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Organo-gold(III) complexes via mechanochemistry in a ball mill 有机金(III)配合物在球磨机中的机械化学反应
IF 2.2 4区 工程技术 Q2 Chemistry Pub Date : 2022-01-21 DOI: 10.1007/s13404-021-00302-8
Chao Hu

Owing to their highly interesting applications in medicine, catalysis, and their luminescence properties, over the past decade, increasing efforts have been devoted to the synthesis of organo-gold(III) complexes. Therefore, the design of mild, practical, and modular protocols for their synthesis is a highly active field of research. In a recent paper in Angewandte Chemie, Hashmi and co-workers developed an efficient and solvent-free method for the mechanochemical synthesis of differently organo-gold(III) complexes; this method opens up a new perspective for the field.

由于有机金(III)配合物在医学、催化和发光方面的广泛应用,在过去的十年中,人们越来越多地致力于有机金(III)配合物的合成。因此,设计温和、实用、模块化的合成方案是一个非常活跃的研究领域。在最近发表于Angewandte Chemie的一篇论文中,Hashmi及其同事开发了一种高效且无溶剂的方法,用于机械化学合成不同的有机金(III)配合物;这种方法为该领域开辟了一个新的视角。
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引用次数: 0
Effect of plasmonic coupling in different assembly of gold nanorods studied by FDTD 用时域有限差分法研究了不同金纳米棒组装过程中等离子体耦合的影响
IF 2.2 4区 工程技术 Q2 Chemistry Pub Date : 2022-01-16 DOI: 10.1007/s13404-022-00307-x
Aditya K. Sahu, Satyabrata Raj

The influence of the orientation of gold nanorods in different assemblies has been investigated using the finite difference time domain (FDTD) simulation method. To understand the relative orientation, we vary the size and angle in dimer geometries. Significant effects of plasmon coupling emerged in longitudinal resonances having end-to-end configurations of gold nanorods. The effect of orientational plasmon coupling in dimers gives rise to both bonding and anti-bonding plasmon modes. Effects of various geometries like primary monomer, dimer, trimer, and tetramer structures have been explored and compared with their higher nanorod ensembles. The asymmetric spectral response in a 4 × 4 gold nanorods array indicates a Fano-like resonance. The variation of gap distance in ordered arrays allowed modulation of the Fano resonance mode. The plasmon modes’ resonance wavelength and field enhancement have been tuned by varying the gap distance, angular orientation, size irregularity between the nanorods, and nanorod numbers in an array. The integrated nanostructures studied here are not only significant for fundamental research but also applications in plasmon-based devices.

采用时域有限差分(FDTD)仿真方法研究了不同装配方式下金纳米棒取向的影响。为了了解相对取向,我们改变了二聚体几何形状的大小和角度。在金纳米棒端到端配置的纵向共振中,等离子体耦合产生了显著的影响。在二聚体中,取向等离子体耦合的作用产生了成键和反键等离子体模式。不同的几何结构,如原生单体、二聚体、三聚体和四聚体结构的影响已经被探索,并与它们的高纳米棒组合进行了比较。4 × 4金纳米棒阵列的非对称光谱响应显示出法诺共振。在有序阵列中间隙距离的变化允许调制Fano谐振模式。等离子体模的共振波长和场增强可以通过改变阵列中纳米棒之间的间隙距离、角取向、尺寸不规则性和纳米棒数量来调节。本文研究的集成纳米结构不仅对基础研究有重要意义,而且在等离子体基器件中也有应用价值。
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引用次数: 3
The potential of marine-based gold nanomaterials in cancer therapy: a mini-review 海洋基金纳米材料在癌症治疗中的潜力:综述
IF 2.2 4区 工程技术 Q2 Chemistry Pub Date : 2022-01-14 DOI: 10.1007/s13404-021-00304-6
Neda Baghban, Arezoo Khoradmehr, Iraj Nabipour, Amin Tamadon, Mujib Ullah

Cancer is still one of the most common causes of death today despite advances in its detection and treatment. The present article reviews the application of marine-based gold nanoparticles in the diagnosis and treatment of cancer. The main data were collected from original research articles on the application of different marine-based gold nanoparticles in detecting and imaging cancer cells as well as in drug delivery systems and treatment of cancer. The results show the excellent anticancer potential of both gold nanoparticles and natural marine products. The most studied marine-based gold nanomaterial was chitosan-based ones, in which the role of chitosan is a stabilizer not an anticancer agent. Despite the excellent anticancer potential of different marine natural products, limited studies have been conducted using gold nanoparticles in their composition in cancer therapy. Moreover, most of these studies are related to their application as a drug delivery system not an anticancer drug. Although there are serious challenges in the application of nanoparticles in medicine, marine-based gold nanomaterials may promise an interesting novel strategy in the oncology field.

尽管癌症的检测和治疗取得了进步,但它仍然是当今最常见的死亡原因之一。本文综述了海洋金纳米颗粒在癌症诊断和治疗中的应用。主要数据收集自不同海洋基金纳米颗粒在检测和成像癌细胞、药物输送系统和癌症治疗中的应用的原始研究文章。结果表明,金纳米颗粒和天然海产品均具有良好的抗癌潜力。研究最多的海洋金纳米材料是壳聚糖基纳米材料,其中壳聚糖的作用是稳定剂而不是抗癌剂。尽管不同的海洋天然产品具有优异的抗癌潜力,但在其组成中使用金纳米颗粒进行癌症治疗的研究有限。此外,这些研究大多与它们作为药物传递系统的应用有关,而不是抗癌药物。虽然纳米颗粒在医学上的应用面临着严峻的挑战,但海洋基金纳米材料可能在肿瘤领域提供一种有趣的新策略。
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引用次数: 4
Fibers covered with 3D interconnected network of Au nanostructures and their application in SERS detection 三维互连金纳米结构覆盖的纤维及其在SERS检测中的应用
IF 2.2 4区 工程技术 Q2 Chemistry Pub Date : 2022-01-04 DOI: 10.1007/s13404-021-00303-7
Cuiping Wang, Huan Zhang, Chunrong Wang

A simple template-free method was developed for the fabrication of fibers whose surfaces were covered by a three-dimensional interconnected network of Au nanostructures (3D-NW AuNSs) without additional stabilizer. The EDS and XPS measurements confirmed the metallic nature of the formed 3D gold nanowire networks on the fiber surface. The morphology of these 3D-NW AuNSs can be controlled by the experimental parameters, such as reaction time, roughness of the glass fiber surface, HAuCl4, and sodium citrate concentration. The 3D gold nanowire networks showed excellent uniformity. Additionally, the nanofiber was used to accurately and reliably detect methyl red (MR), crystal violet (CV), and acridine orange (AO), which can be detected as low as 1, 10, and 5 μg/L, respectively. Since the proposed strategy is simple, cost-effective, and reproducible for the mass production of network-like gold film–covered nanofiber, it is expected to play an important role in the development of trace analytical devices.

开发了一种简单的无模板方法,用于制备表面被三维互连的金纳米结构网络(3D-NW纳米结构)覆盖的纤维,而不需要额外的稳定剂。EDS和XPS测量证实了在纤维表面形成的3D金纳米线网络的金属性质。反应时间、玻璃纤维表面粗糙度、HAuCl4和柠檬酸钠浓度等实验参数可以控制这些3D-NW AuNSs的形貌。三维金纳米线网络表现出良好的均匀性。此外,该纳米纤维可准确可靠地检测甲基红(MR)、结晶紫(CV)和吖啶橙(AO),其检出浓度分别低至1、10和5 μg/L。由于所提出的策略简单,成本效益高,并且可大规模生产网状金膜覆盖纳米纤维,因此有望在痕量分析设备的发展中发挥重要作用。
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引用次数: 1
Gold carbene complexes and beyond: new avenues in gold(I)-carbon coordination chemistry 金碳配合物及其以外:金(I)-碳配位化学的新途径
IF 2.2 4区 工程技术 Q2 Chemistry Pub Date : 2022-01-03 DOI: 10.1007/s13404-021-00298-1
Florian F. Mulks

The different coordination modes in carbon-gold(I) complexes are spotlighted with a focus on gold(I). The emergence of gold carbene complexes and their critical discussion in the community is presented, and an overview of their bonding fundamentals and synthetic procedures is given. Several intriguing and sometimes highly reactive gold-carbon coordination complexes that were recently synthesised and isolated are reviewed and a critical outlook into their potential applications is provided. This includes vinylidene and higher cumulenylidene complexes, free carbenes with gold substituents, carbodicarbene complexes, and non-Fischer/Schrock sesquicarbene complexes.

研究了碳金(I)配合物中不同的配位模式,以金(I)为重点。介绍了金卡宾配合物的出现及其在学界的重要讨论,并概述了它们的键合原理和合成方法。综述了最近合成和分离的几种有趣的、有时反应性很强的金碳配位配合物,并对其潜在的应用前景进行了评述。这包括偏二烯和更高的累积二烯配合物、含金取代基的游离碳烯、碳二烯配合物和非fischer /Schrock倍半碳烯配合物。
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引用次数: 1
Size-dependent optical and electrochemical properties of gold nanoparticles to L-cysteine 金纳米颗粒对l -半胱氨酸的光学和电化学性质的尺寸依赖性
IF 2.2 4区 工程技术 Q2 Chemistry Pub Date : 2021-04-28 DOI: 10.1007/s13404-021-00296-3
Pengfei Cao, Nan Wang, Duo Chen, Shengjun Sun, Houyi Ma, Meng Lin

A series of gold nanoparticles were synthesized by stepwise growth method under the condition of citrate as a reducing agent and stabilizer. The optical properties with the maximum absorption wavelength (λmax) and electrochemical properties of the oxidation potential (Ep) dependence on the particle size were analyzed. The method of calculating the particle size from the UV-visible spectrum and the electrochemical oxidation peak was deduced, following the theoretical prediction trend and consistent with previous observations. Furthermore, we investigated the application performance based on the electrochemical catalytic activity and the aggregation of the spherical gold nanoparticles using L-cysteine as a target. The results indicated that the optical and electrochemical properties of the gold nanoparticles to L-cysteine were closely related to the particle size of gold nanoparticles. With the increased size of the nanoparticles, the full width at half maximum in the UV-visible absorption spectrum increased and the electrochemical oxidation potential was positively shifted.

以柠檬酸盐为还原剂和稳定剂,采用分步生长法制备了一系列金纳米颗粒。分析了最大吸收波长(λmax)的光学性质和氧化电位(Ep)随粒径变化的电化学性质。推导了由紫外可见光谱和电化学氧化峰计算粒径的方法,符合理论预测趋势,与前人的观测结果一致。此外,我们还以l -半胱氨酸为靶,研究了基于电化学催化活性和球形金纳米粒子聚集的应用性能。结果表明,金纳米粒子对l -半胱氨酸的光学和电化学性能与金纳米粒子的粒径密切相关。随着纳米颗粒尺寸的增大,紫外可见吸收光谱中半最大值全宽度增大,电化学氧化电位呈正位移。
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引用次数: 4
Gold nanorods crosslinking PNIPAM hydrogels via dynamic Au-thiolate interaction with stretchable, adhesive, self-healing, and photothermal properties 金纳米棒通过动态金硫酸酯相互作用交联PNIPAM水凝胶,具有可拉伸、粘接、自愈和光热性能
IF 2.2 4区 工程技术 Q2 Chemistry Pub Date : 2021-01-22 DOI: 10.1007/s13404-021-00293-6
Shijun Lin, Sirui Jiang, Yuchen Zhang, Zhengwei Dai, Yu Dai, Fan Xia, Xiaojin Zhang

Gold nanorod (AuNR) nanocomposite hydrogels have attracted increasing attention due to the photothermal effect of AuNRs. However, a facile strategy that avoids multi-step surface modification for synthesis of AuNR crosslinkers is still a critical challenge. Here, AuNRs crosslinking PNIPAM hydrogels were prepared by polymerization of NIPAM with N,N′-bis(acryloyl)cystamine (BACA)-modified AuNRs as crosslinkers. BACA contains a disulfide bond in the structure. Dynamic and reversible Au-thiolate bonding was formed by directly mixing AuNRs and BACA to facilely prepare AuNR crosslinkers before hydrogel formation. The addition of AuNRs gives hydrogels their photothermal effect and remarkable mechanical behaviors. Hydrogels could repeatedly adhere to the surface of pigskin, metal, plastic, and glass with a relatively stable adhesion. The damaged hydrogels heal within 2?min with near-infrared (NIR) laser (808?nm, 300?mW?cm?2) irradiation. This work provides a line of thinking for improvement of PNIPAM hydrogels, making them promising for further applications in biomedicine.

由于纳米金棒的光热效应,纳米金棒复合水凝胶越来越受到人们的关注。然而,一种简单的策略,避免多步骤的表面改性,以合成AuNR交联剂仍然是一个关键的挑战。以N,N′-双(丙烯酰)半胺(BACA)修饰的aunr为交联剂,通过NIPAM聚合制备了aunr交联PNIPAM水凝胶。BACA在结构中含有一个二硫键。在形成水凝胶之前,直接将AuNR与BACA混合,形成动态可逆的Au-thiolate键,方便地制备了AuNR交联剂。aunr的加入使水凝胶具有光热效应和优异的力学性能。水凝胶可以反复粘附在猪皮、金属、塑料、玻璃表面,附着力相对稳定。受损的水凝胶在2?近红外(NIR)激光(808?300毫瓦/厘米/ 2)辐照。这项工作为PNIPAM水凝胶的改进提供了思路,使其在生物医学上有进一步的应用前景。
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引用次数: 5
A causal study on gold, SENSEX, and gold exchange traded funds 黄金、SENSEX和黄金交易所交易基金的因果关系研究
IF 2.2 4区 工程技术 Q2 Chemistry Pub Date : 2020-05-16 DOI: 10.1007/s13404-020-00280-3
Rajit Verma, Dinky Dhiman

Gold exchange traded funds help investors to generate the returns based on the movements of underlying commodity. In current scenario, gold ETFs are emerging as one of the best ETFs for the investments. The present study intended to determine the causal relationship between spot prices of gold, SENSEX, and ten selected BSE listed Gold ETFs. The closing prices gold ETFs, SENSEX and spot prices of gold was collected during 2015–2018. The study applied ADF root test, co-integration test, and Granger causality test to study the causal relationship. The results of the study revealed that out of ten, six gold ETFs has significant causal relationship with gold price and only two schemes has significant relationship with BSE SENSEX during 2015–2018. The study concluded that gold ETFs are largely affected by the spot price movements of gold. Therefore, an investor must understand the pricing dynamics of the underlying asset of ETF.

黄金交易所交易基金帮助投资者根据标的商品的走势产生回报。在目前的情况下,黄金etf正在成为投资的最佳etf之一。本研究旨在确定黄金现货价格、SENSEX指数和10只选定的在BSE上市的黄金etf之间的因果关系。黄金etf的收盘价,SENSEX和黄金现货价格是在2015-2018年期间收集的。本研究采用ADF根检验、协整检验和格兰杰因果检验来研究因果关系。研究结果显示,在2015-2018年期间,10只黄金etf中有6只与黄金价格有显著的因果关系,只有2只与BSE SENSEX有显著的关系。研究得出结论,黄金etf在很大程度上受到黄金现货价格变动的影响。因此,投资者必须了解ETF标的资产的定价动态。
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引用次数: 2
Agglomerates of Au-Pt bimetallic nanoparticles: synthesis and antibacterial activity 金铂双金属纳米颗粒团聚体的合成及其抗菌活性
IF 2.2 4区 工程技术 Q2 Chemistry Pub Date : 2020-05-08 DOI: 10.1007/s13404-020-00277-y
R. Britto Hurtado, M. Cortez-Valadez, N. S. Flores-Lopez, M. Flores-Acosta

The extraction of bimetallic Au-Pt nanoparticles is interesting due to their multiple applications in catalytic processes, electronic devices, photothermal therapies, among others. On the other hand, the tendency of nanoparticles forming agglomerates may modify the behavior of the material, and thus their applications. This study shows a highly reproducible novel synthesis method, which only uses two organic agents (sucrose and ascorbic acid) as the reducing and stabilizing agents from nano-agglomerates of Au-Pt at room temperature. The TEM images show agglomerates with a mass fractal structure. We identified crystalline FCC, corresponding to the Au-Pt alloy. Furthermore, the coexistence of gold and platinum nanoparticles was shown through the EDS analysis. The UV-Vis spectrum showed that the resonance plasmon identified coincides with a great approximation to the results reported in the literature. Additionally, the agglomerates exhibited excellent antibacterial activity against bacteria Escherichia coli.

双金属金铂纳米颗粒的提取是有趣的,因为它们在催化过程、电子器件、光热疗法等方面有多种应用。另一方面,纳米颗粒形成团块的趋势可能会改变材料的行为,从而影响它们的应用。本研究提出了一种在室温下仅使用蔗糖和抗坏血酸两种有机试剂作为Au-Pt纳米团块的还原和稳定剂的高重复性新合成方法。TEM图像显示团块具有质量分形结构。我们发现了晶体FCC,与Au-Pt合金相对应。此外,通过能谱分析证实了金纳米粒子和铂纳米粒子的共存。紫外-可见光谱表明,所鉴定的共振等离子体与文献报道的结果有很大的近似。此外,该聚团物对大肠杆菌具有良好的抑菌活性。
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引用次数: 8
Brazing of CoCrFeNi and CoCrFeMnNi equiatomic alloys using 70Au-8Pd-22Ni filler foil 70Au-8Pd-22Ni填充箔钎焊CoCrFeNi和CoCrFeMnNi等原子合金
IF 2.2 4区 工程技术 Q2 Chemistry Pub Date : 2020-05-04 DOI: 10.1007/s13404-020-00278-x
Chieh Lin, Ren-Kae Shiue, Shyi-Kaan Wu, Jian-Yuan Huang, Yung-Chien Huang

Brazing of CoCrFeNi and CoCrFeMnNi equiatomic alloys using 70Au-8Pd-22Ni (AuPdNi) filler foil by infrared and traditional furnaces was investigated. The wettability of AuPdNi filler on both CoCrFeNi and CoCrFeMnNi substrates is excellent at 1050?°C. CoCrFeNi/AuPdNi/CoCrFeNi joints brazed using infrared and traditional furnaces are composed of Au/Ni-rich solid solutions of different sizes. CoCrFeMnNi/AuPdNi/CoCrFeMnNi joints brazed with an infrared furnace are composed of large globular CoCrFeNi/Ni-rich particles in AuMn intermetallic matrix. In traditional furnace brazed CoCrFeMnNi/AuPdNi/CoCrFeMnNi joints, the AuMn intermetallic compound is uniformly distributed in CoCrFeNi-based and Ni-rich phases. The average shear strengths of both infrared and traditional furnace brazed CoCrFeNi/AuPdNi/CoCrFeNi joints exceed 300?MPa, and all joints fractured at the brazed zone present dimple dominated fracture. In contrast, the traditional furnace brazed CoCrFeMnNi/AuPdNi/CoCrFeMnNi joint has a much lower average shear strength of 173?MPa because of the existence of many solidification shrinkage voids in the brazed zone.

研究了70Au-8Pd-22Ni (AuPdNi)填充箔在红外和传统炉上钎焊CoCrFeNi和CoCrFeMnNi等原子合金的性能。在1050°C时,AuPdNi填料在CoCrFeNi和CoCrFeMnNi衬底上的润湿性都很好。采用红外和传统炉钎焊的CoCrFeNi/AuPdNi/CoCrFeNi接头由不同尺寸的富Au/ ni固溶体组成。采用红外炉钎焊的CoCrFeMnNi/AuPdNi/CoCrFeMnNi接头是由auumn金属间基体中富含CoCrFeNi/ ni的球状大颗粒组成。在传统的炉钎焊CoCrFeMnNi/AuPdNi/CoCrFeMnNi接头中,AuMn金属间化合物均匀分布在cocrfeni基相和富ni相中。红外和传统炉钎焊CoCrFeNi/AuPdNi/CoCrFeNi接头的平均抗剪强度均超过300?在钎焊区断裂的接头均表现为韧窝为主断裂。相比之下,传统的炉钎焊CoCrFeMnNi/AuPdNi/CoCrFeMnNi接头的平均抗剪强度要低得多,为173?由于在钎焊区存在许多凝固收缩空洞。
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引用次数: 4
期刊
Gold Bulletin
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