doi":"10.3390/en17143453","DOIUrl":"https://doi.org/10.3390/en17143453","url":null,"abstract":"To address the high complexity and low accuracy issues of traditional methods in mixed coal vitrinite identification, this paper proposes a method based on an improved DeepLabv3+ network. First, MobileNetV2 is used as the backbone network to reduce the number of parameters. Second, an atrous convolution layer with a dilation rate of 24 is added to the ASPP (atrous spatial pyramid pooling) module to further increase the receptive field. Meanwhile, a CBAM (convolutional block attention module) attention mechanism with a channel multiplier of 8 is introduced at the output part of the ASPP module to better filter out important semantic features. Then, a corrective convolution module is added to the network’s output to ensure the consistency of each channel’s output feature map for each type of vitrinite. Finally, images of 14 single vitrinite components are used as training samples for network training, and a validation set is used for identification testing. The results show that the improved DeepLabv3+ achieves 6.14% and 3.68% improvements in MIOU (mean intersection over union) and MPA (mean pixel accuracy), respectively, compared to the original DeepLabv3+; 12% and 5.3% improvements compared to U-Net; 9.26% and 4.73% improvements compared to PSPNet with ResNet as the backbone; 5.4% and 9.34% improvements compared to PSPNet with MobileNetV2 as the backbone; and 6.46% and 9.05% improvements compared to HRNet. Additionally, the improved ASPP module increases MIOU and MPA by 3.23% and 1.93%, respectively, compared to the original module. The CBAM attention mechanism with a channel multiplier of 8 improves MIOU and MPA by 1.97% and 1.72%, respectively, compared to the original channel multiplier of 16. The data indicate that the proposed identification method significantly improves recognition accuracy and can be effectively applied to mixed coal vitrinite identification.","PeriodicalId":504870,"journal":{"name":"Energies","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141650810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The dynamic control of an active magnetic bearing (AMB) rotor after the rotor falls to its touch-down bearings has always been a difficult problem for applications such as flywheel energy storage. The rotor drop process has obvious nonlinear dynamic characteristics. This paper first discusses the structure of AMBs and the basic principles of their control. Starting from the electromagnetic forces that electromagnets can provide, the problem is simplified to the influence of an electromagnetic force with constant damping characteristics on the dynamic characteristics of a dropped rotor. A dynamic model of an AMB rotor with touch-down bearings was built and the contact force model between the rotor and the touch-down bearings was determined. A constant damping electromagnetic force was applied in two ways to verify the dynamic control feasibility of a dropped rotor through magnetic bearings. The simulation results show that the dropped rotor recovery control is feasible by applying a reasonable electromagnetic force.
在飞轮储能等应用中，如何对主动磁悬浮轴承（AMB）转子落到触地轴承后进行动态控制一直是个难题。转子下落过程具有明显的非线性动态特性。本文首先讨论了 AMB 的结构及其控制的基本原理。从电磁铁可提供的电磁力出发，将问题简化为具有恒定阻尼特性的电磁力对转子下落动态特性的影响。建立了一个带有触地轴承的 AMB 转子动态模型，并确定了转子与触地轴承之间的接触力模型。通过两种方式施加恒定阻尼电磁力，以验证通过磁悬浮轴承对下降转子进行动态控制的可行性。仿真结果表明，通过施加合理的电磁力，掉落转子的恢复控制是可行的。
{"title":"Preliminary Study on Recontrol Evaluation of a Magnetic Bearing Rotor Falling on Touch-Down Bearings","authors":"Kai Zhang, Yang Xu","doi":"10.3390/en17143457","DOIUrl":"https://doi.org/10.3390/en17143457","url":null,"abstract":"The dynamic control of an active magnetic bearing (AMB) rotor after the rotor falls to its touch-down bearings has always been a difficult problem for applications such as flywheel energy storage. The rotor drop process has obvious nonlinear dynamic characteristics. This paper first discusses the structure of AMBs and the basic principles of their control. Starting from the electromagnetic forces that electromagnets can provide, the problem is simplified to the influence of an electromagnetic force with constant damping characteristics on the dynamic characteristics of a dropped rotor. A dynamic model of an AMB rotor with touch-down bearings was built and the contact force model between the rotor and the touch-down bearings was determined. A constant damping electromagnetic force was applied in two ways to verify the dynamic control feasibility of a dropped rotor through magnetic bearings. The simulation results show that the dropped rotor recovery control is feasible by applying a reasonable electromagnetic force.","PeriodicalId":504870,"journal":{"name":"Energies","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141650779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A smart grid protection system based on phasor information at circuit breakers is proposed in this paper. Phasor data for fault diagnosis is obtained from phasor measurement units or intelligent electronic devices installed near circuit breakers, without the need for additional measurement equipment. When a fault occurs, the protection system first locates the core protection circuit breaker closest to the fault point. It then identifies the faulty component by analyzing the current phasor differences between this breaker and adjacent ones. This scheme offers high computational efficiency, enabling rapid identification of faulty equipment and its precise location. The proposed protection system structure can be divided into two types: centralized and decentralized, and the most suitable scheme should be selected based on the actual situation. Finally, the feasibility of the proposed scheme was verified through the IEEE 39-bus system and a simulated actual area power grid model, demonstrating its applicability to practical smart grid scenarios. The simulation network validates the implementation method of the proposed protection strategy.
{"title":"Research on the Protection System for Smart Grid Based on Phasor Information at Circuit Breakers","authors":"Yi Liu, Ding Dang, Seon-Keun Lee","doi":"10.3390/en17143455","DOIUrl":"https://doi.org/10.3390/en17143455","url":null,"abstract":"A smart grid protection system based on phasor information at circuit breakers is proposed in this paper. Phasor data for fault diagnosis is obtained from phasor measurement units or intelligent electronic devices installed near circuit breakers, without the need for additional measurement equipment. When a fault occurs, the protection system first locates the core protection circuit breaker closest to the fault point. It then identifies the faulty component by analyzing the current phasor differences between this breaker and adjacent ones. This scheme offers high computational efficiency, enabling rapid identification of faulty equipment and its precise location. The proposed protection system structure can be divided into two types: centralized and decentralized, and the most suitable scheme should be selected based on the actual situation. Finally, the feasibility of the proposed scheme was verified through the IEEE 39-bus system and a simulated actual area power grid model, demonstrating its applicability to practical smart grid scenarios. The simulation network validates the implementation method of the proposed protection strategy.","PeriodicalId":504870,"journal":{"name":"Energies","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141651820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
L.S. Filina-Dawidowicz, Joanna Sęk, P. Trojanowski, A. Wiktorowska-Jasik
The changes in geopolitical and ecological conditions brought about the need to use environmentally friendly sources of vehicle power. This impacted the accelerated activities related to the use of hydrogen fuel in transport means. Based on the observations carried out in the countries of Central and Eastern Europe, it was found that the process of implementing hydrogen-powered vehicles in public transport is connected with difficulties faced by transport companies with regard to the purchase of these transport means. This study aims to analyse the conditions for making decisions regarding the implementation of hydrogen-powered buses in urban transport. A case study was considered, and the factors influencing the decisions related to the application of hydrogen-powered buses in Poland were analysed. The survey method was used to carry out the research. A questionnaire was developed, and the survey was conducted among representatives of transport companies that provide public transport services in Polish cities. As a result of the research, it was found that city authorities play a key role in deciding on the implementation of hydrogen-powered buses. The highest ranks among the proposed criteria influencing the decision on the purchase of hydrogen-powered buses were the economic ones. The concerns and benefits resulting from the potential purchase of hydrogen-powered buses were also examined. It was revealed that the decision to buy buses is most influenced by factors such as ensuring access to hydrogen and its price. The recommendations for transport companies and city authorities were formulated.
{"title":"Conditions of Decision-Making Related to Implementation of Hydrogen-Powered Vehicles in Urban Transport: Case Study of Poland","authors":"L.S. Filina-Dawidowicz, Joanna Sęk, P. Trojanowski, A. Wiktorowska-Jasik","doi":"10.3390/en17143450","DOIUrl":"https://doi.org/10.3390/en17143450","url":null,"abstract":"The changes in geopolitical and ecological conditions brought about the need to use environmentally friendly sources of vehicle power. This impacted the accelerated activities related to the use of hydrogen fuel in transport means. Based on the observations carried out in the countries of Central and Eastern Europe, it was found that the process of implementing hydrogen-powered vehicles in public transport is connected with difficulties faced by transport companies with regard to the purchase of these transport means. This study aims to analyse the conditions for making decisions regarding the implementation of hydrogen-powered buses in urban transport. A case study was considered, and the factors influencing the decisions related to the application of hydrogen-powered buses in Poland were analysed. The survey method was used to carry out the research. A questionnaire was developed, and the survey was conducted among representatives of transport companies that provide public transport services in Polish cities. As a result of the research, it was found that city authorities play a key role in deciding on the implementation of hydrogen-powered buses. The highest ranks among the proposed criteria influencing the decision on the purchase of hydrogen-powered buses were the economic ones. The concerns and benefits resulting from the potential purchase of hydrogen-powered buses were also examined. It was revealed that the decision to buy buses is most influenced by factors such as ensuring access to hydrogen and its price. The recommendations for transport companies and city authorities were formulated.","PeriodicalId":504870,"journal":{"name":"Energies","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141651295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The introduction of the pilot flame can stabilize the lean premixed flame and promote its industrial application. However, the interaction mechanism between the pilot and main flames is complicated. To reveal the effect of the pilot flame on the main flame, a laminar lean premixed flame adjacent to a rich premixed pilot flame on one side and a similar lean premixed flame on the other side was considered. A two-dimensional numerical model was adopted with detailed chemistry and species transport, also with no artificial flame anchoring boundary conditions. The results show that the pilot flame could promote the main flame stabilized in different locations with various shapes, by adjusting the stretch, heat transfer, and preferential diffusion in a complicated manner. The pilot flame improves the local equivalence ratio and transfer more heat to the main flame. The growth of the pilot flame equivalence ratio and inlet velocity enhances the combustion on the rich side of the main flame and helps it anchor closer to the flame wall. Both the curvature and strain rate show a significant effect on the flame root, which contributes to the main flame bending towards the pilot flame.
{"title":"Numerical Investigation on the Flame Characteristics of Lean Premixed Methane Flame Piloted with Rich Premixed Flame","authors":"Lili Zhang, Yongzhang Cui, Pengfei Yin, Wenlong Mao, Pengzhao Zhang","doi":"10.3390/en17143430","DOIUrl":"https://doi.org/10.3390/en17143430","url":null,"abstract":"The introduction of the pilot flame can stabilize the lean premixed flame and promote its industrial application. However, the interaction mechanism between the pilot and main flames is complicated. To reveal the effect of the pilot flame on the main flame, a laminar lean premixed flame adjacent to a rich premixed pilot flame on one side and a similar lean premixed flame on the other side was considered. A two-dimensional numerical model was adopted with detailed chemistry and species transport, also with no artificial flame anchoring boundary conditions. The results show that the pilot flame could promote the main flame stabilized in different locations with various shapes, by adjusting the stretch, heat transfer, and preferential diffusion in a complicated manner. The pilot flame improves the local equivalence ratio and transfer more heat to the main flame. The growth of the pilot flame equivalence ratio and inlet velocity enhances the combustion on the rich side of the main flame and helps it anchor closer to the flame wall. Both the curvature and strain rate show a significant effect on the flame root, which contributes to the main flame bending towards the pilot flame.","PeriodicalId":504870,"journal":{"name":"Energies","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141652732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The present paper is concerned with a magnetorheological (MR)-damper-based vibration-reduction system with energy harvesting capability considering sprung mass changes. The system represents a mechanical harmonic oscillator with electrical coupling, set in motion by kinematic excitation. The authors examine the system performance in the case when the MR damper control coil (damper control coil) is powered directly by the alternating current resulting from the voltage generated in an electromagnetic harvester in the assumed frequency range of sine excitation. Such a system is able to attenuate vibration in the near-resonance frequency range when the current in the damper control coil increases; however, its drawback is vibration amplification at higher frequencies. To eliminate this negative feature, it is proposed to connect shunt capacitors in parallel with the damper control coil. Then, the system can be tested experimentally in terms of current in the damper control coil, sprung mass, and the capacity of shunt capacitors in order to evaluate system performance according to the assumed performance index. The obtained results demonstrate significant improvement in system performance at higher frequencies of excitation.
{"title":"Performance Improvement of an MR-Damper-Based Vibration-Reduction System with Energy Harvesting at Sprung Mass Changes","authors":"Bogdan Sapiński, Ł. Jastrzębski","doi":"10.3390/en17143436","DOIUrl":"https://doi.org/10.3390/en17143436","url":null,"abstract":"The present paper is concerned with a magnetorheological (MR)-damper-based vibration-reduction system with energy harvesting capability considering sprung mass changes. The system represents a mechanical harmonic oscillator with electrical coupling, set in motion by kinematic excitation. The authors examine the system performance in the case when the MR damper control coil (damper control coil) is powered directly by the alternating current resulting from the voltage generated in an electromagnetic harvester in the assumed frequency range of sine excitation. Such a system is able to attenuate vibration in the near-resonance frequency range when the current in the damper control coil increases; however, its drawback is vibration amplification at higher frequencies. To eliminate this negative feature, it is proposed to connect shunt capacitors in parallel with the damper control coil. Then, the system can be tested experimentally in terms of current in the damper control coil, sprung mass, and the capacity of shunt capacitors in order to evaluate system performance according to the assumed performance index. The obtained results demonstrate significant improvement in system performance at higher frequencies of excitation.","PeriodicalId":504870,"journal":{"name":"Energies","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141652671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Inês Teixeira, A. Ferreira, Nelson Rodrigues, Senhorinha Teixeira
People aim for thermal comfort inside their homes. However, this is not achievable for everyone due to several factors, such as low income, poor building envelope, expensive technology, and increased energy costs, thus leading to energy poverty. This work gathers studies regarding energy poverty and its indicators, identified by different authors and considering different regions, techno-economic, governmental, and political considerations. It was observed that renewable energy sources are a good investment in the long term but require a high initial investment. Government policy measures should be applied to mitigate the costs, especially given the increasing requirement for clean energy use in new buildings. There are still many barriers to overcoming energy poverty, and the variables for action are numerous. The best solution passes through the assessment of adequate technological solutions with economic incentives from the government for the most vulnerable individuals that should be identified by region and economic power. Energy poverty is a multidimensional problem that depends on individual characteristics such as households’ income, specific energy needs, and available technologies, as well as external factors such as energy prices, climatic conditions, and energy access. The majority of energy indicators are directly related to economic aspects, whereas social or environmental considerations are only indirectly accounted for.
{"title":"Energy Poverty and Its Indicators: A Multidimensional Framework from Literature","authors":"Inês Teixeira, A. Ferreira, Nelson Rodrigues, Senhorinha Teixeira","doi":"10.3390/en17143445","DOIUrl":"https://doi.org/10.3390/en17143445","url":null,"abstract":"People aim for thermal comfort inside their homes. However, this is not achievable for everyone due to several factors, such as low income, poor building envelope, expensive technology, and increased energy costs, thus leading to energy poverty. This work gathers studies regarding energy poverty and its indicators, identified by different authors and considering different regions, techno-economic, governmental, and political considerations. It was observed that renewable energy sources are a good investment in the long term but require a high initial investment. Government policy measures should be applied to mitigate the costs, especially given the increasing requirement for clean energy use in new buildings. There are still many barriers to overcoming energy poverty, and the variables for action are numerous. The best solution passes through the assessment of adequate technological solutions with economic incentives from the government for the most vulnerable individuals that should be identified by region and economic power. Energy poverty is a multidimensional problem that depends on individual characteristics such as households’ income, specific energy needs, and available technologies, as well as external factors such as energy prices, climatic conditions, and energy access. The majority of energy indicators are directly related to economic aspects, whereas social or environmental considerations are only indirectly accounted for.","PeriodicalId":504870,"journal":{"name":"Energies","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141653167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Proton Exchange Membrane Fuel Cells (PEMFCs) represent a promising green solution for energy production, traditionally relying on platinum-group-metal (PGM) electrocatalysts. However, the increasing cost and limited global availability of PGMs have motivated extensive research into alternative catalyst materials. PGM-free oxygen reduction reaction (ORR) catalysts typically consist of first-row transition metal ions (Fe, Co) embedded in a nitrogen-doped carbon framework. Key factors affecting their efficacy include intrinsic activity and catalyst degradation. Thus, alternative materials with improved characteristics and the elucidation of reaction and degradation mechanisms have been the main concerns and most frequently explored research paths. High intrinsic activity and active site density can ensure efficient reaction rates, while durability towards corrosion, carbon oxidation, demetallation, and deactivation affects cell longevity. However, when moving to the actual application in PEMFCs, electrode engineering, which involves designing the catalyst layer, and other critical operational factors affecting fuel cell performance play a critical role. Electrode fabrication parameters such as ink formulation and deposition techniques are thoroughly discussed herein, explicating their impact on the electrode microstructure and formed electrochemical interface and subsequent performance. Adjusting catalyst loading, ionomer content, and porosity are part of the optimization. More specifically, porosity and hydrophobicity determine reactant transport and water removal. High catalyst loadings can enhance performance but result in thicker layers that hinder mass transport and water management. Moreover, the interaction between ionomer and catalyst affects proton conductivity and catalyst utilization. Strategies to improve the three-phase boundary through the proper ionomer amount and distribution influence catalyst utilization and water management. It is critical to find the right balance, which is influenced by the catalyst–ionomer ratio and affinity, the catalyst properties, and the layer fabrication. Overall, understanding how composition and fabrication parameters impact electrode properties and behaviour such as proton conductivity, mass transport, water management, and electrode–electrolyte interfaces is essential to maximize electrochemical performance. This review highlights the necessity for integrated approaches to unlock the full potential of PGM-free materials in PEMFC technology. Clear prospects for integrating PGM-free catalysts will drive cleaner and more cost-effective, sustainable, and commercially viable energy solutions.
{"title":"Enhancing Electrode Efficiency in Proton Exchange Membrane Fuel Cells with PGM-Free Catalysts: A Mini Review","authors":"Ioanna Martinaiou, M. Daletou","doi":"10.3390/en17143443","DOIUrl":"https://doi.org/10.3390/en17143443","url":null,"abstract":"Proton Exchange Membrane Fuel Cells (PEMFCs) represent a promising green solution for energy production, traditionally relying on platinum-group-metal (PGM) electrocatalysts. However, the increasing cost and limited global availability of PGMs have motivated extensive research into alternative catalyst materials. PGM-free oxygen reduction reaction (ORR) catalysts typically consist of first-row transition metal ions (Fe, Co) embedded in a nitrogen-doped carbon framework. Key factors affecting their efficacy include intrinsic activity and catalyst degradation. Thus, alternative materials with improved characteristics and the elucidation of reaction and degradation mechanisms have been the main concerns and most frequently explored research paths. High intrinsic activity and active site density can ensure efficient reaction rates, while durability towards corrosion, carbon oxidation, demetallation, and deactivation affects cell longevity. However, when moving to the actual application in PEMFCs, electrode engineering, which involves designing the catalyst layer, and other critical operational factors affecting fuel cell performance play a critical role. Electrode fabrication parameters such as ink formulation and deposition techniques are thoroughly discussed herein, explicating their impact on the electrode microstructure and formed electrochemical interface and subsequent performance. Adjusting catalyst loading, ionomer content, and porosity are part of the optimization. More specifically, porosity and hydrophobicity determine reactant transport and water removal. High catalyst loadings can enhance performance but result in thicker layers that hinder mass transport and water management. Moreover, the interaction between ionomer and catalyst affects proton conductivity and catalyst utilization. Strategies to improve the three-phase boundary through the proper ionomer amount and distribution influence catalyst utilization and water management. It is critical to find the right balance, which is influenced by the catalyst–ionomer ratio and affinity, the catalyst properties, and the layer fabrication. Overall, understanding how composition and fabrication parameters impact electrode properties and behaviour such as proton conductivity, mass transport, water management, and electrode–electrolyte interfaces is essential to maximize electrochemical performance. This review highlights the necessity for integrated approaches to unlock the full potential of PGM-free materials in PEMFC technology. Clear prospects for integrating PGM-free catalysts will drive cleaner and more cost-effective, sustainable, and commercially viable energy solutions.","PeriodicalId":504870,"journal":{"name":"Energies","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141653394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lithium-ion battery pack performance, safety, and lifespan are significantly influenced by temperature, yet little research has focused on the specific effects of temperature during the drying phase in paint booths. This study aims to analyse how drying temperatures affect battery modules compared to operational conditions (e.g., driving, charging) and to analyse the influence of the battery state of charge on the temperature reached by the traction battery during the drying phase. Various temperature measurement methods, including diagnostic equipment and thermocouples, were employed to conduct tests. Results indicate that the battery pack temperature during the drying phase remains below 60 °C. Comparisons with temperature measurements in other scenarios (e.g., charging, high-temperature parking) show significantly higher temperatures, highlighting the relatively low impact of paint booth drying temperatures on battery thermal management.
锂离子电池组的性能、安全性和使用寿命受温度的影响很大，但很少有研究关注喷漆房干燥阶段温度的具体影响。本研究旨在分析干燥温度与运行条件（如驾驶、充电）相比对电池模块的影响，并分析电池充电状态对牵引电池在干燥阶段达到的温度的影响。测试采用了各种温度测量方法，包括诊断设备和热电偶。结果表明，电池组在干燥阶段的温度保持在 60 °C 以下。与其他情况（如充电、高温停车）下的温度测量结果相比，温度明显更高，这说明烤漆房的干燥温度对电池热管理的影响相对较小。
{"title":"Analysis of the Temperature Reached by the Traction Battery of an Electric Vehicle during the Drying Phase in the Paint Booth","authors":"Ana Olona, Luis Castejón","doi":"10.3390/en17143437","DOIUrl":"https://doi.org/10.3390/en17143437","url":null,"abstract":"Lithium-ion battery pack performance, safety, and lifespan are significantly influenced by temperature, yet little research has focused on the specific effects of temperature during the drying phase in paint booths. This study aims to analyse how drying temperatures affect battery modules compared to operational conditions (e.g., driving, charging) and to analyse the influence of the battery state of charge on the temperature reached by the traction battery during the drying phase. Various temperature measurement methods, including diagnostic equipment and thermocouples, were employed to conduct tests. Results indicate that the battery pack temperature during the drying phase remains below 60 °C. Comparisons with temperature measurements in other scenarios (e.g., charging, high-temperature parking) show significantly higher temperatures, highlighting the relatively low impact of paint booth drying temperatures on battery thermal management.","PeriodicalId":504870,"journal":{"name":"Energies","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141652679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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