Environmental Science and Pollution Research最新文献

This paper presents a preliminary assessment of waste accumulation along riverbanks in Italy, aiming to provide baseline data for future monitoring and management efforts. The study surveyed 18 stations along 16 rivers across different regions of Italy, from north to south, to quantify and characterise the types and abundance of litter present along their banks. Field surveys were conducted by Legambiente citizen scientists applying a standardised protocol to record and categorise litter items systematically. Results indicate widespread litter accumulation, with a median density of 457 items/100 m and 0.2 items/m². A diverse range of items was observed, including artificial polymer materials (56%), glass/ceramics (20%), metal (11%), and paper/cardboard (6%). Half of the items belonged to just four categories: glass bottles (17%), cigarette butts (14%), plastic pieces (11%), and wet wipes (8%). Differences in litter density and composition were observed according to the land use (urban, agricultural, natural, urban park) of the area surrounding the monitoring stations. Riverbanks included in urban parks presented the highest litter densities. They were characterised by the high presence of litter from recreational activities (glass bottles, cigarettes, caps, and pull tabs), suggesting uncivil behaviour by visitors. The findings of this study allow for the identification of litter sources and underscore the importance of citizen science in filling information gaps since no previous data on litter on riverbanks in Italy were available.

Energy from renewable resources has been growing in popularity, which ultimately helps reduce emissions of greenhouse gases (GHGs) and contaminants. Since hydrogen (H₂) has a higher combustion production of energy than hydrocarbon fuels, it has been identified as a clean, sustainable, and environmentally friendly energy source. There are several benefits to producing biohydrogen (bioH₂) from renewable sources, including lower cost and increased sustainability. Among the bioH₂ production processes, dark fermentation supports commercialization and scale-up for industrial applications. This paper considers the various bioreactors, such as anaerobic sequencing batch, continuous stirred, up-flow, fixed-bed, and membrane reactors, and their operational approaches for bioH₂ production. This review paper also performs the bibliometric analysis method to identify historical and current developments in a particular field of reactor configuration studies. Furthermore, the main variables influencing reactor performance and methods for increasing process efficiency considering economic and environmental aspects are addressed. The results revealed that continuously stirred reactors are widely utilized for bioH₂ production as a cost-effective reactor configuration. Moreover, the membrane bioreactors and fixed-bed reactors are yielded higher bioH₂ performance than other configurations. Nevertheless, high energy consumption and costs have presented the need for further development of reactors. Consequently, future recommendations to solve the critical problems faced in reactor configurations, the gaps in the literature, and the points that need improvement were comprehensively reported.

In the present study, combustion-synthesized TiO₂ nanoparticles were wet impregnated with Ni, Co, and Ni-Co, respectively. The photocatalytic performance of synthesized catalysts was evaluated against Malachite Green dye. The synthesized materials were characterized for crystallite size, surface morphology, elemental composition, and band gap using X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, and ultra-violet diffused reflectance spectroscopy, respectively. The optimum parameters for maximum degradation were found by examining the effects of catalyst loading, initial dye concentration, and light intensity. A comparative analysis of Ni-doped, Co-doped, and Ni-Co-doped TiO₂ photocatalysts was conducted. The results indicate superior photocatalytic activity of Ni-Co doped TiO₂ among the catalysts investigated under UV light. The degradation kinetics was studied, and the underlying degradation mechanism was proposed with the help of LC-MS analysis. Furthermore, a comparative study on the degradation under solar radiation using Ni-Co/TiO₂ was conducted.

Contamination of water resources by artificial coloring agents and the increasing incidence of bacterial illnesses are two significant environmental and public health issues that are getting worse day by day. Traditional treatment techniques frequently fail to address these problems adequately in a sustainable and environmental friendly way. In response, our study presents a novel photocatalyst that demonstrates superior photodegradation capability and antibacterial qualities in catering the above issues. Sonochemical synthesis route was adopted to synthesize the nanocomposite of zinc oxide/bismuth oxide (ZnO-Bi₂O₃) along with pure ZnO and Bi₂O₃. X-ray diffraction investigation was performed to analyze the crystallographic structure and confirmed the formation of the composite. High-resolution transmission electron microscopic analysis showed that the particle size of the composite to be in 20 to 55 nm range with the formation of heterojunction at ZnO/Bi₂O₃ interface. Fourier transformed infrared spectroscopic and micro Raman studies of the nanocomposite sample helped to detect the presence of stretching vibrations linked with Zn and Bi ions. X-ray photoelectron spectroscopy study revealed the chemical constitution and electronic states of the nanocomposite sample displaying the Zn 2p, Bi 4f, and O 1 s spectral lines. Investigation on the photocatalytic efficiency of the samples was done and the results showed an appreciable increase in photodegradation efficiency for the composite sample in degrading methylene blue (93.24%) and Congo red (92.47%) dyes in 180 min. The effect of pH, photocatalyst amount, and dye concentration on the efficiency of degradation was also been examined. Two primary causes of the enhanced performance of the composite are the generation of hydroxyl radicals (OH•) and the suppression of carrier recombination which is initiated by the synergistic combination of the two metal oxides in the nanocomposite. The nanocomposite sample was found to be stable and reusable for its effective use in environmental cleanup. By using the disk diffusion process, the antibacterial potential of the samples was analyzed and it was discovered that the nanocomposite showed an exceedingly superior antibacterial performance than the pristine samples in preventing the growth of two strains of bacteria, i.e., Escherichia coli and Staphylococcus aureus.

This study evaluates the environmental and human health impact of sewage sludge generated in the Indo-Gangetic region (Uttarakhand and Uttar Pradesh) used as organic fertilizer and landfill disposal. The research conducts a comprehensive risk assessment, including physicochemical and heavy metals analysis, on triplicate sludge samples obtained from 30 sewage treatment plants. The study provides both qualitative and quantitative insights into potential hazards associated with sewage sludge. The results indicate varying concentrations (mg/kg) of heavy metals in sewage sludge (expressed in mean ± SD) as determined by inductively coupled plasma mass spectrometry (ICP-MS) with the following order, zinc (966.15 mg/kg ± 279) > chromium (851.23 mg/kg ± 3079) > cadmium (150.07 mg/kg ± 307) > copper (186.09 mg/kg ± 56.25) > arsenic (5.24 mg/kg ± 3.54) > nickel (21.97 mg/kg ± 2.13) > mercury (1.05 mg/kg ± 0.12). The metal pollution indices underscore greater non-compliance in samples from STPs of Uttar Pradesh compared to those from Uttarakhand, with 40% of samples falling into poor to particularly poor categories. Multivariate analysis of samples reveals potential pollution sources, implicating industrial effluents and agricultural runoff, with identified controlling factors being Cu (0.948, p < 0.05); Zn (0.941 p < 0.05); Pb (0.921 p < 0.05); Ni (0.806 p < 0.05); Cd (0.717, p < 0.05); and electrical conductivity (0.620, p < 0.05). Monte Carlo-based uncertainty analysis emphasizes sludge-based chromium (Cd) as the highest risk at 62.86% (p < 0.001), trailed by chromium (59.29%, p < 0.001) for target cancer risk. The study also suggests potential management options, including the application of AI-based sensors for heavy metal monitoring, exploration of improved trapping or diluting technologies, and raising public awareness about stringent rules regarding sewage sludge remediation for effective risk mitigation strategies.

The focus in the present study is on the quantification soil erodibility properties (representing an erosion threshold (such as the critical shear stress) and a resistance property (e.g., the soil erosion coefficient)). These are necessary for an adequate assessment of soil erosion mechanisms affecting earth-made hydraulic structures (e.g., dams, dykes and levees). The paper gives a quantitative statistical analysis of the aforementioned soil erodibility parameters. To do so, a wide range of experimental tests, used for the study of internal erosion (hole erosion test (HET) and slot erosion test (SET)) and surface erosion (jet erosion test (JET), flume test (FT), erosion function apparatus (EFA), and rotating cylinder test (RCT)), were examined. A dataset of previously published experimental data was collected, harmonized, structured, treated, and used in a multicriteria analysis. The outcomes of the study provide a better understanding of the limitations and ambiguity in the assessment soil erodibility properties, highlight the differences among tests and between processes, and assess their inter-useability. Correlations between the erodibility properties themselves and between each of them and an in-study-defined midrange soil texture diameters were evaluated at specific level of erosion process, erosion test, and/or soil texture. Furthermore, a set of new empirical formulas has been proposed linking soil erodibility properties to themselves or each erodibility properties to the midrange soil texture diameter. A set of reference values and ranges and trends for the studied erodibility properties, useful for design or risk assessment purposes or for evaluating the quality of experimental data, are derived.

Effective microorganisms pose a great potential in wastewater treatment. In the present study, effective microorganisms' formulations were developed using different organic substrates that support the growth of more beneficial microorganisms for sewage treatment. Based on the metagenomic analysis and biochemical profile information, the fish waste-based effective microorganisms' formulation was identified as the effective formulation. Metagenomic analysis showed that fish-based effective microorganisms' formulation had the Lactobacillus and Acetobacter groups of bacteria. The dominant groups were Lactobacillus pontis (64.85%), Acetobacter aceti (8.92%), and Lactobacillus reuteri (8.98%). The developed fish waste-based effective microorganisms' formulation was used to treat the sewage water with different concentrations. Effective microorganisms' formulation at 3% showed appreciable results. It recorded a significant reduction in BOD from 389.2 to 117.9 mg L^-1 and COD from 820.5 to 257.1 mg L^-1 in 96 h. It also significantly decreased the concentration of ammoniacal and nitrate nitrogen, phosphorus, sulphate, and coliforms. Besides, the effective microorganisms' formulation ensured the reduced level of odour from sewage water. Therefore, we can effectively use the effective microorganisms' formulation for sewage water treatment and recycling.

An investigation into the degradation of ciprofloxacin (CIP) under visible light was carried out using an efficient photocatalyst, i.e., CoFe₂O₄@3D-TiO₂@GA, synthesized by doping CoFe₂O₄@three-dimensional-TiO₂ into a hierarchical porous graphene aerogel. Optimal conditions for achieving complete removal of CIP involved a reaction time of 60 min, a catalyst dose of 0.6 g/L, an initial CIP concentration of 25 mg/L, and a solution pH range of 3-5. The reusability of CoFe₂O₄@3D-TiO₂@GA was observed to remain high even after four consecutive cycles, as the CIP degradation only slightly decreased from 94.3 to 87.1%. Following a 2-h photocatalytic degradation process, the intermediate products within the CIP solution no longer posed a threat to E. coli. The TOC analysis confirmed that CIP achieved 86% total mineralization. In the raw sewage, the BOD₅/COD and BOD₅/TOC ratios were 0.774 and 0.232, respectively. However, after a 120-min photocatalytic reaction, these ratios increased to 1.38 and 0.754, respectively. These findings suggest that non-biological sewage can be successfully transformed into biodegradable effluent through photocatalytic degradation. The photocatalytic process has a reaction rate coefficient that is 8.7 to 20.7 times higher than the adsorption process, depending on the concentration. The half-life constant is 117.4 min for the optimal concentration of 10 mg/L for the adsorption process, while for the photocatalytic process, it is 6.24 min. The research has highlighted the importance of integrating adsorption and photocatalysis, whereby primary reactive oxidative species, including superoxide and hydroxyl radicals, were identified. The study presents a pioneering approach for producing CoFe₂O₄@3D-TiO₂@GA, which has promising potential for environmental applications utilizing visible light.

Environmental factors play a fundamental role in shaping fish assemblage in aquatic ecosystems. The present study describes the fish assemblage structure on the spatial scale in Pong Reservoir, which lies in foothills of the Northwestern Himalaya within the river Beas basin. Through sophisticated enviro assessment techniques, using ArcGIS mapping, this study provides valuable insight into how physicochemical factors shape the fish assemblage in the reservoir. In total, 1211 individuals belonging to 8 orders, 10 families, 15 genera, and 19 species were recorded. The order Cypriniformes has the highest number of species. The invasive species Oreochromis niloticus was also documented for the first time in this reservoir. At a spatial scale, diversity indices reveal that the lacustrine zone had the lowest fish diversity. The transitional zone showed more species richness as compared to other riverine and lacustrine. The IUCN conservation status showed that among 19 fish species, two species (Wallago attu and Cyprinus carpio) are under vulnerable and only one species, Tor putitora, is under the endangered category. The majority of recorded water quality parameters fell within the acceptable range. CCA analysis of physiochemical parameters with fish abundance reveals that DO and turbidity were found to positively influence the species abundance. These findings provide a valuable resource for understanding ecology and also lay a solid foundation for the development of effective fisheries management strategies in this reservoir.