Solid Earth Sciences最新文献

Skarn Cu deposits are one of most important deposit-type in Middle-Lower Yangtze River region, eastern China, but skarn formation process remains unclear. Mineralogical, morphological and in situ geochemical data from the skarn stage of Tongguanshan skarn Cu deposit in Tongling region are systemically investigated, to reveal the timing, physical-chemical conditions, and fluid evolution during the skarn formation. The Tongguanshan garnets can be identified homogeneous and unzoned early generation garnet (GrtI), and oscillating zoned late generation garnet (GrtII) with the Fe-rich core (GrtII-Fe) and Al-rich edge (GrtII-Al). Garnet U–Pb dating results show that the Tongguanshan Cu mineralization was formed in 145.6 ± 4.4 Ma. In situ elemental composition results of the garnet samples indicate that they belong to grossular-andradite solid solution series, and are a magmatic-hydrothermal origin. The distinctly geochemical characteristics (e.g., Sn and U contents, (La/Yb)_N, δEu and Y/Ho values) reveal that the physiochemical conditions from GrtI to GrtII-Fe, and GrtII-Fe to GrtII-Al stages in the Tongguanshan skarn formation were an increase and a decrease of fluid salinity and oxygen fugacity, closed to open and then to closed of fluid environment, and neutral-weakly acidic to acidic and acidic to neutral-weakly acidic of fluid pH, respectively. A comprehensive discriminant analysis indicates a fluid boiling occurred in the GrtI to GrtII-Fe stage of the Tongguanshan skarn Cu deposit, and there is little or no external fluid mixed during the skarn stage.

The Panzijian gold deposit is located in the Jiaobei uplift on the eastern margin of North China Craton. It is a quartz vein-type gold deposit in the southern end of the Qixia-Penglai ore belt. In order to explore the source and properties of ore-forming fluids and materials in the Panzijian gold deposit, explore the ore-forming process and reveal the genesis of the deposit, this work has carried out petrographic observation and temperature measurement of gold-bearing quartz fluid inclusions, laser Raman experiment, gold-bearing quartz H–O isotope study, and gold-bearing pyrite Pb isotope study. The Panjian gold deposit is divided into four metallogenic stages and the metallogenic stage Ⅲ is the main gold mineralization stage. Fluid inclusions show that the ore-forming fluids at the Panzijian gold deposit belong to a CO₂–H₂O–NaCl system with low temperature (172–341 °C), salinity (1.57–10.49 wt% NaCl), and density (0.79–0.96 g/cm³). Gold-bearing Quartz H–O isotopic data (δD = −79.8 to −65.1‰, δ¹⁸O_H2O = 1.33–2.63‰) show that the ore-forming fluid was derived from the mixing of magmatic water and meteoric water. Gold-bearing Pyrite Pb isotopes with crustal signature (²⁰⁶Pb/²⁰⁴Pb = 16.06–16.943, ²⁰⁷Pb/²⁰⁴Pb = 15.337–15.858, ²⁰⁸Pb/²⁰⁴Pb = 37.143–38.081, and ²⁰⁶Pb/²⁰⁷Pb = 1.025–1.105) support that some ore-forming materials were crust-derived. We proposed a metallogenic model for the Panzijian gold deposit: Stress transition of Jiaobei uplift tectonic system inducing asthenospheric upwelling. The lithostatic pressure dropped and fluids were exsolved from the magma. The ore-forming fluid ascended along local faults and the pressure further dropped, resulting in fluid immiscibility and gold deposition along structural traps (e.g., faults).

The increasing importance of rare earth elements (REE) and critical metals in contemporary society has led us to investigate the mineral potential of the Ngaoumbol area, located within Cameroon's Central African Fold Belt (CAFB). In this study, we have conducted a comprehensive analysis that includes petrography, whole rock geochemistry, and mineral chemistry, along with the application of an outlook coefficient known as Koult, with the aim to evaluate the prospectivity of the Ngaoumbol iron formations as a potential source of REE-Y resources. This coefficient is defined as the ratio of the relative abundance of critical Rare Earth Elements to the relative abundance of excess REE. The iron formations in the Ngaoumbol area are fine-to medium-grained foliated rocks with alternating magnetite and actinolite bands and quartz bands, suggesting a sedimentary parentage. These rocks have an average REE-Y content of 1438.43 ppm and a Koult of 0.77, indicating their potential as raw sources for REE. Furthermore, the investigated samples exhibit high average Zr content (7748 ppm), suggesting that the rocks may host potentially economic Zr ore. The Zr-REE-Y mineralization in the Ngaoumbol area is hosted in detrital zircon, monazite and xenotime, probably deriving from the weathering of alkaline/subalkaline rocks surrounding the deposits. Our findings suggest that the Ngaoumbol area has promising REE and Zr resources. However, further exploration and evaluation are necessary to determine the extent and economic viability of these resources.

The Zhuqing vanadium–titanium magnetite is a large deposit recently discovered in the western margin of the Yangtze Block, where the Zhuqing gabbroic intrusion and associated Fe–Ti–V oxide deposits are fund and dated at 1647 ± 39 Ma (MSWD = 0.79) through U–Pb dating of gabbro zircons. The εHf(t) values of zircons are all positive, with an average of 10.7. The average age of the one-stage model age (T_DM) is 1661 Ma, which is very close to the diagenetic and metallogenic age 1647 ± 39 Ma (MSWD = 0.79). These new results indicate that the magma source come directly from the mantle. The contents of Al₂O₃, CaO, and (Na₂O + K₂O) increases with the increase of SiO₂ contents, while, the contents of MgO, TiO₂, and Fe₂O₃ decreases with the increase of SiO₂ contents. Mg^# is relatively stable with the increase of SiO₂ contents. In the primitive mantle-normalized trace element spider diagrams and chondrite-normalized rare earth element patterns, the characteristics of all samples are similar to that of ocean island basalts (OIBs), showing a right inclination curve. Meanwhile the western margin of the Yangtze Block as an essential part of the supercontinent of Colombia, began to extend at 1.7 Ga, lasted to ca. 1.4 Ga, and finally split. These suggest that the Zhuqing gabbroic intrusion and associated Fe–Ti–V oxide deposits with OIB characteristics formed in the Late Paleoproterozoic, which is a response to the breakup of the Colombian supercontinent in the western margin of the Yangtze Block.