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ISOTOPIC-RADIOGEOCHEMICAL ANALYSIS OF GROUNDWATERAT THE KALUSH-GOLINSKY POTASSIUM SALT DEPOSIT kalush-golinsky钾盐矿床地下水同位素-放射性地球化学分析
Pub Date : 2022-01-01 DOI: 10.32782/geotech2022.35.14
Y. Malkova, I. Kovalenko, V. Dolin, M I Panasyuk, Y. Demikhov, N. Sosonna, S. Bagriy, E. Kuzmenko
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引用次数: 0
ABOUT THE CONGRUENCE OF FORMATION OF PIVNICHNO-ТЕRSYAN FOLDING FORM AND CONTAINING FORMATIONS (ОRIKHOVО-PAVLOGRAD SUTURE ZONE) 关于pivnichno结构-ТЕrsyan折叠结构与包含结构(ОrikhovО-pavlograd缝合带)的一致性
Pub Date : 2022-01-01 DOI: 10.32782/geotech2022.35.16
L. Osmachko
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引用次数: 0
LONG-TERM RADIOECOLOGICAL MONITORING OF PU-239,240 AND AM-241 BEHAVIOUR ON THE TERRITORY AROUND THE CHORNOBYL NPP 切尔诺贝利核电站周边地区pu-239,240和am-241行为的长期放射生态学监测
Pub Date : 2022-01-01 DOI: 10.32782/geotech2022.35.19
S. Barbashev, V. Nazaryshyn
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引用次数: 0
CHEMICAL COMPOSITION AND STRUCTURE OF THE WEATHERING PRODUCTS OF IRON-NICKEL OF THE GRUZ’KE CHONDRITE (H4) 格鲁兹克球粒陨石(h4)铁镍风化产物的化学组成及结构
Pub Date : 2022-01-01 DOI: 10.32782/geotech2022.36.03
S. Shyrinbekova
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引用次数: 0
COMMON REED (PHRAGMITES AUSTRALIS (CAV.) TRIN. EX STEUD.) AS BIOACCUMULATOR OF FE, MN, CU ON BIO-ENGINEERING FACILITIES OF POLTAVSKY MINING AND PROCESSING PLANT 芦苇(芦苇属)指标。STEUD交货)。作为铁、锰、铜的生物蓄能器应用于波尔塔夫斯基矿山生物工程设施
Pub Date : 2022-01-01 DOI: 10.32782/geotech2022.36.02
O. Orlov, V. Dolin, D. Charny, D.O. Yarochshuk
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引用次数: 0
RADIOECOLOGICAL CONDITIONS WITHIN THE URANIUM MINING IMPACT AREAS INGULSKA MINE CASE STUDY 英戈尔斯卡铀矿开采影响区内的放射生态条件个案研究
Pub Date : 2022-01-01 DOI: 10.32782/geotech2022.35.15
V. Verkhovtsev, T. Dudar, K. Lysychenko, Yu. Tyshchenko, O. Farrakhov
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引用次数: 0
CLIMATE CHANGES AND SITE DISPOSAL OF OBJECTS ON THE CHRONOBYL STATION SITE 气候变化和地点处置的对象在计时站现场
Pub Date : 2022-01-01 DOI: 10.32782/geotech2022.36.07
Yu. O. Olkhovyk
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引用次数: 0
PECULIARITIES OF THE STRATEGIC ECOLOGICAL ASSESSMENT OF THE TERRITORIES OF SETTLEMENT COMMUNITIES AS A MECHANISM FOR PROMOTING SUSTAINABLE DEVELOPMENT 作为促进可持续发展机制的定居点社区领土战略生态评估的特点
Pub Date : 2022-01-01 DOI: 10.32782/geotech2022.36.08
А.І. Reshetchenko, О.І. Shapovalov
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引用次数: 0
REGARDING THE USE OF BENTONITE CLAYS FROM THE CHERKASY DEPOSIT FOR SAFE RADIOACTIVE WASTE DISPOSAL IN NEAR-SURFACE LOW LEVEL WASTE STORAGE FACILTIES: RESEARCHES ON SORPTION PROPERTIES OF BENTONITES 利用切尔卡西矿床的膨润土在近地表低水平废物储存设施中安全处理放射性废物&膨润土吸附性能的研究
Pub Date : 2021-12-25 DOI: 10.15407/geotech2021.34.033
B. Shabalin, K. Yaroshenko, O. Marinich, I. Koliabina, N. Mitsiuk, S. Buhera
The article is devoted to the study of the barrier properties of bentonite clays from the Cherkasy deposit (Ukraine) as the most promising material for engineered barriers in near-surface disposal facilities for low-level radioactive waste. The work presents a description of the Cherkasy bentonite deposit, in particular, of the most promising II layer of the Dashukivka site, and the composition and properties of the natural and soda-modified (PBA20) bentonites which can be used for safe long-term storage and disposal of radioactive waste. The scanning electron microscope (SEM) images of the samples were made and the chemical and mineral composition of the samples was determined. Based on the obtained data, the Dashukivka bentonite was classified as Al-Fe-montmorillonit. The main rock-forming minerals of the bentonite are montmorillonite (75 ± 3 wt. %) and quartz (20 - 25 wt. %). Infrared spectra of the bentonites in the range of 4000 - 400 cm-1 are typical for dioctahedral Al-smectites and are almost identical both for the natural and modified samples. The derivatographic analysis (DTA) of the bentonite samples allows us to conclude that the modified bentonite PBA-20 has greater thermal stability than the natural bentonite. The total weight loss of the samples is about 10.3% and 17.8%, respectively. From the experimental study of 137Cs adsorption from a simulated ChEZ water solution (mineralization – 0.2 g/dm3), it was found that the equilibrium in the sorbent-solution system is established within 12 to 14 h, and the degree of adsorption on the modified bentonite PBA-20 reaches 93%. The degree of adsorption on the natural bentonite is 7 - 10% lower. Analysis of the partition coefficients (Kd) also indicates a higher efficiency of the Na-modified bentonite compared to the natural, and that ion exchange is the main mechanism of caesium adsorption. Increasing of the pH of the initial solution results only in a slight increase of the degree of adsorption. The degree of 137Cs adsorption on Na-modified bentonite is practically independent of the initial concentration of Ca2+ (from 16 to 160 mg/dm3) and Na+ (from 6 to 60 mg/dm3) in the solution. However, 137Cs adsorption on natural bentonite decreases with the increase in Na+ concentration. Thus, the bentonite clays from the Cherkasy deposit (Dashukivka site, II layer) having good barrier properties can be recommend as anti-migration engineered barriers for radioactive waste repositories, in particular, near-surface storage facilities I and II line of Vector complex
本文致力于研究Cherkasy矿床(乌克兰)膨润土粘土的屏障性能,该粘土是低放射性废物近地表处理设施中最有前途的工程屏障材料。该工作介绍了Cherkasy膨润土矿床,特别是Dashukivka场地最有前景的II层,以及可用于安全长期储存和处理放射性废物的天然和苏打改性(PBA20)膨润土的组成和性能。制作了样品的扫描电子显微镜(SEM)图像,并测定了样品的化学和矿物组成。根据所获得的数据,将大舒基夫卡膨润土归类为Al-Fe蒙脱石。膨润土的主要成岩矿物为蒙脱石(75±3wt%)和石英(20-25wt%)。膨润土在4000-400cm-1范围内的红外光谱是典型的二八面体铝蒙脱石,并且对于天然样品和改性样品几乎相同。通过对膨润土样品的差热分析(DTA),我们可以得出改性膨润土PBA-20比天然膨润土具有更高的热稳定性的结论。样品的总重量损失分别约为10.3%和17.8%。从模拟ChEZ水溶液(矿化度–0.2 g/dm3)中吸附137Cs的实验研究中发现,吸附剂溶液系统中的平衡在12至14小时内建立,改性膨润土PBA-20的吸附度达到93%。天然膨润土的吸附度降低了7-10%。分配系数(Kd)的分析还表明,与天然膨润土相比,钠改性膨润土的效率更高,离子交换是铯吸附的主要机制。初始溶液的pH值的增加仅导致吸附程度的轻微增加。137Cs在Na改性膨润土上的吸附程度实际上与溶液中Ca2+(从16到160mg/dm3)和Na+(从6到60mg/dm3)的初始浓度无关。天然膨润土对137Cs的吸附量随Na+浓度的增加而降低。因此,Cherkasy矿床(Dashukivka现场,II层)的膨润土粘土具有良好的屏障性能,可推荐作为放射性废物储存库的防迁移工程屏障,特别是Vector综合体的近地表储存设施I和II线
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引用次数: 0
PROSPECTS OF URANIUM MINERALIZATION OF THE SOUTH-WESTERN SLOPE OF THE UKRAINIAN SHIELD 乌克兰地盾西南斜坡铀矿化前景
Pub Date : 2021-12-25 DOI: 10.15407/geotech2021.34.082
M. Yaroshchuk, O. Vaylo, A. Ganevich
The geological position, composition and genesis of uranium mineralization of ore occurrences on the southwestern slope of the Ukrainian Shield are considered. In the Precambrian basement metamorphic rocks of the Dniester-Bug, Bug and ultrametamorphic rocks of the Golovanev, Pobuzh, Berdichev and Kirovograd complexes were established. On the southwestern slope of the Ukrainian Shield, 4 uranium occurrences and 4 radioactive anomalies have been discovered, studied and prospected. The uranium occurrences are localized along the regional unconformity surface of the Precambrian basement and platform cover. They are often confined to the nodes of the intersection of faults. The uranium occurrences are installed simultaneously both in the rocks of the basement and in the platform cover. The ore deposits form stockwork and vein segregations among the tectonized rocks of the Precambrian. In the rocks of the sedimentary cover they are discontinuous lenticular, subconcordant with the bedding of rocks. The uranium mineralization is vein-disseminated, represented by uraninite, pitchblende, coffinite, uranium black, casolite, etc. The uranium mineralization was caused by both endogenous and exogenous processes; several stages of uranium concentration have been established. The main source of uranium and associated elements was the low-temperature hydrothermal fluids of the “unconformity zone” faults of the Precambrian basement and sedimentary cover. A comparison is given and the similarity of the uranium mineralization of these occurrences with the rich uranium ores of the "zones of unconformity" of the Canadian and North Australian shields is given, which determines the significant prospects for uranium mineralization of the southwestern slope of the Ukrainian shield for the development of the uranium resource base of Ukraine.
考虑了乌克兰地盾西南斜坡矿点的地质位置、组成和铀矿化成因。在前寒武纪基底中,Dniester Bug、Bug的变质岩和Golovanev、Pobuzh、Berdichev和Kirovograd杂岩的超变质岩形成。在乌克兰地盾西南斜坡上,发现、研究和勘探了4个铀矿点和4个放射性异常。铀矿点位于前寒武纪基底和平台盖层的区域不整合面上。它们通常局限于断层交叉点的节点。铀矿点同时安装在基底岩石和平台盖层中。矿床在前寒武纪的构造岩石中形成网状和矿脉分离。在沉积盖层的岩石中,它们是不连续的透镜状,与岩石的层理亚一致。铀矿化呈脉状浸染状,以铀云母、沥青铀矿、钴云母、铀黑、硅铝石等为代表。铀矿化是由内生和外源过程共同引起的;铀浓缩的几个阶段已经确定。铀及其伴生元素的主要来源是前寒武纪基底和沉积盖层“不整合带”断裂的低温热液。比较了这些矿点的铀矿化与加拿大和北澳大利亚地盾“不整合带”的富铀矿的相似性,这决定了乌克兰地盾西南斜坡的铀矿化对乌克兰铀资源基地的开发具有重要前景。
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引用次数: 0
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