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Tectonic controls and earthquake response of thermal fluid geochemistry in southern Yunnan, southeastern Tibetan Plateau 滇南、青藏高原东南部热流体地球化学的构造控制与地震响应
IF 3.9 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2026-01-04 DOI: 10.1016/j.geothermics.2025.103568
Chenhua Li , Xiaocheng Zhou , Miao He , Zhaojun Zeng , Yuwen Wang , Jiao Tian , Yucong Yan , Bingyu Yao , Hejun Su , Ruigang Li
Geochemical variations in thermal spring compositions are sensitive to changes in regional stress, temperature, and space conditions, which are indicators of seismic and tectonic activities. However, the temporal and spatial variations in water chemistry components and their inducing mechanisms are insufficiently understood. This study aims to evaluate the effective temporal coincidence/lag of seismic events based on the long-term continuous water chemistry monitoring of seismic areas and draw attention to water chemistry changes in thermal waters during earthquake hazard monitoring. We investigated the major elements, trace elements, and hydrogen and oxygen isotopes of 21 thermal springs along the Lancang–Gengma fault (LGF) zone, which is in a highly deformed, seismically active area of the Southeastern margin of the Tibetan Plateau. In the LGF zone, the temperatures of the studied thermal springs range from 44.7°C to 96.2°C. The reservoir temperatures range from 91°C to 195°C and the reservoir depth range from 4–9 km. According to the spatiotemporal chemical variations from two-year regular monitoring of Na+, Cl, F, SO42−, Li, B, δD, and δ18O in five thermal springs, the thermal springs in these fault-controlled areas are sensitive and responsive to seismic activity. Different tectonic regions exhibit significant and diverse short-term precursory anomalies in water chemistry before earthquakes with M ≥ 5.0. Their characteristics and mechanisms are region-specific, and the study area is divided into two monitoring capacity range areas. Area 1: The MG, MM and XF monitoring points located on the Baoshan block are highly sensitive to seismic responses in the SW direction of the study area. For example, continuous Na⁺, Cl, SO42−and F anomalies were observed in MG, MM and XF before the ML5.0 and ML5.9 Myanmar earthquakes (southwest of the study area). Area 2: The NKL and EL monitoring points located on the Simao block are highly sensitive to seismic responses in the SE direction. For instance, the Na⁺ concentrations in EL and NKL sharply increased above the normal threshold before the ML6.2 Laos earthquake and ML5.0 Honghe earthquake. Notably, significant spatial directional differences in fluid chemical responses to earthquakes were observed. This directional difference may be related to the complexity of the regional stress field in the area and the local characteristics of fault activities. The chemical composition changes of these thermal springs during fluid circulation in the LGF can be a good tracer of seismic activity.
温泉成分的地球化学变化对区域应力、温度和空间条件的变化非常敏感,是地震和构造活动的指示物。然而,目前对水化学成分的时空变化及其诱导机制的认识还不够充分。本研究旨在通过对地震区长期连续水化学监测,评价地震事件的有效时间重合/滞后,并关注地震灾害监测过程中热水体的水化学变化。本文研究了青藏高原东南缘高变形地震活动区澜沧江-耿马断裂带21个温泉的主元素、微量元素和氢、氧同位素。在LGF区,研究的温泉温度范围为44.7 ~ 96.2℃。储层温度为91℃~ 195℃,储层深度为4 ~ 9 km。根据2年定期监测的5个温泉Na+、Cl−、F−、SO42−、Li、B、δD和δ18O的时空化学变化特征,这些断裂控制区的温泉对地震活动具有敏感性和响应性。不同构造区在M≥5.0级地震前水化学表现出显著而多样的短期前兆异常。它们的特征和机制具有区域特异性,研究区被划分为两个监测能力范围区。区域1:位于宝山地块的MG、MM和XF监测点对研究区西南方向的地震反应高度敏感。例如,在研究区西南方向的缅甸ML5.0和ML5.9地震前,MG、MM和XF连续出现Na +、Cl−、SO42−和F−异常。区域2:位于思茅地块的NKL和EL监测点对东南方向的地震反应高度敏感。例如,在老挝ML6.2级地震和洪河ML5.0级地震前,EL和NKL中的Na⁺浓度急剧升高,超过了正常阈值。值得注意的是,在流体化学对地震的反应中观察到显著的空间方向性差异。这种方向性差异可能与该区区域应力场的复杂性和断层活动的局部特征有关。这些温泉在地层流体循环过程中的化学成分变化可以作为地震活动的良好示踪剂。
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引用次数: 0
Three-dimensional lithospheric-scale thermal model as supporting tool for new exploration campaigns for geothermal resources: Insights from the Calabria region (Southern Italy) 三维岩石圈尺度热模型作为地热资源新勘探活动的辅助工具:来自卡拉布里亚地区(意大利南部)的见解
IF 3.9 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2026-01-20 DOI: 10.1016/j.geothermics.2026.103604
G. Vespasiano , G. Floridia , M. Giuffrida , M. Viccaro , A. Bloise , R. De Rosa , M. Cacace , I. Fuoco , M.F. La Russa , F. Muto , R. Dominici , L. Russo , M. Cipriani , A. Guido , G. Maruca , C. Apollaro
This study presents the first lithosphere-scale, steady-state 3D thermal model of the Calabria region (Southern Italy), developed to support the geothermal resource assessment and exploration. By integrating geological, geophysical, and thermal datasets, a high-resolution 3D geological model was built and used as a structural framework for finite-element thermal simulations. The simulations incorporated spatially variable thermal conductivity, radiogenic heat production, and a range of basal heat flux values applied at the crust-mantle (Moho) interface. Five thermal scenarios were tested and calibrated against 254 measured temperature data points from exploration wells. The results reveal pronounced lateral thermal heterogeneity, with temperatures exceeding 90 °C at 3 km depth beneath the Ionian basins, driven by the local crustal structure, sedimentary blanketing, and Moho geometry. While the model delineates zones suitable for low-to-medium enthalpy geothermal exploitation (1-3 km), deeper high-enthalpy targets remain less constrained and deserve further investigation. This study establishes a geologically consistent framework that enhances the understanding of the regional thermal regime and serves as a strategic tool for guiding future geothermal exploration in Calabria.
本研究提出了卡拉布里亚地区(意大利南部)的第一个岩石圈尺度的稳态三维热模型,以支持地热资源的评估和勘探。通过整合地质、地球物理和热数据集,建立了一个高分辨率的三维地质模型,并将其用作有限元热模拟的结构框架。模拟纳入了空间可变的热导率、辐射成因产热以及应用于地壳-地幔(Moho)界面的一系列基本热通量值。根据探井的254个测量温度数据点,对5种热情景进行了测试和校准。结果显示,受局部地壳结构、沉积覆盖层和莫霍几何形状的影响,爱奥尼亚盆地下3公里深处的温度超过90°C,横向热非均质性明显。虽然该模型描绘了适合低至中焓地热开采的区域(1-3公里),但更深的高焓目标仍然受到较少的限制,值得进一步研究。这项研究建立了一个地质上一致的框架,增强了对区域热机制的理解,并作为指导卡拉布里亚未来地热勘探的战略工具。
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引用次数: 0
Real scale evaluation of geothermal heat exchanger performances integrated to poultry house 禽舍一体化地热换热器性能的实际规模评价
IF 3.9 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-03 DOI: 10.1016/j.geothermics.2025.103553
Oussama Zobiri , Abdelmalek Atia , Müslüm Arıcı
There is a growing body of literature that recognizes the importance of Heating, Ventilation and Air Conditioning systems (HVAC) based on ground to air heat exchangers (GAHEs). In the present experimental work, real field experimental setup of GAHEs to study the air quality of GAHE outlet inside a poultry house compared with air ambient and the conventional poultry house (CPH). Results showed that mean air temperature of heat exchanger at the outlet is stable, which remains closer than 24.2 °C, and the average GAHE efficiency is reached 92 % during the experiment period. GAHE maintains an average relative humidity of around 32 % due to the movement and rotation of air stream caused by the fan. GAHE plays a positive role in the ventilation process of the poultry house, as it renews the amount of air inside the poultry room during the study period. One of the more significant findings to emerge from this study is that the Carbon dioxide (CO2) concentration inside the poultry house integrated with geothermal heat exchangers is less than the concentration that exists in conventional one by 400 parts per million (ppm). The application of geothermal energy systems in buildings holds great potential due to its availability, being considered naturally free and sustainability contributions.
越来越多的文献认识到基于地对空热交换器(GAHEs)的采暖、通风和空调系统(HVAC)的重要性。在本实验工作中,通过对GAHE的现场实验设置,比较了GAHE出风口与环境空气和传统禽舍(CPH)的空气质量。结果表明,换热器出口平均空气温度稳定,保持在24.2℃以下,实验期间GAHE平均效率达到92%。由于风扇引起的气流的运动和旋转,GAHE保持大约32%的平均相对湿度。GAHE在家禽舍通风过程中发挥了积极的作用,因为它在研究期间更新了家禽舍内的空气量。从这项研究中得出的一个更重要的发现是,安装了地热热交换器的鸡舍内的二氧化碳浓度比传统鸡舍内的二氧化碳浓度低400 ppm。地热能系统在建筑物中的应用具有巨大的潜力,因为它的可用性,被认为是自然免费和可持续的贡献。
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引用次数: 0
How useful are outcrop samples to constrain subsurface thermal properties for geothermal exploration? Case study from the Chester formation, UK 在地热勘探中,露头样品对约束地下热性质有多大用处?英国切斯特地层案例研究
IF 3.9 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2026-02-03 DOI: 10.1016/j.geothermics.2026.103617
Maëlle Brémaud , Neil M. Burnside , Zoe K. Shipton , Claire Bossennec , Sven Fuchs , Fiorenza Deon
Hot sedimentary aquifers (HSAs) offer a sustainable option for geothermal energy, but exploration risks remain a major challenge. Drilling is capital intensive, especially for geothermal projects, and early in project appraisal it is often uncertain whether a formation will provide sufficient thermal performance to justify investment. Outcrop samples have therefore gained attention as analogues for subsurface reservoir properties, providing low-cost preliminary data before committing to drilling. While this approach is well established in the hydrocarbon industry, its application to geothermal settings has been limited. Existing geothermal studies have largely focused on structural, petrophysical, or mineralogical characterisation, while systematic comparisons of these properties and thermal properties between outcrop and core samples remain rare. This is a critical gap, as thermal properties govern the long-term performance of a geothermal system. This study compares seventeen outcrop and twenty-one core samples (taken from depths of 22–96 m) from the Triassic Chester Formation in the Cheshire Basin, UK, to assess the transferability of outcrop-derived data. The samples were analysed for mineralogy, petrophysical, and thermal properties. Results show that while outcrop samples exhibit some variability due to weathering at the Earth’s surface, they generally have similar mineralogical and petrophysical properties to core samples. Thermal conductivity is higher in cores (2.15 ± 0.01 W m⁻¹ K⁻¹) compared to outcrops (1.74 ± 0.01 W m⁻¹ K⁻¹). Variations are also observed between different lithotypes, with pebble-rich samples generally exhibiting higher thermal conductivity than massive, layered, or cross-bedded sandstones. These findings highlight the potential of outcrop samples for early-stage geothermal exploration. They provide a cost-effective alternative to drilling for constraining rock properties, particularly thermal conductivity, at depth, while offering insights into depositional environment and lithology. This integrated approach could improve subsurface predictions, reduce exploration costs, and support the growth of the geothermal sector by de-risking investment decisions.
热沉积含水层(HSAs)为地热能源提供了一个可持续的选择,但勘探风险仍然是一个主要挑战。钻井是资本密集型的,特别是地热项目,在项目评估的早期,通常不确定地层是否能提供足够的热性能来证明投资是合理的。因此,露头样品作为地下储层性质的类似物而受到关注,在投入钻井之前提供低成本的初步数据。虽然这种方法在油气工业中已经得到了很好的应用,但它在地热环境中的应用仍然有限。现有的地热研究主要集中在构造、岩石物理或矿物学特征上,而对这些性质以及露头和岩心样品之间的热性质的系统比较仍然很少。这是一个关键的差距,因为热性能决定了地热系统的长期性能。本研究比较了英国柴郡盆地三叠纪切斯特组的17个露头和21个岩心样本(取自22-96米深度),以评估露头数据的可转移性。对样品进行了矿物学、岩石物理和热性质分析。结果表明,虽然露头样品由于地球表面的风化作用而表现出一些变化,但它们通常具有与岩心样品相似的矿物学和岩石物理性质。岩心的热导率(2.15±0.01 W m(⁻¹K⁻))比地表的高(1.74±0.01 W m(⁻))。不同岩性之间也存在差异,富含鹅卵石的样品通常比块状、层状或交错层状砂岩表现出更高的导热性。这些发现突出了露头样品在早期地热勘探中的潜力。它们提供了一种具有成本效益的替代方法,可以在深度上限制岩石性质,特别是热导率,同时可以深入了解沉积环境和岩性。这种综合方法可以改善地下预测,降低勘探成本,并通过降低投资决策的风险来支持地热行业的发展。
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引用次数: 0
Cenozoic tectonic-thermal evolution of the Xihu Sag, East China Sea Basin: Implications for hydrocarbon generation in continental margin basins 东海盆地西湖凹陷新生代构造-热演化:对大陆边缘盆地生烃的启示
IF 3.9 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-15 DOI: 10.1016/j.geothermics.2025.103530
Qiwen Yao , Hui Diao , Jian Chang , Wu Zhang , Ruiheng Zhan , Hangyuan Gao , Kefu Li
This study investigates the Cenozoic tectono-thermal evolution of the Xihu Sag in the East China Sea Basin, a rift–inversion sub-basin at the convergent boundary of the Eurasian, Pacific, and Philippine Sea plates. The findings have broad implications for hydrocarbon generation and thermal history reconstruction in similar continental margin basins globally. By integrating present-day geothermal data, low-temperature thermochronology, vitrinite reflectance, and fluid inclusion analysis, this study reconstructs the thermal history and source rock maturation processes in the Xihu Sag. The geothermal gradient ranges from 16 to 46 °C/km at depths of 0–4 km, with an average of 31.8 °C/km, and surface heat flow varies between 34 and 88 mW/m², averaging 52.3 mW/m². These thermal regimes show a southeast-high to northwest-low trend, primarily influenced by lithospheric thinning, thermal refraction, and basement morphology. Thermal history modeling reveals a significant cooling event during the Late Miocene (14–7 Ma), corresponding to the Longjing tectonic phase, with progressive southeast-to-northwest deformation. Erosion magnitudes exceeded 800 m in marginal anticline zones, while the central Pinghu Slope Belt experienced denudation rates up to 246 m/Ma. Basin modeling indicates that basement heat flow decreased during the Early to Middle Miocene but increased again during tectonic inversion, significantly influencing source rock maturation. The Pinghu Formation source rocks reached peak hydrocarbon generation by the end of the Miocene. Fluid inclusion data indicate two primary hydrocarbon charging phases (∼15–9 Ma and ∼5–0 Ma), consistent with modeled expulsion stages. This study introduces a robust, multi-parameter integrated framework to rigorously assess the geothermal state, tectonic characteristics, and petroleum generation potential of continental margin basins. This methodological paradigm shift fundamentally advances the approaches to thermal history reconstruction and hydrocarbon exploration, providing a reliable and universally applicable solution for analogous geological settings.
本文研究了位于欧亚、太平洋和菲律宾海板块汇聚边界上的裂谷反转子盆地——东海盆地西湖凹陷的新生代构造-热演化。这些发现对全球类似大陆边缘盆地的生烃和热史重建具有广泛的指导意义。综合现今地热资料、低温年代学、镜质组反射率和流体包裹体分析,重建了西湖凹陷热史和烃源岩成熟过程。地温梯度在0 ~ 4 km范围内为16 ~ 46℃/km,平均为31.8℃/km,地表热流在34 ~ 88 mW/m²之间,平均为52.3 mW/m²。这些热区主要受岩石圈减薄、热折射和基底形态的影响,呈现东南高向西北低的趋势。热史模拟显示,晚中新世(14-7 Ma)发生了一次显著的降温事件,与龙井构造相对应,并伴有东南向西北的渐进式变形。边缘背斜带侵蚀强度超过800 m,平湖斜坡带中部剥蚀速率高达246 m/Ma。盆地模拟表明,早中新世至中中新世基底热流减少,构造反转期间基底热流再次增加,对烃源岩成熟有显著影响。平湖组烃源岩在中新世末达到生烃高峰。流体包裹体数据显示了两个主要的烃类充注阶段(~ 15-9 Ma和~ 5-0 Ma),与模拟的排烃阶段一致。该研究引入了一个稳健的多参数综合框架,以严格评估大陆边缘盆地的地热状态、构造特征和生油潜力。这种方法范式的转变从根本上推进了热史重建和油气勘探的方法,为类似的地质环境提供了可靠且普遍适用的解决方案。
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引用次数: 0
3D resistivity model of the los Humeros geothermal field in Mexico, based on magnetotelluric data 基于大地电磁资料的墨西哥los Humeros地热田三维电阻率模型
IF 3.9 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2026-01-24 DOI: 10.1016/j.geothermics.2025.103591
José M. Romo-Jones , Claudia Arango-Galván , Diego Ruiz-Aguilar , Gylfi Páll Hersir , Ásdís Benediktsdóttir , José L. Salas-Corrales , Thalia A. Esquivel-Avilés , Sebastian Held
A joint geothermal project of a European and Mexican consortium (the GEMex project) was carried out between 2016 and 2020 to develop geothermal energy in the easternmost region of the Trans-Mexican Volcanic Belt. GEMex project was funded by the European Union’s Horizon 2020 and SENER-CONACYT Mexican Energy Sustainability programs. One of the key outcomes is the 3D resistivity model of the Los Humeros geothermal field in Mexico, a potentially superheated geothermal reservoir, where fluid temperature reaches close to 400 °C in some areas, based on magnetotelluric (MT) data. The model reveals a shallow resistive zone linked to post-caldera volcanic rocks; underlying this horizon is an updoming conductive anomaly caused by smectite-rich hydrothermally altered rocks that act as cap-rock. Beneath this seal-cap, a deep dome-shaped resistive anomaly is observed, likely corresponding to andesitic reservoir rocks (50–100 Ohm-m) and deeper basement rocks, possibly limestone and granodiorite. This structure aligns with temperature measurements from boreholes, where the 250–300 °C isotherms follow the shape of the top of the resistive dome. The obtained 3D model successfully identifies deep faults that facilitate hot fluid circulation and define the structural limits of the Los Potreros caldera. Faults within the caldera collapse significantly disrupt the cap-rock and the top of the andesites that host the reservoir. This information, together with results derived from other geophysical, geological, and geochemical methods, will help to infer the location and depth at which high-temperature fluids might be found.
欧洲和墨西哥财团的一个联合地热项目(GEMex项目)于2016年至2020年期间进行,旨在开发跨墨西哥火山带最东部地区的地热能源。GEMex项目由欧盟的Horizon 2020和SENER-CONACYT墨西哥能源可持续发展项目资助。其中一个关键成果是基于大地电磁(MT)数据的墨西哥Los Humeros地热田的三维电阻率模型,这是一个潜在的过热地热储层,在某些地区流体温度接近400°C。该模型揭示了一个与后破火山口火山岩有关的浅层电阻带;在这个层位下面是一个由富蒙脱石热液蚀变岩引起的上凸起的导电异常,这些热液蚀变岩充当盖层。在该盖层下,观察到深部圆顶状电阻异常,可能对应于安山岩储集岩(50-100欧姆)和更深的基底岩,可能是灰岩和花岗闪长岩。这种结构与钻孔温度测量结果一致,其中250-300°C等温线遵循电阻圆顶顶部的形状。获得的三维模型成功地识别了有利于热流体循环的深层断层,并确定了Los potereros火山口的结构界限。火山口内的断层崩塌严重破坏了盖层和安山岩的顶部,安山岩承载着储层。这些信息,连同其他地球物理、地质和地球化学方法得出的结果,将有助于推断可能发现高温流体的位置和深度。
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引用次数: 0
Mechanical behavior and constitutive model of thermally damaged granite: Insights from experiments 热损伤花岗岩的力学行为和本构模型:来自实验的见解
IF 3.9 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2026-01-16 DOI: 10.1016/j.geothermics.2026.103602
Ming Min , Qiang Zhang , Xiao-Suo Wu , Bin-Song Jiang
The growing development of deep geothermal energy resources, where rock masses are subjected to high temperatures and significant plastic deformation, demands constitutive models that accurately capture this complex behavior. This study presents a novel thermomechanical constitutive model within a strain-softening framework, which uniquely integrates the coupled effects of temperature (T), confining pressure (σ3), and plastic shear strain (γp). Its primary innovation lies in explicitly formulating the cohesion (c), internal friction angle (φ), and dilation angle (ψ) as functions of both γp, T and/or σ3. This nonlinear evolution function is is underpinned by systematic triaxial compression tests on thermally-treated granite specimens, which reveal that c, φ, and ψ undergo initial increasing followed by an exponential decay with increasing γp. Notably, T and σ3 play a critical role in modulating the evolution law of these fitting parameters. The proposed model, implemented in FLAC3D via a secondary development scheme, successfully reproduces the nonlinear deformation and strain-softening behavior observed in experiments. An engineering case study demonstrates that conventional models assuming constant temperature (T = 25°C) underestimate radial displacements around a deep circular opening by up to 188%, compared to simulations incorporating the proposed model with a realistic nonlinear thermal field. These findings emphasize the critical importance of incorporating thermo-mechanical-plastic coupling in the design and analysis of deep geothermal environments.
随着深部地热能资源的不断开发,岩体受到高温和显著的塑性变形,需要准确捕捉这种复杂行为的本构模型。本文提出了一种基于应变软化框架的热力本构模型,该模型独特地集成了温度(T)、围压(σ3)和塑性剪切应变(γp)的耦合效应。它的主要创新在于将黏聚力(c)、内摩擦角(φ)和膨胀角(ψ)明确表示为γp、T和/或σ3的函数。系统的三轴压缩试验证实了这一非线性演化函数,结果表明,随着γp的增加,c、φ和ψ均呈指数衰减趋势。值得注意的是,T和σ3对这些拟合参数的演化规律起着至关重要的调节作用。该模型通过二次开发方案在FLAC3D中实现,成功地再现了实验中观察到的非线性变形和应变软化行为。一个工程案例研究表明,假设温度恒定(T = 25°C)的传统模型,与将所提出的模型与实际非线性热场相结合的模拟相比,低估了深圆孔周围径向位移高达188%。这些发现强调了在深层地热环境的设计和分析中纳入热-机械-塑性耦合的重要性。
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引用次数: 0
Hydrogeochemical characteristics and geological controls of thermal springs in the Chengde Area, North China 承德地区温泉水文地球化学特征及地质控制
IF 3.9 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2026-01-13 DOI: 10.1016/j.geothermics.2026.103600
Yixuan Wang , Xun Zhou , Jingru Ma , Bin Fang , Ye Shen , Ruige Chen , Yanqiu Wu , Yanxiang Shi , Mengying Chen , Qiqi Liu , Tong Zhang , Guangbin Tao , Linyang Zhuo
Hot springs in the Chengde region of northern Hebei Province, China, occur in scattered locations influenced by varied geological structures. Twenty-eight water samples from 10 sites were analyzed to investigate hydrogeochemistry and geothermal behavior. Stable isotopes indicate meteoric recharge at elevations of 861–1938 m, with northern springs near active faults showing more depleted signatures, reflecting deeper circulation. The waters are weakly alkaline, low- to moderate-TDS, and mainly HCO3·SO4–Na and HCO3–Na types. Na+ derives from silicate weathering and cation exchange, SO42- from evaporite dissolution and pyrite oxidation, and HCO3- from CO2-driven carbonate dissolution. Trace elements (Li, Rb, Cs, Sr, Ba) vary systematically among groups, indicating differences in reservoir lithology and circulation depth; carbonate dissolution is a major Sr and Ba source. Mineral saturation and ion concentrations reflect contrasting water–rock interaction intensities. Reservoir temperatures from silica geothermometers and the SiO2–enthalpy model range from 50 to 143 °C, with circulation depths up to approximately 4500 m and cold water mixing ratios of 46–93%. Springs linked to faults and lithological contacts generally have higher temperatures and deeper flow paths, whereas those in bedrock fractures are shallower and more affected by mixing. These findings highlight the combined influence of topography, geological structure, and lithology on geothermal circulation, providing a geochemical framework for geothermal exploration and resource assessment in intracontinental regions.
河北省承德地区的温泉受不同地质构造的影响,分布较分散。对来自10个地点的28个水样进行了分析,以调查水文地球化学和地热行为。稳定同位素表明海拔861-1938 m的大气补给,靠近活动断层的北部泉水显示出更多的枯竭特征,反映了更深的环流。水体呈弱碱性,tds偏低至中等,主要为HCO3·SO4-Na型和HCO3 - na型。Na+来源于硅酸盐风化和阳离子交换,SO42-来源于蒸发岩溶解和黄铁矿氧化,HCO3-来源于co2驱动的碳酸盐溶解。微量元素(Li、Rb、Cs、Sr、Ba)在组间有系统差异,反映了储层岩性和循环深度的差异;碳酸盐岩溶蚀是Sr和Ba的主要来源。矿物饱和度和离子浓度反映了不同的水岩相互作用强度。石英地温计和sio2 -焓模型的储层温度范围为50 ~ 143°C,循环深度约为4500 m,冷水混合比为46-93%。与断层和岩性接触有关的泉水通常具有较高的温度和较深的流动路径,而基岩裂缝中的泉水则较浅,更容易受到混合的影响。这些发现强调了地形、地质构造和岩性对地热循环的综合影响,为陆内地区地热勘探和资源评价提供了地球化学框架。
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引用次数: 0
Geological and geochemical characteristics of the non-volcanic geothermal system in Surat Thani area, southern Thailand 泰国南部素叻他尼地区非火山地热系统地质地球化学特征
IF 3.9 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2026-01-23 DOI: 10.1016/j.geothermics.2026.103607
Pitsanupong Kanjanapayont , Panupong Kongpet , Petchploy Ninsuwan , Sorawit Duangkhun , Rungroj Arjwech
The approximately 30 hot springs in southern Thailand including Surat Thani area are significantly influenced by the Khlong Marui fault. Water samples were collected throughout the Surat Thani area and subjected to geochemical and stable isotope analysis. The highest water temperature recorded at the hot spring was 69 °C. The geochemical analysis revealed that the water is widely composed of sodium chloride, calcium sulfate, calcium bicarbonate, and sodium bicarbonate. However, stable isotope analysis and the comparison of linear equation data with atmospheric water and samples from Surat Thani area suggest that the water in this hot spring system primarily originates from local meteoric water. Additionally, this study analyzed rare earth elements to explore the interactions between the water and surrounding rock, revealing inconsistencies with the granite rocks in the area. A geophysical assessment employing 2D electrical resistivity tomography (ERT) was performed at the Rattana Kosai hot spring in the central part of the Surat Thani area. It reveals distinct NE-SW fracture patterns along with pressurized aquifers that significantly impact flow. Particularly, the prominent NE-SW fracture zones play a crucial role in groundwater confinement and hot water emergence. Integration of 2D ERT analysis with reliable data sources shows that these NE-SW fracture patterns align with the Khlong Marui fault, which may promote shallow reservoirs and hot spring formation in Surat Thani area. The presence of our geophysical and geochemical data suggests that main faults may provide pathways for the meteoric and ocean water to flow deeper to contact the heat source before flowing back, forming the deep reservoirs near heat sources and shallow reservoirs near to the surface.
包括素叻他尼地区在内的泰国南部约有30个温泉受到Khlong Marui断层的显著影响。在整个素叻他尼地区收集了水样,并进行了地球化学和稳定同位素分析。该温泉的最高水温为69°C。地球化学分析表明,水主要由氯化钠、硫酸钙、碳酸氢钙和碳酸氢钠组成。然而,稳定同位素分析和线性方程数据与大气水和素叻他尼地区样品的比较表明,该温泉系统的水主要来自当地的大气水。此外,本研究还分析了稀土元素,探索了水与围岩的相互作用,揭示了与该地区花岗岩的不一致。利用二维电阻率层析成像(ERT)对素叻他尼地区中部的Rattana Kosai温泉进行了地球物理评估。它揭示了明显的NE-SW断裂模式,以及显著影响流动的承压含水层。其中,NE-SW断裂带对地下水封闭和热水涌现起着至关重要的作用。二维ERT分析与可靠数据来源相结合表明,这些NE-SW断裂模式与Khlong Marui断裂一致,可能促进了素叻他尼地区浅层储层和温泉形成。地球物理和地球化学数据表明,主断层可能为大气和海水向深部流动提供了接触热源再回流的通道,形成了靠近热源的深层储层和靠近地表的浅层储层。
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引用次数: 0
Mechanisms underlying sulfate concentration variations in geothermal waters around the Wugongshan area 武公山地区地热水硫酸盐浓度变化机制
IF 3.9 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2026-03-01 Epub Date: 2025-12-02 DOI: 10.1016/j.geothermics.2025.103550
Li Gong , Zheming Shi , Ximin Bai , Yunfei Bai , Jue Tong , Bangmin Li
Understanding the sources of sulfate in geothermal waters is crucial for elucidating hydrothermal cycling mechanisms and the pathways of sulfur transport and transformation within hydrothermal systems. Distinct SO42– concentrations have been observed in the eastern and western sections of the Wugongshan hydrothermal system; however, the origins and mechanisms of these variations remain unexplored. In this study, a combined hydrogeochemical and microbial analysis was conducted on 11 samples collected from geothermal wells across the Wugongshan geothermal field. The results indicated that silicate weathering, particularly feldspar dissolution influenced by CO2, was the dominant geochemical process in Wugongshan’s geothermal waters. The western samples (XQ and ZK08) exhibited minimal cold-water dilution during ascent, preserving distinct hydrogeochemical signatures. Eight types of sulfur-oxidizing genes were identified, with XQ and ZK08 showing the highest abundances. Strong correlations existed between microbial taxa (e.g., Thiovirga, Thiobacillus in XQ; Tepidimonas, Meiothermus in ZK08), functional genes (fccAB, dsrABC, sox clusters), and SO42– production. Microbial metabolic pathways were the primary drivers of SO42– variation across the region. In the eastern Wugongshan samples, SO42– was sourced exclusively from gypsum dissolution, whereas in the west, microbially mediated sulfide oxidation (e.g., pyrite and H2S) dominated SO42– generation. This study aims to delineate the mechanisms behind sulfate concentration variations in geothermal waters of the Wugongshan area, with particular focus on microbial and mineralogical contributions.
了解地热水中硫酸盐的来源对于阐明热液循环机制和热液系统中硫的转运转化途径至关重要。武公山热液系统东段和西段SO42 -浓度明显不同;然而,这些变异的起源和机制仍未被探索。本研究对武公山地热田11口地热井样品进行了水文地球化学和微生物联合分析。结果表明,在CO2的作用下,硅酸盐风化作用,尤其是长石溶蚀作用是武公山地热水的主要地球化学过程。西部样品(XQ和ZK08)在上升过程中表现出最小的冷水稀释,保留了明显的水文地球化学特征。共鉴定出8种硫氧化基因,其中XQ和ZK08的丰度最高。微生物分类群(如XQ中的thiiovirga、Thiobacillus; ZK08中的Tepidimonas、Meiothermus)、功能基因(fccAB、dsrABC、sox簇)和SO42 -产量之间存在很强的相关性。微生物代谢途径是该地区SO42 -变化的主要驱动因素。在武公山东部样品中,SO42 -主要来自石膏溶解,而在西部样品中,微生物介导的硫化物氧化(如黄铁矿和H2S)主要是SO42 -的生成。本研究旨在探讨武公山地区地热水中硫酸盐浓度变化的机制,重点探讨微生物和矿物学的贡献。
{"title":"Mechanisms underlying sulfate concentration variations in geothermal waters around the Wugongshan area","authors":"Li Gong ,&nbsp;Zheming Shi ,&nbsp;Ximin Bai ,&nbsp;Yunfei Bai ,&nbsp;Jue Tong ,&nbsp;Bangmin Li","doi":"10.1016/j.geothermics.2025.103550","DOIUrl":"10.1016/j.geothermics.2025.103550","url":null,"abstract":"<div><div>Understanding the sources of sulfate in geothermal waters is crucial for elucidating hydrothermal cycling mechanisms and the pathways of sulfur transport and transformation within hydrothermal systems. Distinct SO<sub>4</sub><sup>2–</sup> concentrations have been observed in the eastern and western sections of the Wugongshan hydrothermal system; however, the origins and mechanisms of these variations remain unexplored. In this study, a combined hydrogeochemical and microbial analysis was conducted on 11 samples collected from geothermal wells across the Wugongshan geothermal field. The results indicated that silicate weathering, particularly feldspar dissolution influenced by CO<sub>2</sub>, was the dominant geochemical process in Wugongshan’s geothermal waters. The western samples (XQ and ZK08) exhibited minimal cold-water dilution during ascent, preserving distinct hydrogeochemical signatures. Eight types of sulfur-oxidizing genes were identified, with XQ and ZK08 showing the highest abundances. Strong correlations existed between microbial taxa (e.g., Thiovirga, Thiobacillus in XQ; Tepidimonas, Meiothermus in ZK08), functional genes (fccAB, dsrABC, sox clusters), and SO<sub>4</sub><sup>2–</sup> production. Microbial metabolic pathways were the primary drivers of SO<sub>4</sub><sup>2–</sup> variation across the region. In the eastern Wugongshan samples, SO<sub>4</sub><sup>2–</sup> was sourced exclusively from gypsum dissolution, whereas in the west, microbially mediated sulfide oxidation (e.g., pyrite and H<sub>2</sub>S) dominated SO<sub>4</sub><sup>2–</sup> generation. This study aims to delineate the mechanisms behind sulfate concentration variations in geothermal waters of the Wugongshan area, with particular focus on microbial and mineralogical contributions.</div></div>","PeriodicalId":55095,"journal":{"name":"Geothermics","volume":"136 ","pages":"Article 103550"},"PeriodicalIF":3.9,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145685386","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Geothermics
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