Carlos Magno Oliveira Tadeu, Diego Guimarães Florêncio Pujoni, André Megali Amado, Ludmila Silva Brighenti, Cristiane Freitas de Azevedo Barros, Lorena Torres Oporto, Daiana dos Reis Pelegrine, Gabriel Pereira, Francielle da Silva Cardozo, Stella Pereira Pacheco, Bianca Loureiro do Valle, Layla Mayer Fonseca, Thiago Marques Salgueiro, José Fernandes Bezerra-Neto
Human activities such as agriculture, mining and urbanization have profoundly altered tropical river systems, yet conventional water quality indicators often fail to fully capture these impacts, especially in turbid waters. In the Doce River Basin, Southeast Brazil, the characterization of dissolved organic matter (DOM) through its optical properties offers a promising alternative for monitoring ecological conditions. This study aimed to assess the relationships between water quality, land use and DOM optical properties and to evaluate their potential as complementary indicators in river basin management. Water samples were collected at 27 sites along the Doce River and its tributary, the Santo Antônio River, during both dry and wet seasons. DOM fluorescence and absorbance parameters were quantified and compared with physicochemical variables and surrounding land use. Results revealed marked seasonal differences in DOM composition, with protein-like components predominating and humic-like substances showing strong correlations with nutrient concentrations, particularly total nitrogen and nitrate. Optical indices were also significantly associated with the proportion of forested land, highlighting the role of landscape cover in regulating water quality. These findings indicate that DOM optical properties integrate information on chemical, biological and land use influences, providing a more comprehensive assessment than traditional single-metric approaches. Incorporating optical metrics into water quality monitoring can improve the detection of human-induced changes and strengthen conservation and management strategies in tropical river basins.
{"title":"Linking Land Use, Seasonal Variation and Water Quality Through Dissolved Organic Matter Optical Properties in the Doce River Basin","authors":"Carlos Magno Oliveira Tadeu, Diego Guimarães Florêncio Pujoni, André Megali Amado, Ludmila Silva Brighenti, Cristiane Freitas de Azevedo Barros, Lorena Torres Oporto, Daiana dos Reis Pelegrine, Gabriel Pereira, Francielle da Silva Cardozo, Stella Pereira Pacheco, Bianca Loureiro do Valle, Layla Mayer Fonseca, Thiago Marques Salgueiro, José Fernandes Bezerra-Neto","doi":"10.1002/eco.70130","DOIUrl":"https://doi.org/10.1002/eco.70130","url":null,"abstract":"<p>Human activities such as agriculture, mining and urbanization have profoundly altered tropical river systems, yet conventional water quality indicators often fail to fully capture these impacts, especially in turbid waters. In the Doce River Basin, Southeast Brazil, the characterization of dissolved organic matter (DOM) through its optical properties offers a promising alternative for monitoring ecological conditions. This study aimed to assess the relationships between water quality, land use and DOM optical properties and to evaluate their potential as complementary indicators in river basin management. Water samples were collected at 27 sites along the Doce River and its tributary, the Santo Antônio River, during both dry and wet seasons. DOM fluorescence and absorbance parameters were quantified and compared with physicochemical variables and surrounding land use. Results revealed marked seasonal differences in DOM composition, with protein-like components predominating and humic-like substances showing strong correlations with nutrient concentrations, particularly total nitrogen and nitrate. Optical indices were also significantly associated with the proportion of forested land, highlighting the role of landscape cover in regulating water quality. These findings indicate that DOM optical properties integrate information on chemical, biological and land use influences, providing a more comprehensive assessment than traditional single-metric approaches. Incorporating optical metrics into water quality monitoring can improve the detection of human-induced changes and strengthen conservation and management strategies in tropical river basins.</p>","PeriodicalId":55169,"journal":{"name":"Ecohydrology","volume":"18 7","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/eco.70130","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145529996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
RETRACTION: S. K. Sheir, A. H. Mohamed, G. Y. Osman, A. R. AbdElhafez, and H. H. Abdel-Azeem, “Ecological and Toxicological Impacts of Titanium Dioxide Nanoparticles on the Freshwater Clam Caelatura nilotica and Recovering Role of Dimercaptosuccinic Acid, Gizay Village, Menoufia Governorate, Egypt,” Ecohydrology 18, no. 4 (2025): e70058. https://doi.org/10.1002/eco.70058.
The above article, published online on 04 June 2025 in Wiley Online Library (wileyonlinelibrary.com), has been retracted by agreement between the journal's Editor-in-Chief Professor Keith Smettem; and John Wiley & Sons Ltd. A third party reported that images of comet assays in Figure 1 showed evidence of manipulation. An investigation by the publisher found evidence of image manipulation in Figure 1. The authors responded to an inquiry by the publisher and supplied what were labeled as raw data images. The authors stated that evidence of duplication could be attributed to biological responses and technical factors such as similarity among cells in the same tissue type. However, the authors' response did not satisfactorily answer the concerns of image duplications in Figure 1. Following further review, additional concerns were raised regarding discrepancies in the experimental procedures and the results shown in Figure 1.
The retraction has been agreed to because the evidence of image manipulation and further concerns regarding the experimental procedures fundamentally compromises the editors' confidence in the results presented. The authors were informed of the retraction.
{"title":"RETRACTION: Ecological and Toxicological Impacts of Titanium Dioxide Nanoparticles on the Freshwater Clam Caelatura nilotica and Recovering Role of Dimercaptosuccinic Acid, Gizay Village, Menoufia Governorate, Egypt","authors":"","doi":"10.1002/eco.70137","DOIUrl":"https://doi.org/10.1002/eco.70137","url":null,"abstract":"<p><b>RETRACTION</b>: S. K. Sheir, A. H. Mohamed, G. Y. Osman, A. R. AbdElhafez, and H. H. Abdel-Azeem, “Ecological and Toxicological Impacts of Titanium Dioxide Nanoparticles on the Freshwater Clam Caelatura nilotica and Recovering Role of Dimercaptosuccinic Acid, Gizay Village, Menoufia Governorate, Egypt,” <i>Ecohydrology</i> 18, no. 4 (2025): e70058. https://doi.org/10.1002/eco.70058.</p><p>The above article, published online on 04 June 2025 in Wiley Online Library (wileyonlinelibrary.com), has been retracted by agreement between the journal's Editor-in-Chief Professor Keith Smettem; and John Wiley & Sons Ltd. A third party reported that images of comet assays in Figure 1 showed evidence of manipulation. An investigation by the publisher found evidence of image manipulation in Figure 1. The authors responded to an inquiry by the publisher and supplied what were labeled as raw data images. The authors stated that evidence of duplication could be attributed to biological responses and technical factors such as similarity among cells in the same tissue type. However, the authors' response did not satisfactorily answer the concerns of image duplications in Figure 1. Following further review, additional concerns were raised regarding discrepancies in the experimental procedures and the results shown in Figure 1.</p><p>The retraction has been agreed to because the evidence of image manipulation and further concerns regarding the experimental procedures fundamentally compromises the editors' confidence in the results presented. The authors were informed of the retraction.</p>","PeriodicalId":55169,"journal":{"name":"Ecohydrology","volume":"18 7","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145530027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}