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Hydrocarbon generation potential, palynofacies examination and 1D basin modeling of the Middle Jurassic–Lowermost Cretaceous intervals, Mesopotamian Foredeep Basin, Iraq 伊拉克美索不达米亚前深盆地中侏罗世—下白垩世段生烃潜力、孢相研究及一维盆地模拟
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-22 DOI: 10.1016/j.sesci.2026.100288
Abbas F. Gharib , Iman M. Anwer , Mohammed Y. Najmuldeen , Ali Saaduldeen Abbas
This study evaluates hydrocarbon generation, palynofacies, and burial-thermal evolution of Middle Jurassic-Lowermost Cretaceous source rocks in the Ajeel Field, located in the Mesopotamian Foredeep Basin of Iraq. Through Rock-Eval pyrolysis, Total organic carbon (TOC) analysis, and palynofacies, a comprehensive investigation of 109 core and cutting samples in wells 8 and 12 was supported by one-dimensional (1D) basin modeling. The geochemical data show a TOC maximum of 23.0 wt.%, with reported mean concentrations of 6.22 wt.% in the Sargelu Formation and 10.09 wt.% in the Naokelekan Formation. The Chia Gara Formation bears a broad range of TOC values, as shown by the heterogeneous depositional environment. Hydrogen Index (HI) values reach 457 mg HC/g TOC, indicating dominance of oil-prone Type II kerogen, particularly in the Naokelekan and Chia Gara formations, and with minor Type II/III kerogen content in the Sargelu Formation interval. The calculated Tmax (428–448 °C) plus the estimated vitrinite reflectance (% Ro: 0.53–0.85 %) can define the maturity range that is characterized by early and peak oil window maturities. Palynofacies data confirm the deposition in suboxic–anoxic environments on the marine shelf, and amorphous organic matter (AOM) varies widely between 1 and 98 %. This has been confirmed as the Bajocian-Berriasian age and marine provenance as demonstrated by the presence of diagnostic palynomorphs. Basin modeling shows that hydrocarbons originated in the Oligocene (∼27 Ma) and were expelled during the Miocene (21-15 Ma). This is also supported by the higher transformation ratio (%TR) values, which reached up to 83 % for Sargelu, up to 70 % for Naokelekan Formation, and up to 50 % for the Chia Gara Formation. These findings confirm the identified formations as the main oil-producing horizons in the basin and emphasize their significance as potential oil exploration activities in northern Iraq.
本研究评价了伊拉克美索不达米亚前深盆地Ajeel油田中侏罗统—下白垩统烃源岩的生烃、孢相和埋藏—热演化。通过岩石热解、总有机碳(TOC)分析和孢粉相分析,对8井和12井109个岩心和岩屑样品进行了全面调查,并建立了一维盆地模型。地球化学数据显示TOC最高为23.0 wt.%,其中Sargelu组TOC平均浓度为6.22 wt.%, Naokelekan组TOC平均浓度为10.09 wt.%。甲加拉组TOC值的变化范围较广,这体现在其非均质沉积环境上。氢指数(HI)达到457 mg HC/g TOC,表明在Naokelekan组和Chia Gara组以易油型干酪根为主,而在Sargelu组段ⅱ/ⅲ型干酪根含量较少。计算得到的Tmax(428 ~ 448℃)和镜质组反射率(% Ro: 0.53 ~ 0.85%)可以确定以早、高峰油窗成熟度为特征的成熟度范围。孢粉相资料证实了陆架亚氧缺氧环境下的沉积,无定形有机质(AOM)在1% ~ 98%之间变化很大。诊断性畸形的存在证实了这是巴约西亚-贝里亚时代和海洋来源。盆地模拟表明,油气起源于渐新世(~ 27 Ma),并在中新世(21 ~ 15 Ma)排出。较高的转化比(%TR)值也支持了这一点,Sargelu组高达83%,Naokelekan组高达70%,Chia Gara组高达50%。这些发现证实了已识别的地层是该盆地的主要产油层,并强调了它们作为伊拉克北部潜在石油勘探活动的重要性。
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引用次数: 0
Hot topics in deep-sea sciences 深海科学热点
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-09 DOI: 10.1016/j.sesci.2025.100286
Weidong Sun, Hongli Zhu
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引用次数: 0
Domain adaptation of large language models for geotechnical applications 岩土工程应用中大型语言模型的领域自适应
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-08 DOI: 10.1016/j.sesci.2025.100285
Lei Fan , Fangxue Liu , Cheng Chen
The rapid advancement of large language models (LLMs) is transforming opportunities in geotechnical engineering, where workflows rely on complex, text-rich data. While general-purpose LLMs demonstrate strong reasoning capabilities, their effectiveness in geotechnical applications is constrained by limited exposure to specialized terminology and domain logic. Thus, domain adaptation, tailoring general LLMs for geotechnical use, has become essential. This paper presents the first review of LLM adaptation and application in geotechnical contexts. It critically examines four key adaptation strategies, including prompt engineering, retrieval-augmented generation, domain-adaptive pretraining, and fine-tuning, and evaluates their comparative benefits, limitations, and implementation trends. This review synthesizes current applications spanning geological interpretation, subsurface characterization, design analysis, numerical modeling, risk assessment, and geotechnical education. Findings show that domain-adapted LLMs substantially improve reasoning accuracy, automation, and interpretability, yet remain limited by data scarcity, validation challenges, and explainability concerns. Future research directions are also suggested. This review establishes a critical foundation for developing geotechnically literate LLMs and guides researchers and practitioners in advancing the digital transformation of geotechnical engineering.
大型语言模型(llm)的快速发展正在改变岩土工程领域的机遇,在这些领域,工作流程依赖于复杂的、文本丰富的数据。虽然通用法学硕士展示了强大的推理能力,但它们在岩土工程应用中的有效性受到专业术语和领域逻辑的限制。因此,领域适应,为岩土工程用途定制一般法学硕士,已经变得必不可少。本文首先介绍了LLM在岩土工程领域的适应和应用。它批判性地考察了四种关键的适应策略,包括快速工程、检索增强生成、领域自适应预训练和微调,并评估了它们的相对优势、局限性和实施趋势。这篇综述综合了目前的应用,包括地质解释、地下表征、设计分析、数值模拟、风险评估和岩土工程教育。研究结果表明,适应领域的llm大大提高了推理的准确性、自动化和可解释性,但仍然受到数据稀缺、验证挑战和可解释性问题的限制。并提出了今后的研究方向。这篇综述为培养具有岩土技术素养的法学硕士奠定了重要基础,并指导研究人员和从业者推进岩土工程的数字化转型。
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引用次数: 0
Metallogenic potential and prospecting of orogenic gold deposits in the Shuihouling area of the Dabie Orogenic Belt: A geochemical evidence from stream sediment anomalies 大别造山带水尾岭地区造山带金矿成矿潜力与找矿——来自水系沉积物异常的地球化学证据
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-06 DOI: 10.1016/j.sesci.2025.100278
Xiandong Luo , Lei Chen , Jinlai Tang , Xiaoyong Yang
The Shuihouling ductile shear zone, located in the core of the Dabie Orogenic Belt spanning Anhui and Hubei provinces, is a key structural unit with notable mineral potential. Situated within the Wudang-Tongbai-Dabie Mo-REE-Au-Ag-Pb-Zn polymetallic belt, it shows promising prospecting potential, particularly for gold exploration. Our 1:50,000 stream sediment survey identified three major composite anomalies in the Shuihouling area, each with distinct elemental concentration centers and strong anomaly correlations. After verification, all three were classified as mineral-induced B2 anomalies: The HS-01 anomaly, controlled by a fault zone, is linked to gold-polymetallic mineralization; the HS-02 anomaly, controlled by the ductile shear zone, is associated with copper-molybdenum polymetallic mineralization; and the HS-03 anomaly, in S-type granitic gneiss, shows copper-gold mineralization with significant concentrations of copper (19.41 %) and gold (1.41 g/t), indicating strong deep mineralization potential. The HS-03 anomaly also suggests a combined effect of polymetallic and molybdenum mineralization bodies. The discovery of these gold and copper anomalies highlights significant potential for ductile shear zone-type gold deposits in the Shuihouling area, providing crucial insights for future gold exploration and mineralization studies in the Dabie Orogenic Belt. These geochemical anomalies serve as important markers for guiding future exploration efforts, and their significance for understanding mineralization mechanisms in this region cannot be overstated.
水后岭韧性剪切带位于皖鄂大别造山带的核心,是一个重要的构造单元,具有显著的成矿潜力。该矿床位于武当-桐柏-大别钼-稀土-金-银-铅锌多金属带内,具有很好的找矿潜力,尤其是找金潜力。1:5万水系沉积物调查结果显示,水后岭地区有3个主要的复合异常,每个异常具有不同的元素浓度中心和较强的异常相关性。经验证,3个异常均为矿物成因B2异常:HS-01异常受断裂带控制,与金多金属成矿作用有关;HS-02异常受韧性剪切带控制,与铜钼多金属成矿作用有关;HS-03异常位于s型花岗质片麻岩中,铜和金的富集程度显著(分别为19.41%和1.41 g/t),深部成矿潜力强。HS-03异常还提示多金属成矿体和钼矿化体的联合作用。这些金、铜异常的发现,凸显了水后岭地区韧性剪切带型金矿的巨大潜力,为今后大别造山带的金矿找矿和成矿研究提供了重要的参考。这些地球化学异常是指导今后勘探工作的重要标志,对认识该区成矿机制具有重要意义。
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引用次数: 0
Spatio-temporal distribution of carbon in the Bohai Sea sediments under high human perturbations 人为扰动下渤海沉积物碳的时空分布
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.sesci.2025.100274
Yuchen Li , Chao Tang , Mengxuan Yang , Xiaowen Liu , Quanchao Cui , Die Li , Xiaole Sun
The Bohai Sea is one of marginal seas in the world, which suffers from strong human perturbations. This study collected sediment cores from four stations across the Yellow River estuary to the central Bohai Sea. The profiles of sediment organic and inorganic carbon contents as well as their δ13C values combined with porewater geochemical parameters (dissolved inorganic carbon (DIC), Fe2+, SO42−, NH4+) were analyzed to explore the spatio-temporal distribution of carbon and the controlling processes. The results show that the total organic carbon (TOC) contents are from 0.3 to 1.4 % and the contribution of terrestrial carbon is highest in the Yellow River estuary ranging from 54.11 to 95.09 %, with an average of 71.34 %, while it is lower in central Bohai Sea varying from 39.75 to 78.83 %, with an average of 50.60 %. The total inorganic carbon (TIC) contents in the central Bohai Sea are from 0.33 to 0.63 %, which is much lower than that in the Yellow River estuary with a range of 1.26–1.96 %, suggesting the large influence of riverine inputs. Variations of porewater geochemical parameters in the top meter sediments reflect both iron oxide reduction dominated early diagenetic processes and ongoing regulations on the Yellow River in the past decades, including the re-direction of the Yellow River mouth and the sediment-water regulation scheme. We also estimate a DIC efflux from the Bohai Sediments, 0.16 Tg C/yr, which is up to 10 % of the DIC inputs of the Yellow River. This implies an important role of the sediments in maintaining alkalinity and ocean chemistry in the Bohai Sea.
渤海是世界边缘海之一,受到强烈的人为扰动。本研究收集了黄河口至渤海中部4个站点的沉积物岩心。结合孔隙水地球化学参数(溶解无机碳(DIC)、Fe2+、SO42−、NH4+),分析沉积物有机、无机碳含量及其δ13C值剖面,探讨碳的时空分布及其控制过程。结果表明:总有机碳(TOC)含量在0.3 ~ 1.4%之间,其中陆源碳的贡献在黄河口最大,为54.11% ~ 95.09%,平均为71.34%;在渤海中部较低,为39.75% ~ 78.83%,平均为50.60%。渤海中部的总无机碳(TIC)含量为0.33 ~ 0.63%,远低于黄河口的1.26 ~ 1.96%,表明河流输入的影响较大。表层沉积物孔隙水地球化学参数的变化既反映了以氧化铁还原为主的早期成岩过程,也反映了近几十年来黄河河口改向和泥沙-水调节方案等对黄河的持续调节作用。渤海沉积物的DIC输出量为0.16 Tg C/yr,相当于黄河DIC输入量的10%。这暗示了渤海沉积物在维持碱度和海洋化学方面的重要作用。
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引用次数: 0
Petrographic study of lithic fragments in Chang'e-6 surface regolith “嫦娥六号”地表碎屑岩相学研究
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.sesci.2025.100275
Shen Ji , Chen Deliang , Zuo Zhiwei , Zhang Yingnan , Qin Liping
The Chang'e-6 (CE6) mission has successfully returned samples in the South Pole–Aitken (SPA) basin from the lunar farside. A series of recent works have revealed that there were different types of clasts from the CE6 regolith, including ∼2.8 Ga low-Ti basalts, ∼2.9 Ga very low-Ti basalts, ∼4.2 Ga high-Al basalts, ∼4.25 Ga noritic anorthosites and anorthositic norites. In this study, we have investigated a series of clasts of different weights, and obtained at least four types of igneous rocks, e.g., low-Ti basalts, very low-Ti basalts, KREEP-like clasts, as well as noritic anorthositic clasts, according to their petrological and chemistry compositional features. These clasts might be sourced from diverse lunar mantle sources or different processes. The discovery of these different types of clasts provides a great opportunity to investigate the structure and magma evolution of the lunar farside region.
嫦娥六号(CE6)任务成功地从月球背面的南极-艾特肯盆地(SPA)带回了样本。最近的一系列研究表明,CE6风化层中存在不同类型的碎屑,包括~ 2.8 Ga低钛玄武岩、~ 2.9 Ga极低钛玄武岩、~ 4.2 Ga高铝玄武岩、~ 4.25 Ga北长质斜长岩和斜长花岗岩。在本研究中,我们研究了一系列不同重量的岩屑,根据其岩石学和化学成分特征,获得了低钛玄武岩、极低钛玄武岩、kreep类岩屑和北长斜长岩屑等至少四种类型的火成岩。这些碎屑可能来自不同的月幔源或不同的过程。这些不同类型的碎屑的发现为研究月球背面地区的结构和岩浆演化提供了一个很好的机会。
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引用次数: 0
A potential 4N8-Grade raw material for high-purity quartz from quartzite ore in the Hengshan region, central-southern China: A geochemical-mineralogical study and purification 衡山地区石英岩矿石中潜在的4n8级高纯石英原料:地球化学矿物学研究与提纯
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.sesci.2025.100276
Yanheng Huang , Liting Sun , Yun Du , Jianzhong Liu , Xiaoyong Yang
This study evaluates the high-purity quartz potential of the Jiulongquan quartzite (sample JLQ-D2) from the eastern Nanyue pluton in the Hengshan area, China. This ore is yellowish-brown with low transparency and exhibits a relatively uniform grain size of less than 2 mm. A series of purification processes, including calcination, crushing, screening, ultrasonic desliming, gravity separation, magnetic separation, flotation, and high-temperature acid leaching, were applied to produce a refined quartz concentrate. The microstructure, fluid inclusion characteristics, and chemical composition of both the raw ore and the purified concentrate were analyzed using optical microscopy, scanning electron microscopy (SEM), X-ray fluorescence (XRF), laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), and ICP-MS. Additionally, the formation environment of the high-purity quartz (HPQ) source rock was discussed. Petrographic examination reveals that quartz is the dominant mineral, exhibiting low idiomorphism. In the post-flotation concentrate, fluid inclusions were predominantly two-phase (liquid–vapor), with rare pure liquid inclusions, and were distributed in bands, planes, and clusters. After purification, most quartz grains were free of inclusions, showing a significant reduction in inclusion content. Chemical analysis indicated that the main impurity elements in the raw ore were Al, K, Fe, and Na, with total impurities exceeding 100 mg·g−1. Aluminum was the most abundant impurity, at approximately 14.7 mg·g−1. After purification, the total impurity content of the concentrate was reduced to about 17.14 ppm of very high grade of purity of quartz sand, with specific concentrations of Al (10.1 ppm), Ca (0.05 ppm), Fe (0.95 ppm), K (0.57 ppm), Na (2.47 ppm), and Li (0.83 ppm). The SiO2 purity reached a 4N8 level of 99.998 %. The significance of this study lies in its demonstration that the quartzites are a promising source of high-purity quartz, with substantial potential for large-scale extraction and processing. Additionally, it underscores the importance of the local geology and metamorphic conditions that contributed to the formation of these high-purity quartz deposits.
本文对横山地区南岳岩体东部九龙泉石英岩(JLQ-D2)的高纯石英潜力进行了评价。该矿石呈黄褐色,透明度低,粒度相对均匀,小于2mm。采用煅烧、破碎、筛分、超声脱泥、重选、磁选、浮选、高温酸浸等一系列提纯工艺生产石英精矿。采用光学显微镜、扫描电镜(SEM)、x射线荧光(XRF)、激光烧蚀-电感耦合等离子体质谱(LA-ICP-MS)和ICP-MS对原矿石和纯化精矿的微观结构、流体包裹体特征和化学成分进行了分析。并对高纯石英(HPQ)烃源岩的形成环境进行了探讨。岩石学检查表明,石英为主要矿物,自构性较低。浮选后精矿中流体包裹体以两相(液-气)为主,纯流体包裹体较少,呈带状、平面和簇状分布。提纯后,大部分石英颗粒不含包裹体,包裹体含量明显降低。化学分析表明,原矿中主要杂质元素为Al、K、Fe和Na,总杂质超过100 mg·g−1。铝是最丰富的杂质,含量约为14.7 mg·g−1。提纯后,精矿总杂质含量降至17.14 ppm左右,为纯度极高的石英砂,具体浓度为Al (10.1 ppm)、Ca (0.05 ppm)、Fe (0.95 ppm)、K (0.57 ppm)、Na (2.47 ppm)和Li (0.83 ppm)。SiO2纯度达到99.998%的4N8级。本研究的意义在于证明了石英岩是高纯度石英的重要来源,具有大规模提取和加工的巨大潜力。此外,它还强调了当地地质和变质条件对这些高纯度石英矿床形成的重要性。
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引用次数: 0
Evolution of petroleum systems and hydrocarbon migration in the Dahomey Basin: Insights from basin modeling, machine learning and geochemical analysis 达荷美盆地油气系统演化与油气运移:来自盆地建模、机器学习和地球化学分析的见解
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.sesci.2025.100273
G.O. Aigbadon , B. Overare , O.C. Akakuru , A.I. Obasi , A. Ocheli , E.O. Akudo , S.O. Onyekuru , E.O. Avwenagha , A.N. Odoma , J.B. Ahmed II , A.O. Usman , A. Ogbamikhumi , N.S. Igbinigie , G.E. Maju-Oyovwikowhe , A.U. Okoro , E.O. Akpunonu , S.D. Christopher , D.J. Koffa , M. Baba Aminu , J.O. Odia-Oseghale
An integrated geochemical, machine learning (ML) and 3-D basin modeling investigation was carried-out on the petroleum system evolution of the frontier Dahomey Basin, Nigeria, West Africa. The poor understanding of the basin's petroleum system and its complex tectono-stratigraphic evolution has hindered effective exploration of the hydrocarbons and the evaluation of the resources within the basin. This study aims to provide a detailed evaluation of the basin's hydrocarbon potential by integration geochemical techniques, ML algorithms, and 3-D basin modeling. A total of 237 source rock samples from 18 wells within a 450 km onshore-offshore transect across Cretaceous to Paleogene Formations were analyzed by using compound-specific isotope analysis (CSIA), quantitative biomarker methods, and ML based maturation modeling. The source rocks data revealed that the Maastrichtian-Paleocene Araromi Formation have a mean Total organic carbon (TOC) of 4.12 wt% and a hydrogen index (HI) of 245–675 mg HC/g, and the Paleocene Ewekoro Formation has a mean TOC of 2.31 wt% and HI of 45–634 mg HC/g as prime sources of petroleum in the basin. The CSIA values of (δ13C −25.2 to −28.1 %) and the biomarkers distribution suggest Type II marine organic matter deposited in an anoxic-suboxic conditions. Three hydrocarbon kitchens with the highest generation occurring in Oligocene-Miocene thermal peaks, which were preferentially migrating along the Paleocene unconformities and the Cretaceous fault networks. The diachronous thermal maturation modeling presents a peak oil window of 20-15 Ma eastern kitchens and 15-8 Ma western kitchens, respectively. The total oil volume of 2.1–4.7 billion barrels of oil equivalent (P50: 3.2 BBOE) with 60 % confidence intervals is concentrated in three large kitchen-fairway systems. The Eastern Kitchen (1.4 BBOE) is the most prospective due to source rock maturity (VRo 0.75–0.95 %) and effective migration in the networks of Paleocene faults. The contribution of Central and Western Kitchens is 1.1 and 0.7 BBOE, respectively. The ML algorithm has successfully predicted the quality of source rock with 89 % validation accuracy and mapping of resources basin-wide in spite of sparse well control which remains a persistent challenge of frontier exploration. The integration of ML, high-resolution geochemistry and 3-D modelling has overcome challenges of data scarcity constraints, define the petroleum prospectivity of the Dahomey Basin, and provides a conceptual framework to assess unexploited passive margins in other parts of the world.
对西非尼日利亚Dahomey盆地前缘油气系统演化进行了地球化学、机器学习和三维盆地建模综合研究。对盆地含油气系统及其复杂的构造地层演化认识不清,阻碍了盆地内油气资源的有效勘探和评价。该研究旨在通过综合地球化学技术、ML算法和三维盆地建模,对盆地的油气潜力进行详细评估。通过化合物特异性同位素分析(CSIA)、定量生物标志物方法和基于ML的成熟度建模,研究人员分析了从白垩纪到古近纪450公里陆地-海上样带内18口井的237个烃源岩样本。烃源岩资料显示,马斯垂赫特—古新统Araromi组平均总有机碳(TOC)为4.12 wt%,氢指数(HI)为245 ~ 675 mg HC/g;古新统Ewekoro组平均总有机碳(TOC)为2.31 wt%,氢指数(HI)为45 ~ 634 mg HC/g。CSIA值(δ13C−25.2 ~−28.1%)和生物标志物分布表明II型海相有机质沉积于缺氧-亚氧条件下。3个生成量最高的烃灶产于渐新世—中新世热峰,主要沿古新世不整合面和白垩系断裂网络运移。历时热成熟模拟分别呈现出20 ~ 15 Ma东厨房和15 ~ 8 Ma西厨房的峰值油窗。总油量为21 - 47亿桶油当量(P50: 32 BBOE),置信区间为60%,集中在三个大型厨房-航道系统中。由于烃源岩成熟度(VRo 0.75 ~ 0.95%)和古新世断裂网络的有效运移,东厨区(1.4 BBOE)最具勘探前景。中西区厨房的贡献分别为1.1和0.7 BBOE。ML算法以89%的验证精度成功预测了烃源岩质量,并在稀疏井控的情况下实现了全盆地范围的资源映射,这是前沿勘探的一个长期挑战。ML、高分辨率地球化学和3-D建模的整合克服了数据稀缺限制的挑战,定义了Dahomey盆地的石油远景,并为评估世界其他地区未开发的被动边缘提供了一个概念框架。
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引用次数: 0
Does amphibole-biotite transformation facilitate the formation of apatite in a magma mixing scenario? 在岩浆混合的情况下,角闪岩-黑云母转化是否促进了磷灰石的形成?
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.sesci.2025.100277
Bibhuti Gogoi, Tribujjal Prakash
The work focuses on the underlying mechanisms of apatite crystallization in a magma mixing scenario. The study is based primarily on the porphyritic andesite of the Ghansura Rhyolite Dome (GRD) and the diorites of the Borjuri Diorite Pluton (BDP). The GRD represents a fossilized subvolcanic magma chamber exposed in Ghansura village near Bathani, eastern India. Interaction between mafic and felsic magmas is distinctly evident in the GRD along with three categories of rock types (mafic, felsic, and hybrid). The BDP is a diorite pluton exposed within the Shillong Basin of the Mikir Massif, Northeast India. Inferences based on petrographical, mineralogical, and textural evidence highlight the physico-chemical conditions associated with magma mixing that led to apatite formation in the studied rocks. Magma mixing facilitates the increase in SiO2 content in the mafic domain. In addition to the rise of silica, diffusion of K2O takes place from the felsic to the mafic melt during magma mixing. The diffusion of K2O triggers the breakdown of Ca-rich phase to Ca-poor phase (amphibole to biotite), which increases the overall CaO activity in the mixed system. The increase in CaO activity coupled with the increase in SiO2 concentration due to magma mixing thus fulfills the necessary conditions for apatite saturation. A sequence of crystallization of minerals from clinopyroxene to apatite is established in accordance with calculated and predicted crystallization temperatures. Apatite crystallization in the mixed rocks of our study area is estimated to occur during amphibole-biotite transformation, and the temperature is likely to range approximately between 550 °C and 650 °C. Although the abundance of apatite in mafic magmatic enclaves and mixed rocks is widely discussed, the underlying processes governing its formation in a mixed system remain insufficiently discussed. This study for the first time sheds light on the mechanisms of apatite formation in hybrid rocks in a magma mixing environment.
研究了岩浆混合作用下磷灰石结晶的机制。研究对象主要是gansura流纹岩丘(GRD)的斑岩安山岩和Borjuri闪长岩岩体(BDP)的闪长岩。GRD代表了印度东部巴塔尼附近的Ghansura村暴露的次火山岩浆室化石。GRD中基性岩浆与长英质岩浆的相互作用十分明显,并形成了基性、长英质和混合型三种岩石类型。BDP是暴露在印度东北部Mikir地块西隆盆地内的闪长岩岩体。基于岩石学、矿物学和结构证据的推断强调了与岩浆混合相关的物理化学条件,这些条件导致了研究岩石中磷灰石的形成。岩浆混合作用促进了基性域SiO2含量的增加。在岩浆混合过程中,除了二氧化硅的上升外,K2O也从长硅质向基性熔体扩散。K2O的扩散触发富钙相向贫钙相(角闪洞向黑云母)的分解,提高了混合体系中CaO的整体活性。由于岩浆混合作用,CaO活性的增加和SiO2浓度的增加满足了磷灰石饱和的必要条件。根据结晶温度的计算和预测,建立了从斜辉石到磷灰石的结晶序列。研究区混合岩中的磷灰石结晶过程估计发生在角闪石-黑云母转化过程中,温度可能在550 ~ 650℃之间。尽管人们对镁质岩浆包裹体和混合岩中磷灰石的丰度进行了广泛的讨论,但对其在混合体系中形成的潜在过程的讨论还不够充分。该研究首次揭示了岩浆混合环境下杂岩中磷灰石的形成机制。
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引用次数: 0
Multistage Neoproterozoic granitic magmatism and formation of Yidong tin deposit in northern Guangxi, China 桂北多期新元古代花岗质岩浆作用与宜东锡矿床的形成
IF 2 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-11-12 DOI: 10.1016/j.sesci.2025.100271
Weikang Liang , Jing Wu , Wenting Huang , Zehao Yang , Yukun Zhao , Feiyue Ren , Huaying Liang
A Neoproterozoic tin ore cluster, which is rare for South China, has been discovered in northern Guangxi. The Neoproterozoic granite pluton was formed through multistage magmatism. Previous work suggested that the tin mineralization in this region is genetically related to early-stage granitic activity, which is inconsistent with the classical understanding that tin mineralization is mainly linked to late-stage magmatic activity. The relationship between the formation and evolution of Neoproterozoic granite pluton and tin mineralization in northern Guangxi remains unclear. The Pingying granite pluton, associated with the large-scale Yidong tin deposit, is divided into coarse-grained, medium-grained, and medium-fine-grained granites from the center to the margin. Notably, an intrusive contact relationship exists between coarse-grained and medium-fine-grained granites, which provides an excellent window to reveal the relationship between Neoproterozoic pluton evolution and tin mineralization. Here, we present zircon and cassiterite U–Pb ages, whole-rock major- and trace-element compositions, and zircon Hf isotopic data for the pluton. Zircon U–Pb ages are 835.5 ± 3.0 Ma for the coarse-grained granite and 814.6 ± 7.9 Ma for the medium-fine-grained granite. Cassiterite yields a U–Pb age of 815.2 ± 8.2 Ma, consistent with that of the medium-fine-grained granite. The coarse-grained and medium-fined-grained granites have similar zircon εHf(t) values and TDM2 ages, ranging from −8.1 to −1.1 and 1.78 to 2.24 Ga, respectively. The Granites are plotted in the domains of melts derived from partial melting of metapelitic rocks on the Al2O3/TiO2 vs. CaO/Na2O, Rb/Sr vs. Rb/Ba, and C/MF vs. A/MF diagrams, suggesting the pluton formed by partial melting of Mesoproterozoic to Paleoproterozoic metapelite and underwent high fractional crystallization. Geochemical data indicate strong K-feldspar fractional crystallization from the early stage to late stage, resulting in a higher fractionation and magmatic evolution in late-stage granites compared to early-stage granite. These features demonstrate a genetic link between tin mineralization and late-stage magmatism. Tin deposits in northern Guangxi predominantly formed in association with late-stage magmatic activities during the Neoproterozoic. Exploration should target late-stage highly fractionated granites.
在广西北部发现了华南罕见的新元古代锡矿群。新元古代花岗岩体是由多期岩浆作用形成的。前人的研究表明,该区的锡矿化与早期花岗岩活动有关,这与传统的锡矿化主要与晚期岩浆活动有关的认识不一致。桂北地区新元古代花岗岩体的形成演化与锡矿化的关系尚不清楚。与宜东大型锡矿床伴生的平营花岗岩岩体,从中心到边缘可分为粗粒、中粒和中细粒花岗岩。值得注意的是,粗粒和中细粒花岗岩之间存在侵入接触关系,为揭示新元古代岩体演化与锡矿化关系提供了良好的窗口。本文给出了该岩体的锆石和锡石U-Pb年龄、全岩主量元素和微量元素组成以及锆石Hf同位素数据。粗粒花岗岩锆石U-Pb年龄为835.5±3.0 Ma,中细粒花岗岩为814.6±7.9 Ma。锡石的U-Pb年龄为815.2±8.2 Ma,与中细粒花岗岩一致。粗粒和中细粒花岗岩的锆石εHf(t)值和TDM2年龄相近,分别为−8.1 ~−1.1和1.78 ~ 2.24 Ga。在Al2O3/TiO2 vs. CaO/Na2O、Rb/Sr vs. Rb/Ba、C/MF vs. A/MF图上,花岗岩被标在变质长岩部分熔融形成的熔体域中,表明该岩体是中元古代至古元古代变质长岩部分熔融形成的,并经历了高分数结晶。地球化学数据表明,钾长石从早期到晚期具有强烈的分馏结晶作用,导致晚期花岗岩的分馏作用和岩浆演化高于早期花岗岩。这些特征表明了锡矿化与晚期岩浆活动之间的成因联系。广西北部锡矿床主要与新元古代晚期岩浆活动有关。勘探应以晚期高分选花岗岩为目标。
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Solid Earth Sciences
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