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Water reuse through managed aquifer recharge (MAR): assessment of regulations/guidelines and case studies 通过管理含水层补给(MAR)进行水再利用:法规/准则和案例研究的评估
IF 2 Q3 Environmental Science Pub Date : 2016-11-02 DOI: 10.2166/WQRJC.2016.022
Jie Yuan, M. I. Dyke, P. Huck
Managed aquifer recharge (MAR) with reclaimed water is an important water reuse application. As an intentional way of recharging water into aquifers, MAR can be used to address water shortages and contribute to sustainable water resources management practices. The establishment of a MAR system depends on the source of recharge water, the selection of a recharge method and site, the type of water treatment system, and the ultimate purpose of recovered water, and these components are closely related and integrated. However, at present, detailed regulations or guidelines that specifically guide MAR with reclaimed water are unavailable in most countries. The complexity of MAR systems and the lack of a sophisticated regulatory framework increase the difficulties of MAR implementation. This review provides an introduction to MAR with reclaimed water and a comparison of current worldwide water reuse regulations or guidelines, including a proposed approach for MAR implementation. An analysis of selected MAR with reclaimed water case studies was also done within the context of this proposed approach. This paper recommends the development of specific regulatory or design criteria, including a complete quantitative risk assessment framework for the evaluation and operation of MAR systems.
再生水管理含水层补给(MAR)是一种重要的水回用技术。作为向含水层补充水的一种有意的方式,MAR可用于解决水资源短缺问题并促进可持续水资源管理做法。MAR系统的建立取决于回灌水的来源、回灌方式和场地的选择、水处理系统的类型以及回收水的最终目的,这些组成部分是密切相关和综合的。然而,目前大多数国家都没有专门指导再生水MAR的详细法规或准则。MAR系统的复杂性和缺乏成熟的监管框架增加了MAR实施的困难。这篇综述介绍了再生水的MAR,并比较了目前世界范围内的水再利用法规或指南,包括MAR实施的建议方法。在此建议的方法范围内,还对选定的MAR与再生水案例研究进行了分析。本文建议制定具体的监管或设计标准,包括一个完整的定量风险评估框架,用于评估和运行MAR系统。
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引用次数: 30
Inter-laboratory validation of automated SPME-GC/MS for determination of pesticides in surface and ground water samples: sensitive and green alternative to liquid–liquid extraction 自动SPME-GC/MS测定地表水和地下水中农药的实验室间验证:灵敏和绿色替代液-液萃取
IF 2 Q3 Environmental Science Pub Date : 2016-11-02 DOI: 10.2166/WQRJC.2016.011
Ángel Rodríguez-Lafuente, Hamed Piri-Moghadam, H. Lord, Terry Obal, J. Pawliszyn
An automated solid-phase microextraction gas chromatography/mass spectometry (SPME-GC/MS) method was developed for the determination of semi-volatile pesticides from several classes with a wide range of polarities in an environmental matrix, and validated according to the rigorous standards of a large commercial laboratory reporting data requiring regulatory acceptance with the purpose of being used as a standard test protocol. The target analytes showed a detection limit of 0.05–1 μg L−1, good calibration linearity (R2 > 0.99) with a wide linear range of 0.05–20 μg L−1, and accuracy in the range of 80–110 at three levels of calibration with relative standard deviation below 7% by commercial polydimethylsiloxane/divinylbenzene (PDMS/DVB) SPME fiber. An extensive study between SPME and liquid–liquid extraction as a reference US EPA method was performed from several analytical aspects including sensitivity, accuracy, repeatability, and greenness. The SPME method was validated through split blind analyses of 16 fortified surface and ground water samples within 4 months at Maxxam Analytics, the reference laboratory, and the University of Waterloo. Both methods were shown to be very accurate, with the highest frequency of results falling in the 70–130% accuracy range. The SPME method was shown to be more sensitive than the LLE, while requiring a lower volume of sample.
开发了一种自动固相微萃取气相色谱/质谱(SPME-GC/MS)方法,用于在环境基质中测定几种具有广泛极性的半挥发性农药,并根据大型商业实验室报告数据的严格标准进行验证,这些数据需要监管机构的认可,目的是作为标准测试方案使用。目标分析物的检出限为0.05 ~ 1 μ L−1,线性范围为0.05 ~ 20 μ L−1,校准线性范围为R2 > 0.99,在3级校准时精度在80 ~ 110范围内,相对标准偏差小于7%。从灵敏度、准确性、可重复性和绿色度等几个分析方面对SPME和液液萃取作为参考的US EPA方法进行了广泛的研究。在4个月内,参考实验室Maxxam Analytics和滑铁卢大学对16个强化地表水和地下水样本进行了分盲分析,验证了SPME方法的有效性。这两种方法都非常准确,结果的最高频率在70-130%的准确度范围内。结果表明,SPME法比LLE法更灵敏,同时所需的样品体积更小。
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引用次数: 25
Phosphorus sorption kinetics and sorption capacity in agricultural drainage ditch sediments in reclaimed land, Kasaoka Bay, Japan 日本笠冈湾填海农田排水沟沉积物对磷的吸附动力学及吸附能力
IF 2 Q3 Environmental Science Pub Date : 2016-11-02 DOI: 10.2166/WQRJC.2016.019
Huy V. Nguyen, M. Maeda
Equilibrium analysis is essential to evaluate sorption capacity and to determine whether sediment acts as a source or sink of phosphorus (P). This study was carried out to determine whether or not the sediment in drainage ditches acts as a source or sink of P, evaluate phosphorus sorption kinetics, and determine the potential P sorption by using the Langmuir isotherm sorption model. Surface sediment (0–10 cm) and the overlying water were collected from three drainage ditches for the experiments. Results showed that the drainage ditch that was the most contaminated with P had the highest sediment zero-equilibrium phosphorus concentration (EPC 0 ). Because sediment EPC 0 of the three ditches was higher than water P concentration, they acted as a sink of P across the sediment interface. The kinetic sorption of sediments consisted of two stages that were quick and slow, regardless of the sampling sites. The amounts of P sorbed to sediments at equilibrium ( Q e ) ranged from 50.8 to 77.5 mg kg −1 . Phosphorus sorption capacity ( Q max ) of sediments ranged from 447.0–493.8 mg kg −1 with the constant related to binding energy ( K ) (0.140–0.171 L mg −1 ). The results from this study indicate the importance of ditch sediment in controlling P dynamics in discharge from agricultural farms.
平衡分析对于评价沉积物的吸附能力和确定沉积物是磷的来源还是汇至关重要。本研究采用Langmuir等温吸附模型来确定排水沟中的沉积物是磷的来源还是汇,评估磷的吸附动力学,并确定潜在的磷吸附。从3条排水沟渠中收集地表沉积物(0-10 cm)和上覆水进行实验。结果表明,磷污染最严重的排水沟泥沙零平衡磷浓度(EPC 0)最高。由于3条沟渠的沉积物EPC 0均高于水体P浓度,它们是跨沉积物界面的P汇。无论取样地点如何,沉积物的动力学吸附均分为快速和缓慢两个阶段。在平衡状态下,沉积物中磷的吸收量(Q e)为50.8 ~ 77.5 mg kg−1。沉积物对磷的吸附量(Q max)为447.0 ~ 493.8 mg kg−1,与结合能(K)相关的常数为0.140 ~ 0.171 L mg−1。研究结果表明,沟渠泥沙对控制农田排放磷动态具有重要意义。
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引用次数: 4
Co-treatment of old landfill leachate and municipal wastewater in sequencing batch reactor (SBR): effect of landfill leachate concentration 序批式反应器(SBR)处理旧垃圾渗滤液与城市污水:渗滤液浓度的影响
IF 2 Q3 Environmental Science Pub Date : 2016-11-02 DOI: 10.2166/WQRJC.2016.020
K. Ranjan, Shubhrasekhar Chakraborty, Mohini Verma, J. Iqbal, R. N. Kumar
Sequencing batch reactor (SBR) was assessed for direct co-treatment of old landfill leachate and municipal wastewater for chemical oxygen demand (COD), nutrients and turbidity removal. Nitrogen removal was achieved by sequential nitrification and denitrification under post-anoxic conditions. Initially, SBR operating conditions were optimized by varying hydraulic retention time (HRT) at 20% (v/v) landfill leachate concentration, and results showed that 6 d HRT was suitable for co-treatment. SBR performance was assessed in terms of COD, ammonia, nitrate, phosphate, and turbidity removal efficiency. pH, mixed liquor suspended solids, mixed liquor volatile suspended solids (MLVSS), and sludge volume index were monitored to evaluate stability of SBR. MLVSS indicated that biomass was able to grow even at higher concentrations of old landfill leachate. Ammonia and nitrate removal efficiency was more than 93% and 83%, respectively, whereas COD reduction was in the range of 60–70%. Phosphate and turbidity removal efficiency was 80% and 83%, respectively. Microbial growth kinetic parameters indicated that there was no inhibition of biomass growth up to 20% landfill leachate. The results highlighted that SBR can be used as an initial step for direct co-treatment of landfill leachate and municipal wastewater.
采用序批式反应器(SBR)直接共处理垃圾渗滤液和城市污水,对化学需氧量(COD)、营养物和浊度的去除效果进行了评价。在后缺氧条件下,通过顺序硝化和反硝化实现脱氮。首先,在垃圾渗滤液浓度为20% (v/v)的条件下,通过改变水力停留时间(HRT)对SBR操作条件进行优化,结果表明,HRT为6 d为宜。从COD、氨、硝酸盐、磷酸盐和浊度去除效率等方面评价了SBR的性能。通过对pH、混合液悬浮物、混合液挥发性悬浮物(MLVSS)、污泥体积指数的监测,评价SBR的稳定性。MLVSS表明,即使在高浓度的旧垃圾填埋场渗滤液中,生物质也能生长。氨氮和硝酸盐的去除率分别大于93%和83%,COD的去除率在60-70%之间。磷酸盐和浊度去除率分别为80%和83%。微生物生长动力学参数表明,当垃圾渗滤液浓度达到20%时,对生物质生长没有抑制作用。结果表明,SBR可作为垃圾渗滤液与城市污水直接共处理的初始步骤。
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引用次数: 19
Protein to polysaccharide ratio in EPS as an indicator of non-optimized operation of tertiary nitrifying MBBR EPS蛋白多糖比作为三级硝化MBBR非优化运行的指标
IF 2 Q3 Environmental Science Pub Date : 2016-11-02 DOI: 10.2166/WQRJC.2016.040
Baisha Ren, B. Young, F. Variola, R. Delatolla
The protein (PN), polysaccharide (PS), and extracellular DNA (eDNA) percent concentrations of extracellular polymeric substances (EPS) of biofilms samples harvested from a pilot-scale nitrifying moving bed biofilm reactor (MBBR) were investigated at various operating temperatures and hydraulic retention times (HRTs). Chemically measured EPS PN/PS ratios were shown to correlate to Raman intensity ratios of amide III to carbohydrate at 362 rel. cm−1. The study also demonstrates that tertiary nitrifying MBBR systems may be optimized to operate at HRTs as low as 0.75 to 1.0 h as opposed to conventional HRTs of 2.0 to 6.0 h. The EPS of the nitrifying MBBR biofilm exhibited the lowest percent PN content and the highest percent PSs and eDNA content. In particular, the PN/PS ratios lower than 3 were indicative of non-optimal operation of the nitrifying MBBR systems; whereas PN/PS ratios with values significantly below 3 were observed for ammonia underloaded systems at high operating temperatures and hydraulically overloaded systems at low HRTs. This study demonstrates that the PN/PS ratio in EPS is a potential metric to identify non-optimal operation of nitrifying MBBR systems.
在不同的操作温度和水力保留时间(HRTs)下,研究了从中试规模的硝化移动床生物膜反应器(MBBR)中收获的生物膜样品的细胞外聚合物质(EPS)的蛋白质(PN)、多糖(PS)和细胞外DNA (eDNA)百分比浓度。化学测量的EPS PN/PS比率与酰胺III与碳水化合物在362 rel. cm−1时的拉曼强度比相关。研究还表明,三级硝化MBBR系统可以优化为在0.75 ~ 1.0 h的hrt下运行,而不是传统的2.0 ~ 6.0 h。硝化MBBR生物膜的EPS表现出最低的PN含量,最高的ps和eDNA含量。特别是,PN/PS低于3表明硝化MBBR系统运行不优化;然而,在高工作温度下氨负荷不足的系统和低hrt下水力过载的系统中,PN/PS值明显低于3。该研究表明,EPS中的PN/PS比率是识别硝化MBBR系统非最佳操作的潜在指标。
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引用次数: 13
Optimization of a microwave-assisted extraction procedure for the determination of selected alkyl, aryl, and halogenated phenols in sewage sludge and biosolids 微波辅助萃取法测定污水污泥和生物固体中选定的烷基、芳基和卤代酚的优化
IF 2 Q3 Environmental Science Pub Date : 2016-11-02 DOI: 10.2166/WQRJC.2016.002
Hing‐Biu Lee, M. Svoboda, T. Peart, S. Smyth
A microwave-assisted extraction method for the determination of 15 alkyl, aryl, and halogenated phenols in sewage sludge and biosolids samples was developed and optimized. The effects of solvent, temperature, time, moisture content, acid, and number of extractions on the recovery of phenols were evaluated. Results indicated that extraction solvent had the greatest impact on the recovery of all phenols while pH had the largest effect on recovery of hexachlorophene and pentachlorophenol. Wet sludge samples were extracted with acetone-hexane mixture in the presence of glacial acetic acid. The extract was evaporated, acetylated by acetic anhydride and cleaned up by silica gel. For dry sludge samples, an optional procedure for the simultaneous extraction and acetylation of phenols was also proposed. Triclosan (TCS) and the alkyl and aryl phenols in sludge extracts were analyzed by gas chromatography-mass spectrometry (GC-MS) in electron-impact mode while polyhalogenated phenols were analyzed by GC-MS in negative ion chemical ionization mode. Method detection limits were ca. 200 ng/g for nonylphenol,
建立并优化了微波辅助萃取法测定污水污泥和生物固体样品中15种烷基、芳基和卤化酚的方法。考察了溶剂、温度、时间、水分含量、酸度、提取次数等因素对苯酚回收率的影响。结果表明,萃取溶剂对各酚类化合物的回收率影响最大,而pH对六氯酚和五氯酚的回收率影响最大。在冰醋酸存在下,用丙酮-己烷混合物提取湿污泥样品。提取液经蒸发,乙酸酐乙酰化,硅胶净化。对于干污泥样品,还提出了同时提取和乙酰化酚的可选程序。采用气相色谱-质谱法(GC-MS)分析污泥提取物中的三氯生(TCS)、烷基酚和芳基酚,采用负离子化学电离法(GC-MS)分析多卤代酚。方法对壬基酚的检出限约200 ng/g;
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引用次数: 1
Membrane fouling remediation in ultrafiltration of latex contaminated wastewater 乳胶污染废水超滤膜污染修复研究
IF 2 Q3 Environmental Science Pub Date : 2016-08-11 DOI: 10.2166/WQRJC.2015.011
A. Abdelrasoul, H. Doan, A. Lohi
The current study aimed to remediate membrane fouling by latex effluent by altering membrane surface charge or ionic strength of the effluent. Hydrophilic polysulfone and Ultrafilic flat membranes, with molecular weight cutoff (MWCO) of 60,000 and 100,000, respectively, and hydrophobic polyvinylidene difluoride membrane (PVDF; MWCO 100,000) were used under a constant flow rate and in cross-flow mode for ultrafiltration of latex effluent. The effect of linear alkyl benzene sulfonate (LAS) on the ionic strength of the effluent and the zeta potential of latex particles was investigated. LAS was also used to improve the anti-fouling properties of the membrane surface. The ionic strength of latex effluent was increased by raising its pH from 7 to 12, resulting in an increase of the zeta potential negativity of the latex particles from −26.61 to −42.66 mV. LAS was found to be an ineffective pretreatment for limiting the fouling propensity of latex effluent using hydrophilic membranes even at high concentration and long treatment times. It was concluded that LAS-treated membrane surface is much more favorable than pH changed feed pretreatment. The total mass of fouling decreased by 44.00 and 29.60%, when PVDF membrane surface was treated with LAS at a concentration of 1 × 10−4 g/L, and latex effluent at pH 11 was used, respectively.
本研究旨在通过改变乳胶废水的膜表面电荷或离子强度来修复乳胶废水对膜的污染。亲水性聚砜和超滤膜,分子量分别为6万和10万,疏水性聚偏二氟乙烯膜(PVDF);采用恒流量、横流方式对乳胶出水进行超滤。研究了线性烷基苯磺酸盐(LAS)对出水离子强度和乳胶颗粒zeta电位的影响。LAS还用于提高膜表面的抗污染性能。将乳胶流出液的pH值从7提高到12,可以提高乳胶流出液的离子强度,使乳胶颗粒的zeta负电位从−26.61 mV增加到−42.66 mV。研究发现,在高浓度、长时间处理下,LAS对限制亲水膜乳胶出水的污染倾向是一种无效的预处理方法。结果表明,las处理的膜表面比pH变化的饲料预处理更有利。用浓度为1 × 10−4 g/L的LAS和pH为11的乳胶出水处理PVDF膜表面时,污染总质量分别降低了44.00%和29.60%。
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引用次数: 9
Editorial: Marine and freshwater quality management 社论:海洋和淡水质量管理
IF 2 Q3 Environmental Science Pub Date : 2016-08-11 DOI: 10.2166/WQRJC.2016.000
Bing Chen, Yinchen Ma, Baiyu Zhang
Marine and freshwater are the essential components of the earth's hydrosphere and their quality management has been one of the most critical and overriding challenges for all the involved researchers, engineers and decision makers around the globe. The availability of the world's scarce water resources is increasingly limited due to the worsening pollution problems caused by the release of diverse, large quantities of pollutants from point or non-point sources into rivers, lakes, and oceans. Through the food chain, these pollutants can cause acute or chronic effects on the health of aquatic organisms and human beings. Within a global changing context, more effective quality management of marine and freshwater systems demands continuously improved knowledge and technologies, sound decisions and best practices, and benign legal and socio-economic environments to cope with the situation.This special issue on marine and freshwater quality management contains the selected papers presented during the International Conference on Marine and Freshwater Environments (iMFE2014), which was held in St. John's, Canada, from August 6 to 8, 2014. The conference was organized jointly by the 2014 Atlantic Symposium of the Canadian Association on Water Quality, the 2014 Annual General Meeting and 30th Anniversary Celebration of the Canadian Society for Civil Engineering Newfoundland and Labrador Section, the 2014 Annual Conference of the International Society for Environmental Information Sciences, and the 2nd International Conference of Coastal Biotechnology of the Chinese Society of Marine Biotechnology and Chinese Academy of Sciences. The areas of scientific interest on which over 110 papers and posters were presented in the conference covered an impressively wide range of topics with significant added-value for scientists, engineers, researchers and policy makers in the field. After a rigorous peer-review process, eight papers have been selected for publication in this special issue, addressing the following topics: (1) environmental modeling, risk assessment …
海洋和淡水是地球水圈的重要组成部分,它们的质量管理一直是全球所有相关研究人员、工程师和决策者面临的最关键和最重要的挑战之一。由于各种各样的、大量的污染物从点源或非点源排放到河流、湖泊和海洋中,导致污染问题日益严重,世界上稀缺的水资源的可用性越来越有限。通过食物链,这些污染物可对水生生物和人类的健康造成急性或慢性影响。在全球不断变化的背景下,对海洋和淡水系统进行更有效的质量管理需要不断改进知识和技术、健全的决策和最佳做法以及良好的法律和社会经济环境来应对这种情况。本期关于海洋和淡水质量管理的特刊收录了2014年8月6日至8日在加拿大圣约翰举行的海洋和淡水环境国际会议(iMFE2014)上发表的精选论文。本次会议由加拿大水质协会2014年大西洋研讨会、加拿大土木工程学会纽芬兰与拉布拉多分会2014年年会暨30周年庆典、国际环境信息科学学会2014年年会、中国海洋生物技术学会与中国科学院第二届国际海岸生物技术大会联合主办。会议上发表了110多篇论文和海报,涉及的科学领域非常广泛,对该领域的科学家、工程师、研究人员和政策制定者具有重要的附加价值。经过严格的同行评议过程,八篇论文被选中发表在本期特刊上,涉及以下主题:(1)环境建模,风险评估……
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引用次数: 2
Management of water resources assessment for nuclear power plants in China 中国核电站水资源评价管理
IF 2 Q3 Environmental Science Pub Date : 2016-08-11 DOI: 10.2166/WQRJC.2015.023
Xiaowen Ding, Wei Wang, G. Huang, Qingwei Chen, G. Wei
To deal with global warming and energy shortages, the nuclear power industry has flourished in China. Operation of a nuclear power plant consumes a large amount of water and discharges radioactive wastewater into nearby water bodies. Therefore, assessment and management of water resources are crucial for such projects. This article proposes the contents, procedures and methods of water resources assessment for nuclear power plants in China. Taking a pioneering inland plant as an example, a case study was also developed. It was suggested that assessment of water resources for a nuclear power plant in China should focus on regional water resources analyses, rationality of water-draw and water use of a plant, feasibility of water sources and impacts of water-draw and wastewater discharge on regional water resources. The proposed processes mainly included site survey and data collection, work outline completion and approval, water resources assessment, assessment report completion, expert consultation and public participation, and technological review, as well as administrative approval. The methods presented were referring to legal documents, site survey, model simulation, expert consultation and public participation. Finally, suggestions, including comparing and selecting of several optional sites, improving impact assessment of radioactive wastewater discharge and enhancing public participation, were also proposed.
为了应对全球变暖和能源短缺,中国的核电工业蓬勃发展。核电站的运行消耗大量的水,并将放射性废水排放到附近的水体中。因此,水资源的评价和管理对这类项目至关重要。本文提出了中国核电站水资源评价的内容、程序和方法。并以某内陆先锋工厂为例,进行了案例分析。建议中国核电站水资源评价应从区域水资源分析、核电站取水和用水的合理性、水源的可行性、取水和废水排放对区域水资源的影响等方面着手。建议的流程主要包括现场调查和数据收集、工作大纲的完成和审批、水资源评估、评估报告的完成、专家咨询和公众参与、技术审查和行政审批。提出了法律文件法、现场调查法、模型模拟法、专家咨询法和公众参与法。最后,提出了若干备选场址的比较选择、改进放射性废水排放影响评价、加强公众参与等建议。
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引用次数: 4
Water insecurity in Indigenous Canada: a community-based inter-disciplinary approach 加拿大土著居民的水不安全:以社区为基础的跨学科方法
IF 2 Q3 Environmental Science Pub Date : 2016-08-11 DOI: 10.2166/WQRJC.2015.010
M. Hanrahan, A. Sarkar, A. Hudson
Water insecurity in Northern Indigenous communities in Canada remains a pressing problem, with multiple dimensions and health impacts. We carried out a case study of long-term water insecurity in the Southern Inuit island community of Black Tickle, Labrador, where there is no piped water and people rely on an under-funded potable water dispensing unit (PWDU) and unmonitored water sources. Our community-based multi-disciplinary project involved qualitative and quantitative methods including key informant interviews, focus groups, a census, a literature review, water testing, and an engineering site visit. In Black Tickle, water security was chronically and severely compromised and was linked to poverty, food insecurity, men9s health, and mental health. We have taken a materialist approach; accordingly, later project phases involve research aimed at identifying appropriate solutions, and conducting pre-engineering and engineering work. This article reports on the first two phases of the project, through which we described the problem and identified its impacts.
加拿大北部土著社区的水不安全仍然是一个紧迫的问题,具有多方面的健康影响。我们在拉布拉多Black Tickle的南因纽特岛社区进行了长期水不安全的案例研究,那里没有管道水,人们依赖资金不足的饮用水分配单位(PWDU)和未监测的水源。我们以社区为基础的多学科项目涉及定性和定量方法,包括关键信息提供者访谈、焦点小组、人口普查、文献综述、水测试和工程现场访问。在Black Tickle,水安全长期受到严重损害,并与贫困、粮食不安全、男性健康和精神健康有关。我们采取了唯物主义的方法;因此,后期项目阶段涉及旨在确定适当解决办法的研究,并进行工程前和工程工作。本文报告了项目的前两个阶段,通过这两个阶段,我们描述了问题并确定了其影响。
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引用次数: 15
期刊
Water Quality Research Journal of Canada
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