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Immobilized photocatalyst on stainless steel woven meshes assuring efficient light distribution in a solar reactor 固定化光催化剂上的不锈钢编织网,确保有效的光分配在太阳能反应器
Q2 Engineering Pub Date : 2014-06-03 DOI: 10.5194/DWES-7-41-2014
A. El‐Kalliny, Sara F. Ahmed, L. Rietveld, P. Appel
An immobilized TiO2 photocatalyst with a high specific surface area was prepared on stainless steel woven meshes in order to be used packed in layers for water purification. Immobilization of such a complex shape needs a special coating technique. For this purpose, dip coating and electrophoretic deposition (EPD) techniques were used. The EPD technique gave the TiO2 coating films a better homogeneity and adhesion, fewer cracks, and a higher qOH formation than the dip coating technique. The woven mesh structure packed in layers guaranteed an efficient light-penetration in water treatment reactor. A simple equation model was used to describe the distribution of light through the mesh layers in the presence of absorbing medium (e.g., colored water with humic acids). Maximum three or four coated meshes were enough to harvest the solar UV light from 300 nm to 400 nm with a high penetration efficiency. The separation distance between the mesh layers played an important role in the efficiency of solar light penetration through the coated mesh layers, especially in case of colored water contaminated with high concentrations of humic acid.
在不锈钢编织网上制备了一种具有高比表面积的固定化TiO2光催化剂,用于水的分层包装净化。如此复杂形状的固定需要一种特殊的涂层技术。为此,采用了浸涂和电泳沉积(EPD)技术。与浸镀相比,EPD技术使TiO2涂层具有更好的均匀性和附着力,更少的裂纹和更高的qOH生成率。层叠的编织网结构保证了水处理反应器的高效透光。一个简单的方程模型被用来描述光在吸收介质(例如,带腐植酸的有色水)存在的情况下通过网格层的分布。最多3或4个涂层网足以收获300 nm至400 nm的太阳紫外线,穿透效率高。网层之间的距离对太阳光线穿透涂层网层的效率起着重要的作用,特别是当有色水被高浓度腐植酸污染时。
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引用次数: 24
Water Expert : a conceptualized framework for development of a rule-based decision support system for distribution system decontamination 水专家:一个概念化框架,用于开发基于规则的分配系统净化决策支持系统
Q2 Engineering Pub Date : 2014-05-27 DOI: 10.5194/DWES-8-9-2015
J. Gutenson, A. Ernest, J. Fattic, L. Ormsbee, A. Oubeidillah, X. Zhang
Abstract. Significant drinking water contamination events pose a serious threat to public and environmental health. Water utilities often must make timely, critical decisions without evaluating all facets of the incident. The data needed to enact informed decisions are inevitably dispersant and disparate, originating from policy, science, and heuristic contributors. Water Expert is a functioning hybrid decision support system (DSS) and expert system framework that emphasizes the meshing of parallel data structures in order to expedite and optimize the decision pathway. Delivered as a thin-client application through the user's web browser, Water Expert's extensive knowledgebase is a product of inter-university collaboration that methodically pieced together system decontamination procedures. Decontamination procedures are investigated through consultation with subject matter experts, literature review, and prototyping with stakeholders. This paper discusses the development of Water Expert, analyzing the development process underlying the DSS and the system's existing architecture specifications. Water Expert constitutes the first system to employ a combination of deterministic and heuristic models which provide decontamination solutions for water distribution systems. Results indicate that the decision making process following a contamination event is a multi-disciplinary effort. This contortion of multiple inputs and objectives limit the ability of the decision maker to find optimum solutions without technological intervention.
摘要重大饮用水污染事件对公众健康和环境健康构成严重威胁。水务公司通常必须在没有对事件的各个方面进行评估的情况下做出及时、关键的决定。制定明智决策所需的数据不可避免地分散和分散,来自政策、科学和启发式贡献者。Water Expert是一个有效的混合决策支持系统(DSS)和专家系统框架,强调并行数据结构的网格化,以加快和优化决策路径。Water Expert通过用户的web浏览器作为瘦客户端应用程序交付,其广泛的知识库是大学间协作的产物,系统地将系统净化程序拼凑在一起。通过与主题专家协商、文献回顾和与利益相关者建立原型来调查净化程序。本文讨论了Water Expert的开发,分析了决策支持系统的开发过程和系统现有的体系结构规范。水专家构成了第一个采用确定性和启发式模型相结合的系统,为水分配系统提供去污染解决方案。结果表明,污染事件后的决策过程是一个多学科的努力。这种多种输入和目标的扭曲限制了决策者在没有技术干预的情况下找到最佳解决方案的能力。
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引用次数: 0
Drinking Water: Physics, Chemistry and Biology 饮用水:物理、化学和生物
Q2 Engineering Pub Date : 2014-01-01 DOI: 10.1007/978-3-319-04334-0
V. Goncharuk
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引用次数: 7
Assessment of calculation methods for calcium carbonate saturation in drinking water for DIN 38404-10 compliance 饮用水中碳酸钙饱和度计算方法的评估符合DIN 38404-10
Q2 Engineering Pub Date : 2013-11-18 DOI: 10.5194/DWES-6-115-2013
P. D. de Moel, A. van der Helm, M. van Rijn, J. C. van Dijk, W. G. J. van der Meer
The new German standard on the calculation of calcite saturation in drinking water, DIN 38404-10, 2012 (DIN), marks a change in drinking water standardization from using simplified equations applicable for nomographs and simple calculators to using extensive chemical modeling requiring computer programs. The standard outlines the chemical modeling and presents a dataset with 10 water samples for validating used computer programs. The DIN standard, as well as the Standard Methods 2330 (SM) and NEN 6533 (NEN) for calculation of calcium carbonate saturation in drinking water were translated into chemical databases for use in PHREEQC (USGS, 2013). This novel approach gave the possibility to compare the calculations as defined in the standards with calculations using widely used chemical databases provided with PHREEQC. From this research it is concluded that the computer program PHREEQC with the developed chemical database din38404-10_2012.dat complies with the DIN standard for calculating Saturation Index (SI) and Calcite Dissolution Capacity (Calcitlosekapazitat) or Calcium Carbonate Precipitation Potential (CCPP). This compliance is achieved by assuming equal values for molarity as used in DIN (obsolete) and molality as used in PHREEQC. From comparison with widely used chemical databases it is concluded that the use of molarity limits the use of DIN to a maximum temperature of 45 °C. For current practical applications in water treatment and drinking water applications, the PHREEQC database stimela.dat was developed within the Stimela platform of Delft University of Technology. This database is an extension of the chemical database phreeqc.dat and thus in compliance with SM. The database stimela.dat is also applicable for hot and boiling water, which is important in drinking water supply with regard to scaling of calcium carbonate in in-house drinking water practices. SM and NEN proved to be not accurate enough to comply with DIN, because of their simplifications. The differences in calculation results for DIN, SM and NEN illustrate the need for international unification of the standard for calcium carbonate saturation in drinking water.
关于饮用水中方解石饱和度计算的新德国标准DIN 38404- 10,2012 (DIN)标志着饮用水标准化的变化,从使用适用于nomographs和简单计算器的简化方程到使用需要计算机程序的广泛化学建模。该标准概述了化学建模,并提供了一个包含10个水样的数据集,用于验证使用过的计算机程序。DIN标准以及用于计算饮用水中碳酸钙饱和度的标准方法2330 (SM)和NEN 6533 (NEN)被翻译成PHREEQC中使用的化学数据库(USGS, 2013)。这种新颖的方法可以将标准中定义的计算与PHREEQC提供的广泛使用的化学数据库的计算进行比较。研究结果表明,PHREEQC计算机程序与开发的化学数据库din38404-10_2012.dat符合DIN计算饱和指数(SI)和方解石溶解容量(Calcitlosekapazitat)或碳酸钙沉淀电位(CCPP)的标准。通过假设DIN(已过时)中使用的摩尔浓度与PHREEQC中使用的摩尔浓度相等,可以实现这一一致性。通过与广泛使用的化学数据库的比较,得出结论,使用摩尔浓度限制了DIN的使用,最高温度为45°C。针对目前在水处理和饮用水应用中的实际应用,PHREEQC数据库Stimela .dat是在代尔夫特理工大学的Stimela平台上开发的。该数据库是化学数据库phreeqc.dat的扩展,因此符合SM。数据库stimela.dat也适用于热水和沸水,这在饮用水供应中很重要,因为在室内饮用水实践中碳酸钙结垢。SM和NEN被证明不够精确,不能符合DIN,因为它们简化了。DIN、SM和NEN计算结果的差异说明了饮用水中碳酸钙饱和度的国际统一标准的必要性。
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引用次数: 29
Non-residential water demand model validated with extensive measurements and surveys 非住宅用水需求模型经过广泛的测量和调查验证
Q2 Engineering Pub Date : 2013-10-31 DOI: 10.5194/DWES-6-99-2013
E. J. Pieterse-Quirijns, E. Blokker, E. van der Blom, J. Vreeburg
Existing Dutch guidelines for the design of the drinking water and hot water system of nonresidential buildings are based on outdated assumptions on peak water demand or on unfounded assumptions on hot water demand. They generally overestimate peak demand values required for the design of an efficient and reliable water system. Recently, a procedure was developed based on the end-use model SIMDEUM to derive design-demand-equations for peak demand values of both cold and hot water during various time steps for several types and sizes of non-residential buildings, viz. offices, hotels and nursing homes. In this paper, the design-demand-equations are validated with measurements of cold and hot water patterns on a per second base and with surveys. The good correlation between the simulated water demand patterns and the measured patterns indicates that the basis of the design-demand-equations, the SIMDEUM simulated standardised buildings, is solid. Surveys were held to investigate whether the construction of the standardised buildings based on the dominant variable corresponds with practice. Surveys show that it is difficult to find relationships to equip the standardised buildings with users and appliances. However, the validation proves that with a proper estimation of the number of users and appliances in only the dominant functional room of the standardised buildings, SIMDEUM renders a realistic cold and hot water diurnal demand pattern. Furthermore, the new design-demand-equations based on these standardised buildings give a better prediction of the measured peak values for cold water flow than the existing guidelines. Moreover, the new design-demand-equations can predict hot water use well. In this paper it is illustrated that the new design-demand-equations lead to reliable and improved designs of building installations and water heater capacity, resulting in more hygienic and economical installations.
荷兰现有的非住宅建筑饮用水和热水系统设计指南是基于对峰值用水需求的过时假设或对热水需求的毫无根据的假设。他们通常高估了设计高效可靠的供水系统所需的峰值需求值。最近,基于最终用途模型SIMDEUM开发了一种程序,以推导出几种类型和大小的非住宅建筑(即办公室,酒店和养老院)在不同时间步长的冷热水峰值需求值的设计需求方程。本文通过以每秒为单位的冷热水模式测量和调查验证了设计-需求方程。模拟需水模式与实测模式之间的良好相关性表明,SIMDEUM模拟标准化建筑的设计-需水方程的基础是坚实的。对基于主导变量的标准化建筑的建设是否符合实际进行了调查。调查显示,很难找到为标准化建筑配备用户和设备的关系。然而,验证证明,通过对标准化建筑的主要功能房间的用户数量和设备数量的适当估计,SIMDEUM呈现出现实的冷热水日需求模式。此外,基于这些标准化建筑的新设计-需求方程比现有的指导方针更好地预测了冷水流量的测量峰值。此外,新的设计需求方程可以很好地预测热水的使用情况。本文说明,新的设计需求方程使建筑装置和热水器容量的设计更加可靠和改进,从而使建筑装置更加卫生和经济。
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引用次数: 13
Online data processing for proactive UK water distribution network operation 在线数据处理主动英国供水网络运行
Q2 Engineering Pub Date : 2013-08-28 DOI: 10.5194/DWES-7-23-2014
J. Machell, S. Mounce, B. Farley, J. Boxall
Abstract. Operational benefits and efficiencies generated using prevalent water industry methods and techniques are becoming more difficult to achieve; as demonstrated by English and Welsh water companies' static position with regards the economic level of leakage. Water companies are often unaware of network incidents such as burst pipes or low pressure events until they are reported by customers; and therefore use reactive strategies to manage the effects of these events. It is apparent that new approaches need to be identified and applied to promote proactive network management if potential operational productivity and standards of service improvements are to be realised. This paper describes how measured flow and pressure data from instrumentation deployed in a UK water distribution network was automatically gathered, checked, analysed and presented using recently developed techniques to generate apposite information about network performance. The work demonstrated that these technologies can provide early warning, and hence additional time to that previously available, thereby creating opportunity to proactively manage a network; for example to minimise the negative impact on standards of customer service caused by unplanned events such as burst pipes. Each method, applied individually, demonstrated improvement on current industry processes. Combined application resulted in further improvements; including quicker and more localised burst main location. Future possibilities are explored, from which a vision of seamless integration between such technologies emerges to enable proactive management of distribution network events.
摘要使用普遍的水工业方法和技术产生的业务效益和效率越来越难以实现;正如英格兰和威尔士供水公司在泄漏经济水平方面的静态立场所证明的那样。自来水公司往往不知道管网事故,如管道破裂或低压事件,直到客户报告;因此,使用反应策略来管理这些事件的影响。显然,如果要实现潜在的业务生产力和服务标准的改进,就需要确定和应用新的方法来促进主动的网络管理。本文描述了如何使用最新开发的技术自动收集、检查、分析和呈现部署在英国配水网络的仪器测量的流量和压力数据,以生成有关网络性能的适当信息。工作表明,这些技术可以提供早期预警,从而在以前的基础上增加时间,从而创造主动管理网络的机会;例如,尽量减少因意外事件(如管道爆裂)对客户服务标准的负面影响。每种方法,单独应用,都证明了对当前工业流程的改进。联合应用进一步改善;包括更快和更局部爆发的主要位置。未来的可能性被探索,从这些技术之间的无缝集成的愿景出现,使分销网络事件的主动管理。
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引用次数: 5
Removal of paraquat pesticide with Fenton reaction in a pilot scale water system Fenton反应在中试水系统中去除百草枯农药
Q2 Engineering Pub Date : 2013-08-22 DOI: 10.5194/DWES-7-11-2014
Cátia Oliveira, K. Gruskevica, T. Juhna, K. Tihomirova, A. Alves, L. Madeira
Abstract. Advanced oxidation processes, such as the Fenton's reagent, are powerful methods for decontamination of different environments from recalcitrant organics. In this work, the degradation of paraquat (PQ) pesticide was assessed (employing the commercial product gramoxone) directly inside the pipes of a pilot scale loop system; the effect of corroded cast iron pipe and loose deposits for catalysing the process was also evaluated. Results showed that complete degradation of paraquat ([PQ]0= 3.9 × 10−4 M, T = 20–30 °C, pH0 = 3, [H2O2]0 = 1.5 × 10−2 M and [Fe (II)] = 5.0 × 10−4 M,) was achieved within 8 h, either in lab scale or in the pilot loop. Complete PQ degradation was obtained at pH 3 whereas only 30% of PQ was degraded at pH 5 during 24 h. The installation of old cast iron segments with length from 0.5 to 14 m into PVC pipe loop system had a significant positive effect on degradation rate of PQ, even without addition of iron salt; the longer the iron pipes section, the faster was the pesticide degradation. Addition of loose deposits (mostly corrosion products composed of goethite, magnetite and a hydrated phase of FeO) also catalysed the Fenton reaction due to presence of iron in the deposits. Moreover, gradual addition of hydrogen peroxide improved gramoxone degradation and mineralization. This study showed for the first time that is possible to achieve complete degradation of pesticides in situ pipe water system and that deposits and corroded pipes catalyse oxidation of pesticides.
摘要高级氧化工艺,如芬顿试剂,是去除不同环境中顽固有机物污染的有力方法。在这项工作中,评估了百草枯(PQ)农药的降解(采用商业产品格拉莫酮)直接在中试规模循环系统的管道内;还评价了锈蚀铸铁管和疏松沉积物对该工艺的催化作用。结果表明,在实验室规模或中试循环中,百草枯([PQ]0= 3.9 × 10−4 M, T = 20-30°C, pH0 = 3, [H2O2]0 = 1.5 × 10−2 M, [Fe (II)] = 5.0 × 10−4 M)在8 h内完全降解。pH值为3时,PQ降解完全,而pH值为5时,24 h内PQ的降解率仅为30%。在PVC管环系统中安装长度为0.5 ~ 14 m的旧铸铁段,即使不添加铁盐,对PQ的降解率也有显著的积极影响;铁管段越长,农药降解速度越快。由于沉积物中存在铁,松散沉积物(主要由针铁矿、磁铁矿和FeO水合相组成的腐蚀产物)的加入也催化了芬顿反应。此外,过氧化氢的逐渐加入改善了格莫酮的降解和矿化。该研究首次证明了农药在原位管道水系统中完全降解是可能的,并且沉积物和腐蚀的管道催化了农药的氧化。
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引用次数: 14
Removal and transformation of pharmaceuticals in wastewater treatment plants and constructed wetlands 污水处理厂和人工湿地中药物的去除和转化
Q2 Engineering Pub Date : 2013-08-12 DOI: 10.5194/DWES-6-89-2013
Eunkyung Lee, S. Lee, J. Park, Yunseul Kim, Jung-Min Cho
Abstract. Since trace organic compounds such as pharmaceuticals in surface water have been a relevant threat to drinking water supplies, in this study removal of pharmaceuticals and transformation of pharmaceuticals into metabolites were investigated in the main source of micropollutants such as WWTPs and engineered constructed wetlands. Pharmaceuticals were effectively removed by different WWTP processes and wetlands. Pharmaceutical metabolites with relatively low log D value were resulted in the low removal efficiencies compared to parent compounds with relatively high log D value, indicating the stability of metabolites. And the constructed wetlands fed with wastewater effluent were encouraged to prevent direct release of micropollutants into surface waters. Among various pharmaceuticals, different transformation pattern of ibuprofen was observed with significant formation of 1-hydroxy-ibuprofen during biological treatment in WWTP, indicating preferential biotransformation of ibuprofen. Lastly, transformation of pharmaceuticals depending on their structural position was investigated in terms of electron density, and, the electron rich C1 = C2 bond of carbamazepine was revealed as an initial transformation position.
摘要由于地表水中的微量有机化合物(如药物)已成为饮用水供应的相关威胁,在本研究中,研究了药物的去除和药物转化为代谢物的微污染物的主要来源,如污水处理厂和工程人工湿地。不同的污水处理工艺和湿地都能有效地去除药物。与log D值较高的母体化合物相比,log D值较低的药物代谢物的去除率较低,说明代谢物具有稳定性。鼓励以废水为饵料的人工湿地防止微污染物直接释放到地表水中。在不同的药物中,布洛芬的转化模式不同,在污水处理厂生物处理过程中,1-羟基布洛芬的形成显著,表明布洛芬的生物转化优先。最后,从电子密度的角度考察了药物在结构位置上的转化,发现卡马西平的富电子C1 = C2键是初始转化位置。
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引用次数: 24
Development of water use scenarios as a tool for adaptation to climate change 制定用水情景,作为适应气候变化的工具
Q2 Engineering Pub Date : 2013-06-21 DOI: 10.5194/DWES-6-61-2013
R. Jacinto, M. J. Cruz, F. Santos
Abstract. The project ADAPTACLIMA, promoted by EPAL, the largest Portuguese Water Supply Utility, aims to provide the company with an adaptation strategy in the medium and long term to reduce the vulnerability of its activities to climate change. We used the four scenarios (A1, A2, B1, B2) adopted in the Special Report Emissions Scenarios (SRES) of the IPCC (Intergovernmental Panel on Climate Change) to produce local scenarios of water use. Available population SRES for Portugal were downscaled to the study area using a linear approach. Local land use scenarios were produced using the following steps: (1) characterization of the present land use for each municipality of the study area using Corine Land Cover and adaptation of the CLC classes to those used in the SRES; (2) identification of recent tendencies in land use change for the study area; (3) identification of SRES tendencies for land use change in Europe; and (4) production of local scenarios of land use. Water use scenarios were derived considering both population and land use scenarios as well as scenarios of change in other parameters (technological developments, increases in efficiency, climate changes, or political and behavioural changes). The A2 scenario forecasts an increase in population (+16%) in the study area while the other scenarios show a reduction in the resident population (−6 to 8%). All scenarios, but especially A1, show a reduction in agricultural area and an increase in urban area. Regardless of the scenario, water use will progressively be reduced until 2100. These reductions are mainly due to increased water use efficiency and the reduction of irrigated land. The results accord with several projects modelling water use at regional and global level.
摘要ADAPTACLIMA项目由葡萄牙最大的供水公司EPAL推动,旨在为该公司提供中长期适应战略,以减少其活动对气候变化的脆弱性。我们使用IPCC(政府间气候变化专门委员会)特别报告排放情景(SRES)中采用的四个情景(A1, A2, B1, B2)来生成当地的用水情景。使用线性方法将葡萄牙的可用人口SRES缩小到研究区域。通过以下步骤生成当地土地利用情景:(1)利用Corine land Cover对研究区每个城市的当前土地利用进行表征,并将CLC分类与SRES中使用的分类进行适应;(2)识别研究区土地利用变化的近期趋势;(3)欧洲土地利用变化的SRES趋势识别;(4)地方土地利用情景的生成。水资源利用情景是在考虑人口和土地利用情景以及其他参数变化情景(技术发展、效率提高、气候变化或政治和行为变化)的情况下得出的。A2情景预测研究区域的人口将增加(+16%),而其他情景则显示常住人口将减少(- 6%至8%)。所有情景,尤其是A1情景,都显示农业面积减少,城市面积增加。无论情况如何,用水量将逐步减少,直至2100年。这些减少主要是由于水利用效率的提高和灌溉土地的减少。结果与若干区域和全球水资源利用模拟项目一致。
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引用次数: 10
Technical Note: Wet validation of optical tomography for drinking water discolouration studies 技术说明:饮用水变色研究的光学断层扫描湿法验证
Q2 Engineering Pub Date : 2013-06-13 DOI: 10.5194/DWES-6-55-2013
R. Floris, P. Thienen, H. Beverloo
Abstract. This paper presents a set of validation experiments for the reconstruction of a cross-sectional particle concentration field in a transparent pipe filled with a fluid using optical tomography.
摘要本文提出了一组验证实验,用于用光学层析成像重建充满流体的透明管道中的横截面粒子浓度场。
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引用次数: 0
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Drinking Water Engineering and Science
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