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Electron beam lithography on non-planar, suspended, 3D AFM cantilever for nanoscale thermal probing 电子束光刻在非平面,悬浮,三维原子力显微镜悬臂上的纳米热探测
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2022-06-02 DOI: 10.1088/2399-1984/ac7599
R. Swami, G. Julie, D. Singhal, J. Paterson, J. Maire, S. Le-Denmat, J. Motte, S. Gomes, O. Bourgeois
Electron beam lithography (EBL) on non-planar, suspended, curved or bent surfaces is still one of the most frequently stated problems for fabricating novel and innovative nano-devices and sensors for future technologies. Although spin coating is the most widespread technique for electron resist (e-resist) deposition on 2D or flat surfaces, it is inadequate for suspended and 3D architectures because of its lack of uniformity. In this work, we use a thermally evaporated electron sensitive resist the QSR-5 and study its sensitivity and contrast behaviour using EBL. We show the feasibility of utilizing the resist for patterning objects on non-planar, suspended structures via EBL and dry etching processes. We demonstrate the integration of metal or any kind of thin films at the apex of an atomic force microscopy (AFM) tip. This is showing the great potential of this technology in various fields, such as magnetism, electronic, photonics, phononics and other fields related to near field microscopy using AFM probe like for instance scanning thermal microscopy.
在非平面、悬浮、弯曲或弯曲表面上的电子束光刻(EBL)仍然是为未来技术制造新颖和创新的纳米器件和传感器最常见的问题之一。虽然自旋涂层是在二维或平面上沉积电子抗蚀剂(e-resist)的最广泛的技术,但由于其缺乏均匀性,它不适用于悬浮和三维结构。在这项工作中,我们使用了一种热蒸发电子敏感电阻QSR-5,并使用EBL研究了它的灵敏度和对比行为。我们展示了利用该抗蚀剂在非平面、悬浮结构上通过EBL和干蚀刻工艺进行图案化的可行性。我们展示了金属或任何种类的薄膜在原子力显微镜尖端的集成。这显示了该技术在各个领域的巨大潜力,如磁性、电子、光子学、声子学和其他与使用AFM探针的近场显微镜相关的领域,如扫描热显微镜。
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引用次数: 0
Magnetic nanoparticles and magnetic particle spectroscopy-based bioassays: a 15 year recap. 磁性纳米颗粒和基于磁颗粒光谱的生物测定:15年回顾。
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2022-06-01 DOI: 10.1088/2399-1984/ac5cd1
Kai Wu, Jinming Liu, Vinit Kumar Chugh, Shuang Liang, Renata Saha, Venkatramana D Krishna, Maxim C-J Cheeran, Jian-Ping Wang

Magnetic nanoparticles (MNPs) have unique physical and chemical properties, such as high surface area to volume ratio and size-related magnetism, which are completely different from their bulk materials. Benefiting from the facile synthesis and chemical modification strategies, MNPs have been widely studied for applications in nanomedicine. Herein, we firstly summarized the designs of MNPs from the perspectives of materials and physicochemical properties tailored for biomedical applications. Magnetic particle spectroscopy (MPS), first reported in 2006, has flourished as an independent platform for many biological and biomedical applications. It has been extensively reported as a versatile platform for a variety of bioassays along with the artificially designed MNPs, where the MNPs serve as magnetic nanoprobes to specifically probe target analytes from fluid samples. In this review, the mechanisms and theories of different MPS platforms realizing volumetric- and surface-based bioassays are discussed. Some representative works of MPS platforms for applications such as disease diagnosis, food safety and plant pathology monitoring, drug screening, thrombus maturity assessments are reviewed. At the end of this review, we commented on the rapid growth and booming of MPS-based bioassays in its first 15 years. We also prospected opportunities and challenges that portable MPS devices face in the rapidly growing demand for fast, inexpensive, and easy-to-use biometric techniques.

磁性纳米颗粒(MNPs)具有独特的物理和化学性质,如高表面积体积比和尺寸相关的磁性,完全不同于它们的块状材料。由于其易于合成和化学修饰的优点,MNPs在纳米医学领域的应用得到了广泛的研究。在此,我们首先从材料和物理化学性质的角度总结了适合生物医学应用的MNPs设计。磁粒子光谱(MPS)于2006年首次报道,作为一个独立的平台在许多生物学和生物医学应用中蓬勃发展。它已被广泛报道为各种生物测定的通用平台,以及人工设计的MNPs,其中MNPs作为磁性纳米探针,专门探测流体样品中的目标分析物。在这篇综述中,不同的MPS平台实现体积和表面为基础的生物检测的机制和理论进行了讨论。综述了MPS平台在疾病诊断、食品安全和植物病理学监测、药物筛选、血栓成熟度评估等方面的代表性工作。在这篇综述的最后,我们评论了基于mps的生物检测在最初的15年里的快速增长和蓬勃发展。我们还展望了便携式MPS设备在快速增长的需求中面临的机遇和挑战,快速、廉价和易于使用的生物识别技术。
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引用次数: 11
Nanomaterials and printing techniques for 2D and 3D soft electronics 二维和三维软电子的纳米材料和打印技术
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2022-05-31 DOI: 10.1088/2399-1984/ac74f9
L. Migliorini, Sara Moon Villa, T. Santaniello, P. Milani
The merging of electronically conductive elements with soft polymeric materials gave birth to the novel field of soft and stretchable electronics and robotics, in which the key aspect is the maintenance of electrical properties even under severe mechanical deformation. Here, we review the variety of fabrication techniques (dry, wet, and printed) that have been designed, studied, and tested, which leads to a forecast of how soft technologies will have a revolutionary impact on the progress of biomedicine and pre-clinical practice, wearable electronics, environmental monitoring and recognition, smart farming and precision agriculture, and energy harvesting and storage. A particular focus is given to techniques for the printing of 2D and 3D electronics, which allow compliant conductive elements to be coupled to complex three-dimensional objects and platforms. We discuss why it is now necessary to choose between different nanoscale building blocks, nanomaterials, and deposition techniques and to optimize such choices. The watchwords to be prioritized are scalability, versatility, environmental sustainability and biocompatibility, integration, and reduction of the fabrication steps. The target is the design of an eco-friendly and versatile approach for the fully additive manufacture of free-form advanced soft electronic devices (which will eventually be biocompatible and biodegradable) using a multilayer, multimaterial process that can print both active and passive 3D elements on soft polymeric platforms. The sequential combination of dry and wet spray printing is shown to be one of the most promising approaches.
导电元件与软聚合物材料的结合催生了软可拉伸电子和机器人技术的新领域,其中的关键是即使在严重的机械变形下也能保持电气性能。在这里,我们回顾了已经设计、研究和测试的各种制造技术(干、湿和印刷),从而预测了软技术将如何对生物医学和临床前实践、可穿戴电子、环境监测和识别、智能农业和精准农业的进步产生革命性影响,以及能量收集和储存。特别关注的是用于2D和3D电子器件的打印技术,其允许将柔性导电元件耦合到复杂的三维物体和平台。我们讨论了为什么现在有必要在不同的纳米级构建块、纳米材料和沉积技术之间进行选择,并优化这些选择。优先考虑的口号是可扩展性、多功能性、环境可持续性和生物相容性、集成和减少制造步骤。目标是设计一种环保且通用的方法,使用多层多材料工艺,在软聚合物平台上打印有源和无源3D元件,完全增材制造自由形式的先进软电子设备(最终将具有生物相容性和可生物降解性)。干喷印和湿喷印的顺序组合被证明是最有前途的方法之一。
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引用次数: 1
Synthesis and characterization of a g-C3N4/TiO2-ZnO nanostructure for photocatalytic degradation of methylene blue 光催化降解亚甲基蓝的g-C3N4/TiO2-ZnO纳米结构的合成与表征
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2022-05-31 DOI: 10.1088/2399-1984/ac74fa
Sepide Saeidpour, B. Khoshnevisan, Z. Boroumand
In this study, graphitic carbon nitride (g-C3N4) nanostructures with different molar ratios of ZnO and TiO2 (i.e. g-C3N4/TiO2, g-C3N4/ZnO, and g-C3N4/TiO2-ZnO) were synthesized. The synthesized samples were characterized using field-emission scanning electron microscopy (FE-SEM), x-ray diffraction, Brunauer–Emmett–Teller (BET) analysis, and ultraviolet (UV)–visible diffuse reflectance spectroscopy (UV-vis-DRS) techniques. The FE-SEM images showed the surface morphology of each sample. The UV-vis-DRS results indicated that the bandgap of TiO2 was reduced by adding g-C3N4 and different molar ratios of ZnO. The results obtained from BET analysis confirmed that the surface area of the g-C3N4/TiO2-ZnO (1:10) nanostructure was 97.494 cm2 g−1, which was comparatively higher than other nanostructures, and became suitable for photocatalytic activity. The photocatalytic activity of the g-C3N4/TiO2-ZnO nanostructure was performed by photo-degradation of methylene blue (MB) dye under simulated solar light. The results of the photocatalytic activity showed that the synthesized nanostructure had good degradation under UV and visible light irradiation by 94.6% and 62.4%, respectively. Also, the kinetics of the photocatalytic degradation confirmed that degradation of MB dye in the presence of UV light was faster than visible light. Furthermore, a study of the reusability of the nanostructure exhibited good photo-stability and activity after six runs.
在本研究中,合成了具有不同ZnO和TiO2摩尔比的石墨氮化碳(g-C3N4)纳米结构(即g-C3N4/TiO2、g-C3N4/ZnO和g-C3N4-TiO2-ZnO)。使用场发射扫描电子显微镜(FE-SEM)、x射线衍射、Brunauer–Emmett–Teller(BET)分析和紫外(UV)–可见漫反射光谱(UV-vis-DRS)技术对合成的样品进行了表征。FE-SEM图像显示了每个样品的表面形态。UV-vis-DRS结果表明,添加g-C3N4和不同摩尔比的ZnO可以降低TiO2的带隙。BET分析结果证实,g-C3N4/TiO2-ZnO(1:10)纳米结构的表面积为97.494 cm2 g−1,相对高于其他纳米结构,适合于光催化活性。通过在模拟太阳光下对亚甲基蓝(MB)染料的光降解,研究了g-C3N4/TiO2-ZnO纳米结构的光催化活性。光催化活性的结果表明,合成的纳米结构在紫外光和可见光照射下的降解率分别为94.6%和62.4%。此外,光催化降解动力学证实,在紫外光存在下,MB染料的降解速度快于可见光。此外,对纳米结构的可重复使用性的研究在六次运行后表现出良好的光稳定性和活性。
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引用次数: 3
Bipolar dual-broadband photodetectors based on perovskite heterojunctions 基于钙钛矿异质结的双极双宽带光电探测器
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2022-05-17 DOI: 10.1088/2399-1984/ac7099
Yu Li, F. Guo, Shanshan Yu, Jian Wang, Shihe Yang
The development of efficient photodetectors for color recognition is of great importance for many applications. In this paper, we report a novel bipolar dual-broadband photodetector equipped with a perovskite heterojunction, with bidirectional broadband responses in the short-wavelength and long-wavelength regions at zero bias voltage, enabled by a charge separation reversion mechanism. The unique aerosol–liquid–solid technique allowed the perovskite heterojunction to be fabricated by successively depositing wide-bandgap perovskite (WBP) and narrow-bandgap perovskite (NBP) layers directly on the transparent substrate. For photodetectors based on the perovskite heterojunctions, the short-wavelength photons were depleted by the bottom WBP layer and generated negative responses, while the long-wavelength photons were absorbed by the top NBP layer and generated positive responses. Moreover, the demarcation wavelength between the bipolar responses and the cut-off wavelength can be easily tuned by adjusting the bandgaps (or compositions) of the bottom and top perovskite layers.
开发用于颜色识别的高效光电探测器对于许多应用具有重要意义。在本文中,我们报道了一种新型双极双宽带光电探测器,该探测器配备了钙钛矿异质结,在零偏置电压下,在短波长区域具有双向宽带响应,通过电荷分离反转机制实现。独特的气溶胶-液体-固体技术使钙钛矿异质结能够通过直接在透明衬底上连续沉积宽带隙钙钛矿(WBP)和窄带隙钙钛矿(NBP)层来制造。对于基于钙钛矿异质结的光电探测器,短波长光子被底部WBP层耗尽并产生负响应,而长波长光子被顶部NBP层吸收并产生正响应。此外,通过调节底部和顶部钙钛矿层的带隙(或组成),可以容易地调节双极响应和截止波长之间的分界波长。
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引用次数: 0
Enhanced water oxidation reaction activity of Mn3O4 nanocrystals in an alkaline medium by doping transition-metal ions 掺杂过渡金属离子增强Mn3O4纳米晶体在碱性介质中的水氧化反应活性
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2022-05-17 DOI: 10.1088/2399-1984/ac7098
P. Saraswathi, Anjaly Babu, S. Ramarao, K. Uday Kumar, Hitesh Borkar, C. Rajesh, K. Kumar
Designing low-cost, Earth-abundant, and non-precious catalysts for electrochemical water oxidation reactions is particularly important for accelerating the development of sustainable energy sources and, further, can be fed to fuel cells. In the present work, we report the oxygen evolution reaction (OER) activity of a metal-oxide catalyst, Mn3O4, and study the effect of transition metal doping (Cu and Fe) on the OER activity of Mn3O4 in an alkaline medium. The Mn3O4 and transition metal (Cu and Fe) doped Mn3O4 catalysts were prepared using a hydrothermal reaction technique. Powder x-ray diffraction studies revealed that these compounds adopt a tetragonal spinel structure with an I41/amd space group, and this is further supported with Fourier transform infrared spectroscopic measurements. These results are further supported by high-resolution transmission electron microscopic measurements. The electrochemical measurements of these catalysts reveal that the transition metal (Cu and Fe) doped Mn3O4 catalysts show better OER activity than pristine Mn3O4 (MO). The transition metal (Cu and Fe) doped Mn3O4 catalysts exhibit lower overpotential for the OER (η MCO = 300 mV and η MFO = 240 mV) than the MO (η MO = 350 mV) catalyst. The better performance of Fe-doped Mn3O4 is further supported by turnover frequency calculations.
设计用于电化学水氧化反应的低成本、富含地球的非贵金属催化剂对于加速可持续能源的开发尤其重要,并且可以进一步用于燃料电池。在本工作中,我们报道了金属氧化物催化剂Mn3O4的析氧反应(OER)活性,并研究了过渡金属掺杂(Cu和Fe)对Mn3O4在碱性介质中的OER活性的影响。采用水热反应技术制备了Mn3O4和过渡金属(Cu和Fe)掺杂的Mn3O4催化剂。粉末x射线衍射研究表明,这些化合物采用具有I41/amd空间基团的四方尖晶石结构,傅里叶变换红外光谱测量进一步支持了这一点。这些结果得到了高分辨率透射电子显微镜测量的进一步支持。这些催化剂的电化学测量表明,过渡金属(Cu和Fe)掺杂的Mn3O4催化剂表现出比原始Mn3O4(MO)更好的OER活性。过渡金属(Cu和Fe)掺杂的Mn3O4催化剂对OER(ηMCO=300mV和ηMFO=240mV)表现出比MO(ηMO=350mV)催化剂更低的过电势。转换频率计算进一步支持了Fe掺杂的Mn3O4的更好性能。
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引用次数: 0
Trends in nanomaterial-based biosensors for viral detection 基于纳米材料的病毒检测生物传感器的发展趋势
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2022-05-16 DOI: 10.1088/2399-1984/ac701d
Christian Harito, M. Khalil, N. L. W. Septiani, K. K. Dewi, A. Hardiansyah, B. Yuliarto, F. Walsh
Pandemics such as COVID-19 have highlighted the importance of point-of-care sensors for testing, tracing, and treatment to minimize and manage infection. Biosensors have been widely deployed in portable devices such as glucose sensors and pregnancy tests. Their development for point-of-exposure virus detection or point-of-care devices is anticipated but their reliability for the accurate detection of viruses is critical. Nanomaterials, such as metal nanoparticles (NPs), magnetic NPs, quantum dots, carbon-based nanomaterials, and molecularly imprinted polymer (MIP) NPs, have been utilized in biosensors to enhance sensitivity. Molecular imprinting is a cost-effective method to synthesize polymers for selective binding, which have excellent properties as biosensors. More research on MIP NPs can be expected in the near future. The utilization of nanomaterials in several types of transducers for biosensor devices is also illustrated to give an overview of their use. Finally, a summary is given together with a future perspective on how biosensors can be further developed as reliable, portable viral biosensors.
新冠肺炎等流行病突出了检测、追踪和治疗点护理传感器的重要性,以最大限度地减少和管理感染。生物传感器已广泛应用于便携式设备,如葡萄糖传感器和妊娠测试。它们在接触点病毒检测或护理点设备方面的发展是意料之中的,但它们准确检测病毒的可靠性至关重要。纳米材料,如金属纳米颗粒(NP)、磁性NP、量子点、碳基纳米材料和分子印迹聚合物(MIP)NP,已被用于生物传感器以提高灵敏度。分子印迹是合成选择性结合聚合物的一种成本效益高的方法,聚合物作为生物传感器具有优异的性能。在不久的将来,可以期待对MIP NP进行更多的研究。还举例说明了纳米材料在生物传感器设备的几种类型的换能器中的应用,以概述其用途。最后,总结了生物传感器如何进一步发展成为可靠的便携式病毒生物传感器的未来前景。
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引用次数: 1
Study of the adsorptive removal of (Fe+2) and (Ni+2) from water by synthesized magnetite/corn cobs magnetic nanocomposite 合成磁铁矿/玉米芯磁性纳米复合材料吸附去除水中(Fe+2)和(Ni+2)的研究
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2022-04-25 DOI: 10.1088/2399-1984/ac6a31
Mohamed N Sanad, S. El-Dek, U. Eldemerdash, Mohamed M. ElFaham
Heavy metals are principal concomitant pollutants in industrial wastewaters, posing a serious threat to public health and the environment. Herein, we develop a novel strategy to produce a new nanocomposite formed from corn cobs (CCs) and magnetite as a nanomaterial for the simultaneous removal of Fe+2 and Ni+2. The as-prepared nanocomposite was systematically characterized by x-ray diffraction, field emission scanning electron microscopy, mapping, energy-dispersive x-ray spectroscopy, high-resolution transmission electron microscopy, selected area electron diffraction, zeta size, and zeta potential. Compared to the CCs and Fe3O4, the nanocomposite showed better adsorption performance. The maximum adsorption efficiency of the CC, Fe3O4, and the nanocomposite was calculated by atomic analysis to be around 91.84%, 91.28%, and 98.51%, respectively, under the same conditions. This study indicates that the nanocomposite could be a favorable biomass-derived adsorbent for the simultaneous removal of heavy metals.
重金属是工业废水中主要的伴生污染物,对公众健康和环境构成严重威胁。在此,我们开发了一种新的策略,以生产由玉米芯(CC)和磁铁矿形成的新型纳米复合材料,作为同时去除Fe+2和Ni+2的纳米材料。通过x射线衍射、场发射扫描电子显微镜、图谱、能量色散x射线光谱、高分辨率透射电子显微镜、选区电子衍射、ζ尺寸和ζ电势对所制备的纳米复合材料进行了系统表征。与CC和Fe3O4相比,纳米复合材料表现出更好的吸附性能。通过原子分析计算,在相同条件下,CC、Fe3O4和纳米复合材料的最大吸附效率分别约为91.84%、91.28%和98.51%。该研究表明,该纳米复合材料可能是一种有利的生物质衍生吸附剂,用于同时去除重金属。
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引用次数: 1
Recent developments in functional triboelectric nanogenerators for flame-retardant, human health, and energy-harvesting fields: a crucial review 用于阻燃、人类健康和能量收集领域的功能性摩擦电纳米发电机的最新进展:一篇重要综述
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2022-04-21 DOI: 10.1088/2399-1984/ac691c
Ran Wang, Miaomiao Ji, X. Jin, Qiran Zhang, T. Jiao
In recent years, the rational use and development of energy has become an important research direction. As a novel technology, triboelectric nanogenerators (TENGs) can effectively convert other energy from around the environment into electricity. TENGs have wide applicability due to their adjustable structures, but they are still limited to a certain extent in some special fields. For example, some special requirements for triboelectric materials need to be addressed when a TENG is applied in a high temperature environment, in water, in wind, or for human health. Therefore, this review introduces some TENGs applied in special environments, and provides a reference for the preparation and application of functional TENGs. It provides a new idea for the preparation of multifunctional TENGs and their wide application in various fields.
近年来,合理利用和开发能源已成为一个重要的研究方向。摩擦电纳米发电机(TENGs)作为一种新型技术,可以有效地将周围环境中的其他能量转化为电能。由于其结构可调,因此具有广泛的适用性,但在一些特殊领域仍有一定的局限性。例如,当TENG应用于高温环境、水中、风中或人体健康时,需要解决对摩擦电材料的一些特殊要求。因此,本文综述了一些在特殊环境下应用的高分子材料,为功能性高分子材料的制备和应用提供参考。这为多功能腾烯化合物的制备及其在各个领域的广泛应用提供了新的思路。
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引用次数: 2
Participatory Utopian Sketching: A Methodological Framework for Collaborative Citizen (Re)Imagination of Urban Spatial Futures 参与式乌托邦素描:城市空间未来的协同公民(再)想象的方法论框架
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2022-04-01 DOI: 10.1016/j.futures.2022.102938
Suzanna Törnroth, J. Day, Moritz F. Fürst, S. Mander
{"title":"Participatory Utopian Sketching: A Methodological Framework for Collaborative Citizen (Re)Imagination of Urban Spatial Futures","authors":"Suzanna Törnroth, J. Day, Moritz F. Fürst, S. Mander","doi":"10.1016/j.futures.2022.102938","DOIUrl":"https://doi.org/10.1016/j.futures.2022.102938","url":null,"abstract":"","PeriodicalId":54222,"journal":{"name":"Nano Futures","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2022-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80108028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
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