Pub Date : 2025-11-22DOI: 10.1007/s11356-025-36924-0
Ravi Nath Tiwari, Henri Schneider, Catherine Azzaro-Pantel, Chandrakala Mishra, Ahmed G. Elkafas, Aristide Fausto Massardo
The world’s rapid advancements have increased energy demand, necessitating both traditional and alternative sources. Non-renewable energy sources contribute to greenhouse gas emissions, prompting urgency to address climate change. The study explores the implementation of a hybrid energy microgrid system for a mountain shelter “refuge” in southern France, aiming to reduce environmental impact. The system uses photovoltaics, electrolysers, and batteries, focuses on hydrogen production and storage, as well as renewable electric power generation. The study compares the environmental impacts of the hybrid system and conventional energy systems, focusing on the impact of photovoltaic module production both globally and locally in France. The study highlights the importance of renewable energy sources in reducing environmental impact. A study using SimaPro and the ecoinvent database found that PV arrays account for 97% of environmental impacts, while other components contribute to 3%. Locally manufactured microgrids in France reduced environmental impact by 39% compared to standard systems. The PV system and electrolyser in a mountain shelter showed favourable environmental and economic outcomes. The study emphasizes the importance of local manufacturing locations and electricity mix for PV module manufacturers.
{"title":"Life cycle assessment of an isolated hybrid micro-grid with hydrogen production and storage","authors":"Ravi Nath Tiwari, Henri Schneider, Catherine Azzaro-Pantel, Chandrakala Mishra, Ahmed G. Elkafas, Aristide Fausto Massardo","doi":"10.1007/s11356-025-36924-0","DOIUrl":"10.1007/s11356-025-36924-0","url":null,"abstract":"<div><p>The world’s rapid advancements have increased energy demand, necessitating both traditional and alternative sources. Non-renewable energy sources contribute to greenhouse gas emissions, prompting urgency to address climate change. The study explores the implementation of a hybrid energy microgrid system for a mountain shelter “refuge” in southern France, aiming to reduce environmental impact. The system uses photovoltaics, electrolysers, and batteries, focuses on hydrogen production and storage, as well as renewable electric power generation. The study compares the environmental impacts of the hybrid system and conventional energy systems, focusing on the impact of photovoltaic module production both globally and locally in France. The study highlights the importance of renewable energy sources in reducing environmental impact. A study using SimaPro and the ecoinvent database found that PV arrays account for 97% of environmental impacts, while other components contribute to 3%. Locally manufactured microgrids in France reduced environmental impact by 39% compared to standard systems. The PV system and electrolyser in a mountain shelter showed favourable environmental and economic outcomes. The study emphasizes the importance of local manufacturing locations and electricity mix for PV module manufacturers.</p></div>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":"32 47","pages":"27141 - 27161"},"PeriodicalIF":5.8,"publicationDate":"2025-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145581725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-22DOI: 10.1007/s11356-025-37220-7
Ayşegül Bilen Özkan, Mert Altay, Erdal Ünal, Oğuz Gündüz
This study presents a novel method for integrating amine-based CO₂ capture with mineral carbonation by using steelmaking slag to regenerate monoethanolamine (MEA) solutions. Unlike conventional thermal desorption methods, this approach enables chemical CO₂ desorption under mild conditions while simultaneously sequestering CO₂ as stable carbonates. Although mineral carbonation and MEA-based capture have been widely studied separately, their combination via reactive calcium-rich industrial waste remains largely unexplored. In this work, steel slag was contacted with CO₂-loaded MEA solutions to assess its dual role in promoting CO₂ release and mineralization. The effects of key process parameters—including slag-to-water ratio, CO₂ flow rate, temperature (25–75 °C), MEA concentration (0–0.5 M), and water type (service vs. seawater)—were systematically evaluated. Carbonation efficiency was quantified via TGA, XRF, and XRD analyses. Results showed that MEA significantly enhanced CO₂ uptake and accelerated carbonate formation, especially at higher temperatures and in seawater. Kinetic modeling revealed that the reaction follows a mixed-controlled mechanism involving both surface reaction and product-layer diffusion, with an apparent activation energy of 5.6 kJ/mol. The study demonstrates the feasibility of combining CO₂ desorption and mineralization in a single step, offering a low-energy alternative to MEA regeneration and a sustainable use for steel slag in CO₂ capture systems.
{"title":"Carbonation of steel slag for mineral CO2 sequestration: a novel method for desorption of CO2-loaded monoethanolamine (MEA)","authors":"Ayşegül Bilen Özkan, Mert Altay, Erdal Ünal, Oğuz Gündüz","doi":"10.1007/s11356-025-37220-7","DOIUrl":"10.1007/s11356-025-37220-7","url":null,"abstract":"<p>This study presents a novel method for integrating amine-based CO₂ capture with mineral carbonation by using steelmaking slag to regenerate monoethanolamine (MEA) solutions. Unlike conventional thermal desorption methods, this approach enables chemical CO₂ desorption under mild conditions while simultaneously sequestering CO₂ as stable carbonates. Although mineral carbonation and MEA-based capture have been widely studied separately, their combination via reactive calcium-rich industrial waste remains largely unexplored. In this work, steel slag was contacted with CO₂-loaded MEA solutions to assess its dual role in promoting CO₂ release and mineralization. The effects of key process parameters—including slag-to-water ratio, CO₂ flow rate, temperature (25–75 °C), MEA concentration (0–0.5 M), and water type (service vs. seawater)—were systematically evaluated. Carbonation efficiency was quantified via TGA, XRF, and XRD analyses. Results showed that MEA significantly enhanced CO₂ uptake and accelerated carbonate formation, especially at higher temperatures and in seawater. Kinetic modeling revealed that the reaction follows a mixed-controlled mechanism involving both surface reaction and product-layer diffusion, with an apparent activation energy of 5.6 kJ/mol. The study demonstrates the feasibility of combining CO₂ desorption and mineralization in a single step, offering a low-energy alternative to MEA regeneration and a sustainable use for steel slag in CO₂ capture systems.</p>","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":"32 47","pages":"27162 - 27180"},"PeriodicalIF":5.8,"publicationDate":"2025-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145572758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-22DOI: 10.1007/s11356-025-37230-5
Zakaria Al-Qodah, Guilherme Luiz Dotto, Reyad Shawabkeh, Ahmad T Shawaqfeh, Mohammad Al-Shannag
{"title":"Advances in separation processes for sustainable solutions in energy and environment.","authors":"Zakaria Al-Qodah, Guilherme Luiz Dotto, Reyad Shawabkeh, Ahmad T Shawaqfeh, Mohammad Al-Shannag","doi":"10.1007/s11356-025-37230-5","DOIUrl":"https://doi.org/10.1007/s11356-025-37230-5","url":null,"abstract":"","PeriodicalId":545,"journal":{"name":"Environmental Science and Pollution Research","volume":" ","pages":""},"PeriodicalIF":5.8,"publicationDate":"2025-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145572799","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-21DOI: 10.1007/s11356-025-37243-0
Habib Akyazı, Fatma Çiğdem Güldür, Ebru Beyzi
This study aimed to investigate the effects of anode surface modifications on microbial community composition and chemical oxygen demand (COD) removal efficiency in microbial fuel cells (MFCs). Four different anode electrodes were fabricated: bare nickel foam (NF), reduced graphene oxide-coated nickel foam (rGO/NF), and rGO/NF modified with 30 wt% and 50 wt% molybdenum (Mo). These electrodes were tested in a single-chamber, membraneless, air–cathode MFC. Surface morphology was characterized using scanning electron microscopy (SEM), and microbial diversity was assessed through 16S rRNA metagenomic sequencing. Distinct microbial profiles were observed across the electrode types. The NF anode supported high abundances of Mesoterricola sediminis (22.2%), Klebsiella pneumoniae (10.1%), and other facultative species. The rGO/NF electrode promoted colonization by Cutibacterium acnes (8.1%) and Paracidovorax avenae (5.4%). On the 30Mo/rGO/NF electrode, notable species included Escherichia coli (8.4%) and Salmonella enterica (6.0%). The 50Mo/rGO/NF anode exhibited the highest microbial diversity, with species such as Streptomyces sp. RerS4 (6.9%) and Micromonospora endophytica (6.5%) being predominant. The highest COD removal efficiency (88.58%) was achieved using the 50Mo/rGO/NF anode. These findings demonstrate that molybdenum-modified rGO coatings enhance both microbial colonization and electrochemical performance, offering a promising strategy for improving MFC efficiency in wastewater treatment applications.