An experimental investigation of the effectiveness of nanoclay material additives on the reduction of water absorption into a nylon AM polymer and the corresponding effects on the material and mechanical properties has been performed. The primary objectives of the study were to quantify the effectiveness of nanoclay material additives to mitigate the water absorption characteristics of extruded nylon, and quantify the changes in mechanical properties of the additive based material before and after salt water exposure. In the study three unique material configurations were evaluated: (1) Baseline Nylon, (2) Nylon with 2 % by weight nanoclay, and (3) Nylon with 5 % by weight nanoclay. The nanoclay powder that was used as an additive is Montmorillonite Clay (MMT) with surface modification. Water immersion was conducted with 3.5 % NaCl solution at room temperature for a time duration of 30 days. Each material configuration was being characterized mechanically in both dry and saturated conditions. The changes in mechanical properties were quantified through the controlled tensile testing. Additionally, thermogravimetric analysis (TGA) was conducted to quantify the changes in thermal decomposition. The thermal properties including glass transition temperature (Tg) and melting temperature (Tm) were evaluated by Differential Scanning Calorimetry (DSC). Finally, Dynamic Mechanical Analyzer (DMA) tests were conducted to understand the oscillation stress-strain behavior and thermal response of the neat nylon and the nanoclay modified material. The study's findings show that the use of nanoclay additives can reduce the amount of salt water absorbed by the respective materials, from 1.77 % to 1.63 %. However, there is a corresponding degrading effect on the mechanical properties of the materials themselves, even in the absence of salt water exposure. The incorporation of the nanoclay additives are shown to change the material behavior from highly ductile to highly brittle, with the failure strain being reduced from over 20 % to less than 2.5 %. Furthermore, The thermal properties of the baseline nylon were affected by the inclusion of the nanoclays by which the Glass Transition temperature was reduced from 45 °C to 43 °C and the melting temperature was increased from 200 °C to 204 °C.
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