Z. Birčáková, P. Kollár, B. Weidenfeller, J. Füzer, Radovan Bureš, M. Fáberová
Abstract Soft magnetic composite materials consisting of FeSi powder and polypropylene were prepared by the injection molding method, with different polypropylene contents of 25, 30 and 35 vol. %. The magnetic and electrical properties as well as the structure of the composites were investigated. The samples exhibited very low porosity, high electrical resistivity, relatively low coercivity, sufficient saturation magnetic flux density and permeability, and high resonant frequency. FeSi particles were found to be well insulated from each other and homogeneously dispersed in the polymer matrix of the composite. The observed isotropic structure was confirmed by the fitting of the experimental dependence with the analytical expression of the reversible relative permeability vs. magnetic flux density.
{"title":"Iron Based Soft Magnetic Composite Material Prepared By Injection Molding","authors":"Z. Birčáková, P. Kollár, B. Weidenfeller, J. Füzer, Radovan Bureš, M. Fáberová","doi":"10.2478/pmp-2021-0002","DOIUrl":"https://doi.org/10.2478/pmp-2021-0002","url":null,"abstract":"Abstract Soft magnetic composite materials consisting of FeSi powder and polypropylene were prepared by the injection molding method, with different polypropylene contents of 25, 30 and 35 vol. %. The magnetic and electrical properties as well as the structure of the composites were investigated. The samples exhibited very low porosity, high electrical resistivity, relatively low coercivity, sufficient saturation magnetic flux density and permeability, and high resonant frequency. FeSi particles were found to be well insulated from each other and homogeneously dispersed in the polymer matrix of the composite. The observed isotropic structure was confirmed by the fitting of the experimental dependence with the analytical expression of the reversible relative permeability vs. magnetic flux density.","PeriodicalId":52175,"journal":{"name":"Powder Metallurgy Progress","volume":"21 1","pages":"10 - 17"},"PeriodicalIF":0.0,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47048311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Y. Kyryliuk, G. Bagliuk, Alla Mamonova, V. Maslyuk
Abstract The results of the investigation of the structure, phase composition, and properties of the alloy sintered from a mixture of iron (65 %) and high-carbon ferrochrome (35 %) powders are presented in the article. It was shown that sintering of the consolidated specimens results in a substantially heterogeneous structure consisting of two predominant phases: austenitic phase and double ferrochrome carbide. A mechanism is proposed for the dissolution of ferrochrome particles in the iron matrix as follows: M7C3 → M3C (1000÷1150 ºС) → M7C3 (1200÷1250 ºС).
{"title":"Synthesis of Fe-Based Alloy Reinforced with Chromium Carbide Via Sintering of Iron-Ferrochrome Powder Mixture","authors":"Y. Kyryliuk, G. Bagliuk, Alla Mamonova, V. Maslyuk","doi":"10.2478/pmp-2021-0003","DOIUrl":"https://doi.org/10.2478/pmp-2021-0003","url":null,"abstract":"Abstract The results of the investigation of the structure, phase composition, and properties of the alloy sintered from a mixture of iron (65 %) and high-carbon ferrochrome (35 %) powders are presented in the article. It was shown that sintering of the consolidated specimens results in a substantially heterogeneous structure consisting of two predominant phases: austenitic phase and double ferrochrome carbide. A mechanism is proposed for the dissolution of ferrochrome particles in the iron matrix as follows: M7C3 → M3C (1000÷1150 ºС) → M7C3 (1200÷1250 ºС).","PeriodicalId":52175,"journal":{"name":"Powder Metallurgy Progress","volume":"21 1","pages":"18 - 26"},"PeriodicalIF":0.0,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46371187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Z. Birčáková, P. Kollár, J. Füzer, M. Streckova, J. Szabó, Radovan Bureš, M. Fáberová
Abstract The paper presents the study of the influence of different ferromagnetic powders on magnetic properties of polymer-matrix soft magnetic composites. Samples were prepared from pure Fe and Permalloy powders with the same amount of resin and by the same technological process. The coercivity, the real part of complex permeability, saturation magnetic polarization, hysteresis loops and total energy losses and their components were investigated. It was found that the coercivity, DC losses, classical losses, excess losses and thus the total energy losses of composites depended on intrinsic magnetic properties and/or on the size and shape of ferromagnetic powder particles, while the permeability of composites was affected predominantly by inner demagnetizing fields due to the insulation. The numbers of moving domain walls involved in magnetization reversal were analyzed in connection with the magnetic properties.
{"title":"Influence of the Ferromagnetic Component on the Magnetic Properties of Polymer-Matrix Soft Magnetic Composites","authors":"Z. Birčáková, P. Kollár, J. Füzer, M. Streckova, J. Szabó, Radovan Bureš, M. Fáberová","doi":"10.2478/pmp-2021-0001","DOIUrl":"https://doi.org/10.2478/pmp-2021-0001","url":null,"abstract":"Abstract The paper presents the study of the influence of different ferromagnetic powders on magnetic properties of polymer-matrix soft magnetic composites. Samples were prepared from pure Fe and Permalloy powders with the same amount of resin and by the same technological process. The coercivity, the real part of complex permeability, saturation magnetic polarization, hysteresis loops and total energy losses and their components were investigated. It was found that the coercivity, DC losses, classical losses, excess losses and thus the total energy losses of composites depended on intrinsic magnetic properties and/or on the size and shape of ferromagnetic powder particles, while the permeability of composites was affected predominantly by inner demagnetizing fields due to the insulation. The numbers of moving domain walls involved in magnetization reversal were analyzed in connection with the magnetic properties.","PeriodicalId":52175,"journal":{"name":"Powder Metallurgy Progress","volume":"21 1","pages":"1 - 9"},"PeriodicalIF":0.0,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48773996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
H. Brunckova, M. Kaňuchová, H. Kolev, E. Múdra, A. Kovalčíková, Ľ. Medvecký
Abstract Transparent europium niobate EuNbO4 (ENOF) thin film (~100 nm) was prepared by sol-gel/spin-coating process on alumina substrates with PbZrO3 (PZ) interlayer and annealing at 1000°C. The X-ray diffraction (XRD) analyses verified the formation of the monoclinic M-EuNbO4 and tetragonal T-EuNb5O14 phases in ENO precursor and ENOF film. The surface morphology of powder precursor and microstructure of film were investigated by SEM analyses. Surface chemistry was investigated by X-ray photoelectron spectroscopy (XPS). The XPS demonstrated two valence states of Eu (Eu3+/Eu2+) in powder precursor as nanophosphor for lighting and display technologies. Eu concentration (at. %) decreases from 10 % in the precursor to 2 % in the film considering the substrate contains C, Al, Si, Pb, and Zr elements (40 %) at Nb (6 %) and O (52 %). The single valence state of Eu3+ was confirmed in ENO film designed for the application in environmental electrolytic thin-film devices.
{"title":"X-ray Photoelectron Spectroscopy Study of Europium Niobate Thin Film Prepared by Chemical Solution Deposition","authors":"H. Brunckova, M. Kaňuchová, H. Kolev, E. Múdra, A. Kovalčíková, Ľ. Medvecký","doi":"10.2478/pmp-2020-0009","DOIUrl":"https://doi.org/10.2478/pmp-2020-0009","url":null,"abstract":"Abstract Transparent europium niobate EuNbO4 (ENOF) thin film (~100 nm) was prepared by sol-gel/spin-coating process on alumina substrates with PbZrO3 (PZ) interlayer and annealing at 1000°C. The X-ray diffraction (XRD) analyses verified the formation of the monoclinic M-EuNbO4 and tetragonal T-EuNb5O14 phases in ENO precursor and ENOF film. The surface morphology of powder precursor and microstructure of film were investigated by SEM analyses. Surface chemistry was investigated by X-ray photoelectron spectroscopy (XPS). The XPS demonstrated two valence states of Eu (Eu3+/Eu2+) in powder precursor as nanophosphor for lighting and display technologies. Eu concentration (at. %) decreases from 10 % in the precursor to 2 % in the film considering the substrate contains C, Al, Si, Pb, and Zr elements (40 %) at Nb (6 %) and O (52 %). The single valence state of Eu3+ was confirmed in ENO film designed for the application in environmental electrolytic thin-film devices.","PeriodicalId":52175,"journal":{"name":"Powder Metallurgy Progress","volume":"20 1","pages":"94 - 103"},"PeriodicalIF":0.0,"publicationDate":"2020-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42253528","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
G. Kalss, C. Gierl-Mayer, H. Danninger, G. Stetina
Abstract Sinter hardening is a technique that is frequently employed in powder metallurgy parts production since it is an economical, clean, and environmentally friendly procedure. Since the cooling rates are however significantly lower than e.g. in water or oil quenching, alloy systems have to be used that ensure martensite formation already at moderate cooling rates. In the present study, quenching dilatometry was used to investigate the hardenability of two types of Cr pre-alloyed steels, Fe-3Cr-0.5Mo and Fe-1.5Cr-0.2Mo, the carbon content being varied, and sinter hardening diagrams were plotted. It showed that this parameter has a pronounced influence on the hardenability of the 3 % Cr alloy; in particular in the range 0.3…0.4 % combined C. For the lower alloyed system, in contrast, even 0.52 % combined C was insufficient to ensure martensite formation at the cooling rates typical for industrial sinter hardening. Finally, impact test specimens were prepared by sinter hardening at cooling rates typical for industry, and hardness, as well as impact energy, were determined.
{"title":"Sinter Hardening of Cr-Mo Pre-Alloyed Steels as a Function of the Carbon Content","authors":"G. Kalss, C. Gierl-Mayer, H. Danninger, G. Stetina","doi":"10.2478/pmp-2020-0008","DOIUrl":"https://doi.org/10.2478/pmp-2020-0008","url":null,"abstract":"Abstract Sinter hardening is a technique that is frequently employed in powder metallurgy parts production since it is an economical, clean, and environmentally friendly procedure. Since the cooling rates are however significantly lower than e.g. in water or oil quenching, alloy systems have to be used that ensure martensite formation already at moderate cooling rates. In the present study, quenching dilatometry was used to investigate the hardenability of two types of Cr pre-alloyed steels, Fe-3Cr-0.5Mo and Fe-1.5Cr-0.2Mo, the carbon content being varied, and sinter hardening diagrams were plotted. It showed that this parameter has a pronounced influence on the hardenability of the 3 % Cr alloy; in particular in the range 0.3…0.4 % combined C. For the lower alloyed system, in contrast, even 0.52 % combined C was insufficient to ensure martensite formation at the cooling rates typical for industrial sinter hardening. Finally, impact test specimens were prepared by sinter hardening at cooling rates typical for industry, and hardness, as well as impact energy, were determined.","PeriodicalId":52175,"journal":{"name":"Powder Metallurgy Progress","volume":"20 1","pages":"81 - 93"},"PeriodicalIF":0.0,"publicationDate":"2020-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43550845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Magnetic abrasive flow finishing (MAFF) is an unconventional process capable of producing fine finishing with machining forces controlled by a magnetic field. This process can be utilized for hard to achieve inner surfaces through the activity of extrusion pressure, combined with abrasion activity of a magnetic abrasive powder (MAP) in a polymeric medium. MAP is the key component in securing systematic removal of material and a decent surface finish in MAFF. The research background disclosed various methods such as sintering, adhesive based, mechanical alloying, plasma based, chemical, etc. for the production of bonded MAP. This investigation proposes bonded MAP produced by mechanical alloying followed by heat treatment. The experiments have been conducted on aluminum tubes to investigate the influence of different parameters like magnetic field density, extrusion pressure and number of working cycles. The bonded magnetic abrasive powder used in MAFF is very effective to finish tubes’ inner surfaces and finishing is significantly improved after processing.
{"title":"Finishing of Tubes using Bonded Magnetic Abrasive Powder in an Abrasive Medium","authors":"Palwinder Singh, L. Singh, Sehijpal Singh","doi":"10.2478/pmp-2020-0001","DOIUrl":"https://doi.org/10.2478/pmp-2020-0001","url":null,"abstract":"Abstract Magnetic abrasive flow finishing (MAFF) is an unconventional process capable of producing fine finishing with machining forces controlled by a magnetic field. This process can be utilized for hard to achieve inner surfaces through the activity of extrusion pressure, combined with abrasion activity of a magnetic abrasive powder (MAP) in a polymeric medium. MAP is the key component in securing systematic removal of material and a decent surface finish in MAFF. The research background disclosed various methods such as sintering, adhesive based, mechanical alloying, plasma based, chemical, etc. for the production of bonded MAP. This investigation proposes bonded MAP produced by mechanical alloying followed by heat treatment. The experiments have been conducted on aluminum tubes to investigate the influence of different parameters like magnetic field density, extrusion pressure and number of working cycles. The bonded magnetic abrasive powder used in MAFF is very effective to finish tubes’ inner surfaces and finishing is significantly improved after processing.","PeriodicalId":52175,"journal":{"name":"Powder Metallurgy Progress","volume":"20 1","pages":"1 - 11"},"PeriodicalIF":0.0,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43195633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
T. Konegger, C. Gierl-Mayer, A. Sikora, H. Rojacz, G. Fafilek, H. Danninger, K. Adam
Abstract In this work, iron aluminide materials, which are promising candidates for high temperature applications, are manufactured through reactive hot pressing of elemental powder mixes, facilitating a straightforward preparation of well-densified materials with a high degree of microstructural homogeneity. The impact of varying Al additions on reaction behavior, microstructural and compositional features of the resulting materials is evaluated. Furthermore, the effect of adding 1 wt. % Mg on reactivity and phase formation is illustrated. The results show that reactive hot pressing of elemental powders in the Fe-Al and Fe-Al-Mg systems at 1000 °C results in residual porosities well below 5 %. Magnesium addition significantly increased reactivity between constituents, leading to slightly improved densification without exhibiting potentially detrimental segregation phenomena. The processing approach presented in this work leads to material characteristics which are promising in the context of developing materials with favorable mechanical and tribological performance at elevated temperatures.
{"title":"Powder Metallurgy Manufacturing of Iron Aluminides with Different Aluminium Contents and Magnesium Addition by Reactive Hot Pressing","authors":"T. Konegger, C. Gierl-Mayer, A. Sikora, H. Rojacz, G. Fafilek, H. Danninger, K. Adam","doi":"10.2478/pmp-2020-0005","DOIUrl":"https://doi.org/10.2478/pmp-2020-0005","url":null,"abstract":"Abstract In this work, iron aluminide materials, which are promising candidates for high temperature applications, are manufactured through reactive hot pressing of elemental powder mixes, facilitating a straightforward preparation of well-densified materials with a high degree of microstructural homogeneity. The impact of varying Al additions on reaction behavior, microstructural and compositional features of the resulting materials is evaluated. Furthermore, the effect of adding 1 wt. % Mg on reactivity and phase formation is illustrated. The results show that reactive hot pressing of elemental powders in the Fe-Al and Fe-Al-Mg systems at 1000 °C results in residual porosities well below 5 %. Magnesium addition significantly increased reactivity between constituents, leading to slightly improved densification without exhibiting potentially detrimental segregation phenomena. The processing approach presented in this work leads to material characteristics which are promising in the context of developing materials with favorable mechanical and tribological performance at elevated temperatures.","PeriodicalId":52175,"journal":{"name":"Powder Metallurgy Progress","volume":"20 1","pages":"41 - 55"},"PeriodicalIF":0.0,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44698364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract WC coatings prepared by High Target Utilization Sputtering (HITUS), a relatively new technology, were deposited on three types of substrates. These were silicon (111), steel (100Cr6), and ceramic (WC-Co). The influence of RF plasma power pretreatment on final properties of WC coatings was investigated with two interlayer materials for bonding. The morphology, roughness, and mechanical properties of coatings were studied. The relation between plasma RF power and roughness was found. No significant change in mechanical properties was detected with change in plasma RF power. The dependence of nanohardness and scratch behavior on HITUS WC coatings was investigated.
{"title":"The Effect of Plasma Pretreatment on the Morphology and Properties of Hitus Coatings","authors":"L. Kvetková, Petra Hviščová, D. Medveď, F. Lofaj","doi":"10.2478/pmp-2020-0003","DOIUrl":"https://doi.org/10.2478/pmp-2020-0003","url":null,"abstract":"Abstract WC coatings prepared by High Target Utilization Sputtering (HITUS), a relatively new technology, were deposited on three types of substrates. These were silicon (111), steel (100Cr6), and ceramic (WC-Co). The influence of RF plasma power pretreatment on final properties of WC coatings was investigated with two interlayer materials for bonding. The morphology, roughness, and mechanical properties of coatings were studied. The relation between plasma RF power and roughness was found. No significant change in mechanical properties was detected with change in plasma RF power. The dependence of nanohardness and scratch behavior on HITUS WC coatings was investigated.","PeriodicalId":52175,"journal":{"name":"Powder Metallurgy Progress","volume":"20 1","pages":"21 - 29"},"PeriodicalIF":0.0,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48035249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ľ. Medvecký, R. Stulajterova, M. Giretová, T. Sopčák, M. Fáberová, M. Hnatko, T. Fenclová
Abstract Tetracalcium phosphate/monetite biocement was modified with 10 and 30 wt. % addition of highly porous silicon nitride/α-tricalcium phosphate (αTCP) microgranules with various content of αTCP. A composite cement powder mixture was prepared using mechanical homogenization of basic components. The accelerated release of dexamethasone from composite cement was revealed, which indicates their possible utilization for controlled drug release. The wet compressive strength of cements (<17 MPa) was significantly reduced (more than 30%) in comparison with the unmodified cement and both compressive strength and setting time were influenced by the content of αTCP in microgranules. The addition of microgranules caused a 20% decrease in final cement density. Microgranules with a higher fraction of αTCP showed good in vitro SBF bioactivity with precipitation of hydroxyapatite particles. Microstructure analysis of fractured cements demonstrated excellent interconnection between microgranules and cement calcium phosphate matrix, but also showed lower mechanical strength of microgranule cores.
{"title":"Calcium Phosphate Cement Modified with Silicon Nitride/Tricalcium Phosphate Microgranules","authors":"Ľ. Medvecký, R. Stulajterova, M. Giretová, T. Sopčák, M. Fáberová, M. Hnatko, T. Fenclová","doi":"10.2478/pmp-2020-0006","DOIUrl":"https://doi.org/10.2478/pmp-2020-0006","url":null,"abstract":"Abstract Tetracalcium phosphate/monetite biocement was modified with 10 and 30 wt. % addition of highly porous silicon nitride/α-tricalcium phosphate (αTCP) microgranules with various content of αTCP. A composite cement powder mixture was prepared using mechanical homogenization of basic components. The accelerated release of dexamethasone from composite cement was revealed, which indicates their possible utilization for controlled drug release. The wet compressive strength of cements (<17 MPa) was significantly reduced (more than 30%) in comparison with the unmodified cement and both compressive strength and setting time were influenced by the content of αTCP in microgranules. The addition of microgranules caused a 20% decrease in final cement density. Microgranules with a higher fraction of αTCP showed good in vitro SBF bioactivity with precipitation of hydroxyapatite particles. Microstructure analysis of fractured cements demonstrated excellent interconnection between microgranules and cement calcium phosphate matrix, but also showed lower mechanical strength of microgranule cores.","PeriodicalId":52175,"journal":{"name":"Powder Metallurgy Progress","volume":"20 1","pages":"56 - 75"},"PeriodicalIF":0.0,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44520892","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. T. Tabrizi, Maryam Pouzesh, F. Laleh, H. Aghajani
Abstract In order to enhance the surface properties of a magnesium-based substrate, WC-Co coating was applied on AZ91 alloy by electro spark deposition (ESD), successfully for the first time. The optimum parameters of the ESD process were achieved, based on the corrosion behavior and calculated corrosion rate of the coated samples when 5kHz and 25 A were chosen. For evaluation of the corrosion performance of the achieved WC-Co layers, polarization, and electrochemical impedance spectroscopy tests were carried out in the 3.5 wt % Na3PO4 solution at room temperature. Polarization results show that the corrosion rate (mpy) is in the optimum condition almost half of a bulk sample of uncoated AZ91. Field emission scanning electron microscopy (FE-SEM) was used to examine the surface morphology of applied coatings. These results show that at a lower current, the amount of deposited WC-Co was reduced. The maximum surface microhardness obtained was 193 HV0.2.
{"title":"Evaluation of the Corrosion Resistance of WC-Co Coating on AZ91 Applied by Electro Spark Deposition","authors":"A. T. Tabrizi, Maryam Pouzesh, F. Laleh, H. Aghajani","doi":"10.2478/pmp-2020-0004","DOIUrl":"https://doi.org/10.2478/pmp-2020-0004","url":null,"abstract":"Abstract In order to enhance the surface properties of a magnesium-based substrate, WC-Co coating was applied on AZ91 alloy by electro spark deposition (ESD), successfully for the first time. The optimum parameters of the ESD process were achieved, based on the corrosion behavior and calculated corrosion rate of the coated samples when 5kHz and 25 A were chosen. For evaluation of the corrosion performance of the achieved WC-Co layers, polarization, and electrochemical impedance spectroscopy tests were carried out in the 3.5 wt % Na3PO4 solution at room temperature. Polarization results show that the corrosion rate (mpy) is in the optimum condition almost half of a bulk sample of uncoated AZ91. Field emission scanning electron microscopy (FE-SEM) was used to examine the surface morphology of applied coatings. These results show that at a lower current, the amount of deposited WC-Co was reduced. The maximum surface microhardness obtained was 193 HV0.2.","PeriodicalId":52175,"journal":{"name":"Powder Metallurgy Progress","volume":"20 1","pages":"30 - 40"},"PeriodicalIF":0.0,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48475439","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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