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Hydrochemical and multi-isotopic insights into the genesis model of the karst groundwater system (Southwestern China) 西南岩溶地下水系统成因模式的水化学和多同位素研究
IF 2.8 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 DOI: 10.1007/s12665-025-12723-1
Jinhai Yu, Shiming Yang, Zhan Xie, Xiangchuan Wu, Juan Antonio Torres-Martínez, Yangshuang Wang, Qili Hu, Xiaojun Xu, Ying Wang, Yunhui Zhang

The Karst groundwater system affected by coal-mining activities is complicated, hampering the sustainable management of groundwater resources. In this study, hydrochemical methods, multivariate statistical methods, and multi-isotope tracing techniques were integrated to clarify the genesis of the karst groundwater system in the Sichuan Basin, southwestern China. Three clusters of groundwater samples were identified in the study area. The hydrochemical type of Cluster I and Cluster II waters was mainly HCO3-Ca type, and hydrochemical type of Cluster III water was dominated by HCO3·SO4-Ca type. The main processes dominating hydrochemical compositions consist of sulfide oxidative dissolution, carbonate dissolution, positive cation exchange, and human activities. The oxidation of sulfides exposed to air and water during coal mining is the primary source of the elevated SO42⁻ concentrations. Positive cation exchange resulted in higher Na⁺ concentrations, and agricultural activities added NO3⁻, Cl⁻, and K⁺ ions to the aquifers. Atmospheric precipitation was the major recharge source. Groundwater is also influenced by evaporation and mineral dissolution. This study developed a hydrogeological conceptual model for the basin karst groundwater system within coal-mining activities. These findings provide valuable information for the sustainable development of karst groundwater resources.

受煤矿开采影响的岩溶地下水系统较为复杂,制约了地下水资源的可持续管理。本文综合运用水化学方法、多元统计方法和多同位素示踪技术,对四川盆地岩溶地下水系统的成因进行了研究。在研究区内确定了3组地下水样本。聚类I和聚类II水的水化学类型以HCO3- ca型为主,聚类III水的水化学类型以HCO3·SO4-Ca型为主。水化学组成的主要过程包括硫化物氧化溶解、碳酸盐溶解、正离子交换和人类活动。在采煤过程中暴露在空气和水中的硫化物的氧化是SO42浓度升高的主要来源。正阳离子交换导致Na +浓度升高,农业活动给含水层增加了NO3⁻、Cl⁻和K⁺的离子。大气降水是主要补给源。地下水也受到蒸发和矿物溶解的影响。本文建立了煤矿开采过程中盆地岩溶地下水系统的水文地质概念模型。这些发现为岩溶地下水资源的可持续开发提供了有价值的信息。
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引用次数: 0
Assessing long-term eco-environmental quality dynamics in Akarçay River Basin (1985–2020) using Remote Sensing Ecological Index (RSEI) 基于遥感生态指数(RSEI)的阿喀拉迪河流域1985-2020年长期生态环境质量动态评价
IF 2.8 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 DOI: 10.1007/s12665-025-12701-7
Nur Yagmur Aydin, Filiz Bektas Balcik

Understanding long-term changes in Eco-Environment Quality (EEQ) is vital for managing arid ecosystems under increasing anthropogenic pressure and climate variability. This study investigated the spatio-temporal dynamics of EEQ in the Akarçay Closed Basin from 1985 to 2020. We utilized Landsat-5 TM and Landsat-8 OLI images processed on the Google Earth Engine (GEE) platform. To assess EEQ of the basin, The Remote Sensing Ecological Index (RSEI), constructed from greenness, wetness, heat (LST), and dryness (NDBSI) indicators, was computed at five-year intervals. Principal Component Analysis (PCA) was applied to derive RSEI, and Geographical Detector analysis was used to identify key natural and anthropogenic drivers. Results indicated that NDBSI and LST had the strongest influence on RSEI, with NDBSI emerging as the dominant indicator. RSEI values were lowest in 1990 (0.267) and 2000 (0.303), and highest in 2010 (0.417). A transition was observed from fair to moderate and good ecological classes between 1985 and 2020. Spatial heterogeneity in EEQ was largely shaped by temperature, land use/land cover, and population density. Furthermore, Hotspot analysis and the Mann-Kendall trend test were employed to examine the spatio-temporal consistency of the RSEI results, revealing persistent patterns of degradation and improvement. This study demonstrates the effectiveness of RSEI for long-term environmental monitoring and provides a comprehensive scientific basis for developing sustainable management strategies in arid basins.

了解生态环境质量(EEQ)的长期变化对于管理日益增加的人为压力和气候变率下的干旱生态系统至关重要。研究了1985 - 2020年阿卡拉帕拉河闭盆地EEQ的时空动态特征。我们使用了在谷歌地球引擎(GEE)平台上处理的Landsat-5 TM和Landsat-8 OLI图像。为了评估流域的EEQ,每隔5年计算一次由绿度、湿度、热量(LST)和干燥度(NDBSI)指标组成的遥感生态指数(RSEI)。采用主成分分析(PCA)导出RSEI,采用地理探测器分析(Geographical Detector Analysis)识别主要自然和人为驱动因素。结果表明,NDBSI和LST对RSEI的影响最大,NDBSI成为主导指标。RSEI值最低的年份是1990年(0.267)和2000年(0.303),最高的年份是2010年(0.417)。从1985年到2020年,生态等级从一般到中等和良好。EEQ的空间异质性主要受温度、土地利用/土地覆盖和人口密度的影响。此外,利用热点分析和Mann-Kendall趋势检验对RSEI结果的时空一致性进行了检验,揭示了持续的退化和改善模式。该研究证明了RSEI长期环境监测的有效性,为制定干旱流域可持续管理策略提供了全面的科学依据。
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引用次数: 0
Multi-stage instability mechanisms and risk analysis of accumulation landslides under sequential earthquake-rainfall actions: a case study 序贯地震-降雨作用下堆积性滑坡多阶段失稳机制及风险分析
IF 2.8 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-11-26 DOI: 10.1007/s12665-025-12688-1
Xuehan Zhao, Xiaodong Fu, Kai Wu, Zhenping Zhang, Tian Xi, Jingyu Kang, Qian Sheng

Strong seismic events can induce co-seismic slope instability, and the subsequent rainfall can further aggravate the damage within accumulation landslides, posing compounded hazards. Understanding the multi-stage failure mechanisms and assessing the associated risks under sequential earthquake–rainfall conditions are vital for disaster prevention in seismic regions. This study focuses on the K3-H05 landslide along the Hailuogou Scenic Road, triggered by the 2022 Luding Earthquake. A simplified pre- and post-event landslide model was constructed based on UAV imagery, and the dynamic damage to the slope induced by seismic shaking was analyzed through the Limit Equilibrium Method (LEM) and the Newmark permanent displacement analysis. Coupled stress–seepage simulations, incorporating regional rainfall data, were employed to evaluate slope stability under post-seismic precipitation conditions. Moreover, the secondary instability process was simulated using the Finite Volume Method (FVM) incorporating (mu left( I right)) rheological constitutive model. The results indicate that seismic acceleration is amplified significantly at slope crests and the interface between loose accumulation layer and bedrock, with permanent displacement corresponding to “super high” risk level, consistent with field observations. The post-earthquake degradation of the soil structure, combined with sustained rainfall, reduced the slope safety factor below unity, substantially elevating the likelihood of secondary failure. The landslide subsequently destroyed portions of the scenic road and deposited substantial material at the slope toe. Based on the findings, post-disaster reconstruction strategies such as elevated bridges and piled slab walls are proposed to mitigate future risks. This research provides technical references for slope risk prevention and control in high-intensity seismic zones.

强地震事件可诱发同震边坡失稳,后续降雨可进一步加重堆积性滑坡内部的破坏,构成复合灾害。了解连续地震-降雨条件下的多阶段破坏机制并评估相关风险对于震区的灾害预防至关重要。本文以2022年泸定地震引发的海螺沟景区公路K3-H05滑坡为研究对象。基于无人机图像构建了简化的滑坡前后模型,采用极限平衡法(LEM)和Newmark永久位移分析方法分析了地震震动对边坡的动力损伤。结合区域降雨数据,采用耦合应力-渗流模拟方法对震后降水条件下边坡稳定性进行了评价。此外,采用有限体积法(FVM)结合(mu left( I right))流变本构模型对二次失稳过程进行了模拟。结果表明,坡顶和松散堆积层与基岩界面处地震加速度明显增强,永久位移对应“超高”风险等级,与现场观测结果一致。震后土体结构的退化,加之持续降雨,使边坡安全系数降至1以下,大大提高了二次破坏的可能性。山体滑坡随后摧毁了部分风景优美的道路,并在坡脚沉积了大量物质。根据研究结果,提出了高架桥梁和堆板墙等灾后重建策略,以减轻未来的风险。本研究为高烈度地震区边坡风险防控提供了技术参考。
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引用次数: 0
Soil gas radon (Rn 222) in vadose zone of A cultivated wetland in Southwest Nigeria 尼日利亚西南部某人工湿地渗透带土壤气氡(rn222
IF 2.8 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-11-26 DOI: 10.1007/s12665-025-12706-2
Mustapha Kola Lawal, Michael Olatunde Oni, Moruffdeen Adedapo Adabanija, Emmanuel Abiodun Oni, Riliwan Damilola Abioye, Abraham Adewale Aremu
<div><p>Radon migration, diffusion coefficients and relationships with petrophysical properties of subsoil in a wetland may differ from those in similar subsoil in non-wetland areas due to water constituents of the subsoil material of the wetland as well as irregular radon interactions with air and water. The level of radon in subsoil and influence of the subsoil properties within the vadose zone of a wetland intended for use for intensive cultivation for increased food security by small holder Farmers was investigated in the current study. For this purpose, concentration levels of Rn-222 were measured in-situ using active measurement technique RAD7 at 0.2 m depth interval to total depth of 1.0 m, and 20 m sampling interval corresponding to points of increased and decreased resistivity with depth inferred from the electrical resistivity tomogram (ERT) of the wetland along 8 traverses. Diffusion coefficients were estimated empirically, while the subsoil properties, namely, Atterberg limits, porosity, permeability, and hydraulic conductivity, were determined employing appropriates American Standard of Testing of Materials (ASTM) procedures using disturbed soils samples recovered from 1.0 m deep pits dug at each sampling point. The subsoil which made up the vadose zone comprises silty sands of high plasticity (SM<sub>HP</sub>) as well as clayey sand (SC) of low plasticity (SC<sub>LP</sub>), medium plasticity (SC<sub>MP</sub>), and high plasticity (SC<sub>HP</sub>). The increasing order of abundance of median Rn-222 concentrations in each subsoil: SM<sub>HP</sub> (544.5 Bqm<sup>− 3</sup>) < SC (775 Bqm<sup>− 3</sup>), and SC<sub>LP</sub> (715.25 Bqm<sup>− 3</sup>) < SC<sub>MP</sub> (792.0 Bqm<sup>− 3</sup>) < SC<sub>HP</sub> (797.0 Bqm<sup>− 3</sup>) suggests that Rn-222 concentrations in soils are dependent on the plasticity of the soil and/or the amount of clay present. The increasing order of mean moisture contents and porosity with <sup>222</sup>Rn concentrations: SC<sub>LP</sub> (14.50%, 715.25 Bqm<sup>− 3</sup>) < SC<sub>MP</sub> (19.92%, 792.0 Bqm<sup>− 3</sup>) < SC<sub>HP</sub> (22.75%, 797.0 Bqm<sup>− 3</sup>) and SC<sub>LP</sub> (44.60%, 715.25 Bqm<sup>− 3</sup>) < SC<sub>MP</sub> (44.61%, 792.0 Bqm<sup>− 3</sup>) < SC<sub>HP</sub> (45.13%, 797.0 Bqm<sup>− 3</sup>), respectively, suggests direct interrelation between <sup>222</sup>Rn concentration and each of the moisture contents and porosity for the sub-clayey sands. These are in agreements with relationships obtained for soils other than wetland and reported in several literatures. The inverse correlation between <sup>222</sup>Rn concentration and each of the moisture contents and percentage of gravel in clayey sands of high plasticity, however, was inconsistent with that found for soils other than wetland. Similarly, the inverse relationship between radon diffusion coefficient and porosity as exemplified by increased order of mean and median radon diffusion coeffic
由于湿地底土材料的水成分以及氡与空气和水的不规则相互作用,湿地底土的氡迁移、扩散系数及其与岩石物理性质的关系可能不同于非湿地地区的类似底土。在目前的研究中,调查了拟用于集约耕作以提高小农粮食安全的湿地渗透带内底土中的氡水平和底土性质的影响。为此,采用主动测量技术RAD7,在0.2 m深度至1.0 m总深度区间,沿8条穿越湿地电阻率层析图(ERT)推断电阻率随深度增加和减少的点对应的20 m采样间隔,原位测量了Rn-222的浓度水平。扩散系数是根据经验估计的,而底土特性,即阿特伯格极限、孔隙度、渗透率和水力导电性,是采用适当的美国材料测试标准(ASTM)程序确定的,使用从每个采样点挖的1.0 m深的坑中回收的扰动土样品。构成渗透带的底土包括高塑性粉质砂(SMHP)和低塑性(SCLP)、中塑性(SCMP)和高塑性(SCHP)粘土砂(SC)。各底土中中位Rn-222浓度丰度的递增顺序为:SMHP (544.5 Bqm−3)< SC (775 Bqm−3)和SCLP (715.25 Bqm−3)< SCMP (792.0 Bqm−3)< SCHP (797.0 Bqm−3),表明土壤中的Rn-222浓度取决于土壤的可塑性和/或存在的粘土量。222Rn浓度下平均含水率和孔隙度的递增顺序依次为:SCLP (14.50%, 715.25 Bqm−3)< SCMP (19.92%, 792.0 Bqm−3)< SCHP (22.75%, 797.0 Bqm−3)和SCLP (44.60%, 715.25 Bqm−3)< SCMP (44.61%, 792.0 Bqm−3)< SCHP (45.13%, 797.0 Bqm−3),表明222Rn浓度与亚粘土砂岩含水率和孔隙度之间存在直接的相关关系。这与一些文献报道的湿地以外土壤的关系一致。在高塑性粘土砂中,222Rn浓度与各含水率和砂砾百分比呈负相关关系,但与湿地以外土壤的结果不一致。同样,氡扩散系数与孔隙度呈反比关系,粘土砂底土氡扩散系数均值和中位数依次增大:SCHP(1.16 10−6 m2 s−1,1.11 × 10−6 m2 s−1)<; SCMP(1.32 10−6 m2 s−1,1.34 × 10−6 m2 s−1)< scp (1.91 × 10−6 m2 s−1,1.88 × 10−6 m2 s−1),平均孔隙度依次减小:SCHP (45.13%) > SCMP (44.61%) > scp(44.60%)与湿地以外土壤的结果不一致。然而,氡扩散系数的增加顺序:SCHP(1.16 10−6 m2 s−1,1.11 × 10−6 m2 s−1)<; SCMP(1.32 10−6 m2 s−1,1.34 × 10−6 m2 s−1)< SCLP (1.91 × 10−6 m2 s−1,1.88 × 10−6 m2 s−1)与水分含量的减少顺序:SCHP (22.75%) > SCMP (19.92%) >; SCLP(14.50%)之间呈反比关系,即使在除湿地以外的土壤中也是如此。在湿地渗透带的底土中,222Rn的中位数浓度为1150 Bqm−3,如果低于10,000 Bqm−3瑞典标准,则可以认为风险相对较低。这表明土壤中222Rn氡浓度较低,表明对微生物群落的损害没有风险或风险较低。
{"title":"Soil gas radon (Rn 222) in vadose zone of A cultivated wetland in Southwest Nigeria","authors":"Mustapha Kola Lawal,&nbsp;Michael Olatunde Oni,&nbsp;Moruffdeen Adedapo Adabanija,&nbsp;Emmanuel Abiodun Oni,&nbsp;Riliwan Damilola Abioye,&nbsp;Abraham Adewale Aremu","doi":"10.1007/s12665-025-12706-2","DOIUrl":"10.1007/s12665-025-12706-2","url":null,"abstract":"&lt;div&gt;&lt;p&gt;Radon migration, diffusion coefficients and relationships with petrophysical properties of subsoil in a wetland may differ from those in similar subsoil in non-wetland areas due to water constituents of the subsoil material of the wetland as well as irregular radon interactions with air and water. The level of radon in subsoil and influence of the subsoil properties within the vadose zone of a wetland intended for use for intensive cultivation for increased food security by small holder Farmers was investigated in the current study. For this purpose, concentration levels of Rn-222 were measured in-situ using active measurement technique RAD7 at 0.2 m depth interval to total depth of 1.0 m, and 20 m sampling interval corresponding to points of increased and decreased resistivity with depth inferred from the electrical resistivity tomogram (ERT) of the wetland along 8 traverses. Diffusion coefficients were estimated empirically, while the subsoil properties, namely, Atterberg limits, porosity, permeability, and hydraulic conductivity, were determined employing appropriates American Standard of Testing of Materials (ASTM) procedures using disturbed soils samples recovered from 1.0 m deep pits dug at each sampling point. The subsoil which made up the vadose zone comprises silty sands of high plasticity (SM&lt;sub&gt;HP&lt;/sub&gt;) as well as clayey sand (SC) of low plasticity (SC&lt;sub&gt;LP&lt;/sub&gt;), medium plasticity (SC&lt;sub&gt;MP&lt;/sub&gt;), and high plasticity (SC&lt;sub&gt;HP&lt;/sub&gt;). The increasing order of abundance of median Rn-222 concentrations in each subsoil: SM&lt;sub&gt;HP&lt;/sub&gt; (544.5 Bqm&lt;sup&gt;− 3&lt;/sup&gt;) &lt; SC (775 Bqm&lt;sup&gt;− 3&lt;/sup&gt;), and SC&lt;sub&gt;LP&lt;/sub&gt; (715.25 Bqm&lt;sup&gt;− 3&lt;/sup&gt;) &lt; SC&lt;sub&gt;MP&lt;/sub&gt; (792.0 Bqm&lt;sup&gt;− 3&lt;/sup&gt;) &lt; SC&lt;sub&gt;HP&lt;/sub&gt; (797.0 Bqm&lt;sup&gt;− 3&lt;/sup&gt;) suggests that Rn-222 concentrations in soils are dependent on the plasticity of the soil and/or the amount of clay present. The increasing order of mean moisture contents and porosity with &lt;sup&gt;222&lt;/sup&gt;Rn concentrations: SC&lt;sub&gt;LP&lt;/sub&gt; (14.50%, 715.25 Bqm&lt;sup&gt;− 3&lt;/sup&gt;) &lt; SC&lt;sub&gt;MP&lt;/sub&gt; (19.92%, 792.0 Bqm&lt;sup&gt;− 3&lt;/sup&gt;) &lt; SC&lt;sub&gt;HP&lt;/sub&gt; (22.75%, 797.0 Bqm&lt;sup&gt;− 3&lt;/sup&gt;) and SC&lt;sub&gt;LP&lt;/sub&gt; (44.60%, 715.25 Bqm&lt;sup&gt;− 3&lt;/sup&gt;) &lt; SC&lt;sub&gt;MP&lt;/sub&gt; (44.61%, 792.0 Bqm&lt;sup&gt;− 3&lt;/sup&gt;) &lt; SC&lt;sub&gt;HP&lt;/sub&gt; (45.13%, 797.0 Bqm&lt;sup&gt;− 3&lt;/sup&gt;), respectively, suggests direct interrelation between &lt;sup&gt;222&lt;/sup&gt;Rn concentration and each of the moisture contents and porosity for the sub-clayey sands. These are in agreements with relationships obtained for soils other than wetland and reported in several literatures. The inverse correlation between &lt;sup&gt;222&lt;/sup&gt;Rn concentration and each of the moisture contents and percentage of gravel in clayey sands of high plasticity, however, was inconsistent with that found for soils other than wetland. Similarly, the inverse relationship between radon diffusion coefficient and porosity as exemplified by increased order of mean and median radon diffusion coeffic","PeriodicalId":542,"journal":{"name":"Environmental Earth Sciences","volume":"84 23","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145613068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modeling land use change impacts and identifying erosion hotspots using RUSLE in a northwestern Ethiopian highland watershed 利用RUSLE在埃塞俄比亚西北部高原流域模拟土地利用变化影响并识别侵蚀热点
IF 2.8 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-11-26 DOI: 10.1007/s12665-025-12656-9
Lemlem Sema Gebremariam, Anwar Assefa Adem, Ali Fares, Temesgen Gashaw Tarkegn, Yihun Taddele Dile, Abeyou Wale Worqlul, Hailu Kendie Addis

This study aimed to assess the impact of land use land cover (LULC) changes on soil loss (SL) and sediment yield (SY) using the Revised Universal Soil Loss Equation (RUSLE) model in the Angereb watershed. The 1991, 2001, 2011, and 2021 Landsat TM and OLI images were used for classification. Cover management (C) and conservation practice (P) factors of the RUSLE model were prepared for each LULC map. The other three RUSLE factors, such as slope length and steepness (LS), erosivity (R), and erodibility (K) factors, were prepared from digital elevation model (DEM), rainfall, and soil data, respectively. The sediment delivery ratio (SDR) and the SL maps were used to calculate the mean annual SY of the watershed. Results indicated that cultivated land expanded from 29.6% in 1991 to 42.6% in 2021 at the expense of forest and bush/shrubland. The change in LULC from 1991 to 2021 increased the mean annual SL and SY by 57% and 39%, respectively. The erosion rate increased from 107 t ha⁻¹ yr⁻¹to 134.3 t ha⁻¹ yr⁻¹ on cultivated land between 1991 and 2021. In the Angereb watershed, areas classified under very severe erosion (> 50 t ha⁻¹ yr⁻¹) cover 23.1% of the total area but contribute approximately 99.4% of the overall soil loss, predominantly occurring on steep slopes. These steeply sloped regions represent critical erosion risk zones and should be prioritized for targeted soil and water conservation interventions. The study’s findings offer valuable insights for evidence-based policymaking and the development of effective watershed management strategies.

基于修正通用土壤流失方程(RUSLE)模型,研究了Angereb流域土地利用和土地覆盖变化对土壤流失(SL)和产沙量(SY)的影响。使用1991年、2001年、2011年和2021年的Landsat TM和OLI图像进行分类。为每张LULC地图准备RUSLE模型的覆盖管理因子(C)和保护实践因子(P)。另外三个RUSLE因子,即坡度长度和陡度(LS)、侵蚀力(R)和可蚀性(K)因子,分别由数字高程模型(DEM)、降雨和土壤数据制备。利用输沙比(SDR)和SL图计算流域年平均SY。结果表明:耕地面积从1991年的29.6%增加到2021年的42.6%,森林和灌丛林地面积减少;1991 - 2021年LULC的变化使年平均SL和SY分别增加了57%和39%。从1991年到2021年,耕地的侵蚀率从107‰(⁻- 1)增加到134.3‰(⁻)。在Angereb流域,被划分为非常严重侵蚀(50公顷- 1年)的地区占总面积的23.1%,但造成了大约99.4%的土壤流失,主要发生在陡峭的山坡上。这些陡坡地区是严重的侵蚀风险区,应优先采取有针对性的水土保持干预措施。研究结果为基于证据的政策制定和有效流域管理战略的制定提供了宝贵的见解。
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引用次数: 0
Mapping groundwater quality distribution in Northwest Iran: combining machine and deep learning and Borda scoring algorithms 绘制伊朗西北部地下水质量分布:结合机器和深度学习以及Borda评分算法
IF 2.8 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-11-26 DOI: 10.1007/s12665-025-12694-3
Ali Nasiri Khiavi, Mir Masoud Kheirkhah Zarkesh, Bagher Ghermezcheshmeh, Bayramali Beyrami

The degradation of groundwater quality due to human activities and environmental changes has become a global challenge, especially in semi-arid regions that are highly dependent on these resources. This study presented a comprehensive mapping of Groundwater Quality (GQ) distribution in Northwest Iran, utilizing a combination of Deep Learning (DL) and Machine Learning (ML) algorithms alongside the Borda scoring method for validation. Based on research methodology, the study focused on a range of WQ parameters, including potassium (K+), sodium (Na+), magnesium (Mg2+), calcium (Ca2+), sulfate (SO42−), chloride (Cl), bicarbonate (HCO3), pH levels, Total Dissolved Solids (TDS), and Electrical Conductivity (EC). After creating raster maps of the chemical parameters of GQ, critical and non-critical quality points were identified using the Borda scoring algorithm based on Game Theory (GT). Once these points were established, DL and ML algorithms were employed in Python to spatially map GQ. Finally, water quality classes were categorized into five levels—very low, low, moderate, high, and very high—using ArcGIS software. Key quantitative findings included Total Hardness (TH) values ranging from 2.06 mg/L in Abgharm to 31.92 mg/L in Hamid Bolaghi, and Sodium Adsorption Ratio (SAR) values between 0.1 and 1.89, indicating varying soil sodicity risks. Strong correlations were observed among specific ions, notably a correlation of 0.93 between Na+ and Cl. Borda scoring highlighted significant groundwater concerns, with the highest score of 260 at sampling point 26, while points 21, 25, and 33 showed lower scores of 32, 39, and 70, respectively. Based on the results, LSTM emerged as the most effective model among the DL algorithms, exhibiting the lowest MAE (0.12) and MSE (0.02), along with a high R² value of 0.89 and an AUC of 0.94. Spatial zoning identified areas of very low GQ, particularly in the central and eastern regions, which necessitated targeted management interventions. This research underscored the effectiveness of combining ML and DL methodologies with scoring systems to enhance GQ assessments, thereby fostering improved water management practices in the region.

由于人类活动和环境变化导致的地下水质量退化已成为一个全球性挑战,特别是在高度依赖这些资源的半干旱地区。本研究利用深度学习(DL)和机器学习(ML)算法以及Borda评分方法进行验证,对伊朗西北部的地下水质量(GQ)分布进行了全面的映射。基于研究方法,该研究重点关注了一系列WQ参数,包括钾(K+)、钠(Na+)、镁(Mg2+)、钙(Ca2+)、硫酸盐(SO42−)、氯化物(Cl−)、碳酸氢盐(HCO3−)、pH值、总溶解固体(TDS)和电导率(EC)。在创建GQ化学参数的栅格图后,使用基于博弈论(GT)的Borda评分算法识别关键和非关键质量点。一旦建立了这些点,在Python中使用DL和ML算法对GQ进行空间映射。最后,利用ArcGIS软件将水质等级划分为5个等级——极低、低、中等、高和极高。关键的定量结果包括:总硬度(TH)值在Abgharm的2.06 mg/L到Hamid Bolaghi的31.92 mg/L之间,钠吸附比(SAR)值在0.1 ~ 1.89之间,表明土壤的碱化风险不同。特定离子之间存在较强的相关性,其中Na+和Cl−的相关性为0.93。Borda得分突出了地下水的严重问题,在采样点26处得分最高,为260分,而在采样点21、25和33处得分较低,分别为32、39和70分。结果表明,LSTM是DL算法中最有效的模型,MAE(0.12)和MSE(0.02)最低,R²值为0.89,AUC为0.94。空间区划确定了文化智商非常低的地区,特别是在中部和东部地区,这需要有针对性的管理干预。这项研究强调了将ML和DL方法与评分系统相结合以增强GQ评估的有效性,从而促进了该地区水资源管理实践的改进。
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引用次数: 0
Recent trends in hyporheic zone research 下潜带研究的新动向
IF 2.8 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-11-26 DOI: 10.1007/s12665-025-12708-0
Huan Wang, Zhenfei Zhang, Tianyuan Zheng, Meng Chen, Yunhai Fang

The hyporheic zone is an active ecotone between surface water and groundwater where strong biogeochemical reactions occur, and it underpins various ecosystem functions. In the 21st century, the hyporheic zone has become a research hotspot due to its important role in biogeochemical activities; however, no comprehensive and systematic review of the current literature on the hyporheic zone has been conducted. In this study, we conducted scientometric analysis of 2,308 articles related to the hyporheic zone in the Web of Science Core Collection database using CiteSpace. This article summarizes the literature on the hyporheic zone in the 21st century based on scientometric visualization, thoroughly capturing the recent developments in this field. In addition, we identified and quantitatively analyzed the top authors, publications, references, institutions, countries, and relevant disciplines. Based on the results, we clarify the current developments, research hotspots, and frontiers of research on the hyporheic zone. We also predict the future research trends in this field. This review provides a comprehensive knowledge framework that can provide a detailed and broad perspective on the status and future trends of this interdisciplinary field.

潜流带是地表水和地下水之间的活跃过渡带,是发生强烈生物地球化学反应的地方,是各种生态系统功能的基础。在21世纪,潜回带因其在生物地球化学活动中的重要作用而成为研究热点;然而,目前还没有对隐隐带的文献进行全面和系统的回顾。在本研究中,我们使用CiteSpace对Web of Science Core Collection数据库中与隐隐带相关的2308篇文章进行了科学计量学分析。本文综述了21世纪以来基于科学测量可视化的拟隐带研究文献,全面介绍了该领域的最新进展。此外,我们确定并定量分析了顶级作者、出版物、参考文献、机构、国家和相关学科。在此基础上,阐述了隐隐带的研究现状、研究热点和前沿。展望了该领域未来的研究趋势。这篇综述提供了一个全面的知识框架,可以为这一跨学科领域的现状和未来趋势提供一个详细和广阔的视角。
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引用次数: 0
Long- and short-term impacts of lake dry-downs on groundwater geochemistry for a sinkhole lake in Florida 湖泊干涸对佛罗里达州一个天坑湖地下水地球化学的长期和短期影响
IF 2.8 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-11-26 DOI: 10.1007/s12665-025-12718-y
Kyle Compare, Ming Ye

Lake Jackson in Florida, USA has experienced multiple lake dry-downs, in which the lake partially drained through sinkholes within the lakebed into the karstic Upper Floridan aquifer. This study focused on the lake dry-downs in 2021–2022 and investigated their impacts on groundwater geochemistry at a groundwater monitoring well about 9 km downgradient of the lake and at Wakulla Spring, a first-magnitude spring about 32 km downgradient of the lake. Major ion concentrations were measured for water samples collected at the lake, the monitoring well, and the spring throughout the dry-down occurrences to monitor hydrochemical changes over these events. Following the dry-down events, the hydrochemical facies at the monitoring well shifted from a calcium magnesium bicarbonate hydrochemical facies to a mixed type hydrochemical facies, followed by a return to the original hydrochemical facies within eight days. A three end-member mixing model between meteoric water, water reacting with minerals in the lakebed formation, and aquifer water suggests that a pulse of lake water diluted the calcium carbonate-rich aquifer water and transported ions from weathered minerals in a confining unit below the lakebed. These chemical impacts were not observed at Wakulla Spring, suggesting that the lake water was undetectable after flowing 32 km in the carbonate aquifer. This study showed for the first time in literature that, while lake dry-downs had notable short-term impacts on the water chemistry of karst aquifers, these impacts did not persist over long time periods or long distances.

美国佛罗里达州的杰克逊湖经历了多次湖泊干涸,其中部分湖泊通过湖床内的天坑排到岩溶的上佛罗里达含水层。本研究以2021-2022年湖泊干枯为研究对象,在湖下坡度约9 km的地下水监测井和湖下坡度约32 km的一级泉水Wakulla泉处考察了干枯对地下水地球化学的影响。主要离子浓度测量了在湖泊、监测井和泉水中收集的水样,以监测这些事件中的水化学变化。干油事件发生后,监测井的水化学相从碳酸氢钙镁水化学相转变为混合型水化学相,随后在8天内恢复到原始水化学相。大气水、湖床地层中与矿物质反应的水和含水层水之间的三端元混合模型表明,湖水脉冲稀释了富含碳酸钙的含水层水,并在湖床下方的一个封闭单元中从风化矿物中输送离子。在瓦库拉泉没有观察到这些化学影响,这表明湖水在碳酸盐含水层中流动了32公里后是无法检测到的。这项研究首次在文献中表明,虽然湖泊干涸对喀斯特含水层的水化学有显著的短期影响,但这些影响不会持续很长时间或很长的距离。
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引用次数: 0
Risk of algal blooms by stratification and separated hydrologic regime: large cascade reservoirs in Lancang River Basin, China 分层和分离水文条件下的藻华风险:澜沧江流域大型梯级水库
IF 2.8 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-11-24 DOI: 10.1007/s12665-025-12692-5
Mingwei Guo, Shilu Wang, Kevin M. Yeager, Yuchun Wang, Shehong Li, Yufei Bao, Kun Liu, Qingguang Li, Di Tan, Xiangfeng Han

Impacts on the ecological health of the numerous reservoirs located in the Lancang River Basin (LRB), China has drawn significant attention in recent years. Previous studies here mainly dealt with the conveyance and interception of nutrients by these reservoirs. This study focuses on the influences of hydrological processes in these reservoirs on water chemistry and the implications for host ecosystems. Longitudinal variations of water temperature, water chemistry, and H and O isotope values in the main stem of the Lancang River, and vertical variations in the reservoirs, were analyzed in relation to water sources and mixing. Results indicate that the main stem river waters enter the middle/bottom layers of the reservoirs through interflow/underflow in warm/cold seasons, and that waters from the tributaries enter the surface of the reservoirs through overflow. The large reservoirs are permanently stratified, which is verified by variations of δ18O values versus Cl concentrations. Consequently, surface waters cannot be fully renewed, and phosphorus derived mainly from tributary inflows tends to accumulate in surface layers. These conditions facilitate the development of algal blooms. The mechanism proposed here explains the progressive increases in algal densities observed in the large reservoirs. This study suggests that coupling of permanent stratification and distinctive circulation patterns substantially raises the risk of the development of algal blooms in these large reservoirs. Therefore, long-term and comprehensive observations focused on thermal stratification, water circulation, nutrient cycling, and phytoplankton growth are an urgent task in the future.

澜沧江流域众多水库对生态健康的影响是近年来备受关注的问题。以往的研究主要是研究这些水库对营养物的输送和截留。研究了水库水文过程对水化学的影响及其对宿主生态系统的影响。分析了澜沧江干流水温、水化学和H、O同位素的纵向变化特征,以及各水库的纵向变化特征与水源和混合的关系。结果表明:暖季和寒季干流主要通过中流/下流方式进入水库中层/底层,支流主要通过溢流方式进入水库表层。δ18O值随Cl−浓度的变化证实了大型储层是永久分层的。因此,地表水不能完全更新,主要来自支流流入的磷往往积聚在表层。这些条件促进了藻华的发展。这里提出的机制解释了在大型水库中观察到的藻类密度的逐渐增加。这项研究表明,永久分层和独特循环模式的耦合大大增加了这些大型水库中藻华发展的风险。因此,对热分层、水循环、养分循环和浮游植物生长进行长期、全面的观测是未来的迫切任务。
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引用次数: 0
Reconstruction of palaeoenvironment and vegetation dynamics during the late Permian, Raniganj Coalfield, India: insights from megafossils, palynomorphs, and biomarkers 印度Raniganj煤田晚二叠世古环境和植被动态重建:来自巨化石、巨形态和生物标志物的启示
IF 2.8 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-11-24 DOI: 10.1007/s12665-025-12620-7
Anita Chattoraj, Mrutyunjaya Sahoo, S. Suresh Kumar Pillai, Runcie Paul Mathews, Srikanta Murthy, Anju Saxena, Sandip Majumder, Bibin Mathew

The present work elucidates late Permian vegetation dynamics and palaeoenvironment by analysing the adpressed plant fossils, palynological composition, organic geochemistry, petrography, and FTIR data procured from the sediments of the Bhanora coal mine, Raniganj Coalfield, Damodar Basin, India. The study enhances our understanding of the biostratigraphic age assessment and subtleties of the depositional environment of peat-forming vegetation during the late Permian (Lopingian). A macrofossil assemblage belonging to the typical ‘Glossopteris Flora’ is retrieved, comprising the major elements Glossopteridales-leaf form Glossopteris (23 species), seeds-Samaropsis, Dolianitia, and fructification-Ottokaria, followed by the minor elements Equisetales-Schizoneura, Phyllotheca, and stem axes, and Coenopteridales-Botrychiopsis. The palynological analysis asserts the presence of the Densipollenites magnicorpus assemblage, suggesting a late Permian (Lopingian) age for the studied rock deposits. The palynocomposition reveals the dominance of pollen showing affinities with Glosspotridales, followed by Coniferales, Peltaspermales, Cordaitales, and trilete spores of Filicales and Lycopsidales. The morphological structures, such as the organization of the central body, saccus infrastructures, patterns of striation, and taeniae, indicate the prevalence of a warm climate and high humidity during the deposition of these sediments. The geochemical study of coal reveals a bimodal distribution, suggesting multiple organic matter inputs, while the shale sample shows a unimodal distribution, suggesting increased input of microbially derived organic matter. The higher CH₂/CH₃ ratio and vitrinite reflectance further indicate the lower thermal maturity of the studied coal. The vitrinite reflectance analysis shows a ‘high volatile bituminous’ rank of the studied sample. This study indicates that the Raniganj Formation (Lopingian) marks the pinnacle of Permian Gondwana Flora, following its demise with the advent of Triassic environmental shifts.

本文通过对印度达摩达尔盆地Raniganj煤田Bhanora煤矿沉积物中植物化石、孢粉组成、有机地球化学、岩石学和FTIR数据的分析,阐明了晚二叠世植被动态和古环境。该研究提高了我们对晚二叠世(洛平纪)泥炭形成植被生物地层年龄评价和沉积环境精细性的认识。检索了属于典型“舌蕨植物区系”的大化石组合,包括主要元素舌蕨(23种),种子- samaropsis, Dolianitia和果实- ottokaria,其次是次要元素equisetala - schizoneura, Phyllotheca和茎轴,以及coenopteridals - botrychiopsis。孢粉学分析表明存在Densipollenites magnicorpus组合,表明所研究的岩石矿床的年龄为晚二叠纪(洛平纪)。孢粉组成以Glosspotridales为主,其次为Coniferales、peltaspermale、Cordaitales,其次为Filicales和Lycopsidales的三联体孢子。中心体的组织、囊状结构、条纹模式和带状等形态结构表明,这些沉积物在沉积过程中普遍存在温暖的气候和高湿的环境。煤的地球化学特征为双峰分布,表明有机质输入较多;页岩的地球化学特征为单峰分布,表明微生物源有机质输入增加。较高的CH₂/CH₃比值和镜质体反射率进一步表明煤的热成熟度较低。镜质组反射率分析表明,所研究样品具有“高挥发性沥青”等级。该研究表明,随着三叠纪环境变化的到来,拉尼甘杰组(Lopingian)标志着二叠纪冈瓦纳植物群的顶峰。
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引用次数: 0
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Environmental Earth Sciences
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