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New data on the Turonian nodular phosphate-bearing bed in the Dobrindol Formation south of Kaspichan, NE Bulgaria 关于保加利亚东北部卡斯皮昌以南多布林多尔地层中图伦纪结核磷酸盐床的新数据
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.201
Millena Vetseva, A. Hikov, D. Dochev, Yavor Stefanov
The Turonian nodular phosphate-bearing bed outcropping near Kaspichan consists of early diagenetically mineralized (carbonate-fluorapatite – CFA, glauconite and goethite) limestone lithoclasts (nodules), mineralized macrofauna, and non-mineralized intraclasts, embedded in a glauconite-CFA cement. The characteristics of the nodular bed are consistent with a formation under extremely low net sedimentation rate with nodules demonstrating evidence for reworking. The identified ammonite association assigns late Turonian age of the bed. XRF and LA-ICPMS analyses reveal low P, U, and REE-Y concentrations, with correlations between REE and the other authigenic oxides indicating that glauconite and goethite could be main REE concentrators along with CFA. Fluctuations in the redox conditions are implied by the authigenic mineral association, mineralization stages, presence of diverse fauna and ichnofissils, and applied geochemical proxies.
卡斯皮昌附近出露的都龙纪结核含磷酸盐岩床由早期成岩矿化(碳酸盐-萤石-CFA、青绿石和网纹石)石灰岩碎屑岩(结核)、矿化大型动物和非矿化内碎屑岩组成,嵌入青绿石-CFA胶结物中。结核床的特征与极低净沉积率下的形成相一致,结核显示了再加工的证据。已确定的褐铁矿关联推断该岩床的年代为晚都龙纪。XRF 和 LA-ICPMS 分析表明,P、U 和 REE-Y 的浓度较低,REE 与其他自生氧化物之间的相关性表明,萤石和网纹石可能是主要的 REE 富集物,CFA 也是如此。氧化还原条件的波动是由自生矿物关联、成矿阶段、各种动物群和蛭石的存在以及应用的地球化学代用指标所暗示的。
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引用次数: 0
Dinoflagellate cyst biostratigraphy of the upper Campanian–lower Maastrichtian interval in the Oslen-Krivodol section, Northwest Bulgaria: preliminary results 保加利亚西北部Oslen-Krivodol段上元古代-下元古代间的甲藻囊生物地层学:初步结果
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.189
P. Pavlishina, D. Dochev
A dinoflagellate cyst biostratigraphy for the upper Campanian–lower Maastrichtian interval in the newly described Oslen-Krivodol section, northwest Bulgaria, is proposed. The dinocyst scheme comprises the zones of Areoligera coronata and Cerodinium diebelii, in ascending order, and illustrates the sharp transition between the Campanian and Maastrichtian dinocyst assemblages. The presented results confirm the high potential of dinoflagellate cysts for biostratigraphic correlations in the Campanian–Maastrichtian boundary interval.
在保加利亚西北部新描述的 Oslen-Krivodol 断面中,提出了上元古代-下元古代间的甲藻胞囊生物地层。该二叠体方案由 Areoligera coronata 和 Cerodinium diebelii 区(按升序排列)组成,并说明了钟乳石期和马斯特里赫特期二叠体组合之间的急剧过渡。研究结果证实了甲藻胞囊在营盘期-马斯特里赫特期边界区间生物地层相关性方面的巨大潜力。
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引用次数: 0
New geological and X-ray diffraction data from sedimentary rocks in the area of Underwater Petrified Forest natural phenomenon, Sozopol Bay, Black Sea 黑海索佐波尔湾水下石化森林自然现象地区沉积岩的新地质和 X 射线衍射数据
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.197
Stefan Velev, D. Dochev, Ralica Sabeva, Lubomir Kenderov, Vesela V. Evtimova, Mihail Iliev, Boyanka Angelova
The current study is part of a comprehensive investigation of the natural phenomenon Underwater Petrified Forest, which has no analog in the Black Sea and is very rare worldwide. The team aims to conduct a comprehensive study of the unique habitat, paleontological and geological phenomenon, the Petrified Forest, and to address a series of scientific questions. This research sheds light on the sedimentation processes related to the fossilization of tree species. X-ray phase analyses were used to compare clay rocks that encase and cover the fossilized trees.
目前的研究是对自然现象 "水下石化森林 "进行全面调查的一部分,该现象在黑海没有类似物,在全世界也非常罕见。研究小组旨在对石化森林这一独特的栖息地、古生物和地质现象进行全面研究,并解决一系列科学问题。这项研究揭示了与树种化石有关的沉积过程。通过 X 射线相分析,对包裹和覆盖树木化石的粘土岩进行了比较。
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引用次数: 0
The fault network in the southern foot of Rila Mountains, SW BulgariaThe fault network in the southern foot of Rila Mountains, SW Bulgaria 保加利亚西南部里拉山南麓的断层网保加利亚西南部里拉山南麓的断层网
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.159
I. Gerdjikov, D. Vangelov
Southwestern slopes of Rila Mountain and northern parts of the Mesta graben are one of the least studied areas in terms of brittle tectonics. We carried out studies in the area around Bachevo and Dobarsko villages aiming to observe the fault zone network. The Bachevo fault zone is defined as Paleogene–Eocene Low-Angle Normal Fault that later underwent strike-slip and normal fault reactivation. The zone is an important tectonic boundary, separating the ca. 56 Ma Kapatnik granite from the Ograzhden Unit. Another important and possibly younger extensional zone is the Semkovo Fault. The relationships between the both zones are unclear. In terms of the Quaternary tectonics, it is important to differentiate between the Semkovo fault and the active Southeastern Rila Normal Fault. There are no data about Quaternary activity of the Bachevo fault zone.
里拉山西南坡和梅斯塔地堑北部地区是脆性构造研究最少的地区之一。我们在巴切沃(Bachevo)和多巴尔斯科(Dobarsko)村周围地区进行了研究,旨在观察断层带网络。巴切沃断层带被定义为古新世低角度正断层,后来经历了走向滑动和正断层的重新激活。该断层带是一个重要的构造边界,将约 56 Ma 的卡帕特尼克花岗岩分隔开来。56 Ma 的卡帕特尼克花岗岩与奥格拉日登单元之间的重要构造边界。另一个重要且可能更年轻的延伸带是塞姆科沃断层。这两个地带之间的关系尚不清楚。就第四纪构造而言,必须区分 Semkovo 断层和活跃的东南里拉正断层。没有关于巴切沃断层带第四纪活动的数据。
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引用次数: 0
Defining of prospective areas for the localization of groundwater in fractured massifs (on the example of the Municipality of Brezovo, Plovdiv Region) 确定断裂丘陵区地下水定位的前景区域(以普罗夫迪夫州布雷佐沃市为例)
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.283
S. Kolev, Peter Gerginov, A. Benderev, Aglaida Toteva, Simeon Valchev, Mila Trayanova-Koleva
The northern part of the Municipality of Brezovo falls within the range of a fractured massif, which predetermines the presence of springs with a limited flow rate, insufficient for water supply for the villages there, which necessitates the localization of suitable locations for boreholes drilling. After a complex assessment of the geological-hydrogeological and tectonic conditions and field surveys, favorable sections were determined with prerequisites for the presence of probable water-saturated fractured zones. As a result of geophysical surveys carried out using the SP method, in the area of the villages of Svezhen, Chehlare and Rozovets, deep water-bearing zones were delineated, which were convincingly confirmed during the subsequent exploratory drilling.
布雷佐沃市北部属于断裂丘陵地带,这就决定了这里的泉水流量有限,不足以为当地村庄供水,因此必须确定合适的钻井地点。在对地质-水文地质和构造条件进行了复杂的评估和实地勘测之后,确定了有利地段,这些地段具备可能存在水饱和断裂带的先决条件。在斯韦珍村、切赫拉雷村和罗佐韦茨村地区使用 SP 方法进行地球物理勘测的结果是,划定了深层含水带,并在随后的勘探钻井中得到了令人信服的证实。
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引用次数: 0
Geochemistry of rutiles from metamorphic rocks of Asenitsa and Arda Units, Central Rhodope, Bulgaria – preliminary results 保加利亚中部罗多坡阿塞尼察和阿尔达单元变质岩中金红石的地球化学--初步结果
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.97
Milena Georgieva, Tzvetomila Vladinova
We present new data on the geochemistry of rutiles from metamorphic rock of the Asenitsa and Arda Units, Central Rhodope Massif, Bulgaria. Trace elements in studied rutiles show large variations that depend on protolith type (metapelites and metabasites), metamorphic grade, the rock geochemistry and mineral association. Zr-in-rutile thermometry distinguishes the rutiles from both units with higher temperatures (650–750 °C) for the Arda Unit and lower temperatures (520–630 °C) for the Asenitsa Unit. The uranium content of most rutiles is too low (<0.5 ppm) for U-Pb dating.
我们提供了关于保加利亚罗多彼山脉中部阿塞尼察和阿尔达单元变质岩中金红石地球化学的新数据。所研究的金红石中的痕量元素显示出很大的差异,这种差异取决于原岩类型(玄武岩和变质岩)、变质等级、岩石地球化学和矿物关联。金红石中的锌测温法将两个单元的金红石区分开来,阿尔达单元的金红石温度较高(650-750 °C),阿森尼察单元的金红石温度较低(520-630 °C)。大多数金红石的铀含量太低(<0.5 ppm),无法进行铀-铅年代测定。
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引用次数: 0
3D geological modeling of ore zones in the Sedefche deposit, Bulgaria 保加利亚 Sedefche 矿床矿带的三维地质建模
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.215
Stoyan Klimentov, Kalin Rouskov
In this study, several geostatistical tools have been employed for the spatial analysis and prediction of the ore body contents in the Sedefche deposit, which is located in the easternmost part of the Zvezdel-Pcheloyad ore field. To test the conditions of stationary and to define a domain reflecting this stationarity, the following approach was applied: modeling of the ore bodies (Wireframe modeling); analysis of domain boundaries, and estimation (Variogram models). The resulted three-dimensional model illustrates the spatial characteristics of Au content distribution and the morphology of the ore body within the Sedefche deposit.
本研究采用了多种地质统计工具,对位于兹韦兹德尔-普切洛亚德矿区最东部的塞德夫切矿床的矿体含量进行空间分析和预测。为了测试静止条件并确定反映这种静止性的域,采用了以下方法:矿体建模(线框建模);域边界分析和估算(变异图模型)。结果显示的三维模型说明了 Sedefche 矿床内金含量分布的空间特征和矿体形态。
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引用次数: 0
Sulphate mineralization from one locality in Lozen ore field, Eastern Rhodopes 东罗多佩山脉洛津矿区一处硫酸盐矿化物
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.47
Rositsa Nikolova, Vladyslav Kostov-Kytin, P. Petrov, Liliya Tsvetanova, Nikolay Gospodinov, Kristina Metodieva
A suite of sulphates from a locality in Lozen ore field in the Eastern Rhodopes has been characterized by chemical analyses and X-ray diffraction. Three mineral species have been identified: epsomite (MgSO4), pickeringite (MgAl2(SO4)4•22H2O) and alunogen (Al2(SO4)3•17H2O). An attempt was made to characterize the phase transformations that occur upon wetting of the studied samples. The results show that at high humidity, pickeringite dissolves, providing constituents for subsequent crystallization of epsomite and alunogen. Further on, upon drying alunogen loses some of its crystallization water and recrystallizes again to pickeringite including magnesium species from the surrounding medium. This study draws light on certain genetic aspects related to the mechanisms and sequence of deposition of sulphate mineralization under similar conditions.
通过化学分析和 X 射线衍射,对东罗多彼山脉 Lozen 矿区的一组硫酸盐进行了鉴定。已确定的矿物种类有三种:硫酸镁(epsomite,MgSO4)、泡沸石(MgAl2(SO4)4-22H2O)和矾土(Al2(SO4)3-17H2O)。研究人员试图描述所研究样品在润湿时发生的相变。结果表明,在湿度较高的情况下,泡沸石会溶解,为随后的沸石和矾土的结晶提供成分。此外,褐藻原在干燥时会失去部分结晶水,再次结晶为泡沸石,包括周围介质中的镁元素。这项研究揭示了在类似条件下与硫酸盐矿化沉积机制和顺序有关的某些遗传学问题。
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引用次数: 0
Silver-impregnated zeolitized tuffs for environmental degradation of ozone 用于臭氧环境降解的银浸渍沸石化凝灰岩
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.15
B. Barbov, K. Zaharieva, Petya Karakashkova, H. Penchev
The natural zeolites were ultrasonically treated and impregnated with silver nanoparticles. The surface stabilized silver nanoparticles dispersion was obtained using an effective electrochemical reduction method. The phase and elemental composition, structure of the Ag-impregnated zeolites (clinoptilolite and mordenite) was studied by various methods such as powder X-ray diffraction, X-ray fluorescence analyses and Fourier-transform infrared spectroscopy. The Ag-impregnated clinoptilolite and mordenite natural zeolite materials with 1.20 wt %, 0.97 wt %, 0.83 wt % and 1.18 wt % silver content were established by XRF analysis. As initial materials were used three types clinoptilolite from Beli Plast, Most, Golobradovo (Kardzhali, Bulgaria) deposits and mordenite from Lyaskovets deposit in Eastern Rhodopes, Bulgaria. The catalytic ability of Ag-mordenite and Ag-clinoptilolites was investigated in the ecologically important reaction of ozone decomposition. The Ag-loaded mordenite demonstrates the higher conversion degree of ozone more than 40% in comparison with Ag-clinoptilolite materials at room temperature.
天然沸石经超声波处理后浸渍了纳米银颗粒。利用有效的电化学还原法获得了表面稳定的银纳米粒子分散体。通过粉末 X 射线衍射、X 射线荧光分析和傅立叶变换红外光谱等多种方法研究了银浸渍沸石(clinoptilolite 和 mordenite)的相和元素组成、结构。通过 XRF 分析,确定了含银量分别为 1.20 wt %、0.97 wt %、0.83 wt % 和 1.18 wt % 的 Ag 浸渍霞石和莫代奈天然沸石材料。作为初始材料,使用了来自 Beli Plast、Most 和 Golobradovo(保加利亚 Kardzhali)矿床的三种黝帘石,以及来自保加利亚东罗多佩斯 Lyaskovets 矿床的莫硒石。在具有重要生态意义的臭氧分解反应中,研究了含银莫代锰矿和含银绿帘石的催化能力。在室温下,与 Ag-clinoptilolite 材料相比,Ag-mordenite 的臭氧转化率更高,超过 40%。
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引用次数: 0
Model based impact assessment on groundwater vulnerability during aggregate quarry operation 基于模型的砂石场运营期间地下水脆弱性影响评估
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.311
Nikolay Stoyanov
A general methodological approach is proposed for the preliminary assessment of the potential impact on groundwater during the operation of quarries for aggregates. The practical application and effectiveness of this approach are by using a numerical model to predict groundwater and soil contamination during the implementation of a project in the region of Breznik, Western Bulgaria. The spread of highly mobile pollutants in both the unsaturated and saturated zones of the rock complex is simulated after emergency spills and prolonged discharges of contaminated water in the quarry area. The forecast is made for a period of 100 years. The numerical model was compiled using the VS2DI program.
为初步评估集料采石场运营期间对地下水的潜在影响,提出了一种通用方法。在保加利亚西部布雷兹尼克地区的一个项目实施过程中,通过使用数值模型预测地下水和土壤污染情况,证明了这种方法的实际应用和有效性。该模型模拟了在采石场地区发生紧急溢出和长期排放污染水之后,高流动性污染物在岩石群的非饱和区和饱和区的扩散情况。预测期为 100 年。数值模型是使用 VS2DI 程序编制的。
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引用次数: 0
期刊
Review of the Bulgarian Geological Society
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