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Corrosion Engineering, Science and Technology: The International Journal of Corrosion Processes and Corrosion Control最新文献

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The CO2 corrosion behaviour of 25Mn2 and 2Cr steels under certain downhole condition 25Mn2 和 2Cr 钢在特定井下条件下的二氧化碳腐蚀行为
Yuling Zhang, Qingchao Tian, Deng Xuyan, Xiao Xu, Wang Guofu
An economical 2Cr steel tubing was prepared for application in a certain downhole corrosion condition, and the CO2 corrosion behaviour was investigated by employing the 25Mn2 steel for comparative study. The corrosion films of the two steels under different corrosion conditions were analysed by optical microscope, scanning electron microscope (SEM), energy dispersive spectrometer (EDS) and X-ray diffraction (XRD). It is revealed that the corrosion rate of 25Mn2 steel at static solution is about 2.5 times higher than that at the dynamic solution with the flow velocity of 1 m/s, while the corrosion rate of 2Cr steel keeps almost the same. It is found that both steels show two layers of corrosion film at static corrosion, and the corrosion film is mainly composed of FeCO3, α-FeOOH and dotted Fe3C in the inner layer. It is inferred that carbon pickup phenomenon observed in the corrosion film is attributed to the formation of FeCO3, as well as may also be due to phenomenologically the reaction of Fe3C with carbonic acid.
制备了一种适用于特定井下腐蚀条件的经济型 2Cr 钢管,并采用 25Mn2 钢对二氧化碳腐蚀行为进行了对比研究。通过光学显微镜、扫描电子显微镜(SEM)、能量色散光谱仪(EDS)和 X 射线衍射仪(XRD)分析了两种钢在不同腐蚀条件下的腐蚀膜。结果表明,25Mn2 钢在静态溶液中的腐蚀速率是流速为 1 m/s 的动态溶液中腐蚀速率的约 2.5 倍,而 2Cr 钢的腐蚀速率几乎保持不变。研究发现,两种钢在静态腐蚀时都呈现出两层腐蚀膜,腐蚀膜主要由 FeCO3、α-FeOOH 和内层的点状 Fe3C 组成。由此推断,在腐蚀膜中观察到的碳拾取现象归因于 FeCO3 的形成,也可能是由于 Fe3C 与碳酸发生反应所致。
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引用次数: 0
Analysis of Beibu Gulf tidal zone exposure on properties of carbon steel 北部湾潮汐区暴露对碳钢性能的影响分析
P. Yu, Jianhui Liao, Yitong Zhou, Sheng He
Marine tidal zone is a corrosive environment that has a negative impact on carbon steel. This research investigates the change of mechanical properties and corrosion behaviour of carbon steel specimens subjected to field exposure test and simulation test for 12 and 6 months, respectively. The corrosion behaviour of carbon steel exposed to real marine tidal zone and simulation environment was discussed through morphological observation and corrosion kinetics analysis, in order to reveal the essential reason for the degradation of its mechanical properties. Then the tensile test was performed on the corroded specimens and true stress–strain curves were obtained. In addition, regression equations were derived for the mechanical properties as a function of the degree of corrosion degradation and a constitutive model with time factor for corroded carbon steel is proposed.
海洋潮汐区是一个对碳钢有负面影响的腐蚀环境。本研究调查了碳钢试样分别经受 12 个月和 6 个月的现场暴露试验和模拟试验后的机械性能变化和腐蚀行为。通过形态观察和腐蚀动力学分析,讨论了暴露在真实海洋潮汐区和模拟环境中的碳钢的腐蚀行为,以揭示其机械性能退化的本质原因。然后对腐蚀试样进行了拉伸试验,获得了真实的应力-应变曲线。此外,还得出了力学性能与腐蚀退化程度的回归方程,并提出了带有时间因子的腐蚀碳钢构成模型。
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引用次数: 0
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Corrosion Engineering, Science and Technology: The International Journal of Corrosion Processes and Corrosion Control
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