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Encapsulated Fluorescent Tags to Label Drill Cuttings for Improved Depth Correlation: A Field Application 封装荧光标签用于标记钻屑,以改进深度相关性:现场应用
Pub Date : 2024-06-01 DOI: 10.2118/221466-pa
S. S. Zhu, M. Antoniv, N. Saadoun, G. Thomas, M. Poitzsch, H. Kwak, A. Yousef
Drill cuttings logging (mud logging) is a technology with great potential to deliver formation evaluation and completion efficiency. However, the conventional mud logging technology determines the cutting sample depth using the lag time of the cutting’s return trip, which results in depth uncertainties of ±20 ft or more. We previously proposed to tag cuttings at the bit face with penetrating, impregnating polymeric NanoTags and to determine the cuttings’ depth using the NanoTag’s downward trip time, which could reduce the depth uncertainties to ±1–2 ft. The first field test to test the first generation of NanoTags was completed in December 2019. In that test, the signals of the NanoTags in the cuttings were detected using pyrolysis gas chromatography mass spectrometry (Py-GC/MS) analysis. The second field test for the development of this technology was performed in 2022 using a new generation of optical NanoTags that encapsulated a rhodamine dye. A detection method was also developed to analyze the optical tag on cuttings semiquantitatively using a fluorescent microscope and ImageJ software. Our results suggest that the depth determined by our tagging technology is accurate and correlates well with the mud logging data; the results also indicated that the optimal gap time between each tag injection should be greater than 10 minutes.
钻屑录井(泥浆录井)是一项在地层评估和完井效率方面具有巨大潜力的技术。然而,传统的泥浆测井技术使用切削回程的滞后时间来确定切削样本深度,这导致深度不确定性达到±20 英尺或更高。我们之前曾提议在钻头面使用渗透浸渍聚合物纳米标签(NanoTags)标记切样,并利用纳米标签的下行时间确定切样深度,这样可将深度不确定性降至±1-2 英尺。在该测试中,使用热解气相色谱质谱分析法(Py-GC/MS)检测到了切屑中的 NanoTags 信号。该技术开发的第二次实地测试于 2022 年进行,使用的是封装罗丹明染料的新一代光学 NanoTags。我们还开发了一种检测方法,利用荧光显微镜和 ImageJ 软件对插条上的光学标签进行半定量分析。结果表明,我们的标签技术确定的深度是准确的,与泥浆测井数据相关性良好;结果还表明,每次标签注入之间的最佳间隔时间应大于 10 分钟。
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引用次数: 0
Experimental Study of the Swelling and Rheological Properties of a High-Strength Preformed Particle Gel Lost Circulation Material 高强度预成型颗粒凝胶失重循环材料的膨胀和流变特性实验研究
Pub Date : 2024-06-01 DOI: 10.2118/221465-pa
Yuecheng Zhu, Yingrui Bai, Jinsheng Sun, K. Lv
Preformed particulate gel (PPG) has emerged as a widely utilized lost circulation material in deep oil and gas drilling operations. The objective of our study was to devise a high-strength preformed particle gel (HSPPG) specifically designed to address drilling fluid loss in high-temperature fractured formations. To achieve this, a comprehensive set of laboratory experiments was conducted to assess the swelling and rheological properties of HSPPG under various conditions, and these investigations aimed to provide deeper insights into the pressure-bearing mechanism exhibited by HSPPG. The synthesis of HSPPG involved the copolymerization of acrylamide (AM) and N-hydroxymethacrylamide (NMA) molecular chains, catalyzed by organic peroxides, to form the primary network. Additionally, to enhance its temperature resistance, urea-formaldehyde (UF) resin, known for its superior thermal stability, was incorporated into the secondary network. This unique combination of primary and secondary networks imparted remarkable thermal endurance and structural stability to the resulting HSPPG. The swelling and rheological experiments revealed that HSPPG, with a particle size of 1000 µm, exhibited an equilibrium swelling rate (SR) value of 30.55 and a storage modulus (G’) of 1050 Pa at 120℃. These findings attested to its excellent temperature resistance and structural stability. Furthermore, when subjected to a sodium chloride solution at a temperature of 120℃ and a concentration of 25.0%, HSPPG achieved equilibrium swelling with an SR value of 24.93 and a G’ of approximately 7000 Pa. This significant increase in structural strength was attributed to charge shielding within the highly concentrated brine environment. In the plugging experiments, a wedge-shaped slit with an inlet of 3 mm and an outlet of 1 mm was successfully blocked using a concentration of 4% of HSPPG with a particle size of 1000 μm. The blocking strength achieved was 8.06 MPa. The results of these experiments, as well as the observed filling and plugging state of HSPPG in steel fractured cores, indicated that HSPPG possesses the properties of water absorption, swelling, and extrusion filling. These attributes facilitate the effective formation of a dense blocking layer within the fracture space, exhibiting excellent pressure-bearing capacity. In conclusion, the HSPPG developed in this study represents an advanced swellable granular plugging agent with excellent swelling capacity and structural strength at high temperatures. It offers an ideal solution to mitigate drilling fluid loss from fractured formations under high-temperature and high-salinity conditions.
预成型颗粒凝胶(PPG)已成为深层油气钻井作业中广泛使用的循环损耗材料。我们的研究目标是设计一种高强度预制颗粒凝胶(HSPPG),专门用于解决高温裂缝地层中的钻井液流失问题。为此,我们进行了一系列全面的实验室实验,以评估 HSPPG 在各种条件下的膨胀和流变特性,这些研究旨在深入了解 HSPPG 的承压机理。HSPPG 的合成涉及丙烯酰胺 (AM) 和 N- 羟甲基丙烯酰胺 (NMA) 分子链在有机过氧化物催化下的共聚,形成主网络。此外,为了增强其耐温性,还在二级网络中加入了脲醛(UF)树脂,这种树脂以其出色的热稳定性而著称。这种独特的一级和二级网络组合为 HSPPG 带来了出色的耐热性和结构稳定性。膨胀和流变实验表明,粒径为 1000 微米的 HSPPG 在 120℃ 时的平衡膨胀率(SR)值为 30.55,储存模量(G')为 1050 Pa。这些发现证明了该材料具有出色的耐温性和结构稳定性。此外,在温度为 120℃、浓度为 25.0% 的氯化钠溶液中,HSPPG 实现了平衡膨胀,SR 值为 24.93,G'约为 7000 Pa。结构强度的显著提高归因于高浓度盐水环境中的电荷屏蔽。在堵塞实验中,使用浓度为 4%、粒径为 1000 μm 的 HSPPG 成功堵塞了一个入口为 3 mm、出口为 1 mm 的楔形狭缝。阻塞强度为 8.06 兆帕。这些实验结果以及观察到的 HSPPG 在钢破裂芯中的填充和堵塞状态表明,HSPPG 具有吸水、膨胀和挤压填充的特性。这些特性有助于在断裂空间内有效形成致密的封堵层,表现出优异的承压能力。总之,本研究开发的 HSPPG 是一种先进的可膨胀颗粒堵漏剂,在高温下具有出色的膨胀能力和结构强度。它为缓解高温高盐条件下压裂地层的钻井液流失提供了一种理想的解决方案。
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引用次数: 0
Surveillance Data Analysis Reveals Well Performance and Reservoir Connectivity: A Case Study in Alasehir Geothermal Field 监控数据分析揭示油井性能和储层连通性:阿拉谢希尔地热田案例研究
Pub Date : 2024-06-01 DOI: 10.2118/221454-pa
Hakki Aydin, C. Temizel, C. S. Kabir
The integration of surveillance data analysis, encompassing wellbore pressure, fluid flow rate, tracer injection, and recovery, is pivotal in deciphering the dynamic behavior of wells within a geothermal field. This comprehensive study focuses on the interconnectivity between producers, gauged by the reciprocal-productivity index (RPI), and the synergy between producers and injectors, assessed through capacitance-resistance modeling (CRM). The modified-Hall analysis further corroborates the performance metrics of both injectors and producers, thereby reinforcing operational excellence. These methodologies and related analytical tools are instrumental in refining field management practices. Executing meticulous tracer tests and subsequent analyses is crucial in validating the CRM’s applicability in the field. The fusion of these investigative techniques solidifies the role of CRM in managing geothermal reservoirs. Additionally, this study sheds light on the potential compartmentalization within the reservoir and monitors the evolving performance of producers and injectors over time. Utilizing a suite of analytical tools, including RPI, CRM, and modified-Hall analysis, provides a holistic insight into the reservoir dynamics at the Alaşehir field in Türkiye, ensuring a sustainable and optimized exploitation of geothermal energy.
监控数据分析包括井筒压力、流体流速、示踪剂注入和采收率,这些数据的整合对于解读地热田内油井的动态行为至关重要。这项综合研究的重点是生产者之间的相互联系(通过互惠生产指数(RPI)衡量),以及生产者和注入者之间的协同作用(通过电容-电阻模型(CRM)评估)。修改后的霍尔分析进一步证实了喷射器和生产商的性能指标,从而加强了卓越运营。这些方法和相关分析工具有助于完善油田管理实践。执行细致的示踪测试和后续分析对于验证 CRM 在现场的适用性至关重要。这些调查技术的融合巩固了 CRM 在地热储层管理中的作用。此外,这项研究还揭示了储层内部可能存在的分区,并监测生产者和注入者随时间推移而不断变化的性能。利用包括 RPI、CRM 和修正霍尔分析在内的一整套分析工具,可以全面了解图尔基耶阿拉谢希尔油田的储层动态,从而确保地热能源的可持续优化开发。
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引用次数: 0
Visualization Experimental Study on In-Situ Triggered Displacement Mechanism by Microencapsulated Polymer in Porous Media 多孔介质中微胶囊聚合物原位触发位移机制的可视化实验研究
Pub Date : 2024-06-01 DOI: 10.2118/221460-pa
Yongsheng Liu, Bei Wei, Xulong Cao, Kaoping Song, Fuqing Yuan, Yu Xue, Jianyong Wang, Lei Tang, Yongge Liu, Zhijie Wei, Jian Zhang, Jian Hou
Polymer flooding in deep reservoir profile control presents challenges in balancing injectivity and effective mobility control. To address this, we propose a solution by utilizing a microencapsulated polymer that can be easily injected and thickens over time. However, limited research has been conducted on the flow characteristics and the impact on oil mobilization by such profile control agents. In this study, we approximately simulated the time-varying flow process of microencapsulated polymer through in-situ triggered experiments at high temperature and pressure. The flow characteristics and oil displacement mechanism of the microencapsulated polymer under different trigger times were analyzed, and the displacement efficiency during the triggered viscosity enhancement process in porous media was quantitatively evaluated. The experimental results reveal that microencapsulated polymer exhibits a dual mechanism of near-wellbore reservoir particle temporary plugging and deep formation consistency control mechanisms. The transient aggregation of capsule particles alters the flow path, intensifying after expansion. The interaction between the microcapsule particles and the partially released polymer further enhances the resistance-enhancing property of the solution. The viscosity-enhanced microencapsulated polymer fluid improves the displacement efficiency. Microscopic oil displacement and coreflooding experiments resulted in a decrease in oil saturation of 39.5 and 18.33%, respectively. This study provides valuable microscopic insights into the flow behavior and oil displacement performance of microencapsulated polymer, offering essential guidance for optimizing oil reservoir extraction strategies.
在深层储层剖面控制中,聚合物充注在平衡注入率和有效流动性控制方面面临挑战。为解决这一问题,我们提出了一种解决方案,即利用一种易于注入并能随时间增稠的微胶囊聚合物。然而,关于此类剖面控制剂的流动特性及其对石油动用的影响的研究还很有限。在本研究中,我们通过高温高压下的原位触发实验近似模拟了微胶囊聚合物的时变流动过程。分析了微胶囊聚合物在不同触发时间下的流动特性和驱油机理,并定量评估了微胶囊聚合物在多孔介质中触发增粘过程中的驱油效率。实验结果表明,微胶囊聚合物具有近井筒储层颗粒暂堵和深部地层稠度控制机制的双重机理。胶囊颗粒的瞬时聚集改变了流动路径,并在膨胀后加剧。微胶囊颗粒与部分释放的聚合物之间的相互作用进一步增强了溶液的增阻特性。粘度增强型微胶囊聚合物流体提高了置换效率。微观石油置换和岩心注水实验使石油饱和度分别降低了 39.5% 和 18.33%。这项研究为微胶囊聚合物的流动行为和石油置换性能提供了宝贵的微观见解,为优化油藏开采策略提供了重要指导。
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引用次数: 0
More Biosurfactants and Fewer Synthetic Surfactants to Improve Alkali-Surfactant-Polymer Flooding: Feasibility Study and Large-Scale Field Application 用更多的生物表面活性剂和更少的合成表面活性剂改善碱-表面活性剂-聚合物淹没:可行性研究与大规模现场应用
Pub Date : 2024-06-01 DOI: 10.2118/221458-pa
Yeliang Dong, Dexin Liu, Yu Fan
Alkali-surfactant-polymer (ASP) flooding has achieved highly enhanced oil recovery (EOR) in the Daqing Oil Field; however, there are concerns about synthetic surfactants owing to their high cost and difficulty in biodegradation. Cheap biosurfactants conform to human concepts of green circular economy; however, known biosurfactants, as well as their mixtures with alkali, cannot reduce water/oil interfacial tension (IFT) to ultralow values below 0.01 mN/m, which is necessary for ASP flooding to effectively mobilize residual oil. Therefore, we investigate the feasibility of partially replacing synthetic surfactants with biosurfactants rather than completely replacing them to improve ASP flooding. First, through a series of IFT tests, a blend of rhamnolipids (RLs) and alkylbenzene sulfonate (ABS) in a 1:1 mass ratio is determined to be the optimal mixed surfactant and labeled RL/ABS-opt. Second, the interfacial activities, phase behaviors, and wettability alteration capabilities of ASP solutions with RL/ABS-opt are studied. Then, 1.0 wt% NaOH and 0.2 wt% RL/ABS-opt are determined to construct a new ASP system. Subsequently, the waterflooded cores are displaced using the new and the classical ASP systems. Based on the promising experimental results, the new ASP system floods a test block of 56 wells for 3 years. The EOR and surfactant costs are calculated to determine the technical and economic effects. Finally, the concentrations of surfactants before and after activated sludge treatment (AST) are tested by spectrophotometry to verify the biodegradability of RLs better than that of ABS. The laboratory and field results indicate that more biosurfactants and fewer synthetic surfactants could improve ASP flooding to be more environmentally friendly and cost-effective with a higher EOR.
碱-表面活性剂-聚合物(ASP)水淹法在大庆油田实现了高采收率(EOR);然而,合成表面活性剂因其成本高、生物降解困难而备受关注。廉价的生物表面活性剂符合人类绿色循环经济的理念;然而,已知的生物表面活性剂及其与碱的混合物无法将水/油界面张力(IFT)降至 0.01 mN/m 以下的超低值,而这正是 ASP 淹没有效动员剩余油所必需的。因此,我们研究了用生物表面活性剂部分替代合成表面活性剂而非完全替代合成表面活性剂来改善 ASP 淹没的可行性。首先,通过一系列 IFT 测试,确定鼠李糖脂(RLs)和烷基苯磺酸盐(ABS)以 1:1 的质量比混合为最佳混合表面活性剂,并标记为 RL/ABS-opt。其次,研究了含有 RL/ABS-opt 的 ASP 溶液的界面活性、相行为和润湿性改变能力。然后,确定使用 1.0 wt% NaOH 和 0.2 wt% RL/ABS-opt 构建新的 ASP 系统。随后,使用新的和经典的 ASP 系统对注水岩心进行了置换。基于良好的实验结果,新的 ASP 系统对 56 口井进行了为期 3 年的灌水试验。计算了 EOR 和表面活性剂成本,以确定技术和经济效果。最后,通过分光光度法测试了活性污泥处理(AST)前后表面活性剂的浓度,以验证 RLs 的生物降解性优于 ABS。实验室和现场结果表明,使用更多的生物表面活性剂和更少的合成表面活性剂可以改善 ASP 的淹没情况,使其更环保、更具成本效益和更高的 EOR。
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引用次数: 0
A Simulator Based on Coupling of Reaction Transport Model and Multiphase Hydrate Simulator and Its Application to Studies of Methane Transportation in Marine Sediments 基于反应迁移模型和多相水合物模拟器耦合的模拟器及其在海洋沉积物中甲烷迁移研究中的应用
Pub Date : 2024-06-01 DOI: 10.2118/221456-pa
Haotian Liu, Jiecheng Zhang, Hailong Lu
Methane emissions at seafloor are generally associated with the upward methane migration from the deeper sediments, partly from hydrate dissociation. The anaerobic oxidation of methane (AOM) occurring in the surface sediments acts as an important barrier to methane emissions, caused by the reaction between sulfate ions and dissolved methane molecules. However, the current hydrate simulators rarely consider the transport of sulfate and the subsequent AOM reaction. In this study, to investigate AOM effects in hydrate systems, a new simulator named Tough+Hydrate+AOM (THA) is developed by combining the reaction transport model (RTM) with the widely used Tough+Hydrate (T+H) simulator. The THA simulator is validated using the single-phase cases of the Dvurechenskii mud volcano in Black Sea since the results obtained are in good agreement with previous ones. This simulator is then applied to investigate the response of a hydrate reservoir offshore West Svalbard to seasonal seafloor temperature change and also to confirm its adaptability in multiphase hydrate systems. The results obtained suggest that the AOM filter efficiency is as low as 5%, meaning that the majority of methane released from hydrate dissociation in the deeper sediments will escape into the ocean. The THA simulator considering AOM is expected to be an important tool for assessing methane emissions caused by hydrate destabilization.
海底的甲烷排放一般与甲烷从深层沉积物向上迁移有关,部分原因是水合物解离。发生在表层沉积物中的甲烷厌氧氧化(AOM)是甲烷排放的一个重要障碍,它是由硫酸根离子和溶解的甲烷分子之间的反应引起的。然而,目前的水合物模拟器很少考虑硫酸盐的迁移和随后的 AOM 反应。在本研究中,为了研究水合物系统中的 AOM 效应,通过将反应传输模型 (RTM) 与广泛使用的 Tough+Hydrate (T+H) 模拟器相结合,开发了一种名为 Tough+Hydrate+AOM (THA) 的新模拟器。THA 模拟器使用黑海 Dvurechenskii 泥火山的单相案例进行了验证,因为获得的结果与之前的结果非常一致。随后,该模拟器被用于研究西斯瓦尔巴近海水合物储层对季节性海底温度变化的响应,并确认其在多相水合物系统中的适应性。研究结果表明,AOM 的过滤效率低至 5%,这意味着水合物在深层沉积物中解离释放出的大部分甲烷将逃逸到海洋中。考虑到 AOM 的 THA 模拟器有望成为评估水合物失稳导致甲烷排放的重要工具。
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引用次数: 0
Mississippian (Lower Carboniferous) Facies Heterogeneity and Distribution within the Mixed Carbonate-Siliciclastic Reservoirs of the Midcontinent STACK Play, Oklahoma, USA 美国俄克拉荷马州中大陆 STACK 储层中密西西比(下石炭统)岩相的异质性和分布情况
Pub Date : 2024-06-01 DOI: 10.2118/221455-pa
Jamar Bynum, Jack Pashin, C. Wethington
The objective of this study is to evaluate facies heterogeneity, including both lateral and vertical distributions within the mixed carbonate and siliciclastic reservoirs of the Mississippian System (Lower Carboniferous). This research and statistical approach will aid in future investigations related to determining optimal landing zones, enhancing completion designs, and providing geologic insight into fracture driven well interference studies to increase production efficiency. This study integrates well log, petrographic, sedimentologic, and conventional core analyses along a set of transects across the Anadarko Basin and includes the development of core-based facies logs. Statistical analysis indicates that the Mississippian System in the STACK play of the Anadarko Basin is fundamentally a highly layered rhythmic succession in which a variety of carbonate rock types, siliciclastic rock types, and chert tend to form couplets with siltstone. Thickness-frequency distributions and Markov chain analysis indicate that sediment thickness and lithologic transitions were stochastically regulated and that lithologic cyclicity is not apparent. Overall lithologic trends indicate a transition from carbonate to sandstone in the midramp and from carbonate to mudstone and siltstone in the outer ramp. Stratal geometry defines a series of south-prograding clinoforms, and detailed analysis of vertical trends in the distribution of mudstone, siltstone, sandstone, chert, and carbonate facilitates identification of shoaling-upward parasequences that can be correlated regionally.
本研究的目的是评估面异质性,包括密西西比系统(下石炭统)碳酸盐岩和硅质岩混合储层的横向和纵向分布。这项研究和统计方法将有助于未来与确定最佳着陆区、改进完井设计有关的调查,并为压裂驱动井干扰研究提供地质见解,以提高生产效率。这项研究整合了沿阿纳达科盆地横断面进行的测井记录、岩相学、沉积学和常规岩心分析,包括基于岩心的层位记录的开发。统计分析表明,阿纳达科盆地 STACK 地区的密西西比系基本上是一个高度分层的韵律演替,在这个演替中,各种碳酸盐岩类型、硅质岩类型和白垩岩往往与粉砂岩形成对生。厚度-频率分布和马尔科夫链分析表明,沉积厚度和岩性转换是随机调节的,岩性周期性并不明显。总体岩性趋势表明,中斜坡由碳酸盐岩向砂岩过渡,外斜坡由碳酸盐岩向泥岩和粉砂岩过渡。地层几何定义了一系列向南递变的岩相,对泥岩、粉砂岩、砂岩、白垩岩和碳酸盐岩分布的垂直趋势进行详细分析,有助于确定可在区域内相互关联的浅滩上升准序列。
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引用次数: 0
Predicting Oil Production After Enhancement Techniques Using Multidimensional Feature Representation Learning: A Case Study of Profile Control Technique 利用多维特征表征学习预测增产技术后的石油产量:剖面控制技术案例研究
Pub Date : 2024-06-01 DOI: 10.2118/221461-pa
Lu Yang, Kai Zhang, Huaqing Zhang, Limin Zhang, Jun Yao, Yang Wang, Yongfei Yang, Jian Wang
The prediction of oil production following enhancement techniques has garnered widespread attention, leading scientists to explore this area using machine learning. However, field data collection constraints and single model accuracy limitations mean few models can precisely predict daily oil production after technique implementation. Building upon previous research, this paper introduces a model that predicts oil production after enhancement operations, utilizing multidimensional feature representation learning. It thoroughly examines three characteristic categories affecting the effectiveness of oil production enhancement techniques: geological static parameters, production dynamic parameters, and enhancement technique process parameters. The model comprehensively explores these features with an emphasis on global spatial, local spatial, and temporal information. A complete machine learning prediction process is established, which includes data preprocessing, model training, cross-validation, and oil production prediction after implementing enhancement techniques. The first part of the model involves representation learning on processed data, producing three sets of new features: global spatial, local spatial, and temporal information. These features are fused with the original data, serving as input for the advanced ensemble learning model XGBoost, which predicts daily oil production after implementing the technique. Following the construction of the model, actual field data from profile control techniques are selected to conduct various evaluations based on the model’s performance on validation and test sets. Compared with traditional machine learning regression algorithms, this model demonstrates significantly higher predictive accuracy. The prediction accuracy for oil production using given enhanced techniques reached 96% in the validation set and 94% in the test set. This research provides a technical foundation for selecting appropriate production enhancement techniques in oil fields by accurately predicting oil production after implementing enhancement techniques, which offers guidance for actual oilfield production.
采用增产技术后的石油产量预测受到广泛关注,科学家们开始利用机器学习技术探索这一领域。然而,由于实地数据收集的限制和单一模型精度的局限性,很少有模型能精确预测技术实施后的石油日产量。在以往研究的基础上,本文介绍了一种利用多维特征表示学习预测增产作业后石油产量的模型。它深入研究了影响石油增产技术效果的三个特征类别:地质静态参数、生产动态参数和增产技术工艺参数。该模型以全局空间、局部空间和时间信息为重点,全面探索了这些特征。建立了一个完整的机器学习预测流程,包括数据预处理、模型训练、交叉验证以及实施增产技术后的石油产量预测。模型的第一部分涉及对处理过的数据进行表示学习,产生三组新特征:全局空间信息、局部空间信息和时间信息。这些特征与原始数据融合在一起,作为高级集合学习模型 XGBoost 的输入,用于预测实施技术后的石油日产量。构建模型后,根据模型在验证集和测试集上的表现,选取剖面控制技术的实际现场数据进行各种评估。与传统的机器学习回归算法相比,该模型的预测精度明显更高。在验证集和测试集中,使用给定增强技术的石油产量预测准确率分别达到 96% 和 94%。这项研究通过准确预测实施增产技术后的石油产量,为油田选择合适的增产技术奠定了技术基础,为油田的实际生产提供了指导。
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引用次数: 0
Microbial Sulfate Reduction in Underground Reservoirs: Learnings from Full-Field Modeling and Field Data 地下储层中的微生物硫酸盐还原:从全场建模和现场数据中汲取经验
Pub Date : 2024-06-01 DOI: 10.2118/221453-pa
Ali Mahmoodi, Hamidreza M. Nick
Sulfate-reducing microorganisms are found in various environments, such as shallow marine and freshwater sediments, groundwater, hydrocarbon reservoirs, hydrothermal vents, and mud volcanoes. The reduction of sulfate to hydrogen sulfide (H2S) by sulfate-reducing microorganisms, usually during and after flooding oil reservoirs with seawater (SW), is known as microbial reservoir souring. H2S is a hazardous and corrosive gas, which increases the treatment costs of the produced fluids. Other than the microbiological aspect of this phenomenon, the interplay among the physical aspects of the multiphase flow and (bio)chemical reactions at various scales in the porous media of the subsurface can significantly contribute to the complexity of the problem. This study investigates real field data of several wells in an oil field in the Danish North Sea and presents a modified reservoir souring model coupled with a full-field reservoir model. The effect of various parameters on the production composition data is investigated, and, under various sets of assumptions, the model is matched against the history of the production data. The results demonstrate that sulfate concentration data in the produced water can be a useful compliment to the more common H2S concentration data in the produced gas when tuning the model, thus predicting the future of souring in the field. Moreover, it is shown that the production data can be used to infer the activity of various microbial communities in different locations of the reservoir. Interestingly, the data suggest that the change in the near-wellbore environment during drilling and the completion or the production wells may activate or introduce strains of sulfate-reducing microorganisms, which are responsible for the increase in H2S content in the produced gas during the early stages of production. Microbial souring in the waterflooded regions, on the other hand, corresponds to the increase in H2S production in the later stages of production. Furthermore, it is shown how different sectors of the same field show different souring behaviors and macroscale growth rates (GRs), which are attributed to different elements that affect flow patterns, such as the presence of darcy-scale heterogeneity and fractures.
硫酸盐还原微生物存在于各种环境中,如浅海和淡水沉积物、地下水、碳氢化合物储层、热液喷口和泥火山。通常在油藏被海水(SW)淹没期间和之后,硫酸盐还原微生物会将硫酸盐还原成硫化氢(H2S),这就是所谓的微生物油藏酸化。H2S 是一种有害的腐蚀性气体,会增加采出液的处理成本。除了这种现象的微生物方面,地下多孔介质中不同尺度的多相流物理方面和(生物)化学反应之间的相互作用也会大大增加问题的复杂性。本研究调查了丹麦北海某油田几口油井的实际现场数据,并提出了一个与全油田储层模型相结合的修正储层酸化模型。研究了各种参数对生产成分数据的影响,并在不同的假设条件下,将模型与历史生产数据进行了比对。结果表明,在调整模型时,产水中的硫酸盐浓度数据可以作为产气中更常见的 H2S 浓度数据的有益补充,从而预测油气田未来的酸化情况。此外,研究还表明,生产数据可用于推断储层不同位置的各种微生物群落的活动情况。有趣的是,数据表明,在钻井和完井或生产井过程中,近井筒环境的变化可能会激活或引入硫酸盐还原微生物菌株,这些菌株是生产初期产气中 H2S 含量增加的原因。另一方面,注水区域的微生物酸化与生产后期 H2S 产量的增加相对应。此外,研究还显示了同一气田的不同区域如何表现出不同的酸化行为和宏观增长率(GRs),这归因于影响流动模式的不同因素,如达西尺度异质性和裂缝的存在。
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引用次数: 0
Impact of Pressure-Dependent Interfacial Tension and Contact Angle on Capillary Heterogeneity Trapping of CO2 in Storage Aquifers 随压力变化的界面张力和接触角对蓄水层中二氧化碳毛细管异质性捕集的影响
Pub Date : 2024-06-01 DOI: 10.2118/214925-pa
Bo Ren, James Littlefield, Cunqi Jia, Hailun Ni, Ian Duncan
Carbon dioxide (CO2) capillary trapping increases the total amount of CO2 that can be effectively immobilized in storage aquifers. This trapping, manifesting itself as accumulated CO2 columns at a continuum scale, is because of capillary threshold effects that occur below low-permeability barriers. Considering that capillary pressure is dictated by heterogeneous pore throat size, the trapped CO2 column height and associated CO2 saturation will vary spatially within a storage aquifer. This variation will be influenced by two pressure-dependent interfacial parameters—CO2/brine interfacial tension (IFT) and CO2/brine/rock contact angle. Our objective is to understand how the pressure dependence of these two parameters affects the heterogeneity of capillary trapped CO2 at a continuum scale. Our conceptual model is a 1D two-zone system with the upper zone being a flow barrier (low permeability) and the lower zone being a flow path (high permeability). The inputs to this model include microfacies-dependent capillary pressure vs. saturation curves and permeability values. The input capillary pressure curves were collected in the literature that represents carbonate microfacies (e.g., dolograinstone) in a prevalent formation in the Permian Basin. We then used the Leverett j-function to scale the capillary pressure curve for the two zones that are assigned with the same or different microfacies. During scaling, we considered the influence of pressure on both the IFT and contact angle of CO2/brine/dolomite systems. We varied the zone permeability contrast ratio from 2 to 50. We then assumed capillary gravity equilibriums and calculated the CO2 saturation buildup corresponding to various trapped CO2 column heights. The CO2 saturation buildup is defined as the CO2 saturation in the lower layer minus that in the upper one. We found that the saturation buildup can be doubled when varying pressure in a storage aquifer, after considering pressure-dependent IFT and contact angles. Thus, assuming these two parameters to be constant across such aquifers would cause large errors in the quantification of capillary trapping of CO2. The whole study demonstrates the importance of considering pressure-dependent interfacial properties in predicting the vertical distribution of capillary trapped CO2. It has important implications in developing a better understanding of leakage risks and consequent storage safety.
二氧化碳(CO2)的毛细管截留增加了可有效固定在蓄水层中的二氧化碳总量。这种捕集表现为连续尺度的累积二氧化碳柱,是由于在低渗透障碍物下方发生的毛细管阈值效应。考虑到毛细管压力受异质孔喉大小的影响,封存含水层内的二氧化碳截留柱高度和相关的二氧化碳饱和度会在空间上发生变化。这种变化将受到两个与压力相关的界面参数--二氧化碳/盐水界面张力(IFT)和二氧化碳/盐水/岩石接触角--的影响。我们的目标是了解这两个参数的压力依赖性如何影响毛细管捕集的二氧化碳在连续尺度上的异质性。我们的概念模型是一个一维两区系统,上区为流动屏障(低渗透率),下区为流动路径(高渗透率)。该模型的输入包括与微地层有关的毛细管压力与饱和度曲线以及渗透率值。输入的毛细管压力曲线是在文献中收集的,代表了二叠纪盆地一个普遍地层中的碳酸盐微岩相(如独流岩)。然后,我们使用 Leverett j 函数对两个具有相同或不同微岩相的区域的毛管压力曲线进行缩放。在缩放过程中,我们考虑了压力对二氧化碳/青铜/白云石系统的内渗透率和接触角的影响。我们将区域渗透率对比度从 2 调整为 50。然后,我们假定毛细管重力平衡,并计算了与各种二氧化碳捕集柱高度相对应的二氧化碳饱和积聚量。二氧化碳饱和积聚的定义是下层的二氧化碳饱和度减去上层的饱和度。我们发现,在考虑了与压力相关的 IFT 和接触角之后,当蓄水含水层的压力变化时,饱和积聚量可能会增加一倍。因此,假定这两个参数在此类含水层中保持不变,会导致二氧化碳毛细捕集的量化出现较大误差。整个研究表明,在预测毛细管捕集的二氧化碳的垂直分布时,考虑与压力相关的界面特性非常重要。这对更好地了解渗漏风险和储藏安全具有重要意义。
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引用次数: 0
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SPE Journal
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