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Redistribution of incompatible elements during hydrothermal alteration of pegmatite from the Djurkovo Pb-Zn deposit, Central Rhodopes 中部罗多彼山脉 Djurkovo 铅锌矿床伟晶岩热液蚀变过程中不相容元素的再分布
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.35
Sylvina Georgieva, R. Vassileva, V. Grozdev, Georgi Milenkov, J. Cempírek, R. Škoda, Elitsa Stefanova
Mineralogical and geochemical study was done on weakly deformed, relatively thin pegmatites that intruded the marbles of the Rhodope metamorphic complex in the Djurkovo Pb-Zn deposit, Central Rhodopes. The pegmatites consist mainly of K-feldspar and quartz and contain minor garnet; the pegmatites lack clear zonation except for the preferable crystallization of the garnet in the central parts. The main accessory minerals are ishikawaite, zircon, monazite-(Ce), apatite, and titanite. The textural relationships indicate later hydrothermal alteration of pegmatites which led to the formation of albite, epidote, sericite, chlorite, carbonate, quartz and leucoxene. The (REE+Y, ACT, Nb, Ta, Ti)-bearing pegmatite minerals (oxides, silicates and phosphates) are partly leached and/or replaced by secondary ones. The newly-formed phases precipitated as anhedral grains along fractures and dissolved zones onto/or close to the primary minerals due to the limited mobility of the incompatible elements in fluids conditioned by pH, ligand activity and temperature.
对中部罗多彼山脉 Djurkovo 铅锌矿床中侵入罗多彼变质综合体大理岩的弱变形、相对较薄的伟晶岩进行了矿物学和地球化学研究。伟晶岩主要由钾长石和石英组成,并含有少量石榴石;除了中部的石榴石结晶较好外,伟晶岩缺乏明显的分带。主要的附属矿物有异长石、锆石、独居石(铈)、磷灰石和榍石。纹理关系表明伟晶岩后来经过热液蚀变,形成了白云石、绿泥石、绢云母、绿泥石、碳酸盐、石英和白云母。含(REE+Y、ACT、Nb、Ta、Ti)的伟晶岩矿物(氧化物、硅酸盐和磷酸盐)部分被浸出和/或被次生矿物取代。由于不相容元素在受 pH 值、配体活性和温度影响的流体中的流动性有限,新形成的物相沿着裂缝和溶解带以正方体晶粒的形式沉淀在原生矿物质上/或靠近原生矿物质的地方。
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引用次数: 0
Millerite from the Madan ore field 来自马丹矿区的米勒铁矿
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.67
P. Petrov
Millerite is discovered in samples from Krushev Dol and Mogilata deposits in the Madan ore field. It was found in two associations different in appearance and mineral composition. One of them is with light green ferro­dolomite, and the other with bright green mariposite (chromium-bearing phengite). Only cobalt and iron are detected as impurity elements in some analyses. They are in small concentrations (below 0.01 apfu). The Ni/S ratio is 0.95. The nickel source is associated with bodies of serpentinized ultramafics cut by ore-bearing veins.
在马丹矿区的克鲁舍夫多尔(Krushev Dol)和莫吉拉塔(Mogilata)矿床的样本中发现了米勒铁矿。在两种不同外观和矿物成分的集合体中发现了它。其中一种与浅绿色的铁罗托洛莫来石伴生,另一种与翠绿色的水帘石(含铬辉石)伴生。在一些分析中只检测到钴和铁作为杂质元素。它们的浓度很小(低于 0.01 apfu)。镍/硫比率为 0.95。镍源与被含矿脉切割的蛇纹石化超闪长岩体有关。
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引用次数: 0
Pegmatites from western Rhodope Mts.: zircon data 罗多彼山脉西部的伟晶岩:锆石数据
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.101
V. Grozdev, R. Vassileva, Sylvina Georgieva
Ages of pegmatites from two localities (Rakitovo, Lepenitsa) from the western Rhodope Mts. were acquired by U-Pb geochronology on zircon with LA-ICP-MS. The pegmatites are hosted by the metamorphic rocks of the Chepino lithotectonic unit. The large pegmatite/s accumulation from the “Suhata Reka” quarry (Rakitovo locality) is formed at 68.7±1.3 Ma, while small deformed body southwards of Velingrad town (Lepenitsa locality) yielded age of 63.4±1.2 Ma. Crosscutting altered andesite dyke is presumed to intrude the metamorphic rocks and pegmatite at 59 Ma in the Lepenitsa locality. The data suggests connection with the initial stage of the magmatic activity of the Rila-West-Rhodope Batholith (RWRB).
通过使用 LA-ICP-MS 对锆石进行 U-Pb 地球年代学研究,获得了罗多彼山脉西部两个地方(Rakitovo 和 Lepenitsa)伟晶岩的年龄。伟晶岩由切皮诺岩石构造单元的变质岩所承载。来自 "Suhata Reka "采石场(拉基托沃地点)的大型伟晶岩/堆积体形成于 68.7±1.3 Ma,而位于大林格勒镇以南的小型变形体(莱佩尼察地点)的年龄为 63.4±1.2 Ma。据推测,横切蚀变安山岩堤侵入变质岩和伟晶岩的时间为 59 Ma。这些数据表明与里拉-西-罗多坡岩浆岩(RWRB)岩浆活动的初始阶段有关。
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引用次数: 0
Coastal foredune enlargement – a sign of sea-level change? An example from the Kavatsite beach-dune system 沿海前沙丘扩大--海平面变化的标志?卡瓦茨特海滩沙丘系统的一个例子
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.329
A. Baltakova
Sea level rise is one of the effects of climate change and the Black Sea is affected, regardless its isolated position from the World Ocean. As a consequent, in various locations worldwide is reported shifting of foredune ridges towards inland and overlapping of newly formed ridges over older secondary features, as parabolic dunes, dune fields, etc. During the field study in 2023, in the Kavatsite foredune ridge was observed such migration of newly formed accumulations on older grey dunes. Comparative analysis of UAV-based photogrammetry and generated orthophoto mosaic overlaid to archive aerial images from the early 20th century showed over 20 m migration of the primary dune ridge inland and also increased beach erosion. Regarding the accelerating sea rise tendency, special attention should be taken to the anthropogenic activities in the coastal zone, including the beach-dune systems – the first natural barrier to the wave action on coasts.
海平面上升是气候变化的影响之一,黑海也受到了影响,尽管它与世界海洋隔绝。因此,世界各地都有前沙丘山脊向内陆移动以及新形成的山脊与老的次生地貌重叠的报道,如抛物线沙丘、沙丘地等。在 2023 年的实地考察中,在 Kavatsite 前沙丘山脊就观察到了这种新形成的堆积物向老的灰色沙丘迁移的现象。无人机摄影测量和生成的正射影像镶嵌图与 20 世纪初的航空档案图像进行的对比分析表明,主要沙丘山脊向内陆迁移了 20 多米,海滩侵蚀也加剧了。关于海平面加速上升的趋势,应特别注意沿海地区的人为活动,包括海滩沙丘系统--海岸波浪作用的第一道天然屏障。
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引用次数: 0
Hydrogeological conditions in the recharge area of the Glava Panega spring 格拉瓦-帕内加泉水补给区的水文地质条件
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.275
Peter Gerginov, A. Benderev
Hydrogeological conditions in karst areas reflect the high velocities of groundwater movement in open or material-filled channels. Usually they remain hidden under the ground, and only high flow rates of the flowing underground water reveal them. An example is one of the largest karst springs in Bulgaria – Glava Panega in the village of Zlatna Panega. There are two hydraulically connected lakes close to the spring head. The purpose of the present study is to establish this relationship, as well as to provide a more accurate information of groundwater discharge zones in the lake near the source of groundwater. The methods used include analyzing specific information from speleological studies, combined with conducted on field geophysical studies. Profiling was carried out using the method of the self potential, as well as research with the determination of the values of the natural electromagnetic field. The obtained results support the understanding of the behavior of the karst system in the area of the Glava Panega spring.
岩溶地区的水文地质条件反映了地下水在开放或充满物质的通道中的高速运动。这些通道通常隐藏在地下,只有高流速的地下水才能将其显现出来。保加利亚最大的岩溶泉之一--Zlatna Panega 村的 Glava Panega 泉就是一个例子。泉眼附近有两个水力相连的湖泊。本研究的目的是确定这种关系,并提供地下水源附近湖泊中地下水排放区的更准确信息。采用的方法包括分析岩洞学研究的具体信息,并结合实地地球物理研究。使用自电位方法进行了剖面分析,并对天然电磁场的数值进行了测定研究。研究结果有助于了解 Glava Panega 泉地区岩溶系统的行为。
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引用次数: 0
The monitoring system of “Aurubis Bulgaria” AD as a means for assessing the condition of groundwater 作为地下水状况评估手段的 "Aurubis Bulgaria "AD 监测系统
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.291
Boyka Mihaylova, Mariya Staneva, Todor Ianakiev
Metallurgical productions are a potential source of environmental pollution, including groundwater. For the preservation of groundwater resources, the proper organization of a network of observation wells to monitor the quantity and quality of groundwater in the territory affected by the production is of а great importance. The object of the present study is the groundwater in the area of the Aurubis Bulgaria plant. The development of the largest own monitoring system in the country has been tracked, with a view to obtain a real picture of the ecological state of groundwater and its changes over time.
冶金生产是环境污染的潜在来源,包括地下水。为保护地下水资源,适当组织观测井网络以监测受生产影响地区的地下水数量和质量非常重要。本研究的对象是 Aurubis Bulgaria 工厂地区的地下水。为了获得地下水生态状况及其随时间变化的真实情况,对该国最大的自有监测系统的发展情况进行了跟踪。
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引用次数: 0
The crustal thickness in the Rhodope Metamorphic Complex area from the perspective of the present-day geological knowledge 从当今地质知识的角度看罗多彼变质岩群地区的地壳厚度
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.155
Neven Georgiev
The crustal thickness in the area of the Rhodope Metamorphic Complex decreases from west to east from ~50 km to ~30 km. This regional-scale feature is mostly due to the different rates of extension that the basement rocks experienced in different parts of the complex. In our model, we postulate that the crustal thickness in the area is an effect of the late Eocene zipper-like or hinge-like extensional tectonics that caused a larger amount exhumation of high-grade metamorphic rocks in the eastern parts of the area and lesser one in the west. This zipper-like orogen parallel extension caused a vast tectonic erosion and progressive thinning of the crust from west to east.
罗多彼变质岩群地区的地壳厚度自西向东从约 50 千米减小到约 30 千米。这一区域尺度特征主要是由于基底岩石在该复合体不同地区经历了不同的延伸率。在我们的模型中,我们推测该地区的地壳厚度是晚始新世拉链式或铰链式延伸构造的影响,这种构造导致该地区东部高品位变质岩大量出露,而西部则较少。这种拉链式造山平行延伸造成了巨大的构造侵蚀,地壳自西向东逐渐变薄。
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引用次数: 0
Mineral composition of the Sumer Formation sediments near the village of Sumer (Northwestern Bulgaria) 苏美尔村(保加利亚西北部)附近苏美尔地层沉积物的矿物成分
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.319
Madlena Tsvetkova, Ivanina Sergeeva, Olga Veleva
Previous analyses of the Sumer Formation sediments have been limited to samples up to 400 m deep near the village of Varbitsa. This study extends the investigation, exploring the mineral composition and carbonate content of the sediments near the village of Sumer. Samples were collected from two outcrops at the Montana-Vratsa Road junction (C-1) and the Shugavitsa river basin (C-2). Both outcrops revealed a quartz and calcite content of approximately 75–80%, with a significant variance in calcite levels: 11.4% at C-1 and 31.3% at C-2. Illite (4.5%) and kaolinite (2%), these clay minerals essential for the marls’ sorption properties, were only detected in C-1 samples. The C-2 outcrop exhibits a higher carbonate content (17.65%) compared to C-1 (10.85%). These findings mirror the mineral composition trends observed near Varbitsa, where the content of illite and kaolinite increases with depth. The results provide valuable data for future geochemical and geotechnical evaluations pertinent to the development of geological repositories.
以前对苏美尔地层沉积物的分析仅限于瓦尔比萨村附近最深 400 米的样本。本研究扩大了调查范围,探索苏美尔村附近沉积物的矿物成分和碳酸盐含量。样本采集自蒙大拿-瓦尔比察公路交界处(C-1)和舒加维察河流域(C-2)的两个露头。两个露头均显示石英和方解石含量约为 75-80%,方解石含量差异显著:C-1 为 11.4%,C-2 为 31.3%。伊利石(4.5%)和高岭石(2%)是泥灰岩吸附特性所必需的粘土矿物,仅在 C-1 样品中检测到。C-2 露头的碳酸盐含量(17.65%)高于 C-1(10.85%)。这些发现反映了在 Varbitsa 附近观察到的矿物成分趋势,即伊利石和高岭石的含量随着深度的增加而增加。这些结果为今后与地质储藏库开发有关的地球化学和岩土工程评估提供了宝贵的数据。
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引用次数: 0
Investigating the ground base and the causes for deformations of a building in the town of Russe, Bulgaria 调查保加利亚鲁塞镇一座建筑物的地基和变形原因
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.299
Vanushka Petrova, Mariana Nedelcheva
The building was constructed in the central urban part on a collapsible loess of the II type. The later forms a slope with a height of 10–11 m in the structure proximity. Since the 1990s, the building has been subjected to deformations from strong earthquakes, subsidence and settlement caused by water supply and sewage over-moistening and suffusion flow of loess through the underground galleries beneath it. The present study makes a geotechnical assessment of the ground base, elucidates the causes for the resulting deformations, analyzes the data from the geotechnical monitoring since 2018 and discusses the effectiveness of the performed strengthening of the foundations and the ground base.
该建筑位于城市中心地带,建在二类塌陷黄土上。黄土在建筑附近形成了一个 10-11 米高的斜坡。自 20 世纪 90 年代以来,该建筑一直受到强烈地震、下沉和沉降的影响,下沉和沉降的原因是供水和下水道过度湿润以及黄土在其下方的地下管道中淤积流动。本研究对地基进行了岩土工程评估,阐明了造成变形的原因,分析了 2018 年以来的岩土工程监测数据,并讨论了对地基和地基进行加固的效果。
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引用次数: 0
Engineering geological conditions for the construction of a photovoltaic power plant on coal tailings 在煤炭尾矿上建设光伏发电站的工程地质条件
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.267
Stefan Frangov
Photovoltaic power plants have recently become increasingly common to reduce carbon emissions into the atmosphere. Non-fertile lands occupied by industrial waste are very suitable for their construction. The present study concerns the design and construction of a photovoltaic park on the territory of a reclaimed coal tailings dump “Suhoto Dere” near the TPP “Bobov Dol”. The study includes collection, processing and analysis of archival materials, site mapping, drilling of exploration boreholes, dynamic penetration tests, geophysical electrical resistivity survey, laboratory testing of soil samples to determine physical and mechanical properties; chemical analysis of soil samples to assess soil aggressiveness to concrete and steel. Based on the obtained data, an assessment of the suitability of the site is made and recommendations are given to prevent the occurrence of adverse phenomena and processes.
为了减少大气中的碳排放,光伏发电站最近变得越来越普遍。被工业废弃物占据的非肥沃土地非常适合建造光伏电站。本研究涉及在 "Bobov Dol "风力发电厂附近的 "Suhoto Dere "煤炭尾矿填埋场上设计和建造一个光伏园区。研究内容包括档案资料的收集、处理和分析,现场测绘,钻探孔,动态渗透试验,地球物理电阻率测量,土壤样本的实验室测试,以确定物理和机械性能;土壤样本的化学分析,以评估土壤对混凝土和钢材的侵蚀性。根据获得的数据,对场地的适宜性进行评估,并提出建议,以防止不利现象和过程的发生。
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引用次数: 0
期刊
Review of the Bulgarian Geological Society
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