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Expert-driven geothermal play fairway analysis for low to medium temperature hidden systems in northwestern Luzon Island, Philippines 菲律宾吕宋岛西北部中低温隐蔽系统的专家驱动地热作用航道分析
IF 3.5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-08-10 DOI: 10.1016/j.geothermics.2024.103130
Emmanuel Olvera-García , Socrates Simbe , Lemuel Mangahas , Aylmer Marbello , Angelika Mandig , Cheyenne Stacey Alcantara , Bridget Ayling , Maria Richards , Maxwell Wilmarth , Cary Lindsey , Rainier Halcon , Ariel Fronda

The Philippines is the third largest geothermal power-producing country in the world. However, additional opportunities exist to expand the geothermal portfolio of the country with the exploitation of low- and moderate- temperature resources, as well as assessment and development of hidden geothermal systems (i.e., those with no active surface manifestations). As part of the Geothermal Development Initiative (GEODE) funded through the U.S. Department of State award to the University of Nevada, Reno, a collaboration between the Philippines Renewable Energy Management Bureau (REMB) of the Department of Energy and the University of Nevada in Reno, Great Basin Center for Geothermal Energy occurred from September 2022 to March 2024. As part of this collaboration, an expert-driven geothermal Play Fairway Analysis (PFA) was conducted in the northwestern portion of Luzon Island of the Philippines utilizing existing data sets available to the REMB. The goal of this PFA is to identify areas with greater relative geothermal favorability, determine where the data gaps are, and assist in the discovery of hidden geothermal systems. A geothermal PFA requires the compilation and transformation of datasets into appropriate formats (e.g., tables, shapefiles, and raster files) and evaluation of each dataset to determine how it can be used as a proxy for the key attributes of a geothermal system (e.g., heat and permeability). Once the data are organized, they are weighted for integration into the GIS software to develop a favorability model for heat and permeability. The attribute models are then combined to produce two PFA models: the conventional hydrothermal low- to moderate- temperature geothermal favorability and the hidden systems favorability. The data difference between the conventional geothermal favorability and hidden systems models is that hot springs are not used for the hidden systems model. The conventional favorability model of northwestern Luzon Island indicates areas of higher geothermal favorability in the central and southern sections of the study area. Many of the favorable areas identified in the conventional model already have active leases for geothermal exploration, lending more confidence to the methodology and model, and suggesting that the areas with no current leases and high geothermal favorability could represent future exploration targets. The hidden systems model shows favorable zones in the north, central and southern sectors, and can serve as a tool to decide the areas for exploration of potential hidden geothermal systems, particularly, in the Ilocos Norte, Apayao, and Nueva Viscaya regions.

菲律宾是世界第三大地热发电国。然而,随着低温和中温资源的开发,以及对隐蔽地热系统(即那些没有活跃地表表现的系统)的评估和开发,该国还存在着扩大地热资源组合的更多机会。作为美国国务院授予内华达大学里诺分校的地热开发倡议(GEODE)的一部分,菲律宾能源部可再生能源管理局(REMB)与内华达大学里诺分校大盆地地热能源中心于 2022 年 9 月至 2024 年 3 月开展了合作。作为合作的一部分,利用 REMB 现有的数据集,在菲律宾吕宋岛西北部开展了一项由专家驱动的地热开采航道分析 (PFA)。该分析的目的是确定地热相对优势较大的地区,确定数据缺口在哪里,并协助发现隐藏的地热系统。地热预测分析要求将数据集汇编并转换为适当的格式(如表格、形状文件和栅格文件),并对每个数据集进行评估,以确定如何将其用作地热系统关键属性(如热量和渗透性)的替代物。整理好数据后,对其进行加权处理,以便整合到地理信息系统软件中,开发出热量和渗透性的有利模型。然后将属性模型合并,生成两个 PFA 模型:传统热液低温至中温地热有利度模型和隐藏系统有利度模型。常规地热有利度模型和隐蔽系统模型之间的数据差异在于,隐蔽系统模型没有使用温泉。吕宋岛西北部的常规有利度模型显示,研究区域的中部和南部地热有利度较高。在常规模型中确定的有利区域中,有许多已经签订了地热勘探的有效租约,这增加了对该方法和模型的信心,并表明目前没有租约但地热有利度较高的区域可能是未来的勘探目标。隐蔽系统模型显示了北部、中部和南部的有利区域,可作为决定潜在隐蔽地热系统勘探区域的工具,特别是在北伊洛戈斯、阿帕尧和新维斯卡亚地区。
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引用次数: 0
Seismic anisotropy of granitic rocks from a fracture stimulation well at Utah FORGE using ultrasonic measurements 利用超声波测量犹他州 FORGE 压裂激励井花岗岩岩石的地震各向异性
IF 3.5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-08-09 DOI: 10.1016/j.geothermics.2024.103129
Mayra D.L. Carrasquilla , Min Sun , Teng Long , Virginia Sisson , Thomas Lapen , Clay Jones , Joseph Moore , Lianjie Huang , Yingcai Zheng

For effective fracture stimulation in Enhanced Geothermal Systems (EGS), characterization of subsurface rock elastic properties is essential. Because seismic anisotropy significantly influences hydraulic fracturing, locating and characterizing microseismic events, and forecasting stress trajectories, our research undertakes laboratory experiments to study seismic anisotropy parameters of core samples from the Utah FORGE EGS site. We evaluated two rock samples from well 58–32, at two depths of 2074.16 m (6,805 feet) and 2268.01 m (7,441 feet), respectively. We analyze the mineralogy and classify the shallower rock as syenogranite, and the deeper rock as orthogneiss and monzonite. We cut cylindrical plugs from these two core samples, imaged them by computed tomography (CT) X-ray imaging, and measured their seismic anisotropy using ultrasonic waves at 1 MHz and under varying confining pressures (5–50 MPa) in ambient temperature conditions. With the assumption of the transversely isotropic (TI) medium, we measured three P-wave velocities and two S-wave velocities along different propagation directions to compute the Thomsen anisotropy parameters. Our results showed that the measured seismic velocities of each rock sample increase with increasing effective pressures, a behavior likely caused by closure of microcracks identified in our CT images. We also find that the measured anisotropies are higher at lower effective pressures. The maximum measured anisotropies for P-waves and S-waves are ∼23% and ∼20%, respectively. Therefore, we expect in the field operation that anisotropy should increase with increasing pore pressure caused by injection, which could be valuable in future EGS reservoir management and monitoring.

为了在强化地热系统(EGS)中进行有效的压裂激励,表层岩石弹性特性的表征至关重要。由于地震各向异性对水力压裂、微地震事件的定位和特征描述以及应力轨迹的预测有重大影响,我们的研究开展了实验室实验,研究犹他州 FORGE EGS 现场岩芯样本的地震各向异性参数。我们评估了来自 58-32 号井的两个岩石样本,深度分别为 2074.16 米(6805 英尺)和 2268.01 米(7441 英尺)。我们分析了矿物学,并将较浅的岩石归类为正长岩,较深的岩石归类为正长岩和单斜岩。我们从这两个岩芯样本中切割出圆柱形插块,用计算机断层扫描(CT)X 射线成像技术对其进行成像,并在常温条件下,在不同的约束压力(5-50 兆帕)下,使用频率为 1 兆赫的超声波测量其地震各向异性。假设介质为横向各向同性(TI)介质,我们测量了沿不同传播方向的三个 P 波速度和两个 S 波速度,以计算汤姆森各向异性参数。结果表明,每个岩石样本的测得地震波速度随着有效压力的增加而增加,这可能是 CT 图像中发现的微裂缝闭合造成的。我们还发现,在有效压力较低时,测得的各向异性较高。P 波和 S 波的最大测量各向异性分别为 ∼23% 和 ∼20%。因此,我们预计在油田作业中,各向异性会随着注入孔隙压力的增加而增加,这对未来的 EGS 储层管理和监测很有价值。
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引用次数: 0
Natural state geothermal reservoir modelling: Mineralogical and geochemical evolution perspective 自然状态地热储层建模:矿物学和地球化学演化视角
IF 3.5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-08-08 DOI: 10.1016/j.geothermics.2024.103132
Dale Emet Altar , Eylem Kaya , Sadiq J. Zarrouk , Isabelle Chambefort

Reactive transport modelling plays a crucial role in unravelling the dynamics of geothermal reservoirs as they evolve. By utilising these models, we gain a deeper understanding of the temporal progression of mineral alteration and its influence on the reservoir's characteristics.

This study was designed to understand the mineralogical and geochemical evolutionary process of conventional geothermal reservoirs. An idealised 3D large-scale numerical model was set up to comply with the prevailing conditions in a two-phase liquid-dominated geothermal reservoir with near-neutral pH and a temperature of up to 350 °C. The models were established to assess the long-term fluid-rock interaction in tholeiitic basalt-hosted geothermal systems, including the effects induced by the natural influx of CO2, H2S and H2 from the magmatic body heat source of the theoretical reservoir. As part of the study, gold, which is associated with hydrothermal systems, was included in the geochemical system to investigate ore deposition processes.

Our reactive transport study results indicate that basalt glass, olivine, augite and the primary plagioclase altered to form secondary albite, chlorite, grossular, epidote, quartz, zeolites and carbonates after 100,000 years. Due to mineral alteration, reservoir porosity and permeability are expected to decrease with time. A near-stable state was achieved based on the temperature profile and a comparative analysis of geochemical results over time. Gold in the basalt was shown to dissolve at depth and re-deposit at shallower locations, resulting in high concentration regions.

反应运移模型在揭示地热储层的动态演化过程中起着至关重要的作用。本研究旨在了解常规地热储层的矿物学和地球化学演化过程。建立了一个理想化的三维大型数值模型,以符合 pH 值接近中性、温度高达 350 ℃ 的两相液态地热储层的普遍条件。建立模型的目的是评估透辉玄武岩型地热系统中长期流体与岩石的相互作用,包括理论储层岩浆体热源中自然涌入的 CO2、H2S 和 H2 所引起的影响。我们的反应运移研究结果表明,玄武岩玻璃、橄榄石、辉石和原生斜长石在 10 万年后发生了蚀变,形成了次生白云石、绿泥石、毛玻璃、绿帘石、石英、沸石和碳酸盐。由于矿物蚀变,储层的孔隙度和渗透率预计会随着时间的推移而降低。根据温度曲线和对地球化学结果随时间变化的比较分析,可得出近乎稳定的状态。玄武岩中的金在深处溶解,在较浅的地方重新沉积,从而形成高浓度区域。
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引用次数: 0
Regional structural controls on a hydrothermal geothermal system in the eastern Pingdingshan coalfield, China: A comprehensive review 中国平顶山东部煤田热液地热系统的区域构造控制:全面回顾
IF 3.5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-08-02 DOI: 10.1016/j.geothermics.2024.103131
Yanhe Li , Kun Yu , Zhijun Wan , Yuan Zhang , Zhuting Wang , Peng Shi , Zheng Zhen , Baoxin Zhang

The Cambrian limestone of the Pingdingshan coalfield in central China possesses substantial geothermal waters. The efficient extraction and utilization of these mine geothermal resources are crucial for the reduction of carbon emissions, thereby enhancing the sustainability of energy management in this coalfield. In this work, we collected data on geothermal waters in the eastern Pingdingshan coalfield, analyzed the chemical characteristics of geothermal water, and identified the control of regional structure on the geothermal system. Geochemical results show that the main type of Cambrian geothermal water in the eastern Pingdingshan coalfield is Na-Ca-HCO3-SO4, which is classified as a peripheral water source and is predominantly a product of water-rock interactions. The mean temperature of the Cambrian thermal reservoir is 68.6 °C, with an average geothermal water circulation depth of 1441 m within the Cambrian limestone. Isotopic data (δ18O and δD) indicate that atmospheric precipitation is the principal source of geothermal water, forming hydrothermal geothermal resources through the heating of high-temperature rock during seepage. A slight positive δ18O shift suggests minimal water-rock interaction with the surrounding rock, categorizing it as a low-temperature geothermal resource. Heat flow measurements in the eastern Pingdingshan coalfield range from 65 to 80 mW/m², with an average geothermal gradient of 36.3 °C/km, characteristic of a high geothermal region. A distinct jump at the base of the PBR1 temperature curve points to the presence of a high-temperature Proterozoic thermal reservoir beneath the Cambrian limestone. The dual tectonic heat accumulation model determines the occurrence environment of the hydrothermal system in the eastern Pingdingshan coalfield. The geothermal system here is governed by the spatial configuration of regional structures and rock thermal conductivity, where extensional faults dictate the spatial morphology of hydrothermal systems, and variations in rock thermal conductivity influence heat conduction pathways.

中国中部平顶山煤田的寒武纪石灰岩蕴藏着大量地热水。有效开采和利用这些矿井地热资源对于减少碳排放,从而提高该煤田能源管理的可持续性至关重要。在这项工作中,我们收集了平顶山东部煤田的地热水数据,分析了地热水的化学特征,并确定了区域结构对地热系统的控制。地球化学结果表明,平顶山东部煤田寒武纪地热水的主要类型为 Na-Ca-HCO3-SO4,属于外围水源,主要是水与岩石相互作用的产物。寒武系热储层的平均温度为 68.6 °C,寒武系石灰岩内平均地热水循环深度为 1441 米。同位素数据(δ18O 和 δD)表明,大气降水是地热水的主要来源,通过在渗流过程中加热高温岩石形成热液地热资源。δ18O的轻微正移表明水-岩石与周围岩石的相互作用微乎其微,因此将其归类为低温地热资源。平顶山东部煤田的热流测量值为 65 至 80 mW/m²,平均地热梯度为 36.3 °C/km,具有高地热区的特征。PBR1 温度曲线底部的明显跃升表明寒武纪石灰岩下存在一个高温新生代热储层。双重构造热量堆积模型决定了平顶山东部煤田热液系统的发生环境。这里的地热系统受区域构造的空间构造和岩石导热性的制约,延伸断层决定了热液系统的空间形态,而岩石导热性的变化影响了热量的传导途径。
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引用次数: 0
Enhancing nocturnal microclimate in Tunisian greenhouses: Experimental study on integrating an innovative conic helicoidal heat exchanger with a geothermal heat pump system 改善突尼斯温室的夜间小气候:将创新型圆锥螺旋形热交换器与地源热泵系统相结合的实验研究
IF 3.5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-08-01 DOI: 10.1016/j.geothermics.2024.103127
Hassen Boughanmi, Nawel Khaldi, Mariem Lazaar, Amanallah Guizani

Ensuring an optimal nocturnal microclimate within greenhouses is essential for successful crop cultivation. In regions like Tunisia, characterized by arid and semi-arid climates, managing temperature and humidity during the night, particularly in cold winter months, is challenging and often requires external heating sources. This study aims to investigate the use of geothermal energy as a sustainable solution for greenhouse heating, focusing on an innovative helicoidal geothermal system to maintain ideal nocturnal conditions.

The primary objective of this research is to evaluate the effectiveness of the helicoidal geothermal system in achieving optimal temperature and humidity levels for plant growth during the night. Conducted at the Research and Technology Centre of Energy in Tunisia, the experimental investigation involved a new ground heat exchanger coupled with a heat pump system.

The experimental setup consisted of two greenhouses: one serving as a control and the other equipped with two Conic Helicoidal Ground Heat Exchangers (CHGHE) and a Ground-Source Heat Pump (GSHP) system, which includes both underground and suspended heat exchangers. The results demonstrated that the geothermal system, operating at an optimal flow rate of 0.6 kg/s, successfully maintained the nocturnal comfort temperature required for plant growth. The coefficients of performance for the geothermal heat pump (COPhp) and the overall system (COPsys) were calculated to be 3.12 and 2.7, respectively.

These findings underscore the potential of near-surface geothermal energy, utilizing a geothermal heat pump, to efficiently heat greenhouses under the climatic conditions of Tunisia. This approach not only supports sustainable agricultural practices but also offers significant energy efficiency and cost-saving benefits.

确保温室内最佳的夜间小气候对作物栽培的成功至关重要。在突尼斯这样以干旱和半干旱气候为特征的地区,夜间(尤其是寒冷的冬季)的温度和湿度管理具有挑战性,通常需要外部加热源。这项研究的主要目的是评估螺旋地热系统在夜间实现植物生长所需的最佳温度和湿度水平方面的有效性。实验装置由两个温室组成:一个作为对照,另一个配备了两个圆锥螺旋地热交换器(CGHE)和一个地源热泵(GSHP)系统,其中包括地下和悬挂式热交换器。结果表明,地热系统以 0.6 公斤/秒的最佳流速运行,成功地保持了植物生长所需的夜间舒适温度。经计算,地热泵的性能系数(COPhp)和整个系统的性能系数(COPsys)分别为 3.12 和 2.7。这些研究结果突出表明,在突尼斯的气候条件下,利用地热泵的近地表地热能源可以有效地为温室供暖。这种方法不仅支持可持续农业实践,而且还具有显著的能源效率和成本节约效益。
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引用次数: 0
Chemical control of ferric silicate scaling by phosphonate additives under geothermal stresses 地热应力下磷酸盐添加剂对硅酸铁结垢的化学控制
IF 3.5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-07-30 DOI: 10.1016/j.geothermics.2024.103119
Michaela Kamaratou , Argyro Spinthaki , Duygu Disci , Konstantinos D. Demadis

The formation, precipitation, and deposition of the so-called “iron silicate” in geothermal waters have been among the problematic issues in some geothermal installations. Our approach aims to systematically study the influence of phosphonate-based chemical additives on the formation of precipitates in the presence of both silicate and ferric (Fe3+) ions. The selection of this type of antiscalants was based on their extraordinary affinity for metal ions in general, and in particular for ferric cations. For this purpose, various phosphonate additives that possess diverse chemical structures and variable numbers of functional groups have been systematically evaluated. These additives are PBTC (2-phosphonobutane-1,2,4-tricarboxylic acid), HEDP (hydroxyethylidene-1,1-diphosphonic acid), AMP (amino-tris(methylenephosphonic acid)), HDTMP (hexamethylenediamine-tetrakis(methylenephosphonic acid)), DTPMP (diethylenetriamine-pentakis(methylene phosphonic acid)) and BHMTPAMP (bis-hexamethylenetriamine-pentakis(methylenephosphonic acid)). Experiments were conducted in solutions containing silicate (150 ppm, expressed as SiO2) and iron (150 ppm, as Fe) at pH 7.0. The phosphonate additives used were found to act as stabilizing agents, most likely by complexing the Fe3+cations, thereby preventing ferric silicate formation. The experimental design included a plethora of physicochemical parameters, such as antiscalant concentration, salinity, and temperature. Based on the generated experimental data, numerous functional insights have been generated, contributing to a more complete and comprehensive understanding of the mechanism of ferric silicate control.

地热水中所谓的 "硅酸铁 "的形成、沉淀和沉积一直是一些地热设施的难题之一。我们的方法旨在系统研究膦酸盐类化学添加剂对硅酸盐和铁(Fe3+)离子存在时沉淀物形成的影响。之所以选择这种类型的防垢剂,是因为它们对一般金属离子,特别是铁阳离子具有超强的亲和力。为此,我们系统地评估了各种膦酸盐添加剂,它们具有不同的化学结构和不同数量的官能团。这些添加剂包括 PBTC(2-膦酸丁烷-1,2,4-三羧酸)、HEDP(羟基亚乙基-1,1-二膦酸)、AMP(氨基-三(亚甲基膦酸))、HDTMP(六亚甲基二胺-四烷基(亚甲基膦酸))、DTPMP(二亚乙基三胺-五烷基(亚甲基膦酸))和 BHMTPAMP(双六亚甲基三胺-五烷基(亚甲基膦酸))。实验在 pH 值为 7.0、含有硅酸盐(150 ppm,以 SiO2 表示)和铁(150 ppm,以 Fe 表示)的溶液中进行。实验发现,所使用的膦酸盐添加剂能起到稳定剂的作用,很可能是通过络合 Fe3+ 阳离子,从而防止硅酸铁的形成。实验设计包括大量物理化学参数,如反钙化剂浓度、盐度和温度。根据所生成的实验数据,提出了许多功能性见解,有助于更完整、更全面地了解硅酸铁的控制机制。
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引用次数: 0
Thermal investigation of geothermally activated building systems using Thermal-Response-Test method 利用热响应测试法对地热激活建筑系统进行热调查
IF 3.5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-07-29 DOI: 10.1016/j.geothermics.2024.103116
Fabian Neth, Roland Koenigsdorff

This work presents an evaluation method for thermal response tests (TRT) on geothermally activated building systems (gTABS). In contrast to borehole heat exchangers (BHEs), the infinite plane source model is appropriate for a gTABS. However, the time criteria defining the applicability of the analytical model are more restrictive than those for BHEs. A minimum time criterion serves as the starting point for the evaluation and a maximum time criterion sets an upper limit. With consistent values for the heat penetration coefficient in all three TRTs performed, the method shows good consistency in compliance with these criteria. Together with the investigation of the undisturbed ground temperatures, the TRT method presented here yields valuable data that allows to assess the performance of a gTABS as a heat source for heat pump applications.

这项研究提出了一种对地热激活建筑系统(gTABS)进行热响应测试(TRT)的评估方法。与钻孔热交换器(BHE)相比,无限平面源模型适用于 gTABS。不过,与 BHE 相比,确定分析模型适用性的时间标准更为严格。最小时间标准是评估的起点,最大时间标准设定了上限。在所有三个 TRT 中,热渗透系数的值都是一致的,因此该方法在符合这些标准方面表现出良好的一致性。结合对未扰动地层温度的研究,本文介绍的 TRT 方法可提供宝贵的数据,用于评估 gTABS 作为热泵应用热源的性能。
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引用次数: 0
Reactive transport modeling of the Aquifer Thermal Energy Storage (ATES) system at Stockton University, New Jersey during seasonal operations 新泽西斯托克顿大学含水层热能储存(ATES)系统在季节性运行期间的反应传输模型
IF 3.5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-07-27 DOI: 10.1016/j.geothermics.2024.103121
Ram Kumar , Eric L. Sonnenthal , J. Torquil Smith , Peter S. Nico , Patrick F. Dobson
<div><p>Hydrogeochemical processes associated with Aquifer Thermal Energy Storage (ATES) operations can often impact the system performance owing to mineral precipitation either at the wellbore or in the aquifer owing to changes in temperature and fluid disequilibria. Although failure of ATES systems due to mineral precipitation ("fouling") is common, predictive reactive-transport models have rarely been applied to plan their design and operation. The objective of this study is to develop a reactive-transport model by coupling thermal, hydrological, and chemical (THC) processes to evaluate effects of introduced atmospheric oxygen on water chemistry, mineral precipitation/dissolution, porosity, and permeability changes associated with an ATES system at Stockton University (New Jersey, USA). The THC model builds on a Thermal-Hydrological-Mechanical (THM) model of the site (Smith et al., 2021) that evaluated system failure owing to possible fracturing in the caprock or around the wellbore. The causes of the system failure are not known – potential causes include hydraulic fracturing owing to elevated pump pressures that took place, a flow pathway created by one of the boreholes, or a pre-existing natural hydrologic connection between the upper unconfined aquifer and the ATES aquifer, any of which could have led to oxygenated water entering the reservoir and causing the observed Fe-oxide fouling on well screens. The THC model is used to evaluate some of the hypotheses and observations regarding system failure owing to geochemical processes.</p><p>The reactive-transport code TOUGHREACT V4 (Sonnenthal et al., 2021) was used to model the THC processes during seasonal heating and cooling operations at the Stockton ATES site over 6 years of operation. In the THC simulations, the primary effects on geochemistry were observed when the injection water is saturated with atmospheric oxygen. Simulations show greater precipitation of goethite near the cold wells as compared to the warm wells. Although volume fractions of Fe-hydroxides were relatively small, the model was aimed at processes in the aquifer at the scale of meters and larger rather than at the scale of mm or cm (i.e., a well screen). Kaolinite is the dominant precipitating phase, also around the cold wells. Illite dissolves near the cold wells and precipitates near the warm wells. There is a net decrease in the porosity near the cold wells and increase near the warm wells, although a slight amount of thermal contraction near the cold wells and expansion near the warm wells is responsible for a significant proportion of the porosity change. Owing to the coarse discretization of the numerical grid near the wells (compared to the screen thickness) the magnitude of permeability changes at the wellbore are likely underestimated. The reactive transport model in this study can be used for characterization of aquifers, optimizing the operational parameters (temperature, pressure, pH etc.), and planning of m
与含水层热能储存(ATES)操作相关的水文地质化学过程通常会影响系统性能,原因是温度变化和流体不平衡导致井筒或含水层中的矿物沉淀。虽然矿物质沉淀("结垢")导致 ATES 系统失效的情况很常见,但预测性反应传输模型却很少被用于规划系统的设计和运行。本研究的目的是通过将热、水文和化学(THC)过程结合起来,开发一种反应传输模型,以评估引入大气中的氧气对水化学、矿物沉淀/溶解、孔隙度以及与斯托克顿大学(美国新泽西州)ATES 系统相关的渗透性变化的影响。THC 模型建立在该地点的热-水文-机械(THM)模型基础上(Smith 等人,2021 年),该模型评估了由于盖岩或井筒周围可能发生的断裂而导致的系统故障。系统故障的原因尚不清楚--可能的原因包括水泵压力升高导致的水力压裂、其中一个井眼形成的流动通道或上非承压含水层与 ATES 含水层之间预先存在的天然水文联系,其中任何一种原因都可能导致含氧水进入储层,并在井筛上造成观察到的氧化铁污垢。TOUGHREACT V4(Sonnenthal 等人,2021 年)用于模拟斯托克顿 ATES 站点 6 年运行期间季节性加热和冷却过程中的 THC 过程。在 THC 模拟中,当注入水中的大气氧饱和时,观察到了对地球化学的主要影响。模拟结果显示,与暖井相比,冷井附近析出的高铁酸盐更多。虽然铁氢氧化物的体积分数相对较小,但该模型针对的是含水层中米或更大尺度的过程,而不是毫米或厘米尺度(即井筛)的过程。高岭石是主要的沉淀相,在冷井附近也是如此。伊利石在冷井附近溶解,在暖井附近沉淀。冷井附近的孔隙度净减少,暖井附近的孔隙度净增加,尽管冷井附近的轻微热收缩和暖井附近的膨胀是造成孔隙度变化的主要原因。由于油井附近的数值网格离散度较粗(与滤网厚度相比),井筒处的渗透率变化幅度可能被低估了。本研究中的反应输运模型可用于含水层特征描述、优化运行参数(温度、压力、pH 值等)以及规划 ATES 系统的缓解策略。
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引用次数: 0
Preface: Enhanced Geothermal Systems – Recent Progress 前言:强化地热系统--最新进展
IF 3.5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-07-27 DOI: 10.1016/j.geothermics.2024.103125
Joseph Moore , Biao Shu , Peter Meier
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引用次数: 0
Ferric silicate precipitates relevant to geothermal systems: Delineation of their complex formation 与地热系统有关的硅酸铁沉淀物:划分其复杂的形成过程
IF 3.5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-07-25 DOI: 10.1016/j.geothermics.2024.103118
Michaela Kamaratou , Argyro Spinthaki , Duygu Disci , Konstantinos D. Demadis

The interest in the utilization of geothermal energy has increased exponentially in the past few decades, and researchers internationally are currently focusing on improving harvesting methods and promoting it due to its numerous benefits compared to traditional energy sources. Corrosion and scaling are two of the significant problems in modern geothermal industry that occur during the harvesting of geothermal energy. Scaling occurs due to the variety of anions and cations that the majority of geothermal reservoir waters contain. High levels of dissolved Fe3+ and silicate ions cause the formation of the elusive “iron silicate”, the latter term usually referring to ferric silicate. Its identity, as it is formed in geothermal waters, differs from its geological counterparts. Usually, deposits that contain Fe and Si are referred to as “iron silicate”, revealing very little about its true identity. This research is focused on revealing the true nature of the so-called “ferric silicate”, performing a series of synthesis experiments under various conditions that take into account iron and silicate concentrations (at the supersaturation regime), solution pH, temperature and different sources of iron. Although solutions containing 150 ppm silicate (no ferric) are stable and do not undergo any polycondensation at pH = 7.0, the presence of ferric induces variable silicate loss from solution. Its severity is enhanced as the ferric concentration increases. Ferric loss from solution in the presence of silicate ions is also severe, regardless of the silicate concentration. Both silicate and ferric loss from solution are pH-dependent processes, with a maximum observed around pH = 7.0. This loss is accompanied by precipitate formation, which is corroborated by turbidity measurements. The solubility of ferric silicate (under the conditions studied) increases with temperature. There is a roughly 4-fold solubility increase when the temperature is increased from 25 °C up to 220 °C. However, enhanced ferric incorporation into the final precipitate was observed at higher temperatures. The ferric silicate precipitates were characterized by several techniques, such as powder XRD, ATR-IR, SEM, and EDS, and showed that ferric silicate is an amorphous precipitate with variable Fe:Si atom ratios and a random Fe distribution throughout the solid. These results can serve as a roadmap for ferric silicate precipitation, taking into account the water chemistry of a specific scale-forming brine.

在过去的几十年里,人们对地热能利用的兴趣成倍增长,由于地热能与传统能源相比具有诸多优势,目前国际上的研究人员正致力于改进采集方法并推广地热能。腐蚀和结垢是现代地热工业在采集地热能过程中出现的两个重要问题。出现结垢的原因是大多数地热储层水含有各种阴阳离子。高浓度的溶解 Fe3+ 和硅酸盐离子会形成难以捉摸的 "硅酸铁",后者通常指硅酸铁。它在地热水域中形成的特性不同于其地质对应物。通常情况下,含有铁和硅的矿藏被称为 "硅酸铁",但对其真实身份却知之甚少。这项研究的重点是揭示所谓 "硅酸铁 "的真实性质,在考虑到铁和硅酸盐浓度(过饱和状态)、溶液 pH 值、温度和不同铁源的各种条件下进行了一系列合成实验。虽然含有 150 ppm 硅酸盐(不含铁元素)的溶液是稳定的,并且在 pH = 7.0 时不会发生任何缩聚反应,但铁元素的存在会导致溶液中硅酸盐的不同程度流失。其严重程度随着铁浓度的增加而加剧。无论硅酸盐浓度如何,在硅酸根离子存在的情况下,铁从溶液中流失的情况也很严重。硅酸盐和铁从溶液中流失的过程都与 pH 值有关,在 pH = 7.0 时达到最大值。这种损失伴随着沉淀的形成,这一点可以通过浊度测量得到证实。硅酸铁的溶解度(在研究条件下)随温度升高而增加。当温度从 25 °C 升至 220 °C 时,溶解度大约增加了 4 倍。不过,在较高温度下,最终沉淀中的铁掺入量增加。粉末 XRD、ATR-IR、SEM 和 EDS 等多种技术对硅酸铁沉淀物进行了表征,结果表明硅酸铁是一种无定形沉淀物,其铁:硅原子比可变,铁在整个固体中随机分布。考虑到特定成垢盐水的水化学性质,这些结果可作为硅酸铁沉淀的路线图。
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