Pub Date : 2022-01-21DOI: 10.1007/s13404-021-00302-8
Chao Hu
Owing to their highly interesting applications in medicine, catalysis, and their luminescence properties, over the past decade, increasing efforts have been devoted to the synthesis of organo-gold(III) complexes. Therefore, the design of mild, practical, and modular protocols for their synthesis is a highly active field of research. In a recent paper in Angewandte Chemie, Hashmi and co-workers developed an efficient and solvent-free method for the mechanochemical synthesis of differently organo-gold(III) complexes; this method opens up a new perspective for the field.
{"title":"Organo-gold(III) complexes via mechanochemistry in a ball mill","authors":"Chao Hu","doi":"10.1007/s13404-021-00302-8","DOIUrl":"10.1007/s13404-021-00302-8","url":null,"abstract":"<div><p>Owing to their highly interesting applications in medicine, catalysis, and their luminescence properties, over the past decade, increasing efforts have been devoted to the synthesis of organo-gold(III) complexes. Therefore, the design of mild, practical, and modular protocols for their synthesis is a highly active field of research. In a recent paper in <i>Angewandte Chemie</i>, Hashmi and co-workers developed an efficient and solvent-free method for the mechanochemical synthesis of differently organo-gold(III) complexes; this method opens up a new perspective for the field.</p></div>","PeriodicalId":55086,"journal":{"name":"Gold Bulletin","volume":"55 1","pages":"15 - 18"},"PeriodicalIF":2.2,"publicationDate":"2022-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5122361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-16DOI: 10.1007/s13404-022-00307-x
Aditya K. Sahu, Satyabrata Raj
The influence of the orientation of gold nanorods in different assemblies has been investigated using the finite difference time domain (FDTD) simulation method. To understand the relative orientation, we vary the size and angle in dimer geometries. Significant effects of plasmon coupling emerged in longitudinal resonances having end-to-end configurations of gold nanorods. The effect of orientational plasmon coupling in dimers gives rise to both bonding and anti-bonding plasmon modes. Effects of various geometries like primary monomer, dimer, trimer, and tetramer structures have been explored and compared with their higher nanorod ensembles. The asymmetric spectral response in a 4 × 4 gold nanorods array indicates a Fano-like resonance. The variation of gap distance in ordered arrays allowed modulation of the Fano resonance mode. The plasmon modes’ resonance wavelength and field enhancement have been tuned by varying the gap distance, angular orientation, size irregularity between the nanorods, and nanorod numbers in an array. The integrated nanostructures studied here are not only significant for fundamental research but also applications in plasmon-based devices.
{"title":"Effect of plasmonic coupling in different assembly of gold nanorods studied by FDTD","authors":"Aditya K. Sahu, Satyabrata Raj","doi":"10.1007/s13404-022-00307-x","DOIUrl":"10.1007/s13404-022-00307-x","url":null,"abstract":"<div><p>The influence of the orientation of gold nanorods in different assemblies has been investigated using the finite difference time domain (FDTD) simulation method. To understand the relative orientation, we vary the size and angle in dimer geometries. Significant effects of plasmon coupling emerged in longitudinal resonances having end-to-end configurations of gold nanorods. The effect of orientational plasmon coupling in dimers gives rise to both bonding and anti-bonding plasmon modes. Effects of various geometries like primary monomer, dimer, trimer, and tetramer structures have been explored and compared with their higher nanorod ensembles. The asymmetric spectral response in a 4 × 4 gold nanorods array indicates a Fano-like resonance. The variation of gap distance in ordered arrays allowed modulation of the Fano resonance mode. The plasmon modes’ resonance wavelength and field enhancement have been tuned by varying the gap distance, angular orientation, size irregularity between the nanorods, and nanorod numbers in an array. The integrated nanostructures studied here are not only significant for fundamental research but also applications in plasmon-based devices.</p></div>","PeriodicalId":55086,"journal":{"name":"Gold Bulletin","volume":"55 1","pages":"19 - 29"},"PeriodicalIF":2.2,"publicationDate":"2022-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4648966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cancer is still one of the most common causes of death today despite advances in its detection and treatment. The present article reviews the application of marine-based gold nanoparticles in the diagnosis and treatment of cancer. The main data were collected from original research articles on the application of different marine-based gold nanoparticles in detecting and imaging cancer cells as well as in drug delivery systems and treatment of cancer. The results show the excellent anticancer potential of both gold nanoparticles and natural marine products. The most studied marine-based gold nanomaterial was chitosan-based ones, in which the role of chitosan is a stabilizer not an anticancer agent. Despite the excellent anticancer potential of different marine natural products, limited studies have been conducted using gold nanoparticles in their composition in cancer therapy. Moreover, most of these studies are related to their application as a drug delivery system not an anticancer drug. Although there are serious challenges in the application of nanoparticles in medicine, marine-based gold nanomaterials may promise an interesting novel strategy in the oncology field.
{"title":"The potential of marine-based gold nanomaterials in cancer therapy: a mini-review","authors":"Neda Baghban, Arezoo Khoradmehr, Iraj Nabipour, Amin Tamadon, Mujib Ullah","doi":"10.1007/s13404-021-00304-6","DOIUrl":"10.1007/s13404-021-00304-6","url":null,"abstract":"<div><p>Cancer is still one of the most common causes of death today despite advances in its detection and treatment. The present article reviews the application of marine-based gold nanoparticles in the diagnosis and treatment of cancer. The main data were collected from original research articles on the application of different marine-based gold nanoparticles in detecting and imaging cancer cells as well as in drug delivery systems and treatment of cancer. The results show the excellent anticancer potential of both gold nanoparticles and natural marine products. The most studied marine-based gold nanomaterial was chitosan-based ones, in which the role of chitosan is a stabilizer not an anticancer agent. Despite the excellent anticancer potential of different marine natural products, limited studies have been conducted using gold nanoparticles in their composition in cancer therapy. Moreover, most of these studies are related to their application as a drug delivery system not an anticancer drug. Although there are serious challenges in the application of nanoparticles in medicine, marine-based gold nanomaterials may promise an interesting novel strategy in the oncology field.</p></div>","PeriodicalId":55086,"journal":{"name":"Gold Bulletin","volume":"55 1","pages":"53 - 63"},"PeriodicalIF":2.2,"publicationDate":"2022-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4573836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-04DOI: 10.1007/s13404-021-00303-7
Cuiping Wang, Huan Zhang, Chunrong Wang
A simple template-free method was developed for the fabrication of fibers whose surfaces were covered by a three-dimensional interconnected network of Au nanostructures (3D-NW AuNSs) without additional stabilizer. The EDS and XPS measurements confirmed the metallic nature of the formed 3D gold nanowire networks on the fiber surface. The morphology of these 3D-NW AuNSs can be controlled by the experimental parameters, such as reaction time, roughness of the glass fiber surface, HAuCl4, and sodium citrate concentration. The 3D gold nanowire networks showed excellent uniformity. Additionally, the nanofiber was used to accurately and reliably detect methyl red (MR), crystal violet (CV), and acridine orange (AO), which can be detected as low as 1, 10, and 5 μg/L, respectively. Since the proposed strategy is simple, cost-effective, and reproducible for the mass production of network-like gold film–covered nanofiber, it is expected to play an important role in the development of trace analytical devices.
{"title":"Fibers covered with 3D interconnected network of Au nanostructures and their application in SERS detection","authors":"Cuiping Wang, Huan Zhang, Chunrong Wang","doi":"10.1007/s13404-021-00303-7","DOIUrl":"10.1007/s13404-021-00303-7","url":null,"abstract":"<div><p>A simple template-free method was developed for the fabrication of fibers whose surfaces were covered by a three-dimensional interconnected network of Au nanostructures (3D-NW AuNSs) without additional stabilizer. The EDS and XPS measurements confirmed the metallic nature of the formed 3D gold nanowire networks on the fiber surface. The morphology of these 3D-NW AuNSs can be controlled by the experimental parameters, such as reaction time, roughness of the glass fiber surface, HAuCl<sub>4</sub>, and sodium citrate concentration. The 3D gold nanowire networks showed excellent uniformity. Additionally, the nanofiber was used to accurately and reliably detect methyl red (MR), crystal violet (CV), and acridine orange (AO), which can be detected as low as 1, 10, and 5 μg/L, respectively. Since the proposed strategy is simple, cost-effective, and reproducible for the mass production of network-like gold film–covered nanofiber, it is expected to play an important role in the development of trace analytical devices.</p></div>","PeriodicalId":55086,"journal":{"name":"Gold Bulletin","volume":"55 1","pages":"31 - 40"},"PeriodicalIF":2.2,"publicationDate":"2022-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4164155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-03DOI: 10.1007/s13404-021-00298-1
Florian F. Mulks
The different coordination modes in carbon-gold(I) complexes are spotlighted with a focus on gold(I). The emergence of gold carbene complexes and their critical discussion in the community is presented, and an overview of their bonding fundamentals and synthetic procedures is given. Several intriguing and sometimes highly reactive gold-carbon coordination complexes that were recently synthesised and isolated are reviewed and a critical outlook into their potential applications is provided. This includes vinylidene and higher cumulenylidene complexes, free carbenes with gold substituents, carbodicarbene complexes, and non-Fischer/Schrock sesquicarbene complexes.
{"title":"Gold carbene complexes and beyond: new avenues in gold(I)-carbon coordination chemistry","authors":"Florian F. Mulks","doi":"10.1007/s13404-021-00298-1","DOIUrl":"10.1007/s13404-021-00298-1","url":null,"abstract":"<div><p>The different coordination modes in carbon-gold(I) complexes are spotlighted with a focus on gold(I). The emergence of gold carbene complexes and their critical discussion in the community is presented, and an overview of their bonding fundamentals and synthetic procedures is given. Several intriguing and sometimes highly reactive gold-carbon coordination complexes that were recently synthesised and isolated are reviewed and a critical outlook into their potential applications is provided. This includes vinylidene and higher cumulenylidene complexes, free carbenes with gold substituents, carbodicarbene complexes, and non-Fischer/Schrock sesquicarbene complexes.</p></div>","PeriodicalId":55086,"journal":{"name":"Gold Bulletin","volume":"55 1","pages":"1 - 13"},"PeriodicalIF":2.2,"publicationDate":"2022-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4120618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-04-28DOI: 10.1007/s13404-021-00296-3
Pengfei Cao, Nan Wang, Duo Chen, Shengjun Sun, Houyi Ma, Meng Lin
A series of gold nanoparticles were synthesized by stepwise growth method under the condition of citrate as a reducing agent and stabilizer. The optical properties with the maximum absorption wavelength (λmax) and electrochemical properties of the oxidation potential (Ep) dependence on the particle size were analyzed. The method of calculating the particle size from the UV-visible spectrum and the electrochemical oxidation peak was deduced, following the theoretical prediction trend and consistent with previous observations. Furthermore, we investigated the application performance based on the electrochemical catalytic activity and the aggregation of the spherical gold nanoparticles using L-cysteine as a target. The results indicated that the optical and electrochemical properties of the gold nanoparticles to L-cysteine were closely related to the particle size of gold nanoparticles. With the increased size of the nanoparticles, the full width at half maximum in the UV-visible absorption spectrum increased and the electrochemical oxidation potential was positively shifted.
{"title":"Size-dependent optical and electrochemical properties of gold nanoparticles to L-cysteine","authors":"Pengfei Cao, Nan Wang, Duo Chen, Shengjun Sun, Houyi Ma, Meng Lin","doi":"10.1007/s13404-021-00296-3","DOIUrl":"10.1007/s13404-021-00296-3","url":null,"abstract":"<div><p>A series of gold nanoparticles were synthesized by stepwise growth method under the condition of citrate as a reducing agent and stabilizer. The optical properties with the maximum absorption wavelength (λ<sub>max</sub>) and electrochemical properties of the oxidation potential (E<sub><i>p</i></sub>) dependence on the particle size were analyzed. The method of calculating the particle size from the UV-visible spectrum and the electrochemical oxidation peak was deduced, following the theoretical prediction trend and consistent with previous observations. Furthermore, we investigated the application performance based on the electrochemical catalytic activity and the aggregation of the spherical gold nanoparticles using L-cysteine as a target. The results indicated that the optical and electrochemical properties of the gold nanoparticles to L-cysteine were closely related to the particle size of gold nanoparticles. With the increased size of the nanoparticles, the full width at half maximum in the UV-visible absorption spectrum increased and the electrochemical oxidation potential was positively shifted.</p></div>","PeriodicalId":55086,"journal":{"name":"Gold Bulletin","volume":"54 2","pages":"97 - 103"},"PeriodicalIF":2.2,"publicationDate":"2021-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s13404-021-00296-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5066949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gold nanorod (AuNR) nanocomposite hydrogels have attracted increasing attention due to the photothermal effect of AuNRs. However, a facile strategy that avoids multi-step surface modification for synthesis of AuNR crosslinkers is still a critical challenge. Here, AuNRs crosslinking PNIPAM hydrogels were prepared by polymerization of NIPAM with N,N′-bis(acryloyl)cystamine (BACA)-modified AuNRs as crosslinkers. BACA contains a disulfide bond in the structure. Dynamic and reversible Au-thiolate bonding was formed by directly mixing AuNRs and BACA to facilely prepare AuNR crosslinkers before hydrogel formation. The addition of AuNRs gives hydrogels their photothermal effect and remarkable mechanical behaviors. Hydrogels could repeatedly adhere to the surface of pigskin, metal, plastic, and glass with a relatively stable adhesion. The damaged hydrogels heal within 2?min with near-infrared (NIR) laser (808?nm, 300?mW?cm?2) irradiation. This work provides a line of thinking for improvement of PNIPAM hydrogels, making them promising for further applications in biomedicine.
{"title":"Gold nanorods crosslinking PNIPAM hydrogels via dynamic Au-thiolate interaction with stretchable, adhesive, self-healing, and photothermal properties","authors":"Shijun Lin, Sirui Jiang, Yuchen Zhang, Zhengwei Dai, Yu Dai, Fan Xia, Xiaojin Zhang","doi":"10.1007/s13404-021-00293-6","DOIUrl":"https://doi.org/10.1007/s13404-021-00293-6","url":null,"abstract":"<p>Gold nanorod (AuNR) nanocomposite hydrogels have attracted increasing attention due to the photothermal effect of AuNRs. However, a facile strategy that avoids multi-step surface modification for synthesis of AuNR crosslinkers is still a critical challenge. Here, AuNRs crosslinking PNIPAM hydrogels were prepared by polymerization of NIPAM with <i>N</i>,<i>N</i>′-bis(acryloyl)cystamine (BACA)-modified AuNRs as crosslinkers. BACA contains a disulfide bond in the structure. Dynamic and reversible Au-thiolate bonding was formed by directly mixing AuNRs and BACA to facilely prepare AuNR crosslinkers before hydrogel formation. The addition of AuNRs gives hydrogels their photothermal effect and remarkable mechanical behaviors. Hydrogels could repeatedly adhere to the surface of pigskin, metal, plastic, and glass with a relatively stable adhesion. The damaged hydrogels heal within 2?min with near-infrared (NIR) laser (808?nm, 300?mW?cm<sup>?2</sup>) irradiation. This work provides a line of thinking for improvement of PNIPAM hydrogels, making them promising for further applications in biomedicine.</p>","PeriodicalId":55086,"journal":{"name":"Gold Bulletin","volume":"54 1","pages":"59 - 67"},"PeriodicalIF":2.2,"publicationDate":"2021-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s13404-021-00293-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4858086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-05-16DOI: 10.1007/s13404-020-00280-3
Rajit Verma, Dinky Dhiman
Gold exchange traded funds help investors to generate the returns based on the movements of underlying commodity. In current scenario, gold ETFs are emerging as one of the best ETFs for the investments. The present study intended to determine the causal relationship between spot prices of gold, SENSEX, and ten selected BSE listed Gold ETFs. The closing prices gold ETFs, SENSEX and spot prices of gold was collected during 2015–2018. The study applied ADF root test, co-integration test, and Granger causality test to study the causal relationship. The results of the study revealed that out of ten, six gold ETFs has significant causal relationship with gold price and only two schemes has significant relationship with BSE SENSEX during 2015–2018. The study concluded that gold ETFs are largely affected by the spot price movements of gold. Therefore, an investor must understand the pricing dynamics of the underlying asset of ETF.
{"title":"A causal study on gold, SENSEX, and gold exchange traded funds","authors":"Rajit Verma, Dinky Dhiman","doi":"10.1007/s13404-020-00280-3","DOIUrl":"https://doi.org/10.1007/s13404-020-00280-3","url":null,"abstract":"<p>Gold exchange traded funds help investors to generate the returns based on the movements of underlying commodity. In current scenario, gold ETFs are emerging as one of the best ETFs for the investments. The present study intended to determine the causal relationship between spot prices of gold, SENSEX, and ten selected BSE listed Gold ETFs. The closing prices gold ETFs, SENSEX and spot prices of gold was collected during 2015–2018. The study applied ADF root test, co-integration test, and Granger causality test to study the causal relationship. The results of the study revealed that out of ten, six gold ETFs has significant causal relationship with gold price and only two schemes has significant relationship with BSE SENSEX during 2015–2018. The study concluded that gold ETFs are largely affected by the spot price movements of gold. Therefore, an investor must understand the pricing dynamics of the underlying asset of ETF.</p>","PeriodicalId":55086,"journal":{"name":"Gold Bulletin","volume":"53 2","pages":"121 - 128"},"PeriodicalIF":2.2,"publicationDate":"2020-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s13404-020-00280-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4659162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-05-08DOI: 10.1007/s13404-020-00277-y
R. Britto Hurtado, M. Cortez-Valadez, N. S. Flores-Lopez, M. Flores-Acosta
The extraction of bimetallic Au-Pt nanoparticles is interesting due to their multiple applications in catalytic processes, electronic devices, photothermal therapies, among others. On the other hand, the tendency of nanoparticles forming agglomerates may modify the behavior of the material, and thus their applications. This study shows a highly reproducible novel synthesis method, which only uses two organic agents (sucrose and ascorbic acid) as the reducing and stabilizing agents from nano-agglomerates of Au-Pt at room temperature. The TEM images show agglomerates with a mass fractal structure. We identified crystalline FCC, corresponding to the Au-Pt alloy. Furthermore, the coexistence of gold and platinum nanoparticles was shown through the EDS analysis. The UV-Vis spectrum showed that the resonance plasmon identified coincides with a great approximation to the results reported in the literature. Additionally, the agglomerates exhibited excellent antibacterial activity against bacteria Escherichia coli.
{"title":"Agglomerates of Au-Pt bimetallic nanoparticles: synthesis and antibacterial activity","authors":"R. Britto Hurtado, M. Cortez-Valadez, N. S. Flores-Lopez, M. Flores-Acosta","doi":"10.1007/s13404-020-00277-y","DOIUrl":"https://doi.org/10.1007/s13404-020-00277-y","url":null,"abstract":"<p>The extraction of bimetallic Au-Pt nanoparticles is interesting due to their multiple applications in catalytic processes, electronic devices, photothermal therapies, among others. On the other hand, the tendency of nanoparticles forming agglomerates may modify the behavior of the material, and thus their applications. This study shows a highly reproducible novel synthesis method, which only uses two organic agents (sucrose and ascorbic acid) as the reducing and stabilizing agents from nano-agglomerates of Au-Pt at room temperature. The TEM images show agglomerates with a mass fractal structure. We identified crystalline FCC, corresponding to the Au-Pt alloy. Furthermore, the coexistence of gold and platinum nanoparticles was shown through the EDS analysis. The UV-Vis spectrum showed that the resonance plasmon identified coincides with a great approximation to the results reported in the literature. Additionally, the agglomerates exhibited excellent antibacterial activity against bacteria <i>Escherichia coli</i>.</p>","PeriodicalId":55086,"journal":{"name":"Gold Bulletin","volume":"53 2","pages":"93 - 100"},"PeriodicalIF":2.2,"publicationDate":"2020-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s13404-020-00277-y","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4355704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Brazing of CoCrFeNi and CoCrFeMnNi equiatomic alloys using 70Au-8Pd-22Ni (AuPdNi) filler foil by infrared and traditional furnaces was investigated. The wettability of AuPdNi filler on both CoCrFeNi and CoCrFeMnNi substrates is excellent at 1050?°C. CoCrFeNi/AuPdNi/CoCrFeNi joints brazed using infrared and traditional furnaces are composed of Au/Ni-rich solid solutions of different sizes. CoCrFeMnNi/AuPdNi/CoCrFeMnNi joints brazed with an infrared furnace are composed of large globular CoCrFeNi/Ni-rich particles in AuMn intermetallic matrix. In traditional furnace brazed CoCrFeMnNi/AuPdNi/CoCrFeMnNi joints, the AuMn intermetallic compound is uniformly distributed in CoCrFeNi-based and Ni-rich phases. The average shear strengths of both infrared and traditional furnace brazed CoCrFeNi/AuPdNi/CoCrFeNi joints exceed 300?MPa, and all joints fractured at the brazed zone present dimple dominated fracture. In contrast, the traditional furnace brazed CoCrFeMnNi/AuPdNi/CoCrFeMnNi joint has a much lower average shear strength of 173?MPa because of the existence of many solidification shrinkage voids in the brazed zone.
{"title":"Brazing of CoCrFeNi and CoCrFeMnNi equiatomic alloys using 70Au-8Pd-22Ni filler foil","authors":"Chieh Lin, Ren-Kae Shiue, Shyi-Kaan Wu, Jian-Yuan Huang, Yung-Chien Huang","doi":"10.1007/s13404-020-00278-x","DOIUrl":"https://doi.org/10.1007/s13404-020-00278-x","url":null,"abstract":"<p>Brazing of CoCrFeNi and CoCrFeMnNi equiatomic alloys using 70Au-8Pd-22Ni (AuPdNi) filler foil by infrared and traditional furnaces was investigated. The wettability of AuPdNi filler on both CoCrFeNi and CoCrFeMnNi substrates is excellent at 1050?°C. CoCrFeNi/AuPdNi/CoCrFeNi joints brazed using infrared and traditional furnaces are composed of Au/Ni-rich solid solutions of different sizes. CoCrFeMnNi/AuPdNi/CoCrFeMnNi joints brazed with an infrared furnace are composed of large globular CoCrFeNi/Ni-rich particles in AuMn intermetallic matrix. In traditional furnace brazed CoCrFeMnNi/AuPdNi/CoCrFeMnNi joints, the AuMn intermetallic compound is uniformly distributed in CoCrFeNi-based and Ni-rich phases. The average shear strengths of both infrared and traditional furnace brazed CoCrFeNi/AuPdNi/CoCrFeNi joints exceed 300?MPa, and all joints fractured at the brazed zone present dimple dominated fracture. In contrast, the traditional furnace brazed CoCrFeMnNi/AuPdNi/CoCrFeMnNi joint has a much lower average shear strength of 173?MPa because of the existence of many solidification shrinkage voids in the brazed zone.</p>","PeriodicalId":55086,"journal":{"name":"Gold Bulletin","volume":"53 2","pages":"101 - 109"},"PeriodicalIF":2.2,"publicationDate":"2020-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s13404-020-00278-x","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4176931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}