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The Relationship between Skin Biomechanical Properties Around the Spine and Spinal Kinematics of the Trunk 脊柱周围皮肤生物力学特性与躯干脊柱运动学的关系
IF 0.6 4区 工程技术 Q4 Engineering Pub Date : 2023-01-01 DOI: 10.2115/fiberst.2023-0005
Kohei Yamaguchi, Aya Atomi, Masaki Oyauchi, Miho Shimizu, T. Atomi, Y. Atomi
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引用次数: 0
Design and Sound Absorption Performance of a Laminated Structure Using Natural Materials 天然材料层压结构的设计与吸声性能
IF 0.6 4区 工程技术 Q4 Engineering Pub Date : 2023-01-01 DOI: 10.2115/fiberst.2023-0009
Wendan Yang, H. Xia, T. Natsuki, Q. Ni
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引用次数: 0
Solvent Selectivity in Helical/Linear Nanofiber-Derived Gelation Imparted by Chiral/Achiral Thixotropic Additive Molecules 手性/非手性触变添加剂分子对螺旋/线性纳米纤维凝胶化的溶剂选择性影响
IF 0.6 4区 工程技术 Q4 Engineering Pub Date : 2023-01-01 DOI: 10.2115/fiberst.2023-0013
Yuki Mashiyama, Yuka Hasunuma, A. Fujimori
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引用次数: 1
Fabrication of Bio-Colored and Functional Wool Using Natural Pu’er Tea Extract 利用天然普洱茶提取物制备生物有色功能性羊毛
4区 工程技术 Q4 Engineering Pub Date : 2023-01-01 DOI: 10.2115/fiberst.2023-0025
Yue Zhang, Yanmei Jia, Jipeng Cao, Xuezhi Yu, Mingguang Zhang
Applying synthetic dyes in textile dyeing may lead to severe environmental pollution due to liquid waste emissions; therefore, it is urgent to develop environmentally-friendly ecological dyes to minimize such damage. By using Pu’er tea extract (PTE) as a natural colorant to dye wool, this study created such bio-colored material in experiments, during which the thermal stability and antibacterial activity of wool both with and without PTE dyeing were also explored. Most importantly, it is proved that the dyed wool can deliver better color depth and fastness, with the dyeing ability considerably improved after ferrous sulfate (FeSO4·7H2O) mordant treatment as well. Furthermore, the inhibition rate of wool against Escherichia coli (E. coli) could reach 88.02 % and 90.25 % for direct dyeing and mordant dyeing, respectively, at a PTE concentration of 60 g/L, while the antibacterial rate remains above 70 % after 10 washing cycles of accelerated laundering. Another important phenomenon observed is that the thermal decomposition temperature of the wool dyed with PTE was increased, demonstrating that PTE, as a natural colorant, could improve the thermal stability of wool, in addition to stable dyeing properties.
在纺织染色中使用合成染料会产生废液排放,严重污染环境;因此,开发环保型的生态染料,将这种危害降到最低是当务之急。本研究以普洱茶提取物(PTE)为天然着色剂对羊毛进行染色,通过实验制备了这种生物着色材料,并对PTE染色和未染色羊毛的热稳定性和抗菌活性进行了研究。最重要的是,经硫酸亚铁(FeSO4·7H2O)媒剂处理后的染色羊毛具有较好的色深和牢度,染色能力也有较大提高。PTE浓度为60 g/L时,直接染色和媒介染色对羊毛的抑菌率分别可达88.02%和90.25%,加速洗涤10次后抑菌率仍保持在70%以上。观察到的另一个重要现象是PTE染色羊毛的热分解温度升高,说明PTE作为一种天然着色剂,除了染色性能稳定外,还可以提高羊毛的热稳定性。
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引用次数: 0
Property-Thickness Correlations of Transparent All-Nanocellulose Laminates 透明全纳米纤维素层压板的性能-厚度相关性
4区 工程技术 Q4 Engineering Pub Date : 2023-01-01 DOI: 10.2115/fiberst.2023-0020
Shun Ishioka, Takayuki Hirano, Nobuhiro Matoba, Noriyuki Isobe, Shuji Fujisawa, Tsuguyuki Saito
Millimeter-thick laminated materials comprised solely of cellulose nanofibers (CNFs) combine optical transparency, high strength, and thermal anisotropy. These CNF laminates were fabricated by stacking thin CNF sheets and applying CNFs dispersed in a water/ethanol mixture as binder, followed by hot pressing. The number of stacked CNF sheets can control the laminate thickness within a wide range of dimensions. Here, we report the correlation between the material properties and laminate thickness of this all-CNF plate material. CNF laminates with different thicknesses (~30-500 μm) were fabricated using 1-15 CNF sheets. The crystallinity of the CNFs in the laminates was greatly enhanced by increasing the number of stacked sheets. This trend in crystallinity is explained by the longer period of time required for drying thicker laminates in the hot press process. The visible-light transmittance of the laminates was well described by the Beer–Lambert law; scattering and/or reflection at the binding interface between sheets were estimated to be negligibly small. The elastic modulus of the laminates increased with increasing number of stacked sheets and reached a maximum of 36 GPa. This increasing trend was explained by the enhanced crystallinity of the CNFs in the laminates. The tensile strengths of the laminates varied greatly, and no clear trend as a function of the number of stacked sheets was found. The thermal conductivity increased with increasing number of stacked sheets, which was attributed to the enhanced crystallinity.
仅由纤维素纳米纤维(CNFs)组成的毫米厚层压材料具有光学透明性、高强度和热各向异性。这些CNF层压板是通过堆叠薄的CNF薄片,并将分散在水/乙醇混合物中的CNF作为粘合剂,然后热压制成的。层叠CNF片材的数量可以在很宽的尺寸范围内控制层叠厚度。本文报道了这种全cnf板材料的材料性能与层压厚度之间的关系。采用1 ~ 15片CNF片材,制备了不同厚度(~30 ~ 500 μm)的CNF层压板。层压板中CNFs的结晶度通过增加堆叠层的数量而大大提高。这种结晶度的趋势可以解释为在热压过程中干燥较厚的层压板所需的时间较长。层合板的可见光透过率用Beer-Lambert定律描述得很好;薄片间结合界面处的散射和/或反射估计小得可以忽略不计。层合板的弹性模量随层数的增加而增加,最高可达36gpa。这种增加的趋势可以用层压板中CNFs的结晶度增强来解释。层合板的抗拉强度变化较大,且随层数的变化趋势不明显。热导率随着层数的增加而增加,这是由于结晶度的提高。
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引用次数: 0
<i>In Situ</i> Analysis of Melt-Drawing Behavior of Melt-Spun Ultrahigh-Molecular-Weight Polyethylene Fibers & lt; i&gt Situ&lt; / i&gt;熔融纺丝超高分子量聚乙烯纤维熔拉性能分析
4区 工程技术 Q4 Engineering Pub Date : 2023-01-01 DOI: 10.2115/fiberst.2023-0022
Masaki Kakiage, Yuka Yokochi, Ayaka Takazawa, Takeshi Yamanobe, Hiroki Uehara
In this study, the melt-drawing behavior of melt-spun ultrahigh-molecular-weight polyethylene (UHMW-PE) fibers with different oriented crystalline states was investigated by in situ wide-angle X-ray diffraction (WAXD) measurements. Melt-spun UHMW-PE fibers with different oriented crystalline states were prepared at different take-up speeds. The obtained melt-spun fibers were melt-drawn at 140 °C, and the oriented crystallization behavior during melt-drawing was evaluated by in situ WAXD measurements. Drawing started from a state where molten amorphous and oriented crystals coexisted. As drawing proceeded, the oriented crystallization occurred during melt-drawing. Rapid oriented crystallization occurred for the melt-spun fiber prepared at a high take-up speed with many remaining oriented crystals, indicating the effective transmission of the applied stress through the remaining oriented crystals. On the other hand, gentle oriented crystallization with chain slippage occurred during the melt-drawing of the melt-spun fiber prepared at a low take-up speed with few remaining oriented crystals. The oriented crystallization with chain slippage improved the melt drawability and simultaneously yielded a high crystalline orientation, resulting in melt-drawn fibers with both high tensile strength and small diameter. The findings obtained are important for simultaneously achieving high strength and small diameter of UHMW-PE fibers prepared by melt-processing.
采用原位广角x射线衍射(WAXD)技术研究了不同取向晶态的熔融纺丝超高分子量聚乙烯(UHMW-PE)纤维的熔融拉伸行为。在不同的卷绕速度下,制备了不同取向晶态的熔融纺丝超高分子量聚乙烯纤维。得到的熔融纺丝纤维在140°C下熔融拉伸,并通过原位WAXD测量评估了熔融拉伸过程中的取向结晶行为。绘图开始于熔融非晶和取向晶体共存的状态。随着拉拔的进行,熔体拉拔过程中发生了定向结晶。高卷取速度制备的熔融纺丝纤维发生了快速取向结晶,残余取向晶体较多,表明外加应力通过残余取向晶体有效传递。另一方面,在低卷绕速度下制备的熔融纺丝纤维在熔融拉伸过程中发生了轻微的取向结晶,并伴有链滑,取向晶体残留较少。具有链滑移的定向结晶提高了熔体拉伸性,同时产生了高结晶取向,从而获得了高拉伸强度和小直径的熔体拉伸纤维。研究结果对同时实现熔融法制备的超高分子量聚乙烯纤维的高强度和小直径具有重要意义。
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引用次数: 0
Analysis of Sandwich Composite Manufacture with Triaxial-Processed Foam Core by Vacuum-Assisted Resin Infusion Moulding and Resin Reinforcement 真空辅助树脂注射成型及树脂增强制造三轴加工泡沫芯夹层复合材料分析
IF 0.6 4区 工程技术 Q4 Engineering Pub Date : 2023-01-01 DOI: 10.2115/fiberst.2023-0002
Xueshan Chen, W. Tian, Xiaoke Jin, Chengyan Zhu
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引用次数: 0
脂肪族ポリエステル/セルロースアセテート系ブレンドの相溶性 脂肪族聚酯/纤维素醋酸类混合的相溶性
4区 工程技术 Q4 Engineering Pub Date : 2023-01-01 DOI: 10.2115/fiberst.2023-0029
Masamichi Kiyoura, Kosuke Mizuno, Misato Kobayashi, Yoshiharu Miyashita
Miscibility characterization were performed on binary blends of aliphatic polyester with cellulose acetate (CA). Poly(ethylene succinate) (PES) and poly(butylene adipate) (PBA) were selected as aliphatic polyester components. Three samples of CA having different degrees of substitution (DS = 2.45, 2.70, 2.95) were used. Blend films of aliphatic polyester with CA were prepared from mixed polymer solutions by solvent evaporation. The estimation of the blend miscibility was carried out by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). From thermal data obtained by DSC analysis, it was found that PES was miscible with CA (DS = 2.45) and CA(DS = 2.70). However, it was immiscible with CA(DS = 2.95) and PBA was immiscible with all CAs. The isothermal crystallization behavior of PBA/cellulose ester blends was followed by POM. For blend samples of PES with CA(DS = 2.45), the radial growth rates of PES spherulites were depressed remarkably by increasing the amount of CA in the blends. Such depression of the crystal growth rate may be attributed to the diluent effect of CA, supporting the good miscibility of these blends. When the blend samples were prepared by using PES and CA(DS = 2.95) or PBA and CA(DS = 2.45), the radial growth rates of spherulites were almost constant regardless of the amount of CA in the blends, showing the immiscibility of these blends. From these results, it was assumed that good miscibility of PES/CA blends would be derived from the structural affinity of repeating unit of PES and acetyl side groups of CA.
对脂肪族聚酯与醋酸纤维素(CA)二元共混物进行了混相表征。选择聚琥珀酸乙烯(PES)和聚己二酸丁烯(PBA)作为脂肪族聚酯组分。采用三种不同取代度的CA样品(DS = 2.45, 2.70, 2.95)。采用溶剂蒸发法制备了脂肪族聚酯与CA共混膜。用差示扫描量热法(DSC)和偏光显微镜(POM)对共混物的混相进行了估计。通过DSC分析得到的热数据,发现PES与CA(DS = 2.45)和CA(DS = 2.70)存在混相。但PBA与CA不混溶(DS = 2.95),与所有CA均不混溶。PBA/纤维素酯共混物的等温结晶行为被POM所遵循。对于掺有CA的PES共混样品(DS = 2.45),增加共混物中CA的含量,PES球晶的径向生长速率明显降低。这种晶体生长速率的降低可能是由于CA的稀释作用,支持了这些共混物的良好混相。当使用PES和CA(DS = 2.95)或PBA和CA(DS = 2.45)制备共混物样品时,无论共混物中CA的含量如何,球晶的径向生长速率几乎不变,表明共混物具有非混相性。从这些结果可以推测,PES/CA共混物良好的混溶性来源于PES重复单元和CA乙酰侧基的结构亲和性。
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引用次数: 0
Molecular Dynamics Simulation Study of Chitosan−Zinc Chloride Complex Model 壳聚糖-氯化锌配合物模型的分子动力学模拟研究
IF 0.6 4区 工程技术 Q4 Engineering Pub Date : 2023-01-01 DOI: 10.2115/fiberst.2023-0004
K. Noda, Takuya Uto, T. Yui
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引用次数: 1
Colour Fastness of Silk Fabrics Dyed with Extracts from Oil Palm Tree Kernel Shell and Effect of Metal Ion Mordanting on Fabric Colour 油棕仁壳提取物染色真丝织物的色牢度及金属离子媒染剂对织物颜色的影响
IF 0.6 4区 工程技术 Q4 Engineering Pub Date : 2023-01-01 DOI: 10.2115/fiberst.2023-0014
H. Yasunaga, Akari Oda, Yodsawon Tasa, Kamthorn Intharapichai, Hideyuki Shima, Y. Okahisa, H. Ohara
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引用次数: 0
期刊
Journal of Fiber Science and Technology
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