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Assessment of aroma release in filled chocolate wafers through electronic nose analysis 通过电子鼻分析评估填充巧克力晶片的香气释放情况
IF 3 3区 农林科学 Q2 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-05-19 DOI: 10.1007/s00217-024-04568-y
Pedro Lucas Trombeta Da Silva, Giovana Feltes, Thais Feiden, Sandra Cristina Ballen, Juliana Steffens, Clarice Steffens

The present research sought to evaluate the detection capacity of the electronic nose for the hazelnut aroma in a filled chocolate wafer, measuring its release and physical–chemical, thermal, and microbiological properties during 60 days where the product was stored at 25 °C and 40 °C. It was found that moisture, Aw, pH, thermal resistivity, and diffusivity remained stable during storage at both temperatures, with no significant difference (p > 0.05). While there was variation in color (L*, a*, b*, and ΔE) and in thermal conductivity. The microbiological analyses of mesophilic bacteria, Escherichia coli, Salmonella spp., and coagulase-positive staphylococci were maintained in accordance with the standards established by current legislation. The results obtained with the sensors array showed good sensitivity and a high limit of detection (> 0.001 mg/mL) for hazelnut aroma. The electronic nose was able to discriminate between the release of volatiles from chocolates stored at 25 and 40 °C, with a greater response observed at high temperature (40 °C) at the beginning of storage. Through the application of the Arrhenius model, we successfully determined the activation energy for key color components (L*, a*, b*) and thermal conductivity. Additionally, our findings revealed a good fit of volatile component release to the zero-order model, characterized by a high correlation coefficient (> 0.9). These findings underscore the importance of considering storage temperature when preserving the quality of products such as chocolates. Furthermore, the study validates the use of the electronic nose as a viable technique for analyzing volatiles in food, providing valuable insights for the food industry.

Graphical abstract

本研究旨在评估电子鼻对填充巧克力威化饼中榛子香气的检测能力,测量产品在 25 °C 和 40 °C 下储存 60 天期间的释放、物理化学、热和微生物特性。结果发现,水分、Aw 值、pH 值、热阻率和扩散率在两种温度下储存期间保持稳定,没有显著差异(p > 0.05)。而色泽(L*、a*、b* 和 ΔE)和导热率则存在差异。对中嗜性细菌、大肠杆菌、沙门氏菌和凝固酶阳性葡萄球菌的微生物分析符合现行法律规定的标准。使用传感器阵列获得的结果显示,榛子香气的灵敏度高,检测限(> 0.001 mg/mL)高。电子鼻能够区分巧克力在 25 ℃ 和 40 ℃ 下的挥发物释放情况,在储存初期的高温(40 ℃)条件下,电子鼻的反应更大。通过应用阿伦尼乌斯模型,我们成功确定了主要颜色成分(L*、a*、b*)和热导率的活化能。此外,我们的研究结果表明,挥发性成分的释放与零阶模型非常吻合,相关系数高达 0.9。这些发现强调了在保存巧克力等产品质量时考虑储存温度的重要性。此外,该研究还验证了电子鼻是分析食品挥发性物质的一种可行技术,为食品行业提供了宝贵的见解。
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引用次数: 0
Identifying the sensory profile and fatty acid composition for quality valorization of Marrone chestnut cultivars 确定马龙栗栽培品种的感官特征和脂肪酸组成,提高其质量价值
IF 3 3区 农林科学 Q2 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-05-18 DOI: 10.1007/s00217-024-04579-9
Maria Teresa Frangipane, Stefania Garzoli, Daniela de Vita, Riccardo Massantini, Piermaria Corona

Consumers are increasingly interested in chestnuts for their health benefits and also for their organoleptic qualities. It is therefore very important to enhance the chestnut from a sensorial point of view. The sensorial characteristics of commercial chestnuts from three Italian Marrone cultivars (M1 ‘Marrone di Antrodoco’; M2 ‘Marrone dei Monti Cimini’; M3 ‘Marrone del Mugello’ PGI) were investigated with the aim of identifying their sensory profiles. The sensory evaluation was conducted according to (ISO 8589 in Sensory analysis. General guidance for the design of test rooms, 2007; UNI EN ISO 13299 in Sensory analysis. Methodology. General guidance for establishing a sensory profile, 2016). Each descriptor was scored on a range with intervals ranging from 0 (absence of the descriptor) to 10 (maximum intensity of the descriptor). The M1 cultivar is characterized by greater crunchiness (8.0, on a scale from 0 to 10), sweetness (7.5), aromatic intensity (7.9) and caramel aroma (3.3). The M2 cultivar is distinguished by its buttery (3.2) and floral aroma (3.0) with a wood/musk note (1.9) that is missing from the other two cultivars. The M3 cultivar has an almond aroma (5.2) and is distinguished by walnut (3.0) and citrus (2.8) aromas, which are absent in cultivars M1 and M2. The results of this study are important as they experimentally demonstrate that the identification of characteristic sensory profile makes the qualitative differences between cultivars evident. The results showed that linoleic, oleic and palmitic acids were the main components of the lipid fraction of chestnut nuts. In all samples the unsaturated fraction predominated over the saturated one. It is also important to note that there were significant quantitative differences between cultivars. The valorization of Marrone chestnut cultivars contributes to promoting consumer use of these products with their high nutritional value and therefore contributes to the promotion of public health.

消费者对栗子的健康益处和感官品质越来越感兴趣。因此,从感官角度提升栗子的品质非常重要。我们对来自三个意大利马龙栽培品种(M1'Marrone di Antrodoco';M2'Marrone dei Monti Cimini';M3'Marrone del Mugello' PGI)的商品栗子的感官特性进行了调查,目的是确定它们的感官特征。感官评估是根据(ISO 8589 中的感官分析。试验室设计通用指南,2007 年;感官分析中的 UNI EN ISO 13299。方法。建立感官档案的一般指南,2016 年)。每个描述点的评分范围为 0(无描述点)至 10(描述点强度最大)。M1 栽培品种的特点是脆度更高(8.0,从 0 到 10)、甜度更高(7.5)、芳香强度更高(7.9)和焦糖香味更高(3.3)。M2 栽培品种的特点是黄油香味(3.2)和花香(3.0),并带有其他两个栽培品种所没有的木香/麝香味(1.9)。M3 栽培品种具有杏仁香气(5.2),并有核桃(3.0)和柑橘(2.8)香气,而 M1 和 M2 栽培品种则没有这些香气。这项研究的结果非常重要,因为它们通过实验证明,感官特征的识别使栽培品种之间的质量差异显而易见。结果表明,亚油酸、油酸和棕榈酸是栗果脂质部分的主要成分。在所有样本中,不饱和部分比饱和部分占优势。值得注意的是,不同栽培品种在数量上也存在显著差异。马龙栗栽培品种的价值有助于促进消费者使用这些具有高营养价值的产品,从而有助于促进公众健康。
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引用次数: 0
Characterization, components, and chemical structure of a novel natural pigments derived from Streptomyces tauricus 从金牛链霉菌中提取的新型天然色素的特征、成分和化学结构
IF 3 3区 农林科学 Q2 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-05-17 DOI: 10.1007/s00217-024-04575-z
Minghui Zhou, Min Han, Jiaxue Qing, Min Yu

Microbial pigments have extensive applications in the food, cosmetic, and biopharmaceutical industries. In this study, a pigment-rich actinomycete identified as Streptomyces tauricus was isolated from soil, and the solubility and stability of its were investigated. The pigment was separated and purified through thin-layer chromatography (TLC), column chromatography, and high performance liquid chromatography (HPLC) to determine its components. The chemical structure of the pigment was characterized through infrared (IR) spectroscopy, gas chromatography-mass spectrometry (GC–MS), tandem mass spectrometry (MS/MS–MS), and nuclear magnetic resonance (NMR). Additionally, the antioxidant properties and safety profile of the pigment were assessed. The S. tauricus pigment was bright, vivid brownish-red, intracellular, and fat-soluble; it exhibited considerable photothermal stability and maintained its color below pH 7. The presence of Cu2+, Fe2+, and Fe3+ ions markedly influenced the pigment’s characteristics. The pigment comprised primarily purple and orange components. The purple component, which is relatively rare in microbial sources, was subjected to detailed study. The core structure of the purple component was identified as methylbenzanthracene dione, which has high antioxidant activity and no toxicity in brine shrimp assays. Due to its resilience to high temperatures and acidic environments, coupled with its bioactivity and lack of toxicity, this pigment may serve as a promising candidate for various industrial and food applications.

微生物色素在食品、化妆品和生物制药行业有着广泛的应用。本研究从土壤中分离出了一种富含色素的放线菌--金牛链霉菌,并对其溶解性和稳定性进行了研究。通过薄层色谱(TLC)、柱层析和高效液相色谱(HPLC)对色素进行分离和纯化,以确定其成分。通过红外光谱(IR)、气相色谱-质谱(GC-MS)、串联质谱(MS/MS-MS)和核磁共振(NMR)分析了色素的化学结构。此外,还对色素的抗氧化性和安全性进行了评估。金牛星色素呈明亮、鲜艳的棕红色,在细胞内溶于脂肪;它具有相当高的光热稳定性,在 pH 值为 7 以下时仍能保持颜色。颜料主要由紫色和橙色成分组成。紫色成分在微生物来源中较为罕见,我们对其进行了详细研究。经鉴定,紫色成分的核心结构为甲基苯并蒽二酮,具有很高的抗氧化活性,在盐水虾试验中无毒性。由于这种色素对高温和酸性环境有很强的适应能力,再加上它的生物活性和无毒性,因此有可能成为各种工业和食品应用的候选物质。
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引用次数: 0
Technological characteristics of whole wheat bread: effects of wheat varieties, sourdough treatments and sourdough levels 全麦面包的工艺特点:小麦品种、酸包处理和酸包水平的影响
IF 3 3区 农林科学 Q2 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-05-17 DOI: 10.1007/s00217-024-04560-6
Asiye Seis Subaşı, Recai Ercan

Sourdough bread has gained interest with the increasing demand of consumers for more natural, delicious and healthy foods. Also, consumption of whole grain flour is increasing due to the bioactive compounds it contains. This study aimed to investigate the effects of wheat variety (Tosunbey, Kenanbey, İkizce-96, Bezostaja-1), sourdough treatment [Spontaneous fermentation (SP), Lactiplantibacillus plantarum (LP), Fructilactobacillus sanfranciscensis (LS)] and sourdough level (0–10–20–30%) on the technological characteristics of whole wheat bread. The investigated factors had significant effects on pH, total titratable acidity, specific volume, color and textural parameters. The increasing levels of sourdough decreased the specific volume of whole wheat bread and increased the crumb hardness. The whole wheat sourdough breads produced with LP and LS had lower specific volumes due to the acidity, but were more favorable in terms of smell compared to SP. The hardness and chewiness of the bread samples significantly increased with the three days of storage, while the cohesiveness and springiness decreased. Wheat varieties with higher protein content and Zeleny sedimentation value had better performance for whole wheat sourdough bread production. The study showed that sourdough with selected lactic starters (LP and LS) could be used at 10–20% levels in whole wheat bread formulations to have acceptable technological and sensory characteristics.

随着消费者对天然、美味和健康食品的需求日益增长,酸酵面包越来越受到人们的关注。此外,由于全谷物面粉含有生物活性化合物,其消费量也在不断增加。本研究旨在调查小麦品种(Tosunbey、Kenanbey、İkizce-96、Bezostaja-1)、酸包处理(自发发酵(SP)、植物乳杆菌(LP)、圣弗朗西斯克果乳杆菌(LS))和酸包水平(0-10-20-30%)对全麦面包技术特性的影响。所研究的因素对 pH 值、总滴定酸度、比容、色泽和质地参数有显著影响。酸面团含量的增加降低了全麦面包的比容,增加了面包屑的硬度。用 LP 和 LS 制作的全麦酸面团面包由于酸度较高,比容较小,但与 SP 相比,气味更佳。面包样品的硬度和咀嚼感在储存三天后明显增加,而粘稠度和回弹性则有所下降。蛋白质含量和泽勒尼沉降值较高的小麦品种在全麦酸面团面包生产中表现更佳。研究表明,在全麦面包配方中,酸面团与选定的乳酸发酵剂(LP 和 LS)的比例为 10-20%,可获得可接受的技术和感官特性。
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引用次数: 0
Promising bioactive compounds and biological activities of native Brazilian berries from Myrtaceae and Arecaceae families 巴西本土桃金娘科和山苍子科浆果中具有前景的生物活性化合物和生物活性
IF 3 3区 农林科学 Q2 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-05-16 DOI: 10.1007/s00217-024-04571-3
Stephanie Dias Soares, Adriana de Souza Lima, Cynthia Tereza Correa da Silva, Iramaia Angelica Neri Numa, Glaucia Maria Pastore

The Arecaceae and Myrtaceae families are widespread across Brazil. They include many of Brazil's native fruit species. Local communities use these plants for many purposes. Their health impacts come from bioactive compounds, notably phytochemicals. These compounds are crucial for managing chronic diseases and can serve as antimicrobial agents. Therefore, this review aimed to present and discuss the importance of commercialization, consumption, and development of new products from some plant matrices native to Brazil, such as purple-araçá, bacaba, cherry of Rio Grande, grumixama, juçara, and pitanga with emphasis on the phenolic profile and functional potential as agents in biological activities. The information presented herein serves as a foundation for enhancing practices ranging from cultivation and consumption to the formulation of innovative ingredients and food products. This emphasis is particularly relevant for underexplored fruits, such as purple-araçá and bacaba, which possess untapped potential for further investigation and application.

山茶科(Arecaceae)和桃金娘科(Myrtaceae)广泛分布于巴西各地。它们包括许多巴西本地水果品种。当地社区将这些植物用于多种用途。它们对健康的影响来自于生物活性化合物,特别是植物化学物质。这些化合物对控制慢性疾病至关重要,并可用作抗菌剂。因此,本综述旨在介绍和讨论从巴西原生的一些植物基质中提取的新产品的商业化、消费和开发的重要性,这些植物基质包括紫araçá、bacaba、Rio Grande樱桃、grumixama、juçara和pitanga,重点是酚类概况和作为生物活性剂的功能潜力。本报告提供的信息为加强从种植和消费到创新配料和食品配方的实践奠定了基础。这一重点尤其适用于尚未充分开发的水果,如紫色卡拉卡(pleau-araçá)和巴卡巴(bacaba),它们具有尚未开发的潜力,有待进一步研究和应用。
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引用次数: 0
Almond (Prunus dulcis) varieties classification with genetic designed lightweight CNN architecture 利用遗传设计的轻量级 CNN 架构进行杏仁(Prunus dulcis)品种分类
IF 3 3区 农林科学 Q2 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-05-16 DOI: 10.1007/s00217-024-04562-4
Mustafa Yurdakul, İrfan Atabaş, Şakir Taşdemir

Almond (Prunus dulcis) is a nutritious food with a rich content. In addition to consuming as food, it is also used for various purposes in sectors such as medicine, cosmetics and bioenergy. With all these usages, almond has become a globally demanded product. Accurately determining almond variety is crucial for quality assessment and market value. Convolutional Neural Network (CNN) has a great performance in image classification. In this study, a public dataset containing images of four different almond varieties was created. Five well-known and light-weight CNN models (DenseNet121, EfficientNetB0, MobileNet, MobileNet V2, NASNetMobile) were used to classify almond images. Additionally, a model called 'Genetic CNN', which has its hyperparameters determined by Genetic Algorithm, was proposed. Among the well-known and light-weight CNN models, NASNetMobile achieved the most successful result with an accuracy rate of 99.20%, precision of 99.21%, recall of 99.20% and f1-score of 99.19%. Genetic CNN outperformed well-known models with an accuracy rate of 99.55%, precision of 99.56%, recall of 99.55% and f1-score of 99.55%. Furthermore, the Genetic CNN model has a relatively small size and low test time in comparison to other models, with a parameter count of only 1.1 million. Genetic CNN is suitable for embedded and mobile systems and can be used in real-life solutions.

杏仁(Prunus dulcis)是一种营养丰富的食品。除了食用,它还被用于医药、化妆品和生物能源等领域。由于这些用途,杏仁已成为全球需求量最大的产品。准确确定杏仁品种对于质量评估和市场价值至关重要。卷积神经网络(CNN)在图像分类方面表现出色。本研究创建了一个公共数据集,其中包含四种不同杏仁品种的图像。五种著名的轻量级 CNN 模型(DenseNet121、EfficientNetB0、MobileNet、MobileNet V2、NASNetMobile)被用来对杏仁图像进行分类。此外,还提出了一种名为 "遗传 CNN "的模型,其超参数由遗传算法决定。在知名的轻量级 CNN 模型中,NASNetMobile 的准确率为 99.20%,精确率为 99.21%,召回率为 99.20%,f1 分数为 99.19%,取得了最成功的结果。Genetic CNN 的准确率为 99.55%,精确率为 99.56%,召回率为 99.55%,f1 分数为 99.55%,表现优于知名模型。此外,与其他模型相比,遗传 CNN 模型体积相对较小,测试时间较短,参数数仅为 110 万。遗传 CNN 适用于嵌入式和移动系统,可用于实际解决方案。
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引用次数: 0
Gluten migration from biodegradable food contact materials poses a risk to celiac disease patients 可生物降解食品接触材料中的麸质迁移对乳糜泻患者构成风险
IF 3 3区 农林科学 Q2 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-05-15 DOI: 10.1007/s00217-024-04570-4
Johanna Mossburger, Katharina Anne Scherf

Due to the ban of certain single-use plastics in the European Union, food contact materials (FCM) from biobased and/or biodegradable polymers are increasingly being used. Some FCM are made from wheat or rye and therefore contain gluten, which is a food allergen and known to cause celiac disease. Legislation currently does not require allergen labelling on FCM and there is only some first information that gluten from FCM can migrate into gluten-free foods. Our aim was to analyze the extent of gluten migration from six different FCM into a variety of liquid and solid foods to assess the risk of exposure for wheat allergy and celiac disease patients. We show that the extent of gluten migration depended on the properties of the material, the liquid or solid food it comes into contact with and contact time. There was no clear effect of temperature or pH value. Of the six FCM studied, wheat bran-based plates had the highest potential to release gluten with concentrations of up to 203.0 mg/L of gluten in deionized water after 30 min. To protect patients, it is important to raise awareness of the risk of gluten migration from such FCM and help patients identify and avoid gluten-containing FCM. Further, legislation needs to be adapted urgently to include mandatory labelling of allergens on these biodegradable FCM.

由于欧盟禁止使用某些一次性塑料,由生物基和/或生物可降解聚合物制成的食品接触材料(FCM)正得到越来越多的使用。某些 FCM 由小麦或黑麦制成,因此含有麸质,而麸质是一种食物过敏原,已知会导致乳糜泻。目前,法律并未要求在含氟聚合物上标注过敏原,只有一些初步信息表明,含氟聚合物中的麸质可能会迁移到无麸质食品中。我们的目的是分析麸质从六种不同的含麸质食品中迁移到各种液体和固体食品中的程度,以评估小麦过敏症和乳糜泻患者接触麸质的风险。我们的研究表明,麸质迁移的程度取决于材料的特性、与之接触的液体或固体食物以及接触时间。温度或 pH 值没有明显的影响。在所研究的六种 FCM 中,麦麸基板释放麸质的可能性最大,30 分钟后去离子水中的麸质浓度高达 203.0 毫克/升。为了保护患者,必须提高对此类含麸质食品中麸质迁移风险的认识,并帮助患者识别和避免使用含麸质的含麸质食品。此外,迫切需要修改立法,在这些可生物降解的含麸质食品上强制标注过敏原。
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引用次数: 0
Mechanical and surface properties of semifinished potato tuber exposed to UV-C radiation at varied operational parameters 在不同操作参数下暴露于紫外线-C 辐射的马铃薯块茎半成品的机械和表面特性
IF 3 3区 农林科学 Q2 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-05-15 DOI: 10.1007/s00217-024-04561-5
Addis Lemessa Jembere, Tomasz Jakubowski

The current study aimed at investigating the effect of certain operational parameters of UV-C radiator on the selected mechanical properties of semifinished potato tuber. Innovator potato variety was selected for the preparation of semifinished potato strips. The prepared potato strips were stored for 24 h following exposure at the desired storage condition. The irradiation experiment was carried out using a UV-C chamber at varied UV-C doses, Mode of exposure, and distance from the radiator. UV-C dose has a pronounced effect over the other tested parameters. Samples subjected at 60 mJ/cm2 resulted in higher resistance to compression and bending force while the resistance to cutting force was enhanced at a lower UV-C dose (15 mJ/cm2). Mechanical properties were not significantly impacted by the mode of exposure and distance from the light. Furthermore, the Morphological and microstructural properties of the sample were examined using SEM and AFM resulting in alteration in granule size, spacing, and roughness of the irradiated samples.

目前的研究旨在调查紫外线辐射器的某些操作参数对马铃薯块茎半成品选定机械性能的影响。在制备半成品马铃薯条时选择了 Innovator 马铃薯品种。将制备好的马铃薯条在所需的储存条件下照射后储存 24 小时。辐照实验使用紫外线-C 室进行,紫外线-C 剂量、辐照模式和与辐射器的距离各不相同。紫外线-C 剂量对其他测试参数有明显的影响。在 60 mJ/cm2 下照射的样品抗压缩力和抗弯曲力较高,而在较低的 UV-C 剂量(15 mJ/cm2)下照射的样品抗切割力较强。机械性能并没有受到照射方式和照射距离的明显影响。此外,使用扫描电子显微镜和原子力显微镜检测了样品的形态和微观结构特性,结果显示辐照样品的颗粒大小、间距和粗糙度都发生了变化。
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引用次数: 0
Valorization of plant proteins for meat analogues design—a comprehensive review 植物蛋白在肉类类似物设计中的应用--综述
IF 3 3区 农林科学 Q2 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-05-15 DOI: 10.1007/s00217-024-04565-1
Shahida Anusha Siddiqui, Ibrahim Khalifa, Tao Yin, Mohamed K. Morsy, Ramy M. Khoder, Molla Salauddin, Wasiya Farzana, Sonu Sharma, Nauman Khalid

Animal proteins from meat and its stuffs have recently been one of main concerns in the drive for sustainable food production. This viewpoint suggests that there are exciting prospects to reformulate meat products that are produced more sustainably and may also have health benefits by substituting high-protein nonmeat ingredients for some of the meat. Considering these pre-existing conditions, this review critically reviews recent data on extenders from several sources, including pulses, plant-based components, plant byproducts, and unconventional sources. We used the related keywords from Scopus-database without limiting the publishing date. With an emphasis on how these findings may impact the sustainability of meat products, it sees them as a great chance to enhance the functional quality and technological profile of meat. Therefore, to promote sustainability, meat alternatives such as plant-based meat equivalents are being made available. To boost consumer acceptability of these goods, further initiatives should also be developed to enhance the functioning of these innovative food items and increase public knowledge of plant-based meat analogues.

肉类及其制品中的动物蛋白最近成为可持续食品生产的主要关注点之一。这一观点表明,通过用高蛋白非肉类配料替代部分肉类配料,重新配制更可持续生产的肉类产品具有令人振奋的前景,而且还可能对健康有益。考虑到这些已有的条件,本综述批判性地回顾了有关多种来源扩展剂的最新数据,包括豆类、植物性成分、植物副产品和非常规来源。我们使用了 Scopus 数据库中的相关关键词,但不限制发表日期。该研究强调这些发现可能对肉类产品的可持续性产生的影响,并将其视为提高肉类功能质量和技术特性的绝佳机会。因此,为了促进可持续发展,人们开始提供肉类替代品,如植物肉类替代品。为了提高消费者对这些产品的接受度,还应该制定进一步的措施,提高这些创新食品的功能,增加公众对植物肉类替代品的了解。
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引用次数: 0
Using volatile compounds for the identification of coffee adulterants: marker compounds and non-targeted analysis 利用挥发性化合物鉴定咖啡掺假物:标记化合物和非目标分析
IF 3 3区 农林科学 Q2 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-05-14 DOI: 10.1007/s00217-024-04563-3
João Carlos de Souza, Cinthia de Carvalho Couto, Alexandra Mara Goulart Nunes Mamede, Patrícia Valderrama, Aline Theodoro Toci, Otniel Freitas-Silva

Coffee is one of the most highly valued, consumed and comercialized foods in the world. Due to its considerable importance, it has become the target of numerous adulterations. Detecting a possible adulteration and the presence of additional adulterants in coffee has become an issue of great concern mainly because the compounds used as adulterants exhibit physical features very similar to ground roasted coffee. Aiming to overcome these difficulties, this work reports the development and application of a relatively faster, highly effective and reliable method for the detection and identification of adulterations in roasted coffee through the analysis of the composition of the volatile fraction in the presence of adulterants such as rice, corn, soybeans and barley. The proposed method was based on gas chromatography coupled with mass spectrometry (GC–MS) and chemometric tools. The application of the method led to the exclusive identification of many compounds in the volatile fraction of the adulterants investigated. The adulterants, despite having compounds similar to coffee, differed in terms of their volatile profiles, and consisted mainly of hydrocarbons, aldehydes, esters and carboxylic acids. Among all the compounds identified, five compounds were found to be the main determinants of adulteration: 2-furanmethanol-acetate, 2-methoxy-4-vinylphenol, 5-methyl-2-furancarboxaldehyde, 2-furanmethanol and glycerol-1,2-diacetate.

咖啡是世界上价值最高、消费量最大、商业化程度最高的食品之一。由于其重要性,它已成为众多掺假行为的目标。检测咖啡中可能存在的掺假和其他掺假物质已成为一个备受关注的问题,这主要是因为用作掺假物质的化合物表现出与研磨烘焙咖啡非常相似的物理特征。为了克服这些困难,本研究报告开发并应用了一种相对快速、高效和可靠的方法,通过分析大米、玉米、大豆和大麦等掺杂物存在时的挥发性成分,检测和识别烘焙咖啡中的掺杂物。所提议的方法基于气相色谱-质谱法(GC-MS)和化学计量学工具。通过应用该方法,在所调查的掺假物质的挥发性部分中独家鉴定出了许多化合物。这些掺假物质尽管具有与咖啡相似的化合物,但其挥发性特征却各不相同,主要由碳氢化合物、醛类、酯类和羧酸组成。在所有已确定的化合物中,有五种化合物是掺假的主要决定因素:2-呋喃甲醇乙酸酯、2-甲氧基-4-乙烯基苯酚、5-甲基-2-呋喃甲醛、2-呋喃甲醇和甘油-1,2-二乙酸酯。
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European Food Research and Technology
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