Quaternary Geochronology最新文献

Amino acid geochronology can provide effective relative dating frameworks for the Pleistocene and has enabled correlation of terrestrial deposits to the global climatic fluctuations described by the marine oxygen isotope record. Using methods developed for the analysis of intra-crystalline amino acids in tooth enamel, we aimed to construct an enamel-based amino acid geochronology for the terrace deposits in the valley of the River Thames in southern Britain using different mammalian taxonomic groups: elephant, horse and bison. To achieve this, chiral amino acid analysis was applied to 58 elephantid, 21 horse and 15 bison teeth from 10 horizons in the Upper Thames Valley, three in the Lower Thames Valley and one from a Thames tributary in the Lea Valley. We evaluate differences in the rates of amino acid breakdown between the taxa and establish which species are similar enough to enable comparison for relative dating purposes. The relative dating of the river terrace deposits is in good agreement with the terrace stratigraphy, biostratigraphy, and other independent estimates of age for all three taxonomic groups. These frameworks demonstrate the potential of enamel-based amino acid geochronologies for relative dating of Middle–Late Pleistocene deposits in the UK, and establish an aminostratigraphic framework from which the dating of other tooth material can be refined. Enamel offers an opportunity to evaluate the age of sites where shell material is absent or poorly preserved. It can also, crucially, provide direct relative dating of mammalian fossils, which are often the focus of study in terms of their evolution, distributional changes or extinction. Direct dating negates the risk that the mammal fossils themselves might be reworked, or of different ages to shell, sediments or other dated material in the same deposits; it also enables archived samples with insecure provenance (e.g. from early 17th-19th century collections) to be directly dated.

Trapped charge techniques of luminescence and electron spin resonance (ESR) are classic tools for dating Quaternary deposits. Over the past decade, these techniques have been routinely applied to investigate provenance and/or the sedimentary history of quartz grains based on their different luminescence and ESR characteristics. Of these, optically stimulated luminescence (OSL) sensitivity is one of the most widely investigated parameter for luminescence-based provenance approach. A majority of studies on this parameter are based on evaluation of multi-grain quartz OSL sensitivity of the samples. This is particularly concerning because single-grain quartz luminescence studies have shown that the luminescence signal of a multi-grain aliquot is contributed by less than ∼1–10% of the total grains. Since the sole criteria for discrimination of sources based on luminescence sensitivity relies on its intensity, therefore the results based on multi-grain analysis will most likely be skewed depending on the ‘proportion’ and ‘brightness’ of a few grains. This demands a need to evaluate the potential of single-grain quartz OSL sensitivity in provenance studies. In this study, we investigate single and multi-grain quartz OSL sensitivity from compositionally different sandstones with well-characterised sources based on U–Pb zircon ages. We further complement this analysis with characterisation of ESR centres commonly used in quartz provenance, namely E′₁ and [AlO₄]⁰ centres. Our study shows that single-grain quartz OSL sensitivity can help distinguish between sediments that have a predominant input from a single source as compared to those with contribution from multiple sources, which otherwise cannot be inferred from multi-grain studies. Moreover, our results on characterisation of quartz-based ESR intensity of E′₁ and saturated [AlO₄]⁰ centres successfully differentiates between sandstones and further complements the luminescence-based characterisation.

We have investigated the luminescence properties of plant opal phytoliths to assess their suitability for determination of age and/or thermometric information from soil and sediment sequences. This study examined a <2.37 gcm⁻³ density fraction in parallel with quartz grains from samples collected from alluvial terraces. We observed comparable optically stimulated luminescence (OSL) from the phytolith fraction to the quartz, and thermoluminescence (TL) with broader peaks and continuum to higher temperatures. Scanning electron microscopy (SEM) data suggested the presence of opal clasts and contaminant minerals. To better understand the luminescence from opal phytoliths we analyzed a suite of biogenic materials including very pure diatoms, phytoliths, and quartz reference materials. We observe low sensitivity but measurable OSL signals in all the materials analyzed, and infrared stimulated luminescence (IRSL) signals with fast decay rates exceeding those of more typical feldspars in some of the purer materials. TL signals are similar to those observed for glasses and suggests dose response might extend beyond quartz saturation levels. Preliminary investigations of OSL dose response show very promising growth characteristics for opal phytolith samples and all other biogenic silica materials analyzed.

The aim of this study was to develop an independent luminescence chronology for the upper part of the important Loess Palaeolithic site at Kuldara (Khovaling Loess Plateau, Tajikistan). We applied high sampling-depth resolution (n = 85) luminescence dating to the upper ∼26 m of the sequence from loess L4 to pedocomplex PC0. Luminescence characteristics of the post-IR₂₀₀ IRSL₂₉₀ signal from coarse-silt polymineral grains are satisfactory (reproducible growth and good dose recovery). Comparison with quartz OSL for samples <50 ka and results from modern analogues (Challier et al. these proceedings) shows that the pIRIR_200,290 signal is, as expected, sufficiently bleached at deposition. The luminescence chronology extends back to ∼250 ka and shows distinct erosional hiatuses ranging in duration from ∼15 ka to a full glacial-interglacial cycle (∼100 ka); some of these breaks were not identifiable in the field. We suggest an upper dating limit of 2.5xD_c; this yields minimum ages of ∼300 ka for this material. Dust Accumulation Rates (DAR) are reconstructed for the Late Pleistocene (from ∼100 to ∼40 ka) and reveal, next to several minor dust accumulation peaks, two major peaks at the end of MIS5 (∼75 ka) and at MIS3b (∼40 ka). We conclude that detailed post-IR₂₀₀ IRSL₂₉₀ dating of loess-palaeosol sequences in Tajikistan is necessary to exploit fully the potential of this important terrestrial (dust) record.

The coastal sedimentary record of Galicia (NW Spain) is important to study sea-level oscillations during the Late Quaternary. The alluvial deposits preserved in the Ria de Coruña and Ria de Arousa are remnants of fluvial valleys flooded by the sea during the successive Pleistocene and Holocene transgressions. A first chronological study by Optical Stimulated Luminescence (OSL)- revealed a fast-component dominated, but dim OSL signal emitted by quartz from this area. Equivalent dose distributions, as obtained with the Analyst software, yielded large overdispersion values, which were negatively correlated to the potassium concentration in the sediment, thus suggesting the influence of beta dose rate heterogeneities. Nevertheless, for most samples many aliquots were considered in saturation, leading to a palaeodose and age underestimation – regardless of the model choice for age calculation. In this paper, we present new analyses using the open-source R package BayLum, as the so-called saturated aliquots may be incorporated in age calculation. Thus, we test this model performance and more commonly used models in retrieving large doses. Then, we discuss the implications for age calculation for these continental sediments formed during the Late Pleistocene.

During the Quaternary sedimentation in the southern part of the Caspian Lowland was influenced significantly by the Caspian Sea. This is expressed both in accumulation of marine/lagoon sediments as a result of transgressive phases, as well as erosion of sediments, which leads to an incompleteness in the geological record. The most detailed record of Later Quaternary sedimentation is found in the Lower Volga region, where a series of Caspian Sea transgressions, Volga River alluvium and loess-palaeosol series provide an excellent archive of the evolution of the climate and landscapes of the past. We have studied one of the reference sections, at Chernyy Yar, in which a series of major stages of regional sedimentations is recorded. Description of the Late Quaternary sediments and luminescence dating allowed us to obtain, for the first time, a detailed chronostratigraphy for the southern part of the Lower Volga. Our results show that the quartz OSL and feldspar pIRIR_50,290 signals were sufficiently bleached before deposition and uncertainties in bleaching have a negligible impact on the reliability of the luminescence ages. The new luminescence chronology described here, based on quartz OSL and K-feldspar pIRIR₂₉₀ ages, suggests five major stages during the Late Quaternary: (1) a stable alluvial sedimentation of the Volga River between 130 and 105 ka (MIS 5e/d), when the thick Chernyyar alluvial suite formed regionally during the Late Khazarian transgression of the Caspian Sea; (2) a stage when the retreat of the Khazarian transgression formed a very broad floodplain about 85 ka ago, and promoted Volga channel incision. New findings shows that the Atelian regression – a major event in the Late Quaternary of the Caspian Sea – began after ∼60 ka; (3) subaerial sedimentation during MIS 4 with evidence of cryogenic processes at ∼40 ka, reliably dated for the first time in this southern part of the East European Plain; (4) about 24 ka ago, the largest Late Quaternary Khvalynian transgression reached the Chernyy Yar; (5) after the subsequent regression at ∼14–15 ka some part of the marine record was eroded and the Holocene kastanozem soil formed.

Luminescence signals from portable optically-stimulated luminescence readers (POSL or port-OSL) can provide expedient insights into sample relative age, and under certain conditions can be simplistically calibrated against existing luminescence chronologies to provide first-order estimates of burial age. This is most straightforward in simple sedimentary systems where samples share a common provenance and geomorphic process history. The spatially extensive southern African dune and palaeolake shoreline luminescence database, for which hundreds of non-light exposed bulk sediments are available, offers a valuable test case to examine the conditions under which POSL-bulk sediment calibration approaches are feasible. To do this we combine measurements of inherent luminescence sensitivity of bulk sediment (BSS) with analysis of sedimentary composition (petrology and presence of calcium carbonate) and texture. We show that BSS, along with POSL IRSL:BSL ratios and petrological data, account for region-to-region variations, whilst internal variability (scatter) within the lake shorelines dataset relates to variations in BSS and sediment texture. At the scale of southern African subcontinent drylands, we see that provenance and geomorphological process history influence sample mineralogical composition and POSL signal characteristic, including BSS.

In recent years, luminescence dating has witnessed significant advancements to overcome its traditional boundaries. However, methodological challenges persist when dating high-energy fluvial gravel deposits in proglacial settings, because partial bleaching and the scarcity of sand lenses complicate luminescence age estimation through conventional approaches. To address these issues, using rock surfaces of large clasts may overcome the limited availability of sand layers in some deposits and allow clast specific assessment of luminescence signal resetting at the time of deposition through the analyses of bleaching profiles. The Hartheim gravel pit in the southern Upper Rhine Graben of southwest Germany features a sedimentary succession deposited by distal braided river meltwater streams reworked during the late Pleistocene. Different luminescence approaches have been applied to sand lenses, the sandy matrix of gravel deposits and crystalline cobbles. Quartz optically stimulated luminescence (OSL) ages range between ∼19 and 22 ka, which represents the time just after the last glaciation maximum in the region. The OSL ages of the sandy matrix of ∼24–27 ka are in an agreement with the previous estimates, as these are from a stratigraphic lower position. However, post-IR infrared stimulated luminescence (pIRIR) ages of sand layer and sandy matrix both are some 3–6 ka older than the OSL ages, despite being internally very consistent. Luminescence depth profiles show that the signal was deeply reset in some cobbles, whereas in others only the IRSL signal in the surface layer appears to have been reset. The cobble IRSL ages show a relatively large spread, and it remains uncertain, if this is caused by incomplete bleaching or it reflects dosimetric issues. Nevertheless, overall, our results underscore the potential of rock surface luminescence dating to date fluvial deposits from the Upper Rhine Graben and similar settings.

Accurate dating is the basis for deciphering eustatic and climatic changes on deltaic sedimentary processes. In the Pearl River Delta (PRD) plain of south China, scarce robust chronology hinders the detailed interpretation of sedimentary history. In this study, quartz optically stimulated luminescence (OSL) (21 samples), feldspar post-IR IRSL (pIRIR) (4 samples) and radiocarbon (¹⁴C) (2 samples) dating were applied to obtain detailed chronological framework of core SXG06 (23-m long to bedrock) from the northeastern PRD. SXG06 consists an upper marine unit (M1) and a lower marine unit (M2), separated by a terrestrial unit (mottled clay, T1). For M1, quartz OSL and ¹⁴C samples yielded ages from 5.2 ± 0.3 to 0.32 ± 0.02 ka. The sample on top of T1 produced a quartz OSL age of 35 ± 2 ka. For other 12 samples in T1 and M2, quartz OSL signals reached saturation and generated minimum ages (>51 ka). For these the saturated quartz OSL samples, feldspar pIR₅₀IR₂₅₀ provides an age range of 123 ± 7–105 ± 7 ka. The compilation of all the above ages and previous sedimentology data reveals that: (1) M2 was formed during marine transgression of Marine Isotope Stage (MIS) 5; (2) A hiatus with an age gap of between ∼35 ka and ∼5 ka was observed, which might be due to the low sea level and resultant weathering scouring; (3) Initial M1 deposits from the northeastern PRD postdated the central and southern PRD by ∼3 ka, indicating delayed delta development in the northeastern PRD during the Holocene. (4) SXG06 experienced slow deposition 0.3 m/ka in ∼5–3 ka because of the coevally decreased sediment supply, followed by accelerated deposition rate of 3 m/ka after ∼3 ka associated with strengthen human activity.

Optically stimulated luminescence (OSL) ages of young coastal dune ridges have allowed getting more knowledge on the deposition, erosion and evolution of coastal dune systems in Northern Europe during historical times. However, there is a lack of knowledge of the evolution of the same systems in SW Europe. The studies published in the last years about fossil dunes in NW Spain have allowed the reconstruction of the coastal evolution of this area from the Marine Isotopic Stage (MIS 8) until the Middle Holocene. However, there is still a poor knowledge for the Late Holocene and namely the last centuries. Dating young sediments is challenging due to the low signal to noise ratio of the natural OSL signal and because young samples are very sensitive to thermal transfer or partial bleaching of the luminescence signal during transport. In the last century, erosion and accretion events are better known because remote sensing methods allowed to model some coastal dune systems. However, OSL dating has also been particularly useful in NW Europe to get a better knowledge on the coastal dune evolution. In this work, seven samples from dune ridges and a climbing dune of a coastal system in Playa de Trece (NW Spain) were dated by OSL, as they record the last accretion events occurred in the last two centuries, and above all the 20th Century. For assessing the ages we have compared the results from both parametric central age models and Bayesian statistic using R package BayLum.