Contributions to Mineralogy and Petrology最新文献

In the last two decades, boron has gained significance as a geochemical tracer in mantle studies, particularly related to fluid-mediated processes. In our investigation, we explore how boron and its stable isotopes distribute between basaltic melt and hydrous fluid under conditions relevant to magmatic degassing in the shallow crust (1000–1250 °C, 150–250 MPa). We utilized a synthetic MORB-like composition with added boric-acid isotope standard (NIST-SRM951a) and additional trace elements, subjecting it to varying pressure, temperature, and melt-fluid ratios using an internally heated pressure vessel. The B isotope composition in the quenched glasses were determined through femtosecond laser ablation coupled to a multi-collector inductively-coupled-plasma mass spectrometer. Our experiments revealed that, even at the highest temperatures, boron strongly partitions into the fluid phase, accompanied by significant B isotope fractionation. This leads to an enrichment of the heavy B isotope in the fluid, with a constrained Δ¹¹B_melt-fluid range of -1.7 ± 0.9‰, consistent with ab-initio modeling results. These findings highlight the potential of B isotopes to trace geochemical processes at elevated temperatures with ({Delta}^{11}{{B}}_{melt-fluid}=2.913-9.693frac{{10}^{6}}{{{T}}^{2}}). Our results have implications for predicting the δ¹¹B of degassed, water-bearing basaltic magmas and estimating the B isotope composition of their mantle source.

Garnet and zircon in a marble-hosted eclogite from the Dabie ultrahigh-pressure (UHP) terrane, eastern China record a wealth of information on multistage pervasive fluid–rock interactions and Hf mobility in deep continental subduction zones. The eclogite has a peak mineral assemblage of garnet + omphacite + phengite + coesite + magnesite ± dolomite + rutile. Five (inner patchy core, outer core, mantle, inner rim, outer rim) compositional zones were recognized for garnet. According to phase equilibria modeling, the inner patchy and outer cores of garnet likely document a prograde breakdown of lawsonite to UHP peak (3.0–4.5 GPa and 630–750 °C), while a Ca-metasomatism could have also played a role in their formation. The other three garnet zones resulted from multistage garnet re-equilibration at eclogite-facies conditions during isothermal exhumation. The stepwise compositional changes between these different garnet zones suggest that dissolution and reprecipitation played a key role in the garnet re-equilibration, while the repeated actions of such a re-equilibration mechanism reflect multistage pervasive fluid–rock interactions. Zircon from the rock develops three eclogite-facies domains (1, 2, 3). Textural relationships suggest that domain 2 formed in between domain 1 and 3. LA-ICP-MS analyses yielded ²⁰⁶Pb/²³⁸U ages of 233 ± 6 Ma, 232 ± 2 Ma and 222 ± 3 Ma for domain 1, 2 and 3, respectively. Domain 1 includes coesite and magnesite and its Th/U is usually higher than 0.1. This domain is interpreted to have formed in the absence of allanite during prograde UHP metamorphism. Domain 2 shows slightly lower ∑MREEs (middle rare earth elements; 7.5–13.5 ppm) and lower Ti (3.0–6.0 ppm) contents than domain 1 (∑MREEs = 10.5–21.0 ppm; Ti = 4.5–7.0 ppm) and most likely formed at the UHP peak. Domain 3 contains much lower ∑MREEs (3.5–6.0 ppm) and higher Ti (7.5–11.0 ppm) contents than domain 1 and 2, which is interpreted to have formed in the stability field of epidote during decompression. Domain 2 (0.282354–0.282607) and 3 (0.282449–0.282636) display lower initial ¹⁷⁶Hf/¹⁷⁷Hf values than domain 1 (0.282563–0.282667), suggesting that external fluids introduced Hf into the eclogite. These findings not only shed new light on the flow mode of fluids and their role in resetting mineral compositions in deep subduction zones, but also suggest that Hf (a key high-field strength and tracer element) can be efficiently mobilized by (U)HP fluids. Moreover, this study highlights the influence of epidote-group minerals and pressure on the chemistry (Th/U ratio and REE and Ti contents) of zircon.

Water occurs in Earth’s interior mostly as trace hydroxyl in nominally anhydrous minerals. Clinopyroxene is known to be an important water carrier in the uppermost mantle, and eclogite, which forms a subordinate part of the cratonic lithosphere, contains some 50% of jadeite-rich clinopyroxene, making this potentially a significant H₂O reservoir in the bulk lithospheric mantle. Mantle metasomatism, in particular by small-volume melts like kimberlite, is known to enrich the lithosphere in highly incompatible components, but its effect on H₂O contents in cratonic eclogite remains unclear. We report H₂O concentrations for clinopyroxene and garnet in eclogite and pyroxenite xenoliths from several African kimberlites, obtained by Fourier-Transform Infrared Spectroscopy (FTIR). Except one sample showing evidence for minor within-grain variability of H₂O concentrations (< 15%), FTIR images demonstrate that H₂O is homogeneously distributed in optically clear areas of clinopyroxene fragments mounted for this study. The samples were variably metasomatised by a kimberlite-like melt, as evidenced by elevated MgO contents and abundances of highly incompatible elements (e.g., Sr, Ce, Th). Although metasomatised eclogites and pyroxenites on average show higher H₂O abundances than pristine ones, mantle metasomatism decreases the Al₂O₃ content in clinopyroxene, which is known to enhance hydrogen incorporation in this mineral. As a consequence, hydrogen incorporation is inhibited, and c(H₂O) becomes increasingly decoupled from other highly incompatible components, such as LREE. Thus, eclogite – metasomatised or not - does not significantly contribute to the H₂O inventory in the bulk cratonic mantle.

Apatite has been recognized as a robust tool for the study of magmatic volatiles in terrestrial and extraterrestrial systems due to its ability to incorporate various volatile components and its common occurrence in igneous rocks. Most previous studies have utilized apatite to study individual magmatic systems or regions. However, volatile systematics in terrestrial magmatic apatite formed under different geological environments has been poorly understood. In this study, we filtered a large compilation of data for apatite in terrestrial igneous rocks (n > 20,000), categorized the data according to tectonic settings, rock types, and bulk-rock compositions, and conducted statistical analyses of the F–Cl–OH–S–CO₂ contents (~ 11,000 data for halogen and less for other volatiles). We find that apatite from volcanic arcs preserves a high Cl signature in comparison to other tectonic settings and the median Cl contents differ between arcs. Apatite in various types and compositions of igneous rocks shows overlapping F–Cl–OH compositions and features in some rock groups. Specifically, apatite in kimberlite is characterized as Cl-poor, whereas apatite in plutonic rocks can contain higher F and lower Cl contents than the volcanic counterparts. Calculation using existing partitioning models indicates that apatite with a high OH (or F) content does not necessarily indicate a H₂O-rich (or H₂O-poor) liquid because it could be a result of high (or low) magma temperature. Our work may provide a new perspective on the use of apatite to investigate volatile behavior in magma genesis and evolution across tectonic settings, volatile recycling at subduction zones, and the volcanic-plutonic connection.

Garnet granulite xenoliths from the Nurbinskaya diatreme in the central part of the Archean Anabar province in Siberia are fragments of the local lower crust that experienced multiple metamorphic events in the Paleoproterozoic and reheating events in the Mesoproterozoic and later. This study addresses the timing of metamorphic transformations, and constrains the cooling rate and the time of stabilization of the lower crust. The observed metamorphic mineral assemblage of garnet, clinopyroxene, plagioclase, amphibole, rutile and ilmenite was formed at ~ 800 °C, 1.1–1.2 GPa under water-undersaturated conditions at ~ 1.88 Ga. However, the mineral assemblage is not well equilibrated and retains evidence of earlier and subsequent metamorphic stages. Late titanite formed in response to hydrous fluid influx according to phase equilibria modeling. U-Pb dating shows two events of titanite formation at 1850 ± 5 Ma and at 1788 ± 2 Ma. After deformation, which led to the porphyroclastic rock textures, the granulites underwent near-isobaric cooling. The cooling rate was higher than ~ 6 °C/Myr, to retain the garnet compositional zoning. Rutile ages are discordant, with ²⁰⁷Pb/²⁰⁶Pb dates ranging from 1.43 to 1.53 Ga. However, rutile may have responded to earlier thermal pulses, and was also reset later, so it does not record the stabilization of the crust. Crustal stabilization after Paleoproterozoic orogenic events may have occurred shortly after titanite formation.

Paleoproterozoic (2.05 Ga) komatiites are widespread in the Central Lapland Greenstone Belt (CLGB), northern Finland. Close association with sulfur (S)-rich country rocks and spatiotemporal connection with the Cu-Ni(-PGE) deposits of Kevitsa and Sakatti make these komatiites interesting targets for sulfide deposit exploration. We provide whole-rock geochemical data from Sattasvaara komatiites and combine it with literature data to form a geochemical database for the CLGB komatiites. We construct a model for the komatiites from adiabatic melting of the mantle source to fractional crystallization at crustal conditions. Using MELTS, we calculate three parental melts (MgO = 20.6–25.7 wt%) in equilibrium with Fo₉₂, Fo₉₃, and Fo₉₄ olivine for the CLGB komatiites. Based on REEBOX PRO simulations, these parental melts can form from a single mantle source by different pressures and degrees of melting when the potential temperature is 1575–1700 °C. We calculate ranges of S contents for the parental melts based on the different mantle melting conditions and degrees of melting. We use Magma Chamber Simulator to fractionally crystallize the parental melt at crustal conditions. These simulations reproduce the major element oxide, Ni, Cu, and S contents from our komatiite database. Simulated Ni contents in olivine are compatible with literature data from Kevitsa and Sakatti, hence providing a baseline to identify Ni-depleted olivine in CLGB komatiites and related intrusive rocks. We show that fractional crystallization of the komatiitic parental melt can form either Ni-rich or Cu-rich sulfide melt, depending on the initial Ni and S content of the parental melt.

The Merensky and Bastard reefs of the Bushveld Complex occur within what has been called a transitional macro-unit along the boundary of the Critical and Main zones. The transitional unit is characterised by a geochemical hiatus recording distinct inflections in mineral chemistry and isotopic compositions. Previously these inflections in mineral chemistry and changes in isotopic compositions were attributed mostly to the influx of a magma that was compositionally distinct from the resident magma and that was parental to the Main Zone of the complex. Sr-isotopic variations across this interval have been particularly well-studied, but despite this, little consensus exists regarding the petrogenesis and metallogenesis of this economically important interval. Here we report whole-rock Sr–Nd-isotopic, major- and trace element geochemical and mineral chemical data across the Merensky-Bastard interval as intersected by borehole BH8172 on the farm Hackney in the eastern Bushveld Complex. Variations in whole-rock Cr/MgO values and initial Sr isotopic ratios across the interval are consistent with the results of previous studies that argued for the co-accumulation of minerals from compositionally and isotopically distinct magmas, of Critical and Main Zone lineages, respectively. In our model, a magma of Critical Zone affinity enters the chamber causing erosion along the chamber floor. Orthopyroxene and plagioclase crystallise from the Critical Zone magma to form the Merensky Reef, as suggested by high whole-rock Cr/MgO ratios (> 80) and unradiogenic Sr-isotopic compositions (⁸⁷Sr/⁸⁶Sr_i < 0.7068). A plagioclase-laden magma of Main Zone affinity subsequently intruded the chamber as a basal flow, elevating the resident Critical Zone magma. Plagioclase within the former floated, forming a solid raft onto which the Bastard Reef was deposited, a model that is entirely consistent with density considerations and an upward increase in the An-content of plagioclase as observed in the anorthositic package between the Merensky and Bastard reefs. From a metallogenetic viewpoint, this would imply that the Main Zone could not have been the source of the PGEs within the Merensky Reef.

This study tests experimentally the hypothesis that calculated bulk compositions of multiphase solid inclusions present in minerals of ultrahigh pressure rocks, can be equated to the composition of the former trapped fluids. We investigated samples from the ultrahigh pressure garnet peridotites of the Bohemian Massif, spatially associated with ultrahigh pressure crustal rocks and representing a former subduction interface environment. Inclusions present in garnets, composed of amphibole + Ba-mica kinoshitalite + carbonates (dolomite + magnesite + norsethite), were taken to their entrapment conditions of c. 4.5 GPa and 1075 ºC. They (re)crystallized into a garnet fringe at the boundary between inclusion and host garnet, kinoshitalite ± olivine, carbonatite melt, and a hydrous fluid. Although the latter may have exsolved from the carbonatite melt upon quenching, microstructures suggest it was present at trapped conditions, and mass balance indicates that it corresponds to a Na-K-Cl-F-rich saline aqueous fluid (brine). Experiments demonstrate the stability of kinoshitalite at 4.5 GPa and 1075 ºC, and suggest that Ba-rich mica + carbonatite melt + brine coexisted at near-peak conditions. Barium is compatible in the carbonatite melt and mica with respect to the brine, with a partition coefficient between carbonatite melt and mica of ≈ 2.5–3. The garnet fringe formed from incongruent reaction of the former inclusion assemblage due to reversing the fluid(s)-host garnet reaction that occurred upon natural cooling/decompression. Loss of H₂ or H₂O from the inclusions due to volume diffusion through garnet and/or decrepitation, during geological timeframes upon decompression/cooling, may have prevented rehomogenization to a single homogeneous fluid. Our study shows that great care is needed in the interpretation of multiphase solid inclusions present in ultrahigh pressure rocks.