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STRUCTURE AND MECHANICAL PROPERTIES OF Ti-Cr-Al-Nb AND Ti-Cr-Al-Nb-V MULTICOMPONENT ALLOYS Ti-Cr-Al-Nb和Ti-Cr-Al-Nb- v多组分合金的组织和力学性能
Q4 PHYSICS, NUCLEAR Pub Date : 2023-10-12 DOI: 10.46813/2023-147-059
O.M. Velikodnyi, R.V. Vasilenko, O.S. Kalchenko, I.V. Kolodyi, Y.O. Krainiuk, A.V. Levenets, P.I. Stoev, M.A. Tikhonovsky, G.D. Tolstolutska
The empirical and semi-empirical models were used to analyze the phase-structural state of five- and fourcomponent alloys of the Ti-Cr-Al-Nb-V system. Two compositions of lightweight alloys were selected for experimental study: Ti60Cr11Al7Nb11V11 and Ti60Cr11Al7Nb22 (at. %). Ingots of these alloys were obtained by argonarc melting method, and they were subjected to homogenization, deformation by rolling and subsequent annealing at different temperatures. The influence of annealing temperature on the phase-structural state of the alloys, their hardness, and mechanical properties during tensile tests has been studied experimentally. It was found that the change of phase composition and grain size during annealing in the temperature range of 700…900 ºC practically does not affect the hardness and tensile strength of alloys. Annealing at 900 ºC transforms the alloys into a singlephase state with bcc lattice and significantly increases the elongation to fracture, which is about 30% for both alloys. In addition, the yield strength and tensile strength of the five-component alloy are noticeably higher than those of the four-component alloy.
采用经验和半经验模型分析了Ti-Cr-Al-Nb-V系五组分和四组分合金的相结构状态。采用Ti60Cr11Al7Nb11V11和Ti60Cr11Al7Nb22 (at)两种轻质合金组合进行实验研究。%)。采用氩弧熔炼法制备合金锭,在不同温度下进行均匀化、轧制变形和退火处理。实验研究了退火温度对合金的相组织状态、硬度和拉伸力学性能的影响。结果表明,在700 ~ 900℃退火过程中,相组成和晶粒尺寸的变化对合金的硬度和抗拉强度几乎没有影响。900℃退火使合金转变为具有bcc晶格的单相态,显著提高了合金的断裂伸长率,两种合金的断裂伸长率均在30%左右。此外,五组分合金的屈服强度和抗拉强度明显高于四组分合金。
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引用次数: 0
LONG-LIFE PULSED VACUUM-ARC PLASMA SOURCE 长寿命脉冲真空弧等离子体源
Q4 PHYSICS, NUCLEAR Pub Date : 2023-10-12 DOI: 10.46813/2023-147-152
Iurii Sysoiev, Yurii Shyrokyi, Kseniia Fesenko
The design of a pulsed vacuum-arc plasma source with an ignition system based on dielectric surface breakdown is presented and the principle of its operation is described. In the engineered plasma source, a four-section anode is used along with an equal number of arc ignition sections. Additionally, separate power supply circuits are employed for both the main pulsed arc discharge and the arc ignition circuit. Independent operation of each section of this device is carried out, essentially constituting a combination of four pulsed plasma sources in one, the coordinated functioning of which is ensured by the control system. Practical tests of the pulsed plasma source have revealed its advantages as followed: a fourfold increase in the ignition system life-time; achieving uniform depletion of the cathode working surface; and, under specific conditions, enhancing the productivity of the plasma source.
介绍了一种基于介质表面击穿点火系统的脉冲真空电弧等离子体源的设计,并阐述了其工作原理。在工程等离子体源中,采用四段阳极和等量的引弧段。此外,主脉冲电弧放电和引弧电路均采用单独的供电电路。该装置的每个部分都是独立运行的,基本上构成了四个脉冲等离子体源的组合,控制系统保证了它们的协调运作。脉冲等离子体源的实际试验表明,它具有以下优点:点火系统寿命提高了四倍;实现阴极工作面均匀损耗;并且,在特定条件下,提高等离子体源的生产率。
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引用次数: 0
IMPROVING THE STRENGTH AND CORROSION PROPERTIES OF ALUMINIUM ALLOYS WHEN MODIFICATION WITH NANODISPERSED COMPOSITIONS 纳米分散成分改性提高铝合金的强度和腐蚀性能
Q4 PHYSICS, NUCLEAR Pub Date : 2023-10-12 DOI: 10.46813/2023-147-026
A.V. Davydiuk, N.E. Kalinina, A.F. Sanin, D.B. Hlushkova, S.V. Demchenko, V.O. Sayenko
Aluminium alloys of the Al-Si and Al-Mg-Sc systems, which are promising for nuclear power generating facilities, were studied. The AK9 aluminium casting alloy and the 1545 wrought alloy were selected as the study materials. Modification of aluminium alloys with a multicomponent nanodispersed modifier based on Mg2Si and SiC was proposed. Grain grinding of modifying alloys by 1.5–2 times, strength properties increasing by 12…18% and corrosion resistance improving were achieved. The mechanism of action of the multicomponent nanodispersed modifier in an aluminium melt was proposed. The use of such modifiers facilitates the technological process, is environmentally safe, and leads to a uniform distribution of the introduced nanocompositions, which increases the strength and stability of alloys. The results achieved showed the effectiveness of modification aluminium alloys with nanodispersed compositions.
研究了在核电设施中应用前景广阔的Al-Si和Al-Mg-Sc体系铝合金。选用AK9铝合金和1545变形合金作为研究材料。提出了一种基于Mg2Si和SiC的多组分纳米分散改性剂对铝合金进行改性的方法。改性合金的磨粒率提高1.5 ~ 2倍,强度提高12 ~ 18%,耐蚀性提高。探讨了多组分纳米分散改性剂在铝熔体中的作用机理。这种改性剂的使用简化了工艺过程,对环境安全,并导致引入的纳米成分均匀分布,从而增加了合金的强度和稳定性。结果表明,采用纳米分散成分对铝合金进行改性是有效的。
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引用次数: 0
CONVECTION OF A VISCOUS INCOMPRESSIBLE COOLANT IN A HORIZONTAL CYLINDRICAL PIPE HEATED FROM BELOW. AN ANALYTICAL SOLUTION 粘性的不可压缩的冷却剂在从下面加热的水平圆柱形管道中的对流。解析解
Q4 PHYSICS, NUCLEAR Pub Date : 2023-10-12 DOI: 10.46813/2023-147-046
O.L. Andrieieva, K.V. Abelentseva, V.I. Tkachenko
To intensify heat transfer processes in nuclear power, it is proposed to use natural convection in horizontal heat exchange tubes. In the article, the problem of convection of a viscous, incompressible fluid in a horizontal cylinder heated from below is analyzed analytically. The proposed analytical method is based upon the use of basic functions that satisfy the initial equation but do not satisfy the boundary conditions. The problem with boundary conditions with a sufficient degree of accuracy is solved by dividing the area of the square described around the cylinder into a large number of smaller element cells. This separation has made it possible to obtain analytical expressions of critical Rayleigh numbers for different positions of current lines in a horizontal cylinder with a viscous, incompressible fluid.
为了加强核电中的传热过程,建议在水平换热管中使用自然对流。本文用解析法分析了从下加热的粘性不可压缩流体在水平圆柱体中的对流问题。所提出的解析方法是基于使用满足初始方程但不满足边界条件的基本函数。具有足够精度的边界条件的问题是通过将圆柱周围描述的正方形面积划分为大量较小的单元格来解决的。这种分离使得在具有粘性不可压缩流体的水平圆柱体中,得到电流线不同位置的临界瑞利数的解析表达式成为可能。
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引用次数: 0
CAVITATION EROSION RESISTANCE OF VACUUM-ARC COATINGS BASED ON TiN 锡基真空电弧涂层的抗空化侵蚀性能
Q4 PHYSICS, NUCLEAR Pub Date : 2023-10-12 DOI: 10.46813/2023-147-126
І.О. Klimenko, V.G. Marinin, V.А. Belous, N.A. Azarenkov, М.G. Ishchenko, V.S. Goltvyanytsya, A.S. Kuprin
This review presents an examination of various studies investigating the impact of deposition process conditions and structural characteristics of TiN-based vacuum-arc coatings on their ability to withstand cavitation erosion in water. The structural and phase composition of TiN coatings is influenced by two key technological parameters: the nitrogen pressure in the vacuum chamber and the substrate bias potential. However, it has been observed that vacuum-arc alloy coatings such as TiSiN and TiAlYN exhibit notably lower resistance to cavitation erosion. Additionally, research on multilayer Ti-TiN coatings with varying numbers and thickness ratios of layers has not shown an improvement in resistance to cavitation wear when compared to single-layer coatings deposited under optimal conditions. On the other hand, single-phase stoichiometric TiN coatings deposited at a higher nitrogen pressure of 2 Pa and a bias potential of up to -300 V have demonstrated remarkable resistance to cavitation wear. These coatings could be effectively utilized to protect the titanium alloy Ti-6Al-4V against cavitation damage.
本文综述了各种研究tin基真空电弧涂层的沉积工艺条件和结构特性对其耐水中空化侵蚀能力的影响。TiN涂层的结构和相组成受真空室氮气压力和衬底偏压这两个关键工艺参数的影响。然而,已经观察到真空电弧合金涂层(如TiSiN和TiAlYN)对空化侵蚀的抵抗能力明显较低。此外,对不同层数和层厚比的多层Ti-TiN涂层的研究表明,与在最佳条件下沉积的单层涂层相比,其抗空化磨损性能没有提高。另一方面,在更高的氮气压力(2pa)和高达-300 V的偏置电位下沉积的单相化学测量TiN涂层具有显著的抗空化磨损性能。这些涂层可以有效地保护Ti-6Al-4V钛合金免受空化损伤。
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引用次数: 0
THE GAS IMPURITIES INFLUENCE ON THE CHARACTERISTICS OF VT1-0 AND VT6 TITANIUM ALLOYS 气体杂质对vt1-0和vt6钛合金性能的影响
Q4 PHYSICS, NUCLEAR Pub Date : 2023-10-12 DOI: 10.46813/2023-147-137
Serhii Polishko
This article dials with methods for producing titanium alloys VT1-0 and VT6 and the gaseous impurities effect on plasticity characteristics. It has been shown that electron-beam melting with an intermediate capacity makes it possible to remove a significant number of impurities in titanium alloys VT1-0 and VT6. It has been proven that industrialscale modification of titanium ingots with a total weight of more than 18 t, followed by their pressure treatment without remelting, allows minimizing the energy costs for obtaining finished semi-finished products.
本文介绍了VT1-0和VT6钛合金的生产方法及气体杂质对塑性特性的影响。结果表明,以中等容量的电子束熔化可以去除VT1-0和VT6钛合金中的大量杂质。事实证明,对总重量超过18吨的钛锭进行工业规模的改性,然后进行不重熔的压力处理,可以最大限度地降低获得成品半成品的能源成本。
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引用次数: 0
MODIFIED STEFAN CONDITION IN STEFAN PROBLEM 修正了斯蒂芬问题中的斯蒂芬条件
Q4 PHYSICS, NUCLEAR Pub Date : 2023-10-12 DOI: 10.46813/2023-147-021
D.G. Bielykh, S.F. Skoromnaya, V.I. Tkachenko
The two-phase one-dimensional Stefan problem (SP) with the boundary between the phases moving with time is considered. The position of the boundary is determined by the modified Stefan condition (MSC), which is obtained from the original nonlinear diffusion equation by integrating over a thin transition layer, and by tending its thickness to zero. Upon receipt of the MSC, the diffusion coefficient is represented by the sum of the Heaviside step functions. It is shown that the MSC differs from the standard one in that in the latter, the derivatives of the concentrations with respect to the phase coordinates are interchanged. An expression for the displacement of the interphase boundary is obtained, which, as in the standard SP, is proportional to the square root of time. The results of using the MSC are confirmed by experimental data on the displacement of the Cu/Sn interface during diffusion bonding during isothermal annealing.
研究了两相边界随时间移动的一维Stefan问题。边界的位置由修正的Stefan条件(MSC)决定,该条件由原始的非线性扩散方程通过对薄过渡层进行积分,并使其厚度趋于零得到。在接收到MSC后,扩散系数由Heaviside阶跃函数的和表示。结果表明,MSC与标准MSC的不同之处在于,在标准MSC中,浓度对相坐标的导数是互换的。得到了相间边界位移的表达式,该表达式与标准SP中一样,与时间的平方根成正比。通过等温退火扩散键合过程中Cu/Sn界面位移的实验数据证实了MSC的研究结果。
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引用次数: 0
HARDENING OF LIGHTWEIGHT MULTI-PRINCIPAL ELEMENT TITANIUM-BASED ALLOY UNDER AR ION IRRADIATION 氩离子辐照下轻量化多主元素钛基合金的硬化
Q4 PHYSICS, NUCLEAR Pub Date : 2023-10-12 DOI: 10.46813/2023-147-003
G. Tolstolutska, M. Tikhonovsky, О. Velikodny, S. Karpov, V. Ruzhytskyi, G. Tolmachova, R. Vasilenko
Among new prospective materials multi-principal element alloys (MPEA) have attracted considerable attention in recent years due to their excellent corrosion and irradiation resistance as well as their good mechanical properties over a wide temperature range. The new lightweight multi-principal element titanium-based alloy 61Ti-10Cr-7Al11V-11Nb (at. %) with high ductility at room and elevated temperatures is studied. This single-phase bcc alloy was irradiated with 1.4 MeV Ar ions at room temperature and mid-range doses from 1 to 10 displacements per atom. The effect of irradiation is studied by examining the hardening. A comparison was performed with irradiation-induced hardening behaviour of MPEA, 316 austenitic stainless steel irradiated under an identical condition. It was shown that hardness increases with irradiation dose for all the materials studied, but this increase is lower in multi-principal element alloys both face-centered cubic (FCC) and body-centered cubic (BCC) structures than in stainless conventional steel.
在新型材料中,多主元素合金(MPEA)因其优异的耐腐蚀和耐辐照性能以及在较宽温度范围内良好的力学性能,近年来受到了广泛的关注。新型轻量化多主元素钛基合金61Ti-10Cr-7Al11V-11Nb (at。在室温和高温下具有高延展性的材料。用1.4 MeV的氩离子在室温和每原子1 ~ 10个位移的中剂量照射单相bcc合金。通过观察硬化,研究了辐照的影响。对MPEA、316奥氏体不锈钢在相同辐照条件下的辐照硬化行为进行了比较。结果表明,所有材料的硬度随辐照剂量的增加而增加,但多主元素合金的面心立方(FCC)和体心立方(BCC)组织的硬度增加幅度低于不锈钢。
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引用次数: 0
TECHNOLOGICAL BASIS OF THE PROCESS OF ZIRCONIUM AND HAFNIUM SEPARATION 锆铪分离工艺的技术基础
Q4 PHYSICS, NUCLEAR Pub Date : 2023-10-12 DOI: 10.46813/2023-147-103
A.P. Mukhachev, D.O. Yelatontsev, O.A. Kharytonova, V.G. Shevchenko
The paper presents the results of industrial testing of the process and equipment for the extraction separation of zirconium and hafnium in a single technological cycle with the production of high-purity nitrate compounds and pure nitric acid solutions as raw materials for the production of sodium nitrate. It is shown that the efficiency of the extraction process is determined primarily by the purity of the nitric acid solution by the content of a critical impurity – silicic acid, which causes an undesirable emulsification process and disrupts the stability of the process. Optimal conditions have been determined under which the formation of non-extractable forms of zirconium and hafnium is excluded. The replacement of pulsating columns with centrifugal extractors reduced operating costs by reducing the volume of a one-time load of a flammable extractant and its losses as a result of hydrolysis. This increased the degree of separation of zirconium and hafnium. Centrifugal extractors provided high process kinetics, reduced production areas, and increased labor productivity and product quality.
本文介绍了以生产高纯硝酸化合物和纯硝酸溶液为原料生产硝酸钠的单工艺循环提取分离锆铪的工艺和设备的工业试验结果。结果表明,萃取过程的效率主要取决于硝酸溶液的纯度和关键杂质硅酸的含量,硅酸会引起不良的乳化过程,破坏萃取过程的稳定性。确定了排除锆和铪不可萃取形式形成的最佳条件。用离心萃取器代替脉动塔,减少了一次性可燃性萃取剂负荷的体积及其因水解造成的损失,从而降低了运营成本。这增加了锆和铪的分离程度。离心萃取器提供了高过程动力学,减少了生产面积,提高了劳动生产率和产品质量。
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引用次数: 0
TEXTURAL AND STRUCTURAL REGULARITIES OF DEFORMATION BY ROLLING OF Zr-2.5%Nb ALLOY Zr-2.5%Nb合金轧制变形的织构和组织规律
Q4 PHYSICS, NUCLEAR Pub Date : 2023-10-12 DOI: 10.46813/2023-147-077
D.G. Malykhin, V.M. Grytsyna, K.V. Kovtun
A review of studies of regularities of changes in the crystallographic texture of the longitudinal and cross rolling of the Zr-2.5%Nb alloy is given. Accordingly with this, plates were made from longitudinal fragments and rings of a tube 15.01.5 mm from the fuel assemblies of Russian RBMK reactors. The plates were annealed at 580 °C for 3 h. X-ray studies of texture changes with the degree of deformation of the plates by rolling were carried out. The principle of method of inverse pole figures was used with the calculation of the Kearns texture coefficients, as well as measurements of tilt curves (0002) was. Non-uniformiity of deformation during straightening of the tube blanks was taken into account. It is found that the main rotations of crystallographic c-axes in the plates at any rolling direction are carried out in the plane corresponding to the cross-section of the original tube. Existence of an initial stage of increased textural changes during deformation of the plates is found, what is qualitatively and quantitatively related to activity of tensile twins of the {1012}[1011] system. Regularities in texture changes at the subsequent moderate stage of deformation with the participation of compression twins are considered. The purely twinning nature of the textural doublet, which latter is characteristic of the rolling texture of metals of the titanium subgroup, is explained. It is noted and explained a fact that during cross rolling of plates (made from tube rings), textural changes occur at a rate twice as high as during longitudinal rolling. As considered, all similar regularities can be carried out for the metals of the titanium subgroup.
综述了Zr-2.5%Nb合金纵轧和横轧结晶织构变化规律的研究进展。因此,板是由纵向碎片和管环15.01.5毫米从俄罗斯RBMK反应堆的燃料组件。在580°C下退火3 h, x射线研究了轧制变形程度对织构变化的影响。利用反极图法的原理,计算了Kearns纹理系数,并对倾斜曲线(0002)进行了测量。考虑了管坯矫直过程中变形的不均匀性。结果表明,在任意轧制方向上,板料中c轴的主要旋转都是在与原管截面相对应的平面上进行的。发现在板块变形过程中存在初始阶段增加的织构变化,这在定性和定量上与{1012}[1011]体系的拉伸孪晶的活性有关。考虑了在压缩孪晶的参与下,在随后的中等变形阶段织构变化的规律。解释了纯孪晶的织构性质,后者是钛亚族金属的滚动织构特征。注意到并解释了一个事实,即在板(由管环制成)的交叉轧制过程中,纹理变化发生的速度是纵向轧制的两倍。考虑到这一点,所有类似的规律都可以适用于钛亚族的金属。
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引用次数: 0
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Problems of Atomic Science and Technology
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