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Corrosion deposition in deforming anodes of in-ground cathodic protection systems: A three-dimensional transient study 地面阴极保护系统变形阳极中的腐蚀沉积:三维瞬态研究
M. J. Shirshahi, Abraham Mansouri, Peyman Taheri, S. F. Chini
Cathodic protection as a complementary technique is widely considered in the industry along with the selection of suitable materials as well as efficient coating considerations. In cathodic protection (CP), anode produces a current output to protect the structure (cathode) and part of the current output is wasted by the grounding system. We developed a 3D, and time-dependent numerical model to simulate the anode corrosion (using arbitrary Lagrangian-Eulerian method), find the deposit formation (by interface tracking level set method), anode mass loss and current wasted by the grounding system. We also defined a CP efficiency as anode mass loss times the current percentage received by the structure. The CP efficiency can be utilized for anode quantity and placement pattern. The results showed when the conductivity of corrosion products (deposit) is lower than that of soil, the current output from the anode decreases over time. When the deposit conductivity is higher than that of soil, the current output from the anode increases in time, reaches a peak, then decreases. This is due to the competition among three factors: anode surface increase, medium conductivity change, and inhibition effect of the deposition layer. For the studied case, almost 54% of the current from the anode is wasted by the grounding system. To illustrate the significance of CP efficiency, this study compares three alternative anode configurations with the original design. It is observed that for a 14.5 kg anode, burying the anodes 2 m deeper enhances the mean potential distribution on the structure by 4%. Additionally, the configuration featuring the 7.7 kg anode, owing to its superior dimensional design, demonstrates improved performance compared to other configurations.
阴极保护作为一种补充技术,在选择合适的材料和考虑有效涂层的同时,也被业界广泛采用。在阴极保护(CP)中,阳极产生电流输出以保护结构(阴极),部分电流输出被接地系统浪费掉。我们开发了一个三维和随时间变化的数值模型,以模拟阳极腐蚀(采用任意拉格朗日-欧勒方法)、沉积物形成(采用界面跟踪水平集方法)、阳极质量损失和接地系统浪费的电流。我们还将阳极质量损失乘以结构接收的电流百分比定义为 CP 效率。CP 效率可用于阳极数量和放置模式。结果表明,当腐蚀产物(沉积物)的电导率低于土壤的电导率时,阳极输出的电流会随着时间的推移而减少。当沉积物的电导率高于土壤的电导率时,阳极输出的电流会随着时间的推移而增加,达到一个峰值,然后减小。这是由于阳极表面增加、介质电导率变化和沉积层的抑制作用这三个因素之间的竞争造成的。在所研究的案例中,阳极电流的近 54% 被接地系统浪费掉了。为了说明 CP 效率的重要性,本研究将三种阳极配置与原始设计进行了比较。研究发现,对于 14.5 千克的阳极,将阳极埋深 2 米可将结构上的平均电位分布提高 4%。此外,采用 7.7 千克阳极的配置因其优越的尺寸设计,与其他配置相比性能有所提高。
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引用次数: 0
Comparative study on mechanism of DC and AC current on corrosion of copper–aluminium composites 直流电和交流电对铜铝复合材料腐蚀机理的比较研究
Yulin Cheng, Yifan Zhang, Zhengyuan Li, Xinyue Tang, Xiaoguang Yuan
In this study, corrosion behaviours accelerated by neutral salt spray were thoroughly investigated on copper–aluminium composites with 3 wt% concentration NaCl for 72 h under DC and AC current respectively. The similarities and differences of the corrosion mechanism of the copper–aluminium composite under the two kinds of current were analysed by weight loss analysis, scanning electron microscopy, energy-dispersive X-ray spectroscopy and electrochemical detection methods. It can be concluded that there are two opposing influences of the current on the corrosive effects, including acceleration by the impressed current and inhibition by the heating effect. Of these, the inhibition effect on corrosion is more obvious, as the thermal effect of DC current is greater under the same current value. It is worth noting that the directional migration of ions caused by DC current will affect the degree of corrosion and the composition of the corrosion products on the surfaces of both sides of the samples, which is a unique characteristic not seen with AC current.
本研究分别在直流电和交流电条件下,对铜铝复合材料在 3 wt% 浓度 NaCl 的中性盐雾作用下 72 小时的腐蚀行为进行了深入研究。通过失重分析、扫描电子显微镜、能量色散 X 射线光谱和电化学检测方法,分析了两种电流下铜铝复合材料腐蚀机理的异同。可以得出结论,电流对腐蚀效果有两种相反的影响,包括冲击电流的加速作用和加热效应的抑制作用。其中,直流电对腐蚀的抑制作用更为明显,因为在相同电流值下,直流电的热效应更大。值得注意的是,直流电造成的离子定向迁移会影响样品两侧表面的腐蚀程度和腐蚀产物的成分,这是交流电所不具备的独特特性。
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引用次数: 0
Stress corrosion crack propagation behaviour of MAO ceramic coating on Mg alloy 镁合金 MAO 陶瓷涂层的应力腐蚀裂纹扩展行为
Hong Chen, Guixiang Chang, Jianmin Hao
This study investigates the impact of static tensile loads on magnesium (Mg) alloys with and without ceramic coatings in simulated body fluids (SBF) using a combination of numerical simulation and experimental methods. The surface of an AZ31B Mg alloy was treated with a ceramic coating via micro-arc oxidation (MAO). Subsequently, bare Mg-alloy and MAO ceramic-coated specimens were subjected to static tensile stress testing using a tensiometer. After immersion for 12 h in SBF, the surface morphology and electrochemical corrosion of the stressed specimens were analysed. Notably, under the same tensile stress, the Mg alloy in the SBF exhibited more severe corrosion damage than the ceramic-coated specimen. Furthermore, there was a direct correlation between the corrosion rate of the ceramic coating and the magnitude of the applied tensile stress. Overall, the MAO ceramic coating exhibited superior corrosion resistance compared to the bare Mg alloy, even after undergoing static tensile stresses. The study demonstrates that MAO ceramic coatings can enhance the corrosion resistance of biodegradable Mg implants by protecting them from the combined effects of bodily stresses and fluids.
本研究采用数值模拟和实验相结合的方法,研究了在模拟体液(SBF)中有无陶瓷涂层的镁(Mg)合金所受静态拉伸载荷的影响。通过微弧氧化(MAO)对 AZ31B 镁合金表面进行了陶瓷涂层处理。随后,使用拉伸计对镁合金裸试样和 MAO 陶瓷涂层试样进行静态拉伸应力测试。在 SBF 中浸泡 12 小时后,分析了受压试样的表面形态和电化学腐蚀情况。值得注意的是,在相同的拉伸应力下,SBF 中的镁合金比陶瓷涂层试样表现出更严重的腐蚀破坏。此外,陶瓷涂层的腐蚀速度与施加的拉伸应力大小有直接关系。总体而言,与裸镁合金相比,MAO 陶瓷涂层即使在承受静态拉伸应力的情况下也能表现出更优越的耐腐蚀性。这项研究表明,MAO 陶瓷涂层可以保护可生物降解镁植入体免受身体应力和液体的双重影响,从而增强其耐腐蚀性能。
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引用次数: 0
Evaluation of corrosion behaviour and susceptibility to hydrogen-induced cracking in high-strength low-alloy X70 steels under sour gas conditions 评估酸性气体条件下高强度低合金 X70 钢的腐蚀行为和氢致开裂敏感性
Gonzalo Aurelio Mamani Quiñones, Roger Imata Condori, Diego Apaza-Apaza, E. A. Ariza, J. Quispe-Avilés
High-strength low-alloy (HSLA) steels find extensive usage in the oil industry for manufacturing pipes due to their requirement for materials with high mechanical and corrosion resistance. Among these steels, the HSLA X70 steels are particularly of great interest to the petroleum industry because of its high mechanical resistance, ductility and weldability. In this study, it was aimed to assess the corrosion behaviour of HSLA API X70 pipelines using electrochemical impedance spectroscopy (EIS) technique and evaluate its resistance to hydrogen-induced cracking (HIC). The analyses were conducted in non-sour and sour media, as per NACE TM0284 standard. Microstructural characterisations of polished and corroded samples were also conducted using scanning electron microscopy (SEM) and optical microscopy (OM). The results indicate that the resistance to HIC in API 5L X70 steel is compromised when exposed to surface corrosion in sour gas media. This susceptibility may be attributed to the presence of microconstituents MnS and M/A along the grain boundaries, which were found in the crack trajectory. The identified microstructural features are deemed to exert a significant influence on the propagation of cracks and the consequent susceptibility to HIC. Moreover, the EIS tests revealed the lowest corrosion resistance when exposed to H2S media, as MnS inclusions accelerate the active regions in the matrix, consequently leading to the formation of a plethora of corrosion products and the dissolution of iron.
高强度低合金(HSLA)钢在石油工业中被广泛用于制造管道,这是因为石油工业对材料的机械性能和耐腐蚀性有很高的要求。在这些钢材中,HSLA X70 钢因其较高的机械耐受性、延展性和可焊性,尤其受到石油工业的青睐。本研究旨在使用电化学阻抗光谱(EIS)技术评估 HSLA API X70 管道的腐蚀行为,并评估其抗氢致开裂(HIC)的能力。根据 NACE TM0284 标准,分析在非酸性和酸性介质中进行。此外,还使用扫描电子显微镜(SEM)和光学显微镜(OM)对抛光和腐蚀样品进行了微观结构特征分析。结果表明,API 5L X70 钢在酸性气体介质中受到表面腐蚀时,其抗 HIC 能力会受到影响。这种易损性可能是由于沿晶界存在微成分 MnS 和 M/A,并在裂纹轨迹中发现了这些微成分。已确定的微观结构特征被认为对裂纹的扩展以及由此产生的 HIC 易感性具有重要影响。此外,EIS 测试表明,当暴露在 H2S 介质中时,耐腐蚀性能最低,因为 MnS 包裹体加速了基体中的活性区域,从而导致形成大量腐蚀产物和铁的溶解。
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引用次数: 0
Effect of medium and pressure on stress corrosion cracking susceptibility of a nickel-based alloy 介质和压力对镍基合金应力腐蚀开裂敏感性的影响
Zhenyu Chen, Zhongliang Zhu, Ju Liu, Peihan Li, Zhangyang Chen, Tianyi Zhang, Naiqiang Zhang
Nickel-based alloy Inconel 617 is a candidate material for advanced ultra-supercritical units. Stress corrosion cracking (SCC) susceptibility of Inconel 617 under low-pressure superheated steam (0.1 MPa), high-pressure superheated steam (8 MPa) and supercritical water (25 MPa) at 650 °C was studied through slow strain rate tensile tests at strain rate of 5 × 10−7 s−1. The results indicate that Inconel 617 is susceptible to SCC in both superheated steam and supercritical water, with susceptibility increasing with pressure. In a nitrogen atmosphere, fractures were predominantly transgranular ductile. The fracture surface featured dimples and micropores. In three corrosive environments, both intergranular and transgranular fractures were observed. The rock sugar-like morphology becomes more and more obvious as the pressure increases. A large number of cracks perpendicular to the loading axis were found on gauge surface. The SCC mechanism for Inconel 617 in superheated steam and supercritical water conditions is internal oxidation.
镍基合金 Inconel 617 是先进超超临界机组的候选材料。通过应变速率为 5 × 10-7 s-1 的慢应变拉伸试验,研究了 Inconel 617 在 650 °C 的低压过热蒸汽(0.1 MPa)、高压过热蒸汽(8 MPa)和超临界水(25 MPa)条件下的应力腐蚀开裂(SCC)敏感性。结果表明,Inconel 617 在过热蒸汽和超临界水中都很容易发生 SCC,而且易感性随压力的增加而增加。在氮气环境中,断口主要呈跨晶韧性。断口表面具有凹陷和微孔。在三种腐蚀环境中,均观察到晶间和跨晶断裂。随着压力的增加,岩糖状形态越来越明显。在量规表面发现了大量垂直于加载轴的裂纹。Inconel 617 在过热蒸汽和超临界水条件下的 SCC 机理是内部氧化。
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引用次数: 0
Effect of hydrogen on the pitting corrosion of 2205 duplex stainless steel welded joints 氢对 2205 双相不锈钢焊接接头点腐蚀的影响
Qing Zheng, Houwei Zhang, Dengyun Wang, Lining Xu, Gang Li, Lijie Qiao
The effect of hydrogen on the pitting susceptibility of 2205 duplex stainless steel welded joints was investigated using metallographic characterisation, electrochemical techniques and immersion experiments. The results show that the diffusible hydrogen content in the welded joints is approximately twice that of base material (BM). Hydrogen significantly decreases the pitting potential (Epit) of the welded joints, while increasing the carrier density in the passive film, suggesting that hydrogen weakens the protective properties of the passive film and increases the pitting susceptibility of the welded joints. According to immersion experiments, the pitting susceptibility of the welded joint from high to low is heat-affected zone (HAZ), BM and weld metal (WM), the HAZ tends to be more prone to the formation of larger and more stable pits, and the number of inclusions at the HAZ is significantly greater than that at the BM and WM. For BM under hydrogen charging, austenite phase is usually corroded first, because hydrogen tends to be enriched in the austenitic phase of BM. However, in some regions of WM, ferrite phase corroded first, which is related to the enrichment of hydrogen in the ferrite in the weld area.
采用金相表征、电化学技术和浸泡实验研究了氢对 2205 双相不锈钢焊接接头点蚀敏感性的影响。结果表明,焊点中的扩散氢含量约为母材(BM)的两倍。氢明显降低了焊点的点蚀电位 (Epit),同时增加了被动膜中的载流子密度,这表明氢削弱了被动膜的保护性能,增加了焊点的点蚀敏感性。根据浸泡实验,焊接接头的点蚀敏感性从高到低依次是热影响区(HAZ)、BM 和焊接金属(WM),HAZ 往往更容易形成更大、更稳定的凹坑,而且 HAZ 的夹杂物数量明显多于 BM 和 WM。对于充氢条件下的 BM,奥氏体相通常首先被腐蚀,因为氢往往富集在 BM 的奥氏体相中。然而,在 WM 的某些区域,铁素体相先被腐蚀,这与焊接区域铁素体中氢的富集有关。
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引用次数: 0
Research on the corrosion behavior of floating bead low-density cement stone/P110 steel system under different CO2 pressure 不同二氧化碳压力下浮珠低密度水泥石/P110 钢系统的腐蚀行为研究
Shuliang Wang, Zidan Wen, Shuai Zhang, M. Yao, Wanneng Lei, Ming-hua Wu, Yongbing Liu, Xiaoyan Zhang, Xianguang Zeng, Shidong Wang
This study investigates the corrosion state of the floating bead low-density cement stone/P110 steel system in simulated CO2-saturated formation water under high and atmospheric CO2 pressure. Results show that the resistance of the cement stone reaches a maximum value at 28 days and then decreases. The corrosion rate of P110 steel under high pressure is greater than that under atmospheric pressure. There is a certain gap and accumulation of corrosion products between the cement stone and the steel. Additionally, the maximum gap size and corrosion product thickness reach 27.5 and 67.69 μm, respectively. The composition of the corrosion products on the steel surface is mainly FeCO3, and the presence of the iron oxides are caused by oxidation. The corrosion products of the cement are also confirmed to be CaCO3 and a small amount of SiO2.
本研究调查了浮珠低密度水泥石/P110 钢系统在模拟二氧化碳饱和地层水中的腐蚀状态。结果表明,水泥石的抗腐蚀性在 28 天时达到最大值,然后开始下降。高压下 P110 钢的腐蚀速率大于常压下的腐蚀速率。水泥石和钢之间存在一定的间隙,腐蚀产物在水泥石和钢之间积聚。此外,最大间隙尺寸和腐蚀产物厚度分别达到 27.5 和 67.69 μm。钢表面腐蚀产物的成分主要是 FeCO3,铁氧化物的存在是由氧化引起的。水泥的腐蚀产物也被证实为 CaCO3 和少量 SiO2。
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引用次数: 0
Non-destructive techniques for corrosion detection: A review 非破坏性腐蚀检测技术:综述
Vivek Vasagar, Mohammad K. Hassan, Aboubakr M. Abdullah, Avinashkumar V. Karre, Beibei Chen, Kyoungtae Kim, N. Al-Qahtani, Tianxing Cai
Corrosion detection (CD) has become a high priority in chemical industries, defense and transportation sectors to extend the life of existing or new systems while ensuring the safety of the existing components and reducing downtime to minimise economic losses. Here, this article is aimed to review and discuss non-destructive techniques used widely in the industry to detect, monitor and repair corrosion problems early on. The comprehensive review provides a detailed discussion, a functional mechanism, advantages and disadvantages of crucial non-destructive CD techniques widely used in the industry, helping the reader choose the type of corrosion monitoring methods effectively. An extensive literature review of visual and optical testing techniques, acoustic emissions, eddy current, guided wave and equipment, infrared thermography, radiographic, microwave and millimeter wave, and terahertz imaging is discussed. The underlying mechanism, its merits and limitations, along with the usage scenario, is explained that can be related across different areas making it interdisciplinary research for corrosion monitoring techniques.
腐蚀检测(CD)已成为化学工业、国防和交通部门的重中之重,它可以延长现有系统或新系统的使用寿命,同时确保现有部件的安全,减少停机时间,从而将经济损失降至最低。本文旨在回顾和讨论业内广泛使用的非破坏性技术,以便及早发现、监测和修复腐蚀问题。这篇综述详细论述了行业内广泛使用的关键无损 CD 技术的功能机制和优缺点,帮助读者有效选择腐蚀监测方法的类型。大量文献综述了目视和光学测试技术、声发射、涡流、导波和设备、红外热成像、射线成像、微波和毫米波以及太赫兹成像。还解释了腐蚀监测技术的基本机理、优点和局限性以及使用场景,这些都与不同领域相关,使其成为腐蚀监测技术的跨学科研究。
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引用次数: 0
Tafel slopes and exchange current densities of oxygen reduction and hydrogen evolution on steel 钢上氧还原和氢演化的塔菲尔斜率和交换电流密度
M. V. van Ede, U. Angst
The prediction and prevention of steel corrosion in engineering applications rely on the accurate understanding of kinetic parameters, such as the Tafel slopes and exchange current densities. These parameters show a large spread in literature. We investigated the dependency of these kinetic parameters on the measurement methodology for stainless and carbon steels, in a controlled rotating disk electrode setup with a near-neutral (pH 7.5) buffer solution. Consistent results were found for hydrogen evolution on stainless steel, with Tafel slopes of −0.13 to −0.15 V/dec and exchange current densities around 0.01–0.02 A/m2. The studied oxygen reduction kinetics showed the largest dependency on the measurement methodology, especially the potentiodynamic scan direction. Supported by active light reflectance spectroscopy, the large observed variations were attributed to the influence of an oxide film, which may overshadow the oxygen reduction at small over-potentials. The obtained variation gives insight on the accuracy of documented and measured values.
工程应用中钢铁腐蚀的预测和预防有赖于对动力学参数的准确理解,如塔菲尔斜率和交换电流密度。这些参数在文献中存在很大差异。我们研究了这些动力学参数对不锈钢和碳钢测量方法的依赖性,采用的是近中性(pH 值为 7.5)缓冲溶液的受控旋转盘电极设置。在不锈钢上发现了一致的氢演化结果,塔菲尔斜率为 -0.13 至 -0.15 V/dec,交换电流密度约为 0.01-0.02 A/m2 。所研究的氧还原动力学对测量方法的依赖性最大,尤其是电位动力扫描方向。在主动光反射光谱仪的支持下,观察到的巨大变化归因于氧化膜的影响,它可能会掩盖小过电位下的氧还原。所获得的变化让人了解到记录值和测量值的准确性。
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引用次数: 2
A novel material selection method and application in an aqueous environment containing CO2, H2S, O2, and SO2 新型材料选择方法及在含 CO2、H2S、O2 和 SO2 的水环境中的应用
Kexi Liao, Jihui Leng, Yongbo Yan, T. He, Xidi Lv, Xin Liu, Min Qin, Shuai Zhao, Y. F. Cheng
The corrosion in the aqueous environment of CO2–H2S–O2–SO2 is extremely severe, causing frequent failures of pipeline and posing a challenging issue for material selection. This paper drew on excellent standards and past experiences to provide a suitable method for selecting materials. The method consisted of four components: standard primary selection, corrosion evaluation selection, mechanical property selection, and economic final selection. A case study demonstrated that the applicable materials for the environment (total pressure of 1.5 MPa, temperature of 30–120 °C, H2S content of 0.1–1.5%, CO2 content of 8–55%, SO2 content of 0–0.00015% and O2 content of 1–3%) were composed of 2Cr13 or 316L. Additionally, the main control factors for corrosion rate were ranked as follows: O2 > H2S > temperature > CO2 > SO2. And a reduction in mechanical properties was observed for 2Cr13, 316L, and 825 after corrosion.
CO2-H2S-O2-SO2 的水环境腐蚀极为严重,导致管道故障频发,给材料选择带来了挑战。本文借鉴了优秀标准和以往经验,提供了一种合适的材料选择方法。该方法由四个部分组成:标准初选、腐蚀评估选择、机械性能选择和经济性终选。案例研究表明,适用于该环境(总压为 1.5 兆帕、温度为 30-120 °C、H2S 含量为 0.1-1.5%、CO2 含量为 8-55%、SO2 含量为 0-0.00015% 和 O2 含量为 1-3%)的材料由 2Cr13 或 316L 组成。此外,腐蚀速率的主要控制因素排序如下:O2 > H2S > 温度 > CO2 > SO2。此外,还观察到 2Cr13、316L 和 825 在腐蚀后的机械性能有所下降。
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引用次数: 0
期刊
Corrosion Engineering, Science and Technology: The International Journal of Corrosion Processes and Corrosion Control
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