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Influence of convection on the thermal storage performance of energy tunnels 对流对能量隧道蓄热性能的影响
IF 3.3 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-09-10 DOI: 10.1016/j.gete.2024.100595
Annik Schaufelberger , Lyesse Laloui , Alessandro F. Rotta Loria

The decarbonization of the built environment requires rapid growth in energy storage solutions due to the intermittent nature of most renewable energy sources. This paper focuses on the efficacy of so-called energy tunnels (i.e., tunnels equipped with pipe heat exchangers) used for underground thermal energy storage. By harnessing a 3-D thermo-hydraulic finite element model validated against full-scale experimental data, this work specifically explores seasonal, medium-temperature, thermal energy storage operations of energy tunnels. Numerical simulations are performed to unravel the influence of convection resulting from groundwater flows and airflows on the thermal energy storage performance of energy tunnels. The analyses address the impact of different groundwater flow velocities, air temperatures, and airflow velocities on the thermal losses and storage efficiency of energy tunnels used as thermal batteries. The study discourages underground thermal energy storage in the presence of convection due to significant heat losses. It shows that thermal energy storage operations via energy tunnels are feasible in site conditions characterized by no groundwater flow, limited temperature differentials between the heat carrier fluid circulating in the pipe heat exchangers and the surroundings, and thermal insulation on the tunnel intrados.

由于大多数可再生能源的间歇性,建筑环境的去碳化要求能源储存解决方案的快速增长。本文重点研究了用于地下热能存储的所谓能源隧道(即配备管道热交换器的隧道)的功效。通过利用根据全尺寸实验数据验证的三维热液有限元模型,这项工作专门探讨了能源隧道的季节性中温热能存储操作。通过数值模拟来揭示地下水流和气流产生的对流对能源隧道热能储存性能的影响。分析涉及不同地下水流速、空气温度和气流速度对用作热电池的能源隧道的热损失和存储效率的影响。由于存在大量热损失,该研究不鼓励在存在对流的情况下进行地下热能存储。研究表明,在无地下水流、管道热交换器中循环的载热流体与周围环境的温差有限以及隧道内侧有隔热层的情况下,通过能量隧道进行热能储存是可行的。
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引用次数: 0
Predicting the Representative Elementary Volume by determining the evolution law of the convergence cone 通过确定收敛锥的演变规律来预测代表性基本体积
IF 3.3 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-09-10 DOI: 10.1016/j.gete.2024.100594
Sijmen Zwarts, Martin Lesueur

In order to characterise a rock formation prior to subsurface operations, it is required to find a microscale rock volume for which the homogenised property does not fluctuate when the size of the sample is increased; the Representative Elementary Volume (REV). Its determination usually comes at the cost of a large number of simulations, making it overall a computationally expensive process. Therefore, many scientific studies have been dedicated to optimising the process of finding REV. Using statistical numerical methods, it is shown that the fluctuation of the effective property corresponds overall to a cone-like shape convergence. We suggest determining the generic evolution law of the cone of convergence, which can be used to predict the size of the REV and the effective physical property. This study is based on simulations of Stokes flow through idealised microstructures from which the permeability is upscaled. By tracing and plotting the convergence of permeability for multiple samples, the full cone of convergence appears. The cone shows exponential growth and decay, converging towards the effective permeability of the microstructure. By fitting a log-normal distribution on the collected data points, we show that the generic evolution law of the cone of convergence can always be described with two parameters, independently of the porosity. We show that the determined law of the cone also applies to real microstructures, despite the presence of natural heterogeneities. The new method allows us to reduce the computational costs of finding all characteristics related to REV by simulating several subsamples rather than the full-sized sample, unlocking thereby high-resolution samples which are often too computationally expensive. The use of a statistical model provides quantification of the precision level we can obtain on the REV determination.

为了在地下作业前确定岩层的特征,需要找到一个微尺度的岩石体积(即代表性基本体积,Representative Elementary Volume (REV)),当样本尺寸增大时,该体积的均匀特性不会发生波动。要确定该体积,通常需要进行大量的模拟,因此总体而言,计算成本很高。因此,许多科学研究都致力于优化寻找 REV 的过程。使用统计数值方法表明,有效性质的波动总体上对应于锥形收敛。我们建议确定收敛锥的一般演化规律,可用于预测 REV 的大小和有效物理特性。这项研究基于对流经理想化微结构的斯托克斯流的模拟,在此基础上放大了渗透率。通过追踪和绘制多个样本的渗透率收敛图,可以看到完整的收敛锥。锥体呈指数增长和衰减,向微结构的有效渗透率靠拢。通过对收集到的数据点进行对数正态分布拟合,我们发现收敛锥的一般演变规律总是可以用两个参数来描述,与孔隙率无关。我们证明,尽管存在天然异质性,但确定的锥体法则也适用于真实的微结构。新方法允许我们通过模拟多个子样本而不是全尺寸样本来降低寻找与 REV 相关的所有特征的计算成本,从而解锁通常计算成本过高的高分辨率样本。通过使用统计模型,我们可以量化 REV 测定的精确度。
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引用次数: 0
Small-scale physical modelling of vertically loaded, cyclically thermally-activated helical piles 垂直加载循环热激活螺旋桩的小规模物理建模
IF 3.3 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-09-07 DOI: 10.1016/j.gete.2024.100589
Mohammadreza Bashiri , Mahmoud Ghazavi , Peter J. Bourne-Webb

To investigate the use of thermally-activated helical piles in shallow geothermal energy systems, a 1-g modelling study was conducted. Helical piles with either a single- or double- helix were installed in a medium dense, dry sand, and subjected to mechanical, thermal only and thermo-mechanical loading. The results indicate that during the thermal tests (1 – 3 cycles), a small upwards residual displacement was observed and pile head movements ranged between about 90% and 100% of the free expansion of the pile shaft above the shallowest helix, suggesting that the helices fixed the shaft and little restraint was offered by the surrounding soil. In the thermo-mechanical tests (30 thermal cycles), the pile head developed irrecoverable settlement as a function of the number of helices (more helices, less settlement) and initial load (higher load, greater settlement). No significant alteration in pile axial stiffness or resistance was found for piles with zero mechanical load that underwent only a few thermal cycles; however, an increase in stiffness and resistance, beyond that due to inherent variability in the test setup, was observed for piles with an initial load and following a large number of thermal cycles. The testing of thermally-activated helical piles in sand has confirmed that the response is similar to conventional piles and that thermal ratcheting effects can be managed by the application of suitable margins of safety in design and/or the use of multi-helix piles.

为了研究热激活螺旋桩在浅层地热能源系统中的应用,我们进行了 1-g 建模研究。单螺旋或双螺旋螺旋桩被安装在中等密度的干砂中,并承受机械、仅热和热机械荷载。结果表明,在热试验(1 - 3 个周期)期间,观察到的向上残余位移很小,桩头的移动量约为最浅螺旋线上方桩轴自由膨胀量的 90% 到 100%,这表明螺旋线固定了桩轴,周围土壤的约束很小。在热机械试验(30 次热循环)中,桩头出现了不可恢复的沉降,这与螺旋数量(螺旋数量越多,沉降越小)和初始荷载(荷载越大,沉降越大)有关。对于机械荷载为零且只经历了几个热循环的桩,未发现桩的轴向刚度或阻力有明显变化;但对于有初始荷载且经历了大量热循环的桩,则观察到刚度和阻力的增加,这超出了测试装置固有的变化范围。在砂中对热激活螺旋桩进行的测试证实,其响应与传统桩基类似,而且可以通过在设计中采用适当的安全系数和/或使用多螺旋桩来控制热棘轮效应。
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引用次数: 0
Multi-scale constitutive modeling of the brittle–ductile transition behavior of rocks with microcracks and two populations of pores 具有微裂缝和两种孔隙的岩石脆-韧性转变行为的多尺度构造模型
IF 3.3 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-09-06 DOI: 10.1016/j.gete.2024.100591
Sili Liu , Qizhi Zhu , Jin Zhang

The present paper is devoted to multi-scale constitutive modeling of the brittle–ductile transition in rocks. The rocks are considered as heterogeneous media composed of solid phase weakened by microcracks at the microscale and two different populations of pores at the micro and mesoscales. A Drucker–Prager type criterion is first formulated considering microcracking-induced damage in the solid phase. By means of a two-step modified secant variational method, this criterion is then adopted to derive a micro–macro model for double porous medium taking into account the effects of pores. Considering that the operative deformation mechanism in brittle rocks is microcracking, the Drucker–Prager type microcrack damage model is applied to describe the transition of three typical brittle rocks from brittle faulting to dilatant ductile flow by establishing a linear relation between the critical damage caused by microcrack propagation and confining pressure. By introducing an appropriate plastic hardening law and taking into account the influence of confining pressure on plastic hardening parameter and dilatancy coefficient, the micro–macro model for porous rocks is applied to describe the transition from brittle faulting to compactive ductile flow in two typical porous rocks. Comparisons between numerical simulations and experimental data show that the main features of brittle–ductile transition of two types of rocks are well captured by the proposed model.

本文主要研究岩石脆性-韧性转变的多尺度构造模型。岩石被视为由在微观尺度上被微裂缝削弱的固相以及在微观和中观尺度上两种不同的孔隙群组成的异质介质。首先制定了德鲁克-普拉格(Drucker-Prager)型准则,考虑了固相中由微裂缝引起的破坏。然后,通过两步修正的秒变方法,采用该准则推导出考虑到孔隙效应的双多孔介质微观-宏观模型。考虑到脆性岩的作用变形机制是微裂缝,通过建立微裂缝扩展引起的临界破坏与约束压力之间的线性关系,应用 Drucker-Prager 型微裂缝破坏模型来描述三种典型脆性岩从脆性断裂向扩张延性流动的过渡。通过引入适当的塑性硬化定律,并考虑到约束压力对塑性硬化参数和膨胀系数的影响,应用多孔岩微观-宏观模型描述了两种典型多孔岩从脆性断层向挤压延性流动的过渡。数值模拟与实验数据的比较表明,所提出的模型很好地捕捉到了两种岩石脆性-韧性转变的主要特征。
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引用次数: 0
Quantitative assessment of well leakage, part I: Cement stress evolution 油井渗漏定量评估,第一部分:水泥应力演变
IF 3.3 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-09-04 DOI: 10.1016/j.gete.2024.100586
A. Moghadam, M. Loizzo

A damaged cement sheath in wells can open a leakage pathway to shallow freshwater aquifers and atmosphere. Quantitative assessment of leakage along wells has become an area of interest for both the industry and the regulatory bodies. The well leakage can be of importance in both active and legacy wells. In order to estimate leakage through cement sheaths, the size of the leakage pathway and the damage in the cement sheath must be estimated. In this work, we have developed a hydro-thermo-mechanically coupled near-well model that aims to calculate the evolution of cement’s stress as it cures. This process takes into account the cement’s gradual increase in stiffness, chemical shrinkage, and the heat of hydration. The results are verified using lab measured cement stress and pore pressure data from the literature. A case study was developed based on a low-enthalpy geothermal doublet in the Netherlands. The results show that during the cold water injection, an outer microannulus may open to 60 µm. The presence of an external source of water and formation stiffness are of significant importance in determining the damage to the cement sheath. The heat of hydration in cement increases the temperature of cement during curing. The subsequent drop in temperature due to drilling or completion reduces the cement stress and exacerbates the damage to the cement sheath. The producer well may not form a microannuli, however shear and cyclical failure may be of higher likelihood. The modelling framework presented here allows for estimation of annular cement stress in the well. The analysis provides quantitative estimates of the size of the leakage pathway along a well that can be used to estimate well leakge. Quantitative estimate of well leakage provides crucial information for quantitative risk analysis and provides a framework to optimize well operations to minimize leakage risk.

水井中受损的水泥护套可为浅层淡水含水层和大气打开一条渗漏通道。对油井泄漏的定量评估已成为业界和监管机构共同关注的领域。油井渗漏对使用中的油井和遗留油井都很重要。为了估算穿过水泥护套的渗漏,必须估算渗漏途径的大小和水泥护套的损坏程度。在这项工作中,我们开发了一种水热力学耦合近井模型,旨在计算水泥固化时的应力演变。这一过程考虑了水泥刚度的逐渐增加、化学收缩和水化热。计算结果通过实验室测量的水泥应力和文献中的孔隙压力数据进行验证。以荷兰的低焓地热双层岩层为基础进行了案例研究。结果表明,在冷水注入过程中,外部微空洞可能会张开到 60 µm。外部水源的存在和地层刚度对决定水泥护套的损坏非常重要。水泥中的水化热会在固化过程中提高水泥的温度。随后由于钻井或完井造成的温度下降降低了水泥应力,加剧了水泥护套的损坏。采油井可能不会形成微裂缝,但剪切和周期性失效的可能性较大。本文介绍的建模框架可以估算井内环形水泥应力。该分析提供了沿油井渗漏通道大小的定量估算,可用于估算油井渗漏。对油井渗漏的定量估算为定量风险分析提供了重要信息,并为优化油井作业提供了框架,从而最大限度地降低渗漏风险。
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引用次数: 0
Offshore geotechnical challenges of the energy transition 能源转型带来的近海岩土工程挑战
IF 3.3 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-09-01 DOI: 10.1016/j.gete.2024.100584
Susan Gourvenec

Offshore wind is the most mature of the offshore renewable energy technologies and has a significant role to play in the energy transition. 2000 GW of offshore wind capacity is anticipated globally by 2050 in order meet the targets of the Paris Agreement; 35 times the current installed capacity. The pace and scale of offshore wind ambitions to support the energy transition present a range of challenges for the offshore geotechnical sector and the broader offshore wind sector. Challenges extend across the life-cycle of projects from marine spatial planning, site investigation, design, manufacturing, installation, operation and decommissioning, and across the supply chain regarding availability of raw materials for foundations, anchors and mooring systems, vessels and equipment for site investigation and installation, and trained geotechnical personnel. This paper identifies five key challenges and sets out the necessary shifts in technology, culture and practice in geotechnical engineering to achieve the ambitious targets to deliver offshore wind at the pace and scale required for the energy transition. The paper closes with a reflection on the consequence of delaying or not meeting net-zero targets, and thus identifying the urgency for these shifts in technology, culture and practice to be developed and adopted.

海上风能是最成熟的海上可再生能源技术,在能源转型中发挥着重要作用。为实现《巴黎协定》的目标,预计到 2050 年全球海上风电装机容量将达到 2000 千兆瓦,是目前装机容量的 35 倍。海上风电支持能源转型的速度和规模给海上岩土工程行业和更广泛的海上风电行业带来了一系列挑战。挑战贯穿项目的整个生命周期,包括海洋空间规划、现场勘测、设计、制造、安装、运营和退役,以及整个供应链中的地基、锚和系泊系统原材料、现场勘测和安装船只和设备以及训练有素的岩土技术人员。本文指出了五大挑战,并阐述了岩土工程技术、文化和实践方面的必要转变,以实现以能源转型所需的速度和规模交付海上风电的宏伟目标。最后,本文对延迟或无法实现净零目标的后果进行了反思,从而明确了发展和采用这些技术、文化和实践转变的紧迫性。
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引用次数: 0
Thermo-mechanical behavior of an energy retaining pile for geothermal extraction 用于提取地热的能量保留桩的热力学行为
IF 3.3 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-08-31 DOI: 10.1016/j.gete.2024.100587
Di Wu , Liang Kong , Gangqiang Kong , Jincheng Fang , Chenglong Wang , Yifei Wang

A field test was conducted to assess the thermo-mechanical behavior of a full-scale energy retaining pile (ERP) adjacent to a utility tunnel during geothermal extraction. Numerical models were also established and calibrated using measured data. The extracted thermal power, temperature, thermally induced strain and stress, and bending moment of the ERP were analyzed. Additionally, a comparative analysis was conducted using validated numerical models to assess the impact of the air temperature (Tair) inside the adjacent utility tunnel on the thermo-mechanical behavior of the ERP. The findings highlight that the extraction thermal power of the tested ERP was 57 W/m, with the short-term geothermal extraction operation yielding even higher values of 200–250 W/m. The operation of the adjacent high-temperature utility tunnel can lead to an average increase of approximately 15 % in the extracted thermal power of the ERP. Additionally, during the geothermal extraction, regardless of the value of Tair, the ERP primarily reflected in changes to the axial thermo-mechanical behavior. However, the higher-temperature utility tunnel can result in a notable bending moment of the ERP prior to the geothermal extraction operation. Thus, considering the influence of Tair on the thermo-mechanical behavior of the ERP becomes crucial during the preliminary design phase.

我们进行了一次实地测试,以评估地热开采期间邻近公用事业隧道的全尺寸能量保留桩(ERP)的热机械行为。此外,还利用测量数据建立并校准了数值模型。对提取的热功率、温度、热诱导应变和应力以及 ERP 的弯矩进行了分析。此外,还使用经过验证的数值模型进行了对比分析,以评估邻近公用事业隧道内的空气温度(Tair)对 ERP 热机械行为的影响。研究结果表明,经测试的 ERP 的提取热功率为 57 W/m,短期地热提取操作产生的数值甚至更高,达到 200-250 W/m。相邻高温公用隧道的运行可使企业资源规划系统的提取热功率平均提高约 15%。此外,在地热提取过程中,无论 Tair 值如何,ERP 主要反映在轴向热机械行为的变化上。然而,在地热提取操作之前,较高温度的公用事业隧道会导致 ERP 产生明显的弯矩。因此,在初步设计阶段,考虑 Tair 对 ERP 热机械行为的影响至关重要。
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引用次数: 0
An assessment of the salt caprock creep impact on Pre-salt reservoir geomechanics 盐冠岩蠕变对盐前储层地质力学影响的评估
IF 3.3 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-08-30 DOI: 10.1016/j.gete.2024.100588
Pedro A.L.P. Firme , Deane Roehl , Cristian Mejia , Celso Romanel

Reservoir compaction and surface subsidence are widely studied consequences of hydrocarbon (HC) production. This is an important topic in the Brazilian Pre-salt, where wells cross thick salt layers to reach carbonate reservoirs. Adding knowledge on the behavior of salt as caprock is strategic, considering the upcoming demands for decommissioning and the trends for energy transition, such as carbon capture and storage (CCS). This work presents a literature review on subsidence resulting from HC production and the associated mechanical behavior of the salt caprock. A numerical study of a conceptual Pre-salt reservoir is performed to assess the combined behavior of reservoir compaction/expansion, salt caprock creep, and subsidence. The production, injection (such as CCS), and abandonment periods are considered. From the assumptions and findings of the study, two conclusions are drawn: i) the salt caprock creep contribution to the stress paths and changes in permeability is of small magnitude, while it is relevant to subsidence if the reservoir is abandoned in the depleted condition; and ii) creep prolongs the evolution or reversal of the mechanical behavior and permeability when the external loads acting in the model are reverted. This study is expected to serve as a reference for more advanced analyses in Pre-salt reservoir geomechanics, specially considering the trends for decommissioning and energy transition.

储层压实和地表沉降是碳氢化合物(HC)生产的广泛研究结果。这是巴西前盐层的一个重要课题,因为油井要穿过厚厚的盐层才能到达碳酸盐岩储层。考虑到即将到来的退役需求和能源转型的趋势,如碳捕获与封存(CCS),增加有关盐作为盖岩行为的知识具有战略意义。本研究综述了碳氢化合物生产导致的沉降以及盐岩的相关力学行为。对一个概念性前盐储层进行了数值研究,以评估储层压实/膨胀、盐岩蠕变和沉降的综合行为。考虑了生产期、注入期(如 CCS)和废弃期。根据假设和研究结果,得出两个结论:i) 盐冠岩蠕变对应力路径和渗透率变化的影响很小,但如果储层在枯竭状态下被废弃,则与沉降有关;ii) 当作用于模型的外部载荷恢复时,蠕变会延长力学行为和渗透率的演化或逆转。这项研究有望为盐前储层地质力学的更高级分析提供参考,特别是考虑到退役和能源转型的趋势。
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引用次数: 0
Utilizing high-resolution 3D Voronoi meshing to analyze field data from the Brine Availability Test in Salt (BATS) 利用高分辨率三维 Voronoi 网格分析盐中卤水可用性试验 (BATS) 的现场数据
IF 3.3 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-08-23 DOI: 10.1016/j.gete.2024.100585
Richard Jayne, Kristopher Kuhlman

Salt is an attractive disposal medium for radioactive waste because intact salt is essentially impermeable and non-porous. However, upon drift or borehole excavation a damaged region develops surrounding the excavation which causes increased permeability and porosity creating potential flow paths for brine. Brine leads to corrosion of waste forms and waste packages and is a possible transport vector for radionuclides, so it is important to better understand the early-time behavior and evolution of brine flow in a salt. As a result, this study is part of Task E of DECOVALEX-2023 which focuses on understanding the evolution of thermal, two-phase hydrological, and mechanical processes in the excavation damaged zone in salt. Field measurements from The Brine Availability Test in Salt (BATS) 1a heater experiment are analyzed by implementing a high-resolution three-dimensional numerical model. This salt heater experiment consists of 28 days of heating and 13 days of cooling in a central borehole within bedded salt at the Waste Isolation Pilot Plant (WIPP). Here, the flow simulator PFLOTRAN is utilized; simulations are run on a Voronoi mesh, with temperature-dependent thermal conductivity, permeability and porosity decay away from excavations. The temperature-dependency of permeability is done to match field measurements. Results from the simulation match temperature measured in the field within + /- 0.1 °C and the total brine inflow over the 41-day experiment. This study illustrates that the accuracy of the temperature evolution within salt is critically important when analyzing and modeling experimental data by simulating three heating scenarios of the BATS 1a experiment showing that temperature has a direct effect on total brine inflow.

盐是一种具有吸引力的放射性废物处置介质,因为完整的盐基本上是不渗透和无孔的。然而,在漂流或钻孔挖掘过程中,挖掘物周围会出现一个受损区域,导致渗透性和孔隙率增加,从而为盐水创造了潜在的流动路径。卤水会导致废物形式和废物包的腐蚀,并可能成为放射性核素的运输载体,因此更好地了解盐中卤水流动的早期行为和演变非常重要。因此,本研究是 DECOVALEX-2023 任务 E 的一部分,其重点是了解盐中挖掘受损区的热力、两相水文和机械过程的演变。通过实施高分辨率三维数值模型,对盐中盐水可用性试验(BATS)1a 加热器实验的实地测量结果进行了分析。该盐加热器实验包括在废物隔离试验厂(WIPP)层状盐内的中心钻孔中进行 28 天的加热和 13 天的冷却。这里使用的是流动模拟器 PFLOTRAN;模拟在 Voronoi 网格上运行,热传导率、渗透率和孔隙率衰减与温度有关,远离挖掘区。渗透率的温度依赖性是为了与实地测量结果相匹配。模拟结果与现场测得的温度和 41 天实验中盐水流入总量的吻合度在 + /- 0.1 °C 范围内。这项研究通过模拟 BATS 1a 实验的三种加热情况,说明在分析和模拟实验数据时,盐内温度变化的准确性至关重要,这表明温度对盐水总流入量有直接影响。
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引用次数: 0
Effects of supercritical CO2 based fluids imbibition on the mechanical properties of shale: An experimental study at high-temperature and high-pressure condition 超临界二氧化碳流体浸泡对页岩力学性能的影响:高温高压条件下的实验研究
IF 3.3 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-08-09 DOI: 10.1016/j.gete.2024.100583
Qiao Lyu , Jinghong Deng , Jingqiang Tan , Yonggang Ding , Yushuai Shi , Yiwei Liu , Yijun Shen

In the process of integrating supercritical CO2 (ScCO2)-enhanced shale gas recovery and geological sequestration, the mechanical properties of shale can be impacted by ScCO2 under high-temperature and high-pressure conditions. This can affect wellbore stability, production efficiency, and the safety of sequestration. To address this issue, this study investigated the interactions between shale and three types of fluids: ScCO2, water, and a combination of ScCO2 and water. Experiments were conducted at high pressure (15 MPa and 45 MPa) and high temperature (100 °C). Changes in shale's mechanical properties before and after immersion were analyzed using uniaxial compression tests and acoustic emission monitoring. The main cation content, microstructure, and element minerals of shale's solution after immersion were also studied. The results show that immersion in ScCO2 and related fluids deteriorates shale's mechanical properties. Immersion in ScCO2 has the least effect on shale strength, followed by the change in shale strength caused by immersion in water, and shale strength is the lowest after immersion in a combination of water and ScCO2. ScCO2 imbibition promotes the occurrence of micro-cracks, while immersion in water makes shale's matrix loose, forming a pore network structure that is most significantly affected by a combination of water and ScCO2. For unsoaked and water-immersed shale samples, the acoustic emission events mainly occur during the unstable crack propagation stage, while the acoustic emission events in shale samples treated with ScCO2 are more dispersed. Compared with previous dynamic pressure immersion experiments, the strength of shale after static pressure immersion increases by 10–30 MPa. This study aims to provide a more comprehensive understanding of the alterations in the mechanical properties of shale when subjected to high temperature and high-pressure immersion conditions. The findings provide valuable data for shale gas extraction and carbon sequestration.

在整合超临界二氧化碳(ScCO2)强化页岩气采收和地质封存的过程中,ScCO2 在高温高压条件下会影响页岩的机械性能。这会影响井筒稳定性、生产效率和封存安全性。为解决这一问题,本研究调查了页岩与三种流体之间的相互作用:ScCO2、水以及 ScCO2 和水的组合。实验在高压(15 兆帕和 45 兆帕)和高温(100 °C)条件下进行。使用单轴压缩试验和声发射监测分析了浸泡前后页岩机械性能的变化。此外,还研究了浸泡后页岩溶液中的主要阳离子含量、微观结构和元素矿物。结果表明,在 ScCO2 和相关流体中浸泡会降低页岩的机械性能。在 ScCO2 中浸泡对页岩强度的影响最小,其次是在水中浸泡引起的页岩强度变化,而在水和 ScCO2 混合液中浸泡后页岩强度最低。ScCO2 的浸泡会促进微裂缝的出现,而浸泡在水中会使页岩的基质变得疏松,形成孔隙网络结构,这种结构受水和 ScCO2 混合浸泡的影响最大。对于未浸泡和浸水的页岩样品,声发射事件主要发生在不稳定的裂纹扩展阶段,而用 ScCO2 处理过的页岩样品的声发射事件则更为分散。与之前的动压浸泡实验相比,静压浸泡后页岩的强度提高了 10-30 兆帕。本研究旨在更全面地了解页岩在高温高压浸泡条件下的力学性能变化。研究结果为页岩气开采和碳封存提供了宝贵的数据。
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Geomechanics for Energy and the Environment
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