Environmental Science and Pollution Research最新文献

Lead (Pb) is known to be extremely toxic to plants and awfully affects growth and productivity by interacting with morphological, biochemical, and physiological processes. Micronutrients are considered to reduce ion toxicity and modify various physiological processes involved in oxidative stress tolerance in plants. Hence, the limited literature about the application of micronutrients, particularly manganese (Mn), under lead stress thus demands more investigations. To sort out the role of priming treatments of Mn (1.0 and 0.1 mg/L) in lead stress (200 mg/kg) induced oxidative stress tolerance in wheat cultivars (Anaj-17 and Akbar-19), current experiment was designed. The experiment was arranged with completely randomized design (CRD) with three replicates. The results explored the positive role of Mn priming in strengthening the antioxidant system with increased activities of antioxidants under Pb stress. Mn priming level (0.1 mg/L) significantly increased the germination percentage, germination percentage, growth traits, grain yield per plant, shoot P, shoot Ca²⁺, and shoot K⁺ while decreasing the MDA and H₂O₂ levels, of Anaj-17 and Akbar-19 under Pb stress (200 mg/kg). Seed priming levels of Mn further upgraded the antioxidant enzymatic activities and organic osmolytes such as proline, total phenolics, flavonoids, total soluble sugars, and glycine betaine, under Pb stress. Conclusively, the 0.1 mg/L level of Mn priming and Akbar-19 cultivar has proven superior in lead detoxification under Pb-induced oxidative stress. Furthermore, the outcomes revealed more accumulation of Pb in the roots of wheat than in the shoots of both wheat cultivars and emphasized the use of lower Mn levels of 0.1 mg/L as the best strategy in alleviating the toxic impacts of lead in wheat. However, the conduct of large field trials is a necessity of current scenario to study the molecular aspects and associated genes contributing Pb stress tolerance with priming application of Mn and other micronutrients.

In the paper, a mathematical model was constructed that describes the specifications of the wind flow and the dispersion of pollutants, taking into account the variable temperature on the roadway surface, which varies depending on the time for some quarter of the city of Almaty. The impact of the traffic tidal flow was studied based on the data of measuring passing vehicles as a source of pollution by the CFD and on the spatial distribution of pollutants for various types of pollution. A test problem was performed to validate the numerical algorithm and the mathematical model. From the obtained numerical solutions, it was determined that the existing barriers along the road have a positive effect on pedestrian zones regardless of the type of pollution. It was also found that, taking into account the variable temperature on the carriageway, the presence of barriers with a height of 4 m shows favorable behavior on the adjacent areas, in which the average concentration value drops by 6.4 times for the pedestrian zone, which is located on the left side and 2.9 times for the pedestrian zone, which is on the right side compared to the option without a barrier.

The occurrence, spatiotemporal changes, and health hazard of antibiotics in source water and finished water in the Wuhan section of the Yangtze River are not well understood. In this study, 43 source water and finished water samples were collected from 11 water plants in Wuhan in August 2021 and May 2022. Fifty-one antibiotics from eight categories were measured. A total of 41 antibiotics were detected in the source water samples, and 24 in the finished water samples. The total antibiotic concentration in source water ranged from 1.68 to 437.18 ng/L, which is significantly higher than that in finished water (2.04-87.25 ng/L). Sulfonamides and lincosamides were predominant, accounting for nearly 80% of the total antibiotic concentration. Lincomycin constituted nearly 30% of the total antibiotic concentration in the source water. In August 2021, the average total antibiotic concentration in source water was 107.12 ng/L, higher than in May 2022 (63.13 ng/L). Spatially, the total antibiotic concentrations in samples collected from the Han River, a tributary of the Yangtze River, were higher than those in the main stream of the Yangtze River. Ecological risk assessment indicated that the hazard posed by most antibiotics were negligible. Lincomycin potentially posed a high health hazard, and clarithromycin and roxithromycin posed a moderate hazard to infants.

Bioaccumulation of trace elements in aquatic environments can be influenced by local environmental conditions such as temperature fluctuations, pH levels, sediment composition, dissolved organic matter content, and the presence of other chemical substances. We analyzed the differences in trace elements accumulation (S, Cl, K, Ca, Ti, Cr, Mn, Fe, Cu, Zn, Rb, Sr, Mo, Ba, and Pb) between two trophic guilds-scrapers (Ephemeroptera) and predators (Plecoptera)-of freshwater benthic macroinvertebrates collected from mountain streams in Kazakhstan and Slovakia. Trace elements in dried insect bodies were analyzed using an X-ray spectrometer, and physicochemical parameters of stream water were investigated at each sampling site. Our results showed significant differences in Fe, Ti, and Sr levels in predators from Kazakhstan and Cu levels in predators from Slovakia. Despite some trace elements showing higher concentrations in one group over another, the overall differences between regions were more pronounced. Principal component analysis (PCA) revealed that the primary factors influencing trace elements variability were associated with environmental conditions such as temperature, oxygen levels, and total dissolved solids (TDS). PCA components indicated a higher load of trace elements in the warmer, less oxygenated streams, particularly in Kazakhstan. These findings suggest that both biotic (feeding strategies) and abiotic (geographical and environmental conditions) factors significantly influence trace elements dynamics in freshwater ecosystems.

Biofuel has gained significant attention as a potential source to meet fuel demands instead of fossil fuel. The price of biofuel and alternative fuel have a considerable impact on biofuel demand. Thus, it is important to design a biofuel supply chain network that incorporates the biofuel price into an elastic demand. More precisely, a variable demand, including customer importance level (to the environment), biofuel price, and substituted fuel price, is considered in this research. Furthermore, this research presents a bi-objective mixed-integer quadratic formulation that aims to maximize the total profit of the supply chain and carbon absorption in harvesting areas. The problem is solved by the ε-constraint and lagrangian relaxation methods due to its complexity. Moreover, substituted fuel price uncertainty is addressed by two-stage stochastic programming. Finally, a real case study utilizing the data envelopment analysis approach is applied to assess the efficiency and currency of the addressed model. Several consequences are illustrated in the case study, such as rich areas for exporting algae, suggesting hub locations for biofuel production, etc.

Activated carbon (AC) and hydroxyapatite (HAp) composite were successfully prepared via mechanical mixing and exhibited a crushed snack-like morphology compared to the well-defined pore structure of pure AC. The purpose of this research was to explore the potential of AC/HAp for the degradation of methylene blue (MB) dye and hydrogen production. Despite the morphological changes, AC and AC/HAp achieved a high MB degradation rate (92.75 and 82.05) % under sunlight, at a temperature of 26.24 °C and pH of 4.18, and showed optimum hydrogen production (3579 mol/g.h). These performances are suspected from the decrease in crystallite size and narrowed $\Delta (LO-TO)$ and confirmed by image processing results with RBG enhancement showing more light transmitted by the solution. Increasing in ${ϵ}_2$ indicates the potential for improved light interaction. IoT-enabled real-time monitoring system demonstrates its efficacy in facilitating wastewater treatment and hydrogen production, offering a promising solution for aquatic ecosystem restoration.

Aquatic ecosystems face multiple stressors, including thermal fluctuations and chemical pollutants, which can detrimentally impact fish health and ecosystem integrity. This study investigates the individual and combined toxic effects of 4-nonylphenol (4-NP) and thermal stress on juvenile tilapia fish (Oreochromis niloticus). Four groups of fish were exposed to different stressors for 15 days: control, thermal stress (35 °C ± 1 °C), 4-NP exposure (1 mg/L), and a combination of thermal stress and 4-NP. Results reveal significant alterations in antioxidant enzyme activity, lipid peroxidation levels, and cytokine expression in response to stressors. Thermal stress and 4-NP exposure disrupt antioxidant defense mechanisms and increase oxidative stress. Thermal stress profoundly affects fish health and metabolism, impacting physiological functions and immunity. Thermal stress induces reactive oxygen species production, triggering antioxidant responses and affecting immune parameters. Exposure to 4-NP exacerbates oxidative stress, further compromising fish health. The observed increase in pro-inflammatory cytokines implies an immunostimulatory reaction to stressors. These findings underscore the complex interactions between environmental stressors, immune responses, and fish health. Further research is needed to fully understand these interactions and their implications for aquatic ecosystems. Implementing these biomarkers in ecological risk assessments can provide insights into the impacts of environmental stressors and inform conservation and management strategies in aquaculture.

Evidence on prospective remediation of municipal solid waste contaminated with toxic heavy metals by Eudrilus eugeniae (Eu) and Lampito mauritii (L) is very scarce and yet to be explored. In this study, heavy metal detoxification potential of E. eugeniae and L. mauritii in municipal solid waste (MSW) + cowdung (CD) (3:1)-based feedstocks were investigated against Eisenia fetida (E) (a well-known vermi-remediator) and aerobic composting. Excellent reduction (70.01-93.04%) of potentially toxic heavy metals (PTHMs) (Pb, Cr, Cd and Zn) were evident in both E. eugeniae and L. mauritii employed treatments. Moreover, the results on heavy metal budget quotient clearly demonstrated the unique detoxification route undertaken by E. eugeniae and L. mauritii via humic composite facilitated chelation over the nominal bioaccumulation pathway. The principal component analysis (PCA) confirmed the strong negative correlation between the heavy metal (HM) level in earthworm gut and MSW substrate, whereas a strong positive correlation between humic substances and HM remediation. Furthermore, analysis of ecological health parameters indicated substantial reduction of environmental risk and guaranteed negligible risk of PTHM if utilized as manure. Moreover, significant increment in total N content (3.2-3.8-fold), available P (4-5.9-fold), exchangeable K (3.66-fourfold) and enzyme activity along with significant reduction of TOC (~ 87%) confirmed E. eugeniae and L. mauritii could effectively stabilize MSW. Thus, the metal-binding potential of humic substances produced by earthworms during the detoxification of municipal solid waste (MSW), coupled with a metal budget analysis, has offered valuable insights into the usage of E. eugeniae and L. mauritii as effective contenders for sanitizing heavy metal-laden MSW.

In today's world, water is a highly valued resource, and enhancing the quality of this natural endowment is a significant concern and a worldwide endeavor. This study sought to purify real wastewater and water tainted with methylene blue (MB) by immobilizing ZnO nanoparticles onto an alginate matrix using a straightforward approach and a three-dimensional structure. After analyzing the impact of ${\text{H}}_2{\text{O}}_2$ , it was determined that 93.84% of MB was successfully removed (time = 120 min, dye concentration = 15 mg/L, catalyst amount = 2.5 g). The effects of inorganic ions and water types were investigated to simulate real wastewater conditions, and the catalyst performed satisfactorily. Alginate played a significant role in selectively removing dye, and the catalyst effectively removed 80.36% of MB and, in contrast, 20% of methyl orange (MO). The practical application of the catalyst was evaluated in textile wastewater treatment, and the catalyst showed satisfactory performance. An average 2.49% reduction in dye removal was observed after five stages of using the catalyst, demonstrating the beads' excellent stability. The composites were subjected to free radical trapping experiments to ascertain the active species. According to the results, ${\text{h}}^{+}$ and $·\text{OH}$ acted as the main reaction species in the degradation of MB. At the end, the synergistic mechanism of adsorption and degradation in MB removal was presented.

This study investigated the size-segregated carbonaceous components of particulate matter (PM), including ultrafine particles (UFP or PM_0.1), across three distinct urban settings in Phnom Penh, Cambodia: an educational site (University of Health Sciences, UHS), an institutional site (Ministry of Environment, MoE), and a residential area near a landfill. A cascade impactor-type sampler equipped with an inertial filter was used to collect size-segregated particles down to UFPs. Carbonaceous species, including organic carbon (OC) and elemental carbon (EC), were analyzed using a thermal/optical carbon analyzer to determine their composition and ratios. The results indicated no significant differences in mass concentration between weekdays and weekends at all sites; however, PM profiles varied across the location. The UHS site displayed higher EC levels in UFP, with concentrations suggesting significant local vehicular emissions, underscored by a lower OC/EC ratio (2.39 ± 1.13) compared to other sites. In contrast, the landfill site exhibited higher OC components in finer particles, suggesting emissions from organic sources such as waste burning and cooking activities, evidenced by higher OC/EC ratios across all particle sizes (e.g., OC/EC ratio in UFP at 3.78 ± 0.98). The MoE site presented a balanced profile with moderate levels of both OC and EC, influenced by its proximity to natural dispersion factors like the Tonle Sap River. Additionally, air mass backward trajectory analysis integrated with hotspot data indicated transboundary influences, particularly from agricultural burning in surrounding provinces, including Vietnam. Therefore, both local and transboundary emissions influenced the PM levels in Phnom Penh city.