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Effect of nanoclay additives on the salt water absorption and material characteristics of nylon additive manufactured polymers 纳米粘土添加剂对尼龙添加剂合成聚合物的吸水性能及材料特性的影响
Q1 Engineering Pub Date : 2025-08-05 DOI: 10.1016/j.ijlmm.2025.07.011
Irine Chenwi, Julianna Martinez, Dillon Fontaine, Catherine DuBois, James LeBlanc
An experimental investigation of the effectiveness of nanoclay material additives on the reduction of water absorption into a nylon AM polymer and the corresponding effects on the material and mechanical properties has been performed. The primary objectives of the study were to quantify the effectiveness of nanoclay material additives to mitigate the water absorption characteristics of extruded nylon, and quantify the changes in mechanical properties of the additive based material before and after salt water exposure. In the study three unique material configurations were evaluated: (1) Baseline Nylon, (2) Nylon with 2 % by weight nanoclay, and (3) Nylon with 5 % by weight nanoclay. The nanoclay powder that was used as an additive is Montmorillonite Clay (MMT) with surface modification. Water immersion was conducted with 3.5 % NaCl solution at room temperature for a time duration of 30 days. Each material configuration was being characterized mechanically in both dry and saturated conditions. The changes in mechanical properties were quantified through the controlled tensile testing. Additionally, thermogravimetric analysis (TGA) was conducted to quantify the changes in thermal decomposition. The thermal properties including glass transition temperature (Tg) and melting temperature (Tm) were evaluated by Differential Scanning Calorimetry (DSC). Finally, Dynamic Mechanical Analyzer (DMA) tests were conducted to understand the oscillation stress-strain behavior and thermal response of the neat nylon and the nanoclay modified material. The study's findings show that the use of nanoclay additives can reduce the amount of salt water absorbed by the respective materials, from 1.77 % to 1.63 %. However, there is a corresponding degrading effect on the mechanical properties of the materials themselves, even in the absence of salt water exposure. The incorporation of the nanoclay additives are shown to change the material behavior from highly ductile to highly brittle, with the failure strain being reduced from over 20 % to less than 2.5 %. Furthermore, The thermal properties of the baseline nylon were affected by the inclusion of the nanoclays by which the Glass Transition temperature was reduced from 45 °C to 43 °C and the melting temperature was increased from 200 °C to 204 °C.
实验研究了纳米粘土材料添加剂对尼龙AM聚合物吸水率的影响及其对材料力学性能的影响。本研究的主要目的是量化纳米粘土材料添加剂对缓解挤出尼龙吸水特性的有效性,并量化添加剂基材料在盐水暴露前后力学性能的变化。在研究中评估了三种独特的材料配置:(1)基线尼龙,(2)尼龙含有重量为2%的纳米粘土,(3)尼龙含有重量为5%的纳米粘土。采用表面改性的蒙脱土(MMT)纳米粘土粉作为添加剂。用3.5% NaCl溶液在室温下浸泡30天。在干燥和饱和条件下,每种材料结构都被机械地表征。通过控制拉伸试验,量化了其力学性能的变化。此外,热重分析(TGA)量化了热分解的变化。热性能包括玻璃化转变温度(Tg)和熔融温度(Tm)用差示扫描量热法(DSC)评估。最后,通过动态力学分析仪(DMA)测试了解了纯尼龙和纳米粘土改性材料的振荡应力-应变行为和热响应。研究结果表明,纳米粘土添加剂的使用可以将各自材料的盐水吸收量从1.77%降低到1.63%。然而,即使在没有盐水暴露的情况下,也会对材料本身的机械性能产生相应的降解作用。纳米粘土添加剂的掺入使材料从高延性变为高脆性,破坏应变从20%以上降低到2.5%以下。此外,纳米粘土的加入影响了基准尼龙的热性能,使玻璃化转变温度从45℃降低到43℃,熔融温度从200℃提高到204℃。
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引用次数: 0
Laser powder bed fusion of AlSi10Mg with increased layer thickness for higher building rate 激光粉末床熔接AlSi10Mg,增加熔层厚度,提高熔成率
Q1 Engineering Pub Date : 2025-08-05 DOI: 10.1016/j.ijlmm.2025.07.010
Stanislav Chernyshikhin , Leonid Fedorenko , Vladimir Egorov , Boris Zotov , Veniamin Brykin , Konstantin Korobov , Anton Nalivaiko , Dmitriy Zherebtsov , Maria Lyange , Ivan Pelevin
Among existing metal additive manufacturing technologies, laser powder bed fusion (LPBF) has an outstanding resolution but, from the other side, inferior building rate. In this work, the LPBF process of AlSi10Mg with increased layer thickness was comprehensively studied to enhance productivity. The samples were manufactured at 30, 50, 70, and 90 μm layer thicknesses with an additional variation in laser power and scanning speed. To find a quasi-optimal process conditions for each layer thickness, the specimens were investigated in terms of relative density, defect generation, microstructure, mechanical properties, and surface roughness. A transition in the pores’ morphologies along the building direction was identified. Namely, small metallurgical pores at the bottom surface, and irregular pores in the rest of the volume were observed. Therefore, special attention should be provided to the downskins of parts. The surface roughness tends to increase with the layer thickness, but it has been shown that the deterioration of the top surface quality is insignificant, and Ra for the side surface can be minimized via optimization of process conditions. It was demonstrated that an increase of layer thickness up to 50 μm is possible with a minor decrease in relative density and almost complete preservation of mechanical properties.
在现有的金属增材制造技术中,激光粉末床熔融(LPBF)具有出色的分辨率,但从另一方面来看,其构建速度较差。本文全面研究了AlSi10Mg增加层厚的LPBF工艺,以提高生产率。样品的层厚分别为30、50、70和90 μm,激光功率和扫描速度不同。为了找到每一层厚度的准最佳工艺条件,研究了试样的相对密度、缺陷产生、显微组织、力学性能和表面粗糙度。沿着建筑方向,孔隙形态发生了转变。即在底部表面观察到细小的冶金孔隙,而在体积的其余部分观察到不规则的孔隙。因此,应特别注意零件的下表皮。表面粗糙度随层厚的增加而增加,但表面质量的恶化不明显,通过优化工艺条件可以使侧面的Ra最小。结果表明,可以将层厚增加到50 μm,而相对密度略有下降,力学性能几乎完全保持不变。
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引用次数: 0
Analysis and optimisation of parent grain reconstruction for additively manufactured Ti–6Al–4V 增材制造Ti-6Al-4V母晶重构分析与优化
Q1 Engineering Pub Date : 2025-08-05 DOI: 10.1016/j.ijlmm.2025.07.009
Lu Yang , Saranarayanan Ramachandran , Axieh Bagasol , Fan Wu , Qiyu Guan , David J. Browne , Denis Dowling , Wajira Mirihanage
During solidification processing, most common titanium alloys solidify as high-temperature parent phase and it subsequently transforms into the room-temperature child phase. This parent to child transformation occurred as a solid-state transformation. Even though the parent phase is not observable at room temperature, it is considerably associated with solidification defects such as porosity. Parent grain reconstruction based on Burgers orientation relationship, which shows the crystallographic relationship between two phases, has been applied to examine the high temperature and transitional parent phases of titanium alloys and steels. This contribution presents the reconstructed high temperature parent phase and the sensitivity analysis related to a series of parameters for three crucial parent phase reconstruction steps for additively manufactured titanium alloy Ti–6Al–4V. The analysis examines the reconstruction, merging of very small and neighbouring grains together, and finally cleaning of inclusive noise, which referred as inclusions during the rendering process of the parent phase. The analysis offers an instruction for threshold selection that enables optimised parent phase reconstruction.
在凝固过程中,大多数常见的钛合金凝固为高温母相,随后转变为室温子相。这种从父到子的转换是作为固态转换发生的。尽管在室温下不能观察到母相,但它与气孔等凝固缺陷有很大的关系。基于Burgers取向关系的父相晶粒重建方法显示了两相之间的结晶学关系,并应用于钛合金和钢的高温和过渡母相的研究。本文介绍了Ti-6Al-4V增材制造钛合金高温母相重建及三个关键母相重建步骤的一系列参数敏感性分析。分析检查了重建,非常小的和邻近的颗粒合并在一起,最后清除包含噪声,这被称为在母相渲染过程中的包裹体。该分析为阈值选择提供了指导,使优化的父相重建成为可能。
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引用次数: 0
Feasibility of electrical discharge machining (EDM) of AZ31 lightweight magnesium alloy in dielectric fluids of hydrocarbon oil and deionized water 在烃类油和去离子水介质中电火花加工AZ31轻质镁合金的可行性
Q1 Engineering Pub Date : 2025-07-23 DOI: 10.1016/j.ijlmm.2025.07.004
Saeed Asghari , Mohammad Reza Shabgard , Maghsoud Shalvandi , S. Abolfazl Roudehchi , Farzad Habibi
In the current study, the effect of different types of dielectric fluids, including hydrocarbon oil and deionized water, on the material removal rate (MRR) and tool wear rate (TWR) of AZ31 magnesium alloy in the EDM process was investigated. X-ray diffraction (XRD) and FE-SEM coupled with energy dispersive spectroscope (EDS) were used to characterize the machined parts, while surface roughness and microhardness tests were used to evaluate the quality of the surface. The results revealed that the machining rate was significantly lower when using deionized water as the dielectric fluid. This was attributed to the formation of a 90 μm layer of magnesium oxide (MgO) on the machined surface, which was confirmed through EDS, XRD, and microhardness analyses. On the other hand, using oil as the dielectric fluid resulted in the formation of elemental carbon and Mg2C3 phase due to alloying with the workpiece. It was also observed that increasing the electric discharge current led to higher MRR and TWR values, with a smaller increase observed in specimens machined with deionized water. The surface roughness of the machined surfaces also increased significantly, from 10.12 to 19.2 μm for parts machined at 48 A/100 μs, indicating poor electrical discharge machinability of magnesium alloy in an aqueous environment.
本研究研究了不同类型的介质流体(烃类油和去离子水)对AZ31镁合金电火花加工过程中材料去除率(MRR)和刀具磨损率(TWR)的影响。采用x射线衍射(XRD)、FE-SEM和能谱仪(EDS)对加工零件进行表征,并采用表面粗糙度和显微硬度测试对加工零件的表面质量进行评价。结果表明,以去离子水为介质时,加工速率明显降低。这是由于在加工表面形成了90 μm的氧化镁(MgO)层,通过EDS, XRD和显微硬度分析证实了这一点。另一方面,使用油作为介质流体,由于与工件合金化,导致单质碳和Mg2C3相的形成。我们还观察到,增加放电电流导致更高的MRR和TWR值,而在去离子水处理的样品中观察到的增幅较小。在48 A/100 μs条件下,镁合金的表面粗糙度从10.12 μm增加到19.2 μm,表明镁合金在水环境下的放电可加工性较差。
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引用次数: 0
Low-velocity impact response of novel hierarchical hexagonal multicell structures 新型分层六方多室结构的低速冲击响应
Q1 Engineering Pub Date : 2025-07-23 DOI: 10.1016/j.ijlmm.2025.07.008
M Hafid , Abian Nurrohmad , Dony Hidayat , Riki Ardiansyah , Aryandi Marta , Citra Asti Rosalia , Zaini Ahmad
This study introduces two novel hierarchical hexagonal multicell (HHM) tube designs inspired by honeycomb and grass stem structures: full triangular hierarchical hexagonal multicell (FTHHM) and internal clone hierarchical hexagonal multicell (ICHHM). These tubes feature a triangular pattern and hierarchical arrangement with four orders (0th-3rd). The tubes, fabricated from PLA-ST using FDM 3D printing technology, were analyzed through finite element simulations of all hierarchical cross-sectional structures and validated against experimental results. Tubes with higher hierarchical orders consistently reduced total displacement and enhanced crashworthiness performance indices, particularly in crush force efficiency (CFE). Among the designs, the FTHHM-3 tube outperformed the ICHHM-3 tube. Furthermore, the effect of wall thickness on the FTHHM-3 tube was investigated by incrementally increasing the impactor mass until the densification phase was reached across the entire wall thickness. As a result, the FTHHM-3 model exhibited significant improvements in CFE by 24.77 % and in specific energy absorption (SEA) by 52.76 % compared to conventional hexagonal tubes. These findings indicate that 3D-printed FTHHM tubes, especially those with higher hierarchical orders, hold strong potential for application in future lightweight structural systems.
本文介绍了受蜂窝和草茎结构启发设计的两种新型分层六边形多细胞(HHM)管:全三角形分层六边形多细胞(FTHHM)管和内无性系分层六边形多细胞(ICHHM)管。这些管具有三角形的图案和四阶(0 -3)的分层排列。利用FDM 3D打印技术制造的PLA-ST管通过有限元模拟分析了所有分层横截面结构,并根据实验结果进行了验证。等级顺序越高的管子总位移越小,耐撞性能指数也越高,特别是在抗压力效率(CFE)方面。在设计中,FTHHM-3管的性能优于ICHHM-3管。进一步研究了壁厚对FTHHM-3管的影响,通过逐步增加冲击器质量,直到整个壁厚达到致密化阶段。结果表明,FTHHM-3模型的CFE比常规六方管提高24.77%,比能量吸收(SEA)比常规六方管提高52.76%。这些发现表明,3d打印的FTHHM管,特别是那些具有更高层次顺序的FTHHM管,在未来的轻量化结构系统中具有巨大的应用潜力。
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引用次数: 0
Development of magneto-rheological polishing process with NON-Newtonian fluid and uniform magnetic yoke for surface quality Ti–6Al–4V enhancement 采用非牛顿流体和均匀磁轭的磁流变抛光工艺提高Ti-6Al-4V表面质量
Q1 Engineering Pub Date : 2025-07-22 DOI: 10.1016/j.ijlmm.2025.07.007
Nguyen Minh Quang, Nguyen Tien Tung, Le Thi Phuong Thanh, Nguyen Duy Trinh
Ti–6Al–4V is a widely used and crucial alloy in various industries, particularly in manufacturing. Aiming to achieve a flat and smooth Ti–6Al–4V surface, this study proposes a new magneto-rheological (MR) polishing process, enhanced by a non-Newtonian fluid (thickening fluids) and a uniformly distributed magnetic yoke. A new MR fluid formulation is presented and discussed in detail in this study to address issues of poor particle bonding and non-uniformity. The authors also analyse the magnetic field to evaluate the effectiveness and feasibility of using uniformly dispersed magnetic particles in the MR process. Through evaluations of magnetic field strength, magnetic flux distribution and field variations, the study concludes that this approach is suitable and can enhance polishing performance. A polishing process employing the novel MR suspension and uniformly distributed magnetic yoke was established. The underlying mechanisms and key characteristics of this method were examined and discussed. An experimental setup, based on the previous MR processes, was used to conduct a series of experiments to demonstrate the potential of this method. The experiments also investigated the influence of several key factors, including fluid thickness, magnetic disk speed, working gap and container speed, on surface quality improvement. After 100 min of polishing, the Ti–6Al–4V workpiece achieved a smooth and flat surface with a surface roughness of Ra = 17 nm, demonstrating the high polishing efficiency of the proposed method. This research offers a promising solution for the precision polishing of difficult-to-machine materials and contributes to the advancement of smart finishing technologies for next-generation manufacturing.
Ti-6Al-4V是一种广泛应用于各个行业,特别是制造业的关键合金。为了获得平坦光滑的Ti-6Al-4V表面,本研究提出了一种新的磁流变(MR)抛光工艺,该工艺由非牛顿流体(增稠流体)和均匀分布的磁轭增强。提出了一种新的磁流变液配方,并对其进行了详细的讨论,以解决颗粒结合不良和不均匀性的问题。作者还对磁场进行了分析,以评价在磁流变过程中使用均匀分散磁颗粒的有效性和可行性。通过对磁场强度、磁通量分布和磁场变化的评价,研究表明该方法是合适的,可以提高抛光性能。建立了一种采用新型磁流变悬浮和均匀磁轭的抛光工艺。对该方法的基本机理和关键特性进行了研究和讨论。实验装置,基于以前的核磁共振过程,进行了一系列的实验,以证明该方法的潜力。实验还考察了流体厚度、磁盘速度、工作间隙和容器速度等关键因素对表面质量改善的影响。抛光100 min后,Ti-6Al-4V工件表面光滑平整,表面粗糙度Ra = 17 nm,表明该方法具有较高的抛光效率。这项研究为难加工材料的精密抛光提供了一个有前途的解决方案,并有助于下一代制造智能抛光技术的进步。
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引用次数: 0
Investigating the role of WEDM surface texturing in the degradation and biocompatibility of Mg–Zn–Ca alloy 研究电火花线切割表面织构在镁锌钙合金降解和生物相容性中的作用
Q1 Engineering Pub Date : 2025-07-15 DOI: 10.1016/j.ijlmm.2025.07.006
Ingilela Aswith Babu , Prithivirajan Sekar , Ashwini Prabhu , S. Narendranath , A.S.S. Balan
Magnesium (Mg) alloy-based biodegradable implants are gaining popularity for their low density, high strength, and biocompatibility. The corrosion and wear performance of Mg is poor in physiological environments, leading to premature failure. Surface modification, particularly through surface texturing, reduces the effective contact area of Mg–Zn–Ca alloy with corrosive media and tribological partners, potentially optimizing its degradation kinetics and cytocompatibility. Wire Electric Discharge Machining (WEDM) offers a stable oxide layer on the surface, unlike laser surface texturing, which may thermally damage the Mg alloy. In this study, three types of textures, mainly Wavy Texture (WT), microchannels (MC), and micropillars (MP), were created using WEDM on the Mg–Zn–Ca samples, and their corrosion, wear, cytotoxicity, and cell adhesion performance were evaluated. Texturing on the surface of the samples enhanced the corrosion performance, from 3.14 mm/year for the untextured sample to 0.98 mm/year for the micropillar textured sample, representing a 68.8 % reduction. This improvement after texturing is attributed to the superior surface finish (1.049 μm) and increased hydrophobicity (130.3°), equating to a 50.8 % improvement. The coefficient of friction (COF) value decreased from 0.364 for an untextured sample to 0.208 for microchannels, a 42.9 % reduction, due to the entrapment of debris in the textures and effective heat transfer. The samples' cell adhesion and cell viability have been improved after texturing. The combination of cytocompatibility, appropriate mechanical properties, and a reduced bio-corrosion rate highlights the potential of this surface texturing method, utilizing WEDM, as a promising approach to enhance biodegradable implant materials.
镁(Mg)合金基生物可降解植入物因其低密度、高强度和生物相容性而越来越受欢迎。Mg在生理环境中的腐蚀磨损性能较差,导致过早失效。表面改性,特别是通过表面织构,减少了Mg-Zn-Ca合金与腐蚀性介质和摩擦学伙伴的有效接触面积,有可能优化其降解动力学和细胞相容性。电火花线切割加工(WEDM)在表面提供稳定的氧化层,不像激光表面变形,这可能会热损伤镁合金。在本研究中,利用WEDM在Mg-Zn-Ca样品上制备了三种类型的织构,主要是波浪织构(WT)、微通道(MC)和微柱(MP),并对它们的腐蚀、磨损、细胞毒性和细胞粘附性能进行了评估。样品表面的织构增强了腐蚀性能,从未织构样品的3.14 mm/年到微柱织构样品的0.98 mm/年,减少了68.8%。织构后的改善主要归功于优异的表面光洁度(1.049 μm)和疏水性(130.3°)的提高,相当于改善了50.8%。摩擦系数(COF)值从无织构样品的0.364下降到微通道样品的0.208,降低了42.9%,这是由于织构中碎片的夹持和有效的传热。经纹理处理后,样品的细胞黏附力和细胞活力均有所提高。结合细胞相容性,适当的机械性能和降低的生物腐蚀速率,突出了这种表面纹理方法的潜力,利用WEDM,作为一种有前途的方法来增强生物可降解植入材料。
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引用次数: 0
Biocidal and reinforced PETG/antibacterial blend nanocomposite for extrusion-based additive manufacturing: Optimization course and printability scores 用于挤压增材制造的杀生物和增强PETG/抗菌混合纳米复合材料:优化过程和可打印性分数
Q1 Engineering Pub Date : 2025-07-08 DOI: 10.1016/j.ijlmm.2025.07.003
Nectarios Vidakis , Nikolaos Michailidis , Nektarios K. Nasikas , Constantine David , Dimitrios Sagris , Apostolos Argyros , Ioannis Valsamos , Katerina Gkagkanatsiou , Vassilis Papadakis , Markos Petousis
Polyethylene terephthalate glycol (PETG) is an amorphous polymer that has been widely used in numerous applications, from everyday life to medical and even defense-related applications. The latter constitute very demanding environments in which, in many cases, specific multifunctionalities are required. Herein, we aim for specific functionalities to appear simultaneously, thus creating novel materials that can provide important solutions to applications. Therefore, inducing antibacterial properties along with enhanced mechanical properties for use in the defense and security domains constitutes an additional asset when disease spread becomes very important. To address this challenge, we mixed pure PETG with an antibacterial nanopowder to investigate these novel multifunctionalities in detail. Concomitantly, the enhancement of the mechanical properties of the 3D printed PETG/antibacterial nanocomposites was thoroughly examined. Several PETG nanocomposites were manufactured with different nanopowder loadings and turned into filaments for use in the AM method of material extrusion (MEX). The several 3D printed PETG/antibacterial nanocomposites were thoroughly investigated for their mechanical and rheological properties, thermal stability, and morphological, structural, and chemical characteristics, combined with antibacterial performance, against two common pathogens, s. aureus and e. coli, using the agar well diffusion method. The outcome of the nanopowder introduction to the quality metrics of the 3D printed PETG, namely the geometrical accuracy and pores of the 3D printed structure was also investigated through high-resolution micro-computed tomography. The PETG/antibacterial nanocomposites exhibited improved mechanical properties. A 13.6 % tensile strength increase was achieved with 8 wt% content. 10 wt % achieved 17 % Young's modulus increase, 19 % flexural strength and 18.2 % flexural modulus improvement and can be considered the optimum loading of the research. Nanocompounds also showed strong antibacterial activity against s. aureus and E. coli. These induced multifunctionalities can constitute a new class of materials where the desired properties can have significant applications in two or more different fields for functional, durable, and infection-resistant materials, such as in the demanding defense and security sector, the medical field, or both.
聚对苯二甲酸乙二醇酯(PETG)是一种无定形聚合物,已广泛应用于众多应用,从日常生活到医疗甚至国防相关应用。后者构成了非常苛刻的环境,在许多情况下,需要特定的多功能。在这里,我们的目标是同时出现特定的功能,从而创造出可以为应用提供重要解决方案的新材料。因此,当疾病传播变得非常重要时,诱导抗菌性能以及用于防御和安全领域的增强机械性能构成了额外的资产。为了解决这一挑战,我们将纯PETG与抗菌纳米粉末混合,以详细研究这些新的多功能。同时,深入研究了3D打印PETG/抗菌纳米复合材料的力学性能增强情况。制备了几种不同纳米粉末负载的PETG纳米复合材料,并将其加工成长丝,用于材料挤压增材制造(MEX)。采用琼脂孔扩散法,对几种3D打印的PETG/抗菌纳米复合材料的力学和流变性能、热稳定性、形态、结构和化学特性以及对金黄色葡萄球菌和大肠杆菌两种常见病原体的抗菌性能进行了深入研究。通过高分辨率微计算机断层扫描,研究了纳米粉末对3D打印PETG质量指标的影响,即3D打印结构的几何精度和孔隙。PETG/抗菌纳米复合材料的力学性能得到改善。当质量分数为8wt %时,拉伸强度提高13.6%。10 wt %可使杨氏模量提高17%,抗弯强度提高19%,抗弯模量提高18.2%,可认为是研究的最佳荷载。纳米化合物对金黄色葡萄球菌和大肠杆菌也有较强的抗菌活性。这些诱导的多功能可以构成一类新的材料,其中所需的性能可以在两个或多个不同领域中作为功能性,耐用性和抗感染材料具有重要应用,例如在要求苛刻的国防和安全部门,医疗领域,或两者兼而有之。
{"title":"Biocidal and reinforced PETG/antibacterial blend nanocomposite for extrusion-based additive manufacturing: Optimization course and printability scores","authors":"Nectarios Vidakis ,&nbsp;Nikolaos Michailidis ,&nbsp;Nektarios K. Nasikas ,&nbsp;Constantine David ,&nbsp;Dimitrios Sagris ,&nbsp;Apostolos Argyros ,&nbsp;Ioannis Valsamos ,&nbsp;Katerina Gkagkanatsiou ,&nbsp;Vassilis Papadakis ,&nbsp;Markos Petousis","doi":"10.1016/j.ijlmm.2025.07.003","DOIUrl":"10.1016/j.ijlmm.2025.07.003","url":null,"abstract":"<div><div>Polyethylene terephthalate glycol (PETG) is an amorphous polymer that has been widely used in numerous applications, from everyday life to medical and even defense-related applications. The latter constitute very demanding environments in which, in many cases, specific multifunctionalities are required. Herein, we aim for specific functionalities to appear simultaneously, thus creating novel materials that can provide important solutions to applications. Therefore, inducing antibacterial properties along with enhanced mechanical properties for use in the defense and security domains constitutes an additional asset when disease spread becomes very important. To address this challenge, we mixed pure PETG with an antibacterial nanopowder to investigate these novel multifunctionalities in detail. Concomitantly, the enhancement of the mechanical properties of the 3D printed PETG/antibacterial nanocomposites was thoroughly examined. Several PETG nanocomposites were manufactured with different nanopowder loadings and turned into filaments for use in the AM method of material extrusion (MEX). The several 3D printed PETG/antibacterial nanocomposites were thoroughly investigated for their mechanical and rheological properties, thermal stability, and morphological, structural, and chemical characteristics, combined with antibacterial performance, against two common pathogens, <em>s. aureus</em> and <em>e. coli</em>, using the agar well diffusion method. The outcome of the nanopowder introduction to the quality metrics of the 3D printed PETG, namely the geometrical accuracy and pores of the 3D printed structure was also investigated through high-resolution micro-computed tomography. The PETG/antibacterial nanocomposites exhibited improved mechanical properties. A 13.6 % tensile strength increase was achieved with 8 wt% content. 10 wt % achieved 17 % Young's modulus increase, 19 % flexural strength and 18.2 % flexural modulus improvement and can be considered the optimum loading of the research. Nanocompounds also showed strong antibacterial activity against <em>s. aureus</em> and <em>E. coli</em>. These induced multifunctionalities can constitute a new class of materials where the desired properties can have significant applications in two or more different fields for functional, durable, and infection-resistant materials, such as in the demanding defense and security sector, the medical field, or both.</div></div>","PeriodicalId":52306,"journal":{"name":"International Journal of Lightweight Materials and Manufacture","volume":"8 6","pages":"Pages 726-746"},"PeriodicalIF":0.0,"publicationDate":"2025-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145371064","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tribological aspects of AA6082/graphene/TiC hybrid composite using Taguchi and Machine Learning 使用田口和机器学习的AA6082/石墨烯/TiC杂化复合材料的摩擦学方面
Q1 Engineering Pub Date : 2025-07-05 DOI: 10.1016/j.ijlmm.2025.07.002
Sohan Lal , Rashmi Mittal , Neeraj Sharma , Guru Prakash
In the present research, hybrid composite consists of AA6082 aluminum base with TiC and n-graphene ceramics reinforcements ranging from 1 to 6 wt.%. High-energy ball milling created homogeneous mixtures between the two reinforcing components that together occupied 50 wt.% of total content. The hybrid aluminum matrix composite was fabricated through stir casting before being examined for wear resistance against the counter surface of EN32 steel by means of a pin-on-disc tribometer. The optimization process for pin-on-disc testing parameters merged Taguchi method with machine learning (ML) approaches. Load stands as the primary factor determining the dry sliding wear rate (WR) of materials according to analysis of variance (ANOVA) results while reinforcement content and speed play additional roles. The slope of both two-factor interaction effects demonstrated meaningful change. The Taguchi and ML determined that the optimized parameters would lead to a WR of 6.94×10-4 mg/s as the minimum value. Microstructural examination using scanning electron microscopy (SEM) finds that very small grooves are seen at optimal settings, whereas severe ploughing is shown at other settings. The wear mechanism transitions from adhesive to abrasive when the speed between the pin and disc increases.
在本研究中,杂化复合材料由AA6082铝基与TiC和n-石墨烯陶瓷增强剂组成,增强剂的重量为1% ~ 6%。高能球磨在两种增强成分之间产生均匀的混合物,共占总含量的50 wt.%。混合铝基复合材料是通过搅拌铸造制备的,然后用针盘式摩擦计检测了其对EN32钢表面的耐磨性。将田口法与机器学习方法相结合,对针盘式测试参数进行优化。方差分析结果表明,载荷是决定材料干滑动磨损率的主要因素,钢筋含量和速度也起着辅助作用。两因素交互作用的斜率均有显著变化。Taguchi和ML确定,优化后的WR最小值为6.94×10-4 mg/s。使用扫描电子显微镜(SEM)进行显微结构检查发现,在最佳设置下可以看到非常小的凹槽,而在其他设置下则显示出严重的犁耕。当销与盘之间的速度增加时,磨损机制由黏合剂转变为磨料。
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引用次数: 0
Effects of tool geometry on the weld quality of friction stir welded ultra-thin 1060 aluminum alloy plate 刀具几何形状对超薄1060铝合金板搅拌摩擦焊焊缝质量的影响
Q1 Engineering Pub Date : 2025-06-13 DOI: 10.1016/j.ijlmm.2025.06.001
Saiyu Yang, Shiqi Chen, Huiyu Song, Jun Shen
Friction Stir Welding (FSW) has gained widespread application in aluminum alloy joining due to its ability to produce high-strength, defect-free welds. However, welding ultra-thin aluminum alloy plates (thickness <2 mm) presents challenges such as joint softening, surface thinning, and warping. In this study, 1.4 mm-thick 1060 aluminum alloy plates were friction stir welded using tools with varying geometric parameters—including shoulder diameter, concave angle, and stir pin taper—under fixed welding conditions of 3000 r/min rotation speed and 300 mm/min welding speed. Through metallographic observation, Vickers microhardness testing, and tensile strength evaluation, it was found that the tool with a conical stir pin (Tool No. 2), featuring a 5 mm flat shoulder, root diameter of 2 mm, and end diameter of 1 mm, produced the highest-quality weld. The resulting joints exhibited a smooth surface finish, minimal internal defects, and a maximum tensile strength of 131.80 MPa–99.55 % of the base material strength (132.40 MPa). The fracture consistently occurred in the base material region, indicating excellent joint integrity. Additionally, the weld zones demonstrated fine-grained microstructures and maintained or exceeded the base material's hardness across all regions. This research confirms that by optimizing stir tool geometry, FSW can effectively eliminate defects such as thinning, grooves, and warping in ultra-thin aluminum sheets. The findings offer practical guidance for the reliable application of FSW in high-precision, lightweight structures such as aerospace components and new energy vehicle battery trays.
搅拌摩擦焊(FSW)由于能够产生高强度、无缺陷的焊缝,在铝合金连接中得到了广泛的应用。然而,焊接超薄铝合金板(厚度为2毫米)面临着诸如接头软化、表面变薄和翘曲等挑战。在3000 r/min转速和300 mm/min焊接速度的固定焊接条件下,使用不同几何参数(包括肩径、凹角和搅拌销锥度)的工具对1.4 mm厚1060铝合金板进行搅拌摩擦焊接。通过金相观察、维氏显微硬度测试和抗拉强度评估,发现采用锥形搅拌销(工具2号)的焊缝质量最高,其平肩为5mm,根部直径为2mm,端部直径为1mm。所得到的接头表面光洁度高,内部缺陷最小,最大抗拉强度为131.80 MPa -母材强度(132.40 MPa)的99.55%。断裂始终发生在基材区域,表明关节完整性良好。此外,焊缝区显示出细晶微结构,并在所有区域保持或超过母材的硬度。该研究证实,通过优化搅拌工具的几何形状,搅拌搅拌可以有效地消除超薄铝板中的变薄、沟槽和翘曲等缺陷。研究结果为FSW在高精度、轻量化结构(如航空航天部件和新能源汽车电池托盘)中的可靠应用提供了实用指导。
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International Journal of Lightweight Materials and Manufacture
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