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Powder Metallurgy Progress, an international open-access journal with 20 years of publishing history announces the Extension of the Journal`s Scope 拥有20年出版历史的国际开放获取期刊《粉末冶金进展》宣布扩大期刊范围
Q4 Materials Science Pub Date : 2020-06-01 DOI: 10.2478/pmp-2020-0007
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引用次数: 0
Temperature-Dependent Electrical Characteristics of Disc-Shaped Compacts Fabricated using Calcined Eggshell Nano Powder and Dry Cassava Starch 用煅烧蛋壳纳米粉和干木薯淀粉制备圆盘状压块的温度相关电学特性
Q4 Materials Science Pub Date : 2020-06-01 DOI: 10.2478/pmp-2020-0002
U. Robert, S. Etuk, O. Agbasi, Ubong A. Iboh, S. Ekpo
Abstract Disc-shaped compacts were fabricated from two mix proportions of calcined eggshell nanopowder and dry cassava starch and then used as test samples. The electrical resistance (R), thermal sensitivity index (β) and electronic activation energy (Ea) of the samples measured over a temperature range from 35 to 75oC were found to decrease non-linearly in values with increasing temperature. It was also observed that the results obtained (R = 3.691E6 Ω – 6.210E7 Ω, β = 3812K – 5316K and Ea = 0.33 eV – 0.46 eV) fulfill market requirements by comparing very well with the established values for NTC thermistors. Hence, from manufacturing viewpoint, recycling of chicken eggshell wastes and cassava effluents can avail electronic industry with promising and alternative materials for fabrication of temperature sensing / monitoring / control devices suitable for engineering applications. This will also help to reduce environmental pollution.
摘要用煅烧蛋壳纳米粉和干木薯淀粉两种混合比例制备了圆盘状压块,并将其用作试样。在35-75oC的温度范围内测量的样品的电阻(R)、热敏指数(β)和电子活化能(Ea)随温度的升高呈非线性下降。还观察到,通过与NTC热敏电阻的既定值进行很好的比较,获得的结果(R=3.691E6Ω–6.210E7Ω,β=3812K–5316K和Ea=0.33 eV–0.46 eV)满足了市场要求。因此,从制造业的角度来看,回收蛋壳废料和木薯废水可以为电子工业提供有前景的替代材料,用于制造适合工程应用的温度传感/监测/控制设备。这也将有助于减少环境污染。
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引用次数: 4
Supersolidus Sintering of Cr Prealloyed Steels by Inductive Heating 感应加热Cr预合金钢的超固相烧结
Q4 Materials Science Pub Date : 2019-12-01 DOI: 10.1515/pmp-2019-0006
C. Gierl-Mayer, M. Huemer, H. Danninger, M. Dlapka, G. Stetina, R. Ratzi
Abstract For powder metallurgy products, high density is an essential requirements to obtain maximum mechanical properties. Here, supersolidus liquid phase sintering (SSPLS) is an effective means to attain high sintered density, as known from PM high speed steels. In the present work it is shown that this technique can also be applied to Cr prealloyed low alloy steel grades. Supersolidus sintering through indirect heating requires precise control of temperature and also the atmosphere, to avoid uncontrolled changes of the carbon level. Higher C contents are beneficial here since they enable lower temperatures and result in wider temperature windows for sintering. The temperatures necessary for SSLPS at moderate C levels are fairly high for standard sintering furnaces, therefore induction sintering was studied in this work. It showed that, as was to be expected, also here precise temperature control is required, but for any carbon level tested a sintering temperature could be identified that yielded high sintered density and good shape retention. The high density attained, in combination with the very high temperatures, results in pronounced grain growth, this process no more being inhibited by the presence of pores, which is undesirable but can however be remedied by suitable heat treatment.
摘要对于粉末冶金产品来说,高密度是获得最大机械性能的基本要求。在这里,超固相液相烧结(SSPLS)是获得高烧结密度的有效手段,正如从PM高速钢中已知的那样。本工作表明,该技术也可应用于Cr预合金低合金钢牌号。通过间接加热的超固体烧结需要精确控制温度和大气,以避免碳含量的不可控变化。较高的C含量在这里是有益的,因为它们能够实现较低的温度并导致更宽的烧结温度窗口。对于标准烧结炉来说,在中等C水平下进行SSLPS所需的温度相当高,因此本文对感应烧结进行了研究。结果表明,正如预期的那样,这里也需要精确的温度控制,但对于任何测试的碳水平,都可以确定烧结温度,该温度产生高的烧结密度和良好的形状保持性。所获得的高密度与非常高的温度相结合,导致显著的晶粒生长,这一过程不再受到孔隙存在的抑制,这是不希望的,但可以通过适当的热处理来补救。
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引用次数: 0
Experimental Investigations on Impact Toughness and Shear Strength of Novel Lead Free Solder Alloy Sn-1Cu-1Ni-XAg 新型无铅钎料Sn-1Cu-1Ni-XAg冲击韧性和剪切强度的实验研究
Q4 Materials Science Pub Date : 2019-12-01 DOI: 10.1515/pmp-2019-0009
S. Jayesh, Jacob Elias
Abstract Lead is known to be banned in alloy making, highlighting toxicity concerns and environmental legislations. Researchers and scholars around the globe were in immediate search of new lead free solder alloys which could potentially replace the old Sn-Pb alloy. In this comprehensive study, shear strength and impact toughness tests were conducted on Sn-1Cu-1Ni when different amounts of Ag (0.25, 0.5, 0.75 1 % by wt.) is added. Shear strength test is tested using micro force test system. Impact toughness test is analyzed using Charpy impact test set up by calculating the energy difference before and after impact. The study reveals that, Ultimate shear stress increased from 19 MPa to 21.3 MPa. Yield strength increased from 27.4 MPa to 29.7 Mpa. Impact toughness of the alloys increased from 9.4 J to 10.1 J. Thus, Sn-1Cu-1Ni-1Ag is found to have improved shear strength and impact toughness than Sn-1Cu-1Ni.
摘要众所周知,铅在合金制造中是被禁止的,这突出了毒性问题和环境立法。全球各地的研究人员和学者正在立即寻找新的无铅焊料合金,这种合金有可能取代旧的Sn-Pb合金。在这项综合研究中,当添加不同量的Ag(0.25、0.5、0.75 1wt%)时,对Sn-1Cu-1Ni进行了剪切强度和冲击韧性测试。剪切强度试验采用微力试验系统进行。冲击韧性试验采用夏比冲击试验,通过计算冲击前后的能量差进行分析。研究表明,极限剪切应力从19MPa增加到21.3MPa。屈服强度从27.4MPa提高到29.7MPa。合金的冲击韧性从9.4J增加到10.1J。因此,发现Sn-1Cu-1Ni-1Ag比Sn-1Cu-1-Ni具有改进的剪切强度和冲击韧性。
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引用次数: 0
Preparation, Microstructure Evaluation and Performance Analysis of Diamond-Iron Bonded Magnetic Abrasive Powder 金刚石-铁结合剂磁性磨料的制备、微观结构评价及性能分析
Q4 Materials Science Pub Date : 2019-12-01 DOI: 10.1515/pmp-2019-0008
Palwinder Singh, L. Singh, Sehijpal Singh
Abstract The customary edged tool for machining is uneconomical for harder and hard to machine materials and furthermore the level of surface finish accomplished is not that great. As of late, a lot of consideration in mechanical engineering has been centered on finishing tasks. Not many investigations have been accounted for till date on the advancement of substitute magnetic abrasive powder (MAP). In this paper, to improve the finishing performance, the abrasive powder were prepared by mechanical alloying of diamond powder and iron (Fe) powder, compacting these with universal testing machine (UTM) and then sintered at different temperature in a sintering machine in an inert gas (H2) atmosphere. These compacts were crushed and sieved to obtain various sizes of MAP. This abrasive powder were micro-structurally examined. The results indicate that the densification increases and porosity decreases with increasing temperature. Moreover, the prepared bonded MAP has potential performance as a new MAP for fine finishing in Magnetic Abrasive Flow Machining (MAFM) process.
摘要对于较硬、较难加工的材料,传统的刃具加工不经济,而且表面光洁度也不高。最近,机械工程中的许多考虑都集中在完成任务上。迄今为止,关于替代磁性磨料粉(MAP)的研究还不多。为了提高磨料的精加工性能,本文将金刚石粉和铁粉机械合金化,在万能试验机(UTM)上进行压实,然后在烧结机上在惰性气体(H2)气氛中进行不同温度的烧结。这些压实物被粉碎和筛分得到不同尺寸的MAP。对该磨料粉末进行了显微结构检测。结果表明:随着温度的升高,致密性增大,孔隙率减小;此外,所制备的粘结MAP具有作为磁磨料流加工(MAFM)精细精加工的新型MAP的潜在性能。
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引用次数: 6
Additive Manufacturing of Steel and Copper Using Fused Layer Modelling: Material and Process Development 使用熔融层建模的钢和铜的增材制造:材料和工艺发展
Q4 Materials Science Pub Date : 2019-12-01 DOI: 10.1515/pmp-2019-0007
J. Ecker, K. Dobrezberger, J. Gonzalez-Gutierrez, M. Spoerk, C. Gierl-Mayer, Herbert Danninger
Abstract Fused Layer Modelling (FLM) is one out of several material extrusion (ME) additive manufacturing (AM) methods. FLM usually deals with processing of polymeric materials but can also be used to process metal-filled polymeric systems to produce metallic parts. Using FLM for this purpose helps to save costs since the FLM hardware is cheap compared to e.g. direct metal laser processing hardware, and FLM offers an alternative route to the production of metallic components. To produce metallic parts by FLM, the methodology is different from direct metal processing technologies, and several processing steps are required: First, filaments consisting of a special polymer-metal composition are produced. The filament is then transformed into shaped parts by using FLM process technology. Subsequently the polymeric binder is removed (”debinding”) and finally the metallic powder body is sintered. Depending on the metal powder used, the binder composition, the FLM production parameters and also the debinding and sintering processes must be carefully adapted and optimized. The focal points of this study are as following: 1. To confirm that metallic parts can be produced by using FLM plus debinding and sintering as an alternative route to direct metal additive manufacturing. 2. Determination of process parameters, depending on the used metal powders (steel and copper) and optimization of each process step. 3. Comparison of the production paths for the different metal powders and their debinding and sintering behavior as well as the final properties of the produced parts. The results showed that both materials were printable after adjusting the FLM parameters, metallic parts being produced for both metal powder systems. The production method and the sintering process worked out well for both powders. However there are specific challenges in the sintering process that have to be overcome to produce high quality metal parts. This study serves as a fundamental basis for understanding when it comes to the processing of steel and copper powder into metallic parts using FLM processing technology.
摘要熔融层建模(FLM)是材料挤压(ME)增材制造(AM)的一种方法。FLM通常处理聚合物材料的加工,但也可用于加工金属填充的聚合物系统以生产金属部件。为此目的使用FLM有助于节省成本,因为与直接金属激光加工硬件相比,FLM硬件便宜,并且FLM为金属部件的生产提供了另一种途径。通过FLM生产金属零件,其方法不同于直接金属加工技术,需要几个加工步骤:首先,生产由特殊聚合物-金属成分组成的细丝。然后利用FLM加工技术将长丝加工成成形件。随后,聚合物粘结剂被除去(“脱脂”),最后金属粉末体被烧结。根据所使用的金属粉末,粘合剂组成,FLM生产参数以及脱脂和烧结工艺必须仔细调整和优化。本研究的重点如下:1.研究方法:确认FLM +脱脂和烧结可以作为直接金属增材制造的替代路线来生产金属零件。2. 工艺参数的确定,取决于所使用的金属粉末(钢和铜)和每个工艺步骤的优化。3.比较了不同金属粉末的制备路径及其脱粘、烧结性能和成品的最终性能。结果表明,调整FLM参数后,两种材料均可打印,两种金属粉末体系均可生产金属零件。两种粉末的生产方法和烧结工艺均取得了良好的效果。然而,在烧结过程中有一些特殊的挑战,必须克服这些挑战才能生产出高质量的金属零件。本研究为了解利用FLM加工技术将钢和铜粉末加工成金属零件提供了基础基础。
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引用次数: 7
Polymorphs of Neodymium Niobate and Tantalate Thin Films Prepared by Sol-Gel Method Sol-Gel法制备铌钽酸钕薄膜的多晶型
Q4 Materials Science Pub Date : 2019-09-01 DOI: 10.1515/pmp-2019-0004
H. Brunckova, Ľ. Medvecký, E. Múdra, A. Kovalčíková
Abstract Neodymium niobate NdNbO4 (NNO) and tantalate NdTaO4 (NTO) thin films (~100 nm) were prepared by sol-gel/spin-coating process on Pb(Zr0.52Ti0.48)O3/Al2O3 substrates with annealing at 1000°C. The precursors of films were synthesized using Nb or Ta tartrate complexes. The XRD results of NNO and NTO films confirmed tetragonal T-NdNbO4 and T-NdTaO4 phases, respectively, with traces of monoclinic MNdNbO4 and M´-NdTaO4. The surface morphology and topography were investigated by SEM and AFM analysis. NTO was smoother with roughness 5.24 nm in comparison with NNO (6.95 nm). In the microstructure of NNO, small spherical (~ 20-50 nm) T-NdNbO4 and larger needle-like particles (~100 nm) of M-NdNbO4 phase were observed. The compact clusters composed of fine spherical T-NdTaO4 particles (~ 50 nm) and cuboidal M´-NdTaO4 particles (~ 100 nm) were found in NTO. The results of this work can contribute to formation of different polymorphs of films for the application in environmental electrolytic thin film devices.
摘要:在Pb(Zr0.52Ti0.48)O3/Al2O3衬底上,经1000℃退火,采用溶胶-凝胶/旋涂法制备了铌酸钕NdNbO4 (NNO)和钽酸NdTaO4 (NTO)薄膜(~100 nm)。采用酒石酸钠或酒石酸钠配合物合成了薄膜前驱体。NNO膜和NTO膜的XRD结果分别证实了T-NdNbO4和T-NdTaO4的四方相,并有微量的单斜MNdNbO4和M´-NdTaO4。采用扫描电镜(SEM)和原子力显微镜(AFM)对其表面形貌和形貌进行了研究。NTO的粗糙度为5.24 nm, NNO的粗糙度为6.95 nm。在NNO的微观结构中,观察到T-NdNbO4的小球形(~ 20 ~ 50 nm)和M-NdNbO4相较大的针状颗粒(~100 nm)。在NTO中发现了细小的球形T-NdTaO4颗粒(~ 50 nm)和立方M´-NdTaO4颗粒(~ 100 nm)组成的致密团簇。本研究结果有助于形成不同的多晶薄膜,用于环境电解薄膜器件。
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引用次数: 2
Die Wall - Vs. Bulk Lubrication in Warm Die Compaction: Density, Microstructure and Mechanical Properties of Three Low Alloyed Steels 温压模壁与本体润滑:三种低合金钢的密度、组织和力学性能
Q4 Materials Science Pub Date : 2019-09-01 DOI: 10.1515/pmp-2019-0005
M. Zadra, L. Girardini, G. Pederzini, G. Patuelli, M. Piva, S. Bordin, L. De Mitri, A. Popolizio, I. Cristofolini, A. Molinari
Abstract The influence of die wall lubrication during warm die compaction on densification, microstructure and mechanical properties of three low alloy ferrous powders was investigated. Specimens were sintered at 1250°C. Die wall lubrication leads to higher green and sintered density and enhances the dimensional stability. It does not affect the microstructure of the matrix, while pores are smaller and more rounded than in bulk lubricated specimens. In TRS tests, both strength and deformation are higher in die wall lubricated specimens than bulk lubricated ones.
研究了温压过程中模具壁润滑对三种低合金铁基粉末致密化、组织和力学性能的影响。样品在1250°C下烧结。模具壁润滑导致更高的生坯和烧结密度,并增强尺寸稳定性。它不会影响基体的微观结构,而孔隙比大块润滑试样更小、更圆。在TRS试验中,模壁润滑试样的强度和变形均高于整体润滑试样。
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引用次数: 0
Influence of Sodium Alginate on Properties of Tetracalcium Phosphate/Nanomonetite Biocement 海藻酸钠对磷酸四钙/纳米蒙脱石生物水泥性能的影响
Q4 Materials Science Pub Date : 2019-09-01 DOI: 10.1515/pmp-2019-0001
R. Stulajterova, Ľ. Medvecký, M. Giretova, T. Sopčák, J. Briančin
Abstract The tetracalcium phosphate/nanomonetite (TTCPMH) biocements with the addition of sodium alginate were prepared by mechanical homogenization of powder mixture with hardening liquid containing sodium alginate. The effect of various viscosity of different alginates on properties of TTCPMH cement mixture was investigated. The medium viscous (MED) alginate had a more negative effect on setting process and compressive strength than low viscous (LOW) alginate. An approx. 50% decrease in mechanical properties (compressive strengths, Young´s modulus, work of fracture (WOF)) was revealed after an addition of 0.25 wt % with rapid fall above 1 wt % of LOW alginate in biocement. A statistically significant difference in the WOF was found between of 0.25 and 0.5 LOW alginate biocements (p<0.035) whereas no statistical differences were revealed between WOF of 0.5 and 1 LOW alginate biocements (p˃0.357). In the microstructure of composite cements, the increased amounts of granular or finer needle-like nanohydroxyapatite particles arranged into the form of more separated spherical agglomerates were observed. A low cytotoxicity of cement extracts based on measurement of cell proliferation was revealed.
摘要用含藻酸钠的固化液对粉末混合物进行机械均质,制备了添加藻酸钠后的磷酸四钙/纳米莫来石(TTCPMH)生物材料。研究了不同海藻酸盐粘度对TTCPMH水泥混合料性能的影响。中等粘度(MED)海藻酸盐对固化过程和抗压强度的负面影响大于低粘度(low)海酸盐。在生物水泥中添加0.25wt%的LOW藻酸盐后,机械性能(抗压强度、杨氏模量、断裂功(WOF))下降了约50%,并迅速下降到1wt%以上。0.25和0.5 LOW藻酸盐生物复合物的WOF存在统计学显著差异(p<0.035),而0.5和1 LOW藻酸盐生物复合材料的WOF没有统计学差异(p=0.357)。在复合水泥的微观结构中,观察到颗粒或更细的针状纳米羟基磷灰石颗粒以更分离的球形团聚体的形式排列的量增加。基于细胞增殖的测量,揭示了水泥提取物的低细胞毒性。
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引用次数: 1
T Dependence of the Mechanical Properties on the Microstructural Parameters of WC-Co WC-Co合金力学性能与显微组织参数的关系
Q4 Materials Science Pub Date : 2019-09-01 DOI: 10.1515/pmp-2019-0003
L. Emanuelli, A. Molinari, G. Arrighetti, G. Garoli
Abstract The effect of binder content and WC grain size on the mechanical properties is widely investigated in literature. An increase in binder amount and WC grain size leads to a decrease in hardness and an increase in fracture toughness. Actually, these correlations are related to the influence of binder content and WC grain size through the contiguity and mean binder free path, which are the microstructural parameters that affect the mechanical properties. The aim of this study is to verify the dependence of the two microstructural parameters that govern the WCCo mechanical behaviour, namely the contiguity and mean binder free path, on the mechanical properties of an extended range of WC-Co samples, which differ in terms of Co content and tungsten carbide grain size.
摘要文献中广泛研究了粘结剂含量和WC晶粒度对力学性能的影响。粘结剂用量和WC晶粒尺寸的增加导致硬度降低和断裂韧性增加。实际上,这些相关性与粘结剂含量和WC晶粒度通过邻接度和平均粘结剂自由程的影响有关,这是影响力学性能的微观结构参数。本研究的目的是验证控制WCCo机械行为的两个微观结构参数,即接触度和平均粘结剂自由程,对一系列WC-Co样品的机械性能的依赖性,这些样品在Co含量和碳化钨晶粒度方面有所不同。
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引用次数: 1
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Powder Metallurgy Progress
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