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Comparative assessment of biochar produced from LDPE and neem leaves using batch and semi-batch biomass fuel-based reactors 利用间歇和半间歇生物质燃料反应器对LDPE和印楝叶生产的生物炭进行比较评估
4区 工程技术 Q2 Environmental Science Pub Date : 2023-11-10 DOI: 10.1080/17597269.2023.2281099
Kingsley O. Iwuozor, Ebuka Chizitere Emenike, Joy Adeleke, Taiwo Temitayo Micheal, Samuel Ogunniyi, Adewale George Adeniyi
AbstractThis research aims to investigate and compare the properties of biochar derived from low-density polyethylene (LDPE) and neem leaves, utilizing both batch and semi-batch biomass fuel-based reactors for co-carbonization. While previous studies have primarily employed electrical-powered or biomass fuel-based batch reactors, this study introduces the innovative approach of utilizing a semi-batch reactor, marking a significant advancement in biochar production. The co-carbonization process lasted for ∼2 h in the batch-based system and nearly 3 h in the semi-batch system. The semi-batch system achieved higher temperature peaks in comparison to the batch-based system. In terms of biochar yield, the batch-based system generated a biochar yield of 30.35%, while the semi-batch system yielded 17.3%. Through BET analysis, it was determined that the biochar produced using the semi-batch reactor had a surface area of 227 m2/g and a pore diameter of 2.116 nm. Similarities and differences in functional groups among the biochar samples produced using the semi-batch and batch reactors were identified through FTIR analysis. By utilizing EDX spectroscopy, it was observed that the batch-based system contained seven elements, whereas the semi-batch-reacted sample had similar elements but lacked nitrogen, potassium, and magnesium. The semi-batch-reacted sample exhibited an increased carbon content, whereas the concentrations of other elements decreased when compared to the batch-reacted sample. The biochar samples can be applied in various applications, including water treatment, energy conversion, and storage. The findings of this study contribute to sustainable waste management practices, carbon sequestration efforts, and the development of innovative solutions for various industries.Keywords: Batch reactorcharacterizationenergy utilizationgasificationgreen chemistrysemi-batch reactor Author contributionsKingsley O. Iwuozor: conceptualization, data curation, formal analysis, investigation, methodology, validation, visualization, roles/writing—original draft, writing—review and editing. Ebuka Chizitere Emenike: conceptualization, data curation, formal analysis, investigation, methodology, validation, visualization, writing—review and editing. Joy Adeleke: conceptualization, data curation, formal analysis, investigation, methodology, validation, visualization, writing—review and editing. Taiwo Temitayo Micheal: validation, visualization, roles/writing—original draft, writing—review and editing. Ogunniyi Samuel: validation, visualization, roles/writing—original draft, writing—review and editing. Adewale George Adeniyi: conceptualization, data curation, formal analysis, investigation, methodology, supervision, validation, visualization, writing—review and editing.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work received no external funding.
摘要本研究旨在研究和比较低密度聚乙烯(LDPE)和印楝叶制备的生物炭的性能,利用间歇和半间歇生物质燃料反应器进行共碳化。虽然以前的研究主要采用电力或生物质燃料间歇反应器,但本研究引入了利用半间歇反应器的创新方法,标志着生物炭生产的重大进步。共碳化过程在间歇体系中持续了~ 2小时,在半间歇体系中持续了近3小时。与基于批处理的系统相比,半批处理系统实现了更高的温度峰值。在生物炭产率方面,间歇体系的生物炭产率为30.35%,而半间歇体系的生物炭产率为17.3%。通过BET分析,确定半间歇反应器生产的生物炭的比表面积为227 m2/g,孔径为2.116 nm。通过FTIR分析,确定了半间歇反应器和间歇反应器生产的生物炭样品中官能团的异同。利用EDX光谱分析发现,批反应体系中含有7种元素,而半批反应样品中含有类似元素,但缺少氮、钾和镁。与批量反应样品相比,半批量反应样品的碳含量增加,而其他元素的浓度降低。生物炭样品可以应用于各种应用,包括水处理、能量转换和储存。这项研究的结果有助于可持续的废物管理实践,碳封存工作,以及为各行业开发创新的解决方案。关键词:间歇反应器表征能源利用气化绿色化学半间歇反应器作者贡献:概念化,数据管理,形式分析,调查,方法论,验证,可视化,角色/写作-原始草稿,写作-审查和编辑。Ebuka Chizitere Emenike:概念化,数据管理,形式分析,调查,方法论,验证,可视化,写作-审查和编辑。Joy Adeleke:概念化、数据管理、形式分析、调查、方法论、验证、可视化、写作审查和编辑。Taiwo Temitayo michael:验证,可视化,角色/写作-原稿,写作-审查和编辑。Ogunniyi Samuel:验证,可视化,角色/写作-原稿,写作-审查和编辑。Adewale George Adeniyi:概念化、数据管理、形式分析、调查、方法论、监督、验证、可视化、写作-审查和编辑。披露声明作者未报告潜在的利益冲突。本工作未获得外部资助。
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引用次数: 0
Bio-electricity production in a single-chamber microbial fuel cell using urine as a substrate 以尿液为底物的单室微生物燃料电池的生物电生产
4区 工程技术 Q2 Environmental Science Pub Date : 2023-11-09 DOI: 10.1080/17597269.2023.2277991
Wilgince Apollon, Sathish-Kumar Kamaraj, Humberto Rodríguez-Fuentes, Juan Florencio Gómez-Leyva, Juan Antonio Vidales-Contreras, María Verónica Mardueño-Aguilar, Alejandro Isabel Luna-Maldonado
AbstractThis study aimed to evaluate the performance of a single-chamber microbial fuel cell (SC-MFC) using undiluted livestock urine (i.e. cow, goat, and sheep urine). Data showed that the MFC with cow urine reached a maximum power density of 110.72 ± 0.42 mW m−2 at the maximum current density of 230.88 ± 0.65 mA m−2 and voltage of 277 ± 0.04 mV in a polarization experiment. Whereas, in terms of the long-term operation experiment, the same reactor reached a maximum power density of 7.60 ± 0.06 mW m−2 (on day 10), with an external resistance of 1000 Ω. Besides, 44.30% of microorganisms (strains) were found in the anode of Sheep-MFC due to the association of urine with the substrate, compared to other reactors. The study's findings indicated that the composition of the livestock urine positively affected power generation in the evaluated MFCs. In addition, cow urine was the best substrate for driving MFC technology compared to other types of urine used in this study.Keywords: Electrochemically active bacteriamicrobial fuel cellpower densityorganic substrateurine waste AcknowledgmentsThe first author (WA) acknowledges the National Council of Humanities, Science, and Technology (CONAHCyT). In addition, the authors acknowledge the Support Program for Scientific and Technological Research (PAICYT) at the Autonomous University of Nuevo León, as well as the Molecular Laboratory at the Technological Institute of Tlajomulco for their support.Disclosure statementNo potential conflict of interest was reported by the author(s).
摘要本研究旨在评价单室微生物燃料电池(SC-MFC)使用未稀释家畜尿液(如牛、山羊和绵羊尿液)的性能。极化实验结果表明,在电流密度为230.88±0.65 mA m−2、电压为277±0.04 mV时,牛尿MFC的最大功率密度为110.72±0.42 mW m−2。而在长期运行实验中,同一反应器的最大功率密度为7.60±0.06 mW m−2(第10天),外阻为1000 Ω。此外,与其他反应器相比,绵羊- mfc阳极中由于尿液与底物的关联而发现的微生物(菌株)占44.30%。研究结果表明,在被评估的mfc中,牲畜尿液的组成对发电有积极影响。此外,与本研究中使用的其他类型的尿液相比,牛尿是驱动MFC技术的最佳底物。关键词:电化学活性细菌微生物燃料电池功率密度有机基质废物致谢第一作者(WA)感谢美国国家人文科学技术委员会(CONAHCyT)。此外,作者感谢新自治大学León的科学和技术研究支持计划(PAICYT)以及Tlajomulco技术研究所的分子实验室的支持。披露声明作者未报告潜在的利益冲突。
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引用次数: 1
Environmental footprint evaluation of Jatropha biodiesel production and utilization in Ethiopia: a comprehensive well-to-wheel life cycle analysis 埃塞俄比亚麻疯树生物柴油生产和利用的环境足迹评价:从油井到车轮的综合生命周期分析
4区 工程技术 Q2 Environmental Science Pub Date : 2023-11-08 DOI: 10.1080/17597269.2023.2277990
Yohannes Alemu, Ramchandra Bhandari, Venkata Ramayya Ancha
AbstractIn Ethiopia, a Life Cycle Analysis of Jatropha-based biodiesel was conducted using the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation model to assess energy consumption, efficiency, and greenhouse gas (GHG) emissions in the well-to-tank (WTT) and well-to-wheel stages. The inventory analysis involved field surveys and scenarios to evaluate energy savings, emission reductions, and air pollutants in biodiesel-diesel blends. In the WTT analysis, the energy consumption for producing 1 MJ of Jatropha-based biodiesel was found to be 0.43 MJ under rain-fed and 0.68 MJ under irrigated conditions. The net energy value was positive, and the net energy ratio was higher compared to that in other countries. The results show that GHG emissions at 19.8 g CO2 eq/MJ during the WTT stage can reduce environmental impacts by up to 45–87% depending on the type of irrigation used. When examining the global warming potential, it was found that the cultivation of Jatropha accounted for the highest share of GHG at 57.58%, followed by the biodiesel production process at 23.88%. On the other hand, vehicles employing B20 blend could replace 14.78% of fossil energy use and reduce 13.95% of GHG emissions per km, compared to pure diesel vehicle.Keywords: Jatropha biodieselGHG emissionLife cycle assessmentWell-to-tankWell-to-wheel AcknowledgmentsThe authors would like to acknowledge the German Federal Ministry of Education and Research (BMBF) for funding this research under the framework of the WESA-ITT project. Thanks are also due to the German Development Bank (KfW) for their support in the form of a scholarship to the corresponding author of this article through ExiST project.Author contributionsY.A., performed the data collection and literature review; R.B., V.R., and Y.A. developed the methodology, and performed the data analysis and simulation models; Y.A. and R.B. contributed to writing the paper; R.B. and V.R. reviewed and edited the manuscript; R.B., as a main supervisor, followed up all study steps and gave helpful advice. All authors discussed the results, and read and approved the manuscript. All authors have read and agreed to the published version of the manuscript.Disclosure statementNo potential conflict of interest was reported by the author(s).Data availability statementThe data presented in this manuscript are available on request from the corresponding author.Additional informationFundingGermen Federal Ministry of Education and Research (BMBF) through its Project Management Agency (Pt-DLR) under the framework of WESA-ITT Project with grant No 01DG16010B, and Germen Development Bank (KfW) under ExiST Project with grant No. 51235 funded this research.
在埃塞俄比亚,利用温室气体、管制排放和运输中的能源使用模型对麻疯树生物柴油的生命周期进行了分析,以评估从井到罐(WTT)和从井到车轮(WTT)阶段的能源消耗、效率和温室气体(GHG)排放。清单分析包括实地调查和场景,以评估生物柴油-柴油混合物的节能、减排和空气污染物。WTT分析发现,雨养条件下生产1 MJ麻疯树生物柴油的能耗为0.43 MJ,灌溉条件下为0.68 MJ。净能值为正,净能比高于其他国家。结果表明:根据灌溉方式的不同,WTT阶段19.8 g CO2当量/MJ的温室气体排放可减少高达45-87%的环境影响。在分析全球变暖潜势时,发现麻疯树的种植占温室气体的57.58%,其次是生物柴油的生产过程,占23.88%。另一方面,与纯柴油汽车相比,使用B20混合燃料的汽车可以替代14.78%的化石能源使用,每公里温室气体排放量减少13.95%。关键词:麻疯树生物柴油;温室气体排放;生命周期评估;从井到罐;从井到轮致谢作者感谢德国联邦教育与研究部(BMBF)在WESA-ITT项目框架下资助本研究。还要感谢德国开发银行(KfW)通过ExiST项目以奖学金的形式支持本文的通讯作者。作者contributionsY.A。进行资料收集和文献综述;r.b., v.r.和Y.A.开发了方法,并进行了数据分析和模拟模型;Y.A.和R.B.参与了论文的撰写;R.B.和V.R.审阅和编辑手稿;r.b.作为主要的指导老师,跟进了所有的学习步骤,并给出了有益的建议。所有作者讨论结果,阅读并批准稿件。所有作者都已阅读并同意稿件的出版版本。披露声明作者未报告潜在的利益冲突。数据可用性声明本文中提供的数据可向通讯作者索取。德国联邦教育和研究部(BMBF)通过其项目管理机构(Pt-DLR)在WESA-ITT项目框架下(资助号01DG16010B)和德国开发银行(KfW)在ExiST项目下(资助号51235)资助了这项研究。
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引用次数: 0
Potential of thermophilic bacteria isolated from cow dung-grass compost for bioethanol production using floral waste 从牛粪草堆肥中分离的嗜热细菌利用花卉废弃物生产生物乙醇的潜力
4区 工程技术 Q2 Environmental Science Pub Date : 2023-10-30 DOI: 10.1080/17597269.2023.2274697
Smita Dutta, Prerna J. Yesankar, M. Suresh Kumar
AbstractIn recent years, various efforts have been invested in producing bioethanol from lignocellulosic biomass (LCB) using thermophilic bacteria. Twelve thermophilic ethanologenic bacteria were isolated from cow dung-grass compost using an enrichment technique, and the isolate, CSD6, which produced the highest bioethanol, was studied further. CSD6 utilized both pentose and hexose sugars producing ethanol, lactic acid and acetic acid as major soluble products and was identified through 16S rRNA gene sequencing as a strain of Geobacillus stearothermophilus. The highest ethanol production was found to be 25.05 mM from 5 g/L glucose, equivalent to 55% of the theoretical ethanol yield at 55 °C and initial pH 7.5. The isolate showed average tolerance to ethanol and acetic acid concentration and initial substrate loading. The bioethanol potential of CSD6 was also studied using autoclave-treated mixed floral waste (FW) as a no-cost substrate. CSD6 produced a maximum of 8.9 mM of bioethanol with a 75.47% decrease in reducing sugars using 20 g/L FW as substrate without any enzymatic pretreatment, indicating the ability of CSD6 to produce bioethanol from easily available substrates.Keywords: Bioethanol productionfloral wastethermophilic bacteriaGeobacillus AcknowledgementWe are thankful to the Director, CSIR- NEERI, Nagpur, India, for providing the necessary facilities and funds. We also would like to thank Dr. Anshuman A. Khardenavis, CSIR-NEERI, for allowing us to use his laboratory facilities.Author’s contributionSD: Conceptualization, Methodology, Investigation, Validation, Writing-Original Draft, Review and editing; PJY: Investigation, Writing- Review and Editing; MSK: Supervision, Conceptualization, Writing- Review and EditingDisclosure statementNo potential conflict of interest was reported by the author(s).Data availability statementAll data generated during this study are included in this manuscript.Notes1 LCB- Lignocellulosic biomass, FW- Floral waste, GHG- Green house gas, MSW- Municipal solid waste, CBP- Consolidated bioprocessing, PCR- Polymerase Chain Reaction, CMC- carboxymethyl cellulose, TS- Total solid.Additional informationFundingThis research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.
近年来,利用嗜热细菌从木质纤维素生物质(LCB)中生产生物乙醇的研究取得了很大进展。采用富集技术从牛粪草堆肥中分离出12株嗜热产乙醇菌,并对产乙醇量最高的菌株CSD6进行了进一步研究。CSD6利用戊糖和己糖生产乙醇、乳酸和乙酸为主要可溶性产物,通过16S rRNA基因测序鉴定为嗜脂热地杆菌菌株。在55°C和初始pH 7.5条件下,5 g/L葡萄糖的乙醇产量最高为25.05 mM,相当于理论乙醇产量的55%。该分离物对乙醇、乙酸浓度和初始底物负荷的耐受性均为中等。利用高压灭菌处理的混合花卉废弃物(FW)作为无成本底物,研究了CSD6的生物乙醇潜力。使用20 g/L FW作为底物,无需任何酶处理,CSD6最多可生产8.9 mM的生物乙醇,还原糖减少75.47%,表明CSD6能够从容易获得的底物中生产生物乙醇。感谢印度那格浦尔CSIR- NEERI主任为我们提供了必要的设施和资金。我们还要感谢neeri的csir Anshuman A. Khardenavis博士允许我们使用他的实验室设施。作者贡献:概念、方法、调查、验证、写作-原稿、审稿和编辑;PJY:调查,写作-审查和编辑;MSK:监督,构思,写作-审查和编辑披露声明作者未报告潜在的利益冲突。数据可用性声明本研究过程中产生的所有数据都包含在本文中。注1 LCB—木质纤维素生物质,FW—花卉废弃物,GHG—温室气体,MSW—城市固体废弃物,CBP—综合生物处理,PCR—聚合酶链反应,CMC—羧甲基纤维素,TS—总固体。本研究没有从公共、商业或非营利部门的资助机构获得任何特定的资助。
{"title":"Potential of thermophilic bacteria isolated from cow dung-grass compost for bioethanol production using floral waste","authors":"Smita Dutta, Prerna J. Yesankar, M. Suresh Kumar","doi":"10.1080/17597269.2023.2274697","DOIUrl":"https://doi.org/10.1080/17597269.2023.2274697","url":null,"abstract":"AbstractIn recent years, various efforts have been invested in producing bioethanol from lignocellulosic biomass (LCB) using thermophilic bacteria. Twelve thermophilic ethanologenic bacteria were isolated from cow dung-grass compost using an enrichment technique, and the isolate, CSD6, which produced the highest bioethanol, was studied further. CSD6 utilized both pentose and hexose sugars producing ethanol, lactic acid and acetic acid as major soluble products and was identified through 16S rRNA gene sequencing as a strain of Geobacillus stearothermophilus. The highest ethanol production was found to be 25.05 mM from 5 g/L glucose, equivalent to 55% of the theoretical ethanol yield at 55 °C and initial pH 7.5. The isolate showed average tolerance to ethanol and acetic acid concentration and initial substrate loading. The bioethanol potential of CSD6 was also studied using autoclave-treated mixed floral waste (FW) as a no-cost substrate. CSD6 produced a maximum of 8.9 mM of bioethanol with a 75.47% decrease in reducing sugars using 20 g/L FW as substrate without any enzymatic pretreatment, indicating the ability of CSD6 to produce bioethanol from easily available substrates.Keywords: Bioethanol productionfloral wastethermophilic bacteriaGeobacillus AcknowledgementWe are thankful to the Director, CSIR- NEERI, Nagpur, India, for providing the necessary facilities and funds. We also would like to thank Dr. Anshuman A. Khardenavis, CSIR-NEERI, for allowing us to use his laboratory facilities.Author’s contributionSD: Conceptualization, Methodology, Investigation, Validation, Writing-Original Draft, Review and editing; PJY: Investigation, Writing- Review and Editing; MSK: Supervision, Conceptualization, Writing- Review and EditingDisclosure statementNo potential conflict of interest was reported by the author(s).Data availability statementAll data generated during this study are included in this manuscript.Notes1 LCB- Lignocellulosic biomass, FW- Floral waste, GHG- Green house gas, MSW- Municipal solid waste, CBP- Consolidated bioprocessing, PCR- Polymerase Chain Reaction, CMC- carboxymethyl cellulose, TS- Total solid.Additional informationFundingThis research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.","PeriodicalId":56057,"journal":{"name":"Biofuels-Uk","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136067471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing biochar properties through doping: A comparative study of sugarcane bagasse and chicken feather 通过掺杂提高生物炭性能:蔗渣和鸡毛的比较研究
4区 工程技术 Q2 Environmental Science Pub Date : 2023-10-30 DOI: 10.1080/17597269.2023.2274694
Ebuka Chizitere Emenike, Victor Temitope Amusa, Kingsley O. Iwuozor, Toluwalase Ojeyemi, Taiwo Temitayo Micheal, Kehinde Temitope Micheal, Adewale George Adeniyi
AbstractThis comparative study explores the production and characterization of biochar derived from a combination of sugarcane bagasse (SB) and chicken feathers (CF), with a doping strategy for each biomass in the other. Two biochars, SB92CF-BC (92% SB and 8% CF) and CF92SB-BC (92% CF and 8% SB), were produced using a top-lit updraft reactor, resulting in a yield of 34% and 27%, respectively. Fourier transform infrared spectroscopy (FTIR) analysis revealed characteristic functional groups in both biochars, with minimal impact from the doping process. Scanning electron spectroscopy (SEM) analysis showed distinct morphological features, with SB92CF-BC exhibiting a smoother surface and CF92SB-BC displaying an irregular and rough morphology. Energy dispersive X-ray spectroscopy (EDS) analysis confirmed the presence of several elements in both biochars, with a higher nitrogen content in CF92SB-BC. Brunauer-Emmett-Teller (BET) analysis demonstrated significant specific surface areas for both biochars, exceeding those reported for unmodified SB and CF biochars. The findings suggest potential synergistic effects resulting from the doping strategy. The study expands knowledge on biochar production from diverse biomass sources and highlights the potential for utilizing lignocellulosic and non-lignocellulosic biomass waste materials for sustainable biochar production.Article HighlightsComparative study on biochar production from sugarcane bagasse and chicken feathers.Unique properties observed in resulting biochars, including functional groups, morphology, and elemental composition.Versatile potential applications in soil amendment, carbon sequestration, and wastewater treatment.Keywords: Sustainable waste managementbiocharsugarcane bagassechicken feathersdoping AcknowledgementAll authors whose works are cited in this article are hereby acknowledged.Author contributionsEbuka Chizitere Emenike; Methodology, Data curation, Writing - original draft; Writing - review & editing; Victor Temitope Amusa; Writing - original draft; Writing - review & editing; Kingsley O. Iwuozor; Methodology, Writing - original draft; Writing - review & editing; Taiwo Temitayo Micheal; Writing - original draft; Writing - review & editing; Kehinde Temitope Micheal; Writing – original draft; Writing – review and editing; Adewale George Adeniyi; Conceptualization, Methodology, Writing - original draft; Writing - review & editing; Validation; SupervisionDisclosure statementNo potential conflict of interest was reported by the author(s).Data availability statementData sharing is not applicable to this article as no new data were created or analyzed in this study
摘要本研究以甘蔗渣(SB)和鸡毛(CF)为原料,采用掺杂策略制备生物炭。两种生物炭分别为SB92CF-BC (92% SB和8% CF)和CF92SB-BC (92% CF和8% SB),产率分别为34%和27%。傅里叶变换红外光谱(FTIR)分析揭示了两种生物炭的特征官能团,掺杂过程的影响最小。扫描电子能谱(SEM)分析表明,SB92CF-BC表面光滑,CF92SB-BC表面不规则粗糙。能量色散x射线能谱(EDS)分析证实了两种生物炭中存在多种元素,CF92SB-BC中氮含量较高。brunauer - emmet - teller (BET)分析表明,这两种生物炭的比表面积显著高于未改性的SB和CF生物炭。研究结果表明,兴奋剂策略可能产生协同效应。该研究扩展了从不同生物质来源生产生物炭的知识,并强调了利用木质纤维素和非木质纤维素生物质废料生产可持续生物炭的潜力。本文重点研究了以蔗渣和鸡毛为原料生产生物炭的比较研究。在所得生物炭中观察到的独特性质,包括官能团、形态和元素组成。在土壤修复、固碳和废水处理方面具有广泛的潜在应用。关键词:可持续废弃物管理生物炭甘蔗甘蔗渣鸡毛肥料致谢所有在本文中被引用的作者在此致谢。作者:sebuka Chizitere Emenike;方法论、数据整理、写作——原稿;写作-审查和编辑;维克多·特米托普·阿莫萨;写作——原稿;写作-审查和编辑;金斯利·o·乌佐尔;方法论、写作——初稿;写作-审查和编辑;michael;写作——原稿;写作-审查和编辑;凯欣德·特米托普·迈克尔;写作——原稿;写作——审阅和编辑;阿德瓦莱·乔治·阿德尼伊;概念、方法、写作——初稿;写作-审查和编辑;验证;监督披露声明作者未报告潜在的利益冲突。数据可用性声明数据共享不适用于本文,因为本研究没有创建或分析新的数据
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引用次数: 0
Proteobacterial dominance in endophytic bacterial diversity in switchgrass growing under nitrogen range and effect on plant growth 氮胁迫下柳枝稷内生细菌多样性的变形菌优势及其对植物生长的影响
4区 工程技术 Q2 Environmental Science Pub Date : 2023-10-19 DOI: 10.1080/17597269.2023.2266629
Rahul Bahulikar
AbstractSwitchgrass (Panicum virgatum L.) is native to North America and cultivated as a forage and bioenergy crop. Inorganic fertilizers enhance biomass production, increase production costs, and pollute the environment. Switchgrass cultivation using an eco-friendly approach might be achieved by inoculation with beneficial microbes. Therefore, the diversity of cultivable endophytic bacteria from roots and shoots of switchgrass growing under a nitrogen regime was studied. The potential of bacteria for plant growth promotion (PGP) was tested under in vitro conditions. A total of 216 bacterial isolates obtained belonged to four phyla and 33 genera, and most isolates were obtained from plants growing under no (0 kg/ha) or low nitrogen (90 kg/ha) input, rather than higher N (180 kg/ha). Higher numbers of isolates belonged to the phylum Proteobacteria, and genus-wise representation showed the dominance of Pseudomonas, Enterobacter, and rhizobia. Bacterial isolates were tested for PGP properties, e.g. phosphate solubilization, 1-aminocyclopropane-1-carboxylic acid (ACC) deaminase, Indole Acetic Acid (IAA) production, and nitrogen fixation. Many isolates were positive for one or more PGP properties. In in vitro analysis, selected bacterial isolates were inoculated in two commercial switchgrass cultivars and a showed cultivar-specific response. PGP isolates can be used for pot or field trials and eventually for the sustainable cultivation of switchgrass.Keywords: Biofuel plantendophytesplant growth promotionnitrogen fixation Disclosure statementThe author declares no competing interests.Additional declarationsAs the author used plant material and this study does not report any animal or human research, ethics approval, consent to participate, and consent for publication are not required.Author contributionsThe author carried out all experiments, data analysis, and manuscript writing.Data availability statementThe raw data are available on request to the corresponding author. The bacterial strains are available from the Noble Research Institute, Ardmore, OK, USA.Additional informationFundingNoble Research Institute, Ardmore, OK, USA. This is the link of the institute (https://www.noble.org/).
摘要柳枝稷(Panicum virgatum L.)是一种原产于北美的牧草和生物能源作物。无机肥料促进生物质生产,增加生产成本,污染环境。柳枝稷的生态友好栽培可以通过接种有益微生物来实现。因此,对氮肥条件下柳枝稷根、芽可培养内生细菌的多样性进行了研究。在体外条件下,研究了细菌促进植物生长(PGP)的潜力。共分离得到216株细菌,分属4门33属,大多数分离株来自无(0 kg/ha)或低氮(90 kg/ha)条件下生长的植物,而不是高氮(180 kg/ha)条件下生长的植物。较高数量的分离物属于变形菌门,属代表显示假单胞菌,肠杆菌和根瘤菌的优势。对分离的细菌进行了PGP性能测试,如磷酸增溶、1-氨基环丙烷-1-羧酸(ACC)脱氨酶、吲哚乙酸(IAA)生产和固氮。许多分离株对一种或多种PGP特性呈阳性。在体外分析中,选定的细菌分离株接种于两个商品柳枝稷品种,并表现出品种特异性反应。PGP分离株可用于盆栽或田间试验,并最终用于柳枝稷的可持续栽培。关键词:生物燃料植物;植物;促进植物生长;附加声明:由于作者使用植物材料,本研究不涉及任何动物或人类研究,因此不需要伦理批准、参与同意和发表同意。作者完成了所有实验、数据分析和论文撰写。数据可用性声明原始数据可根据通信作者的要求提供。细菌菌株可从诺贝尔研究所,阿德莫尔,OK,美国。资助诺布尔研究所,阿德莫尔,OK,美国。这是研究所的链接(https://www.noble.org/)。
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引用次数: 0
Biodiesel production from waste cooking oil using KOH/HY-type nano-catalyst derived from silica sand 利用硅砂衍生的KOH/ hy型纳米催化剂从废食用油中制备生物柴油
4区 工程技术 Q2 Environmental Science Pub Date : 2023-10-19 DOI: 10.1080/17597269.2023.2267849
Huda A. Abdul-Kader, Zaidoon M. Shakor, Bashir Y. Sherhan, Shurooq T. Al-Humairi, Mohamed Aboughaly, M. A. Hazrat, Islam Md Rizwanul Fattah
AbstractThe present study aimed to synthesize a Y-nanozeolite catalyst using the hydrothermal method and Iraqi sand-derived silica as a low-cost and readily available raw material. The catalyst was tested before and after loading with potassium hydroxide (KOH). The experiments were conducted in a batch reactor under different temperatures (40, 50, and 60 °C) and a 3-h reaction time, using the prepared Y-catalyst with three different particle sizes (75, 600, and 1000 μm). The results showed that increasing the temperature and/or reaction time generally resulted in increased conversion and yield when the catalyst was unpromoted with KOH, reaching a range of 55.56% and 33.33%, respectively. However, a significant increase in the conversion and yield was observed after promoting the catalyst with 10% KOH molecules. The optimal conditions for achieving the highest conversion and yield of biodiesel were determined to be 86.67% and 82.22%, respectively. These conditions involved a temperature of 60 °C, a reaction time of 2 h, and the use of a catalyst with a particle size of 75 μm loaded with 10% KOH. The use of a heterogeneous catalyst loaded with the base in a low percentage helps to dispense with the use of homogeneous catalysts with a high percentage of bases.Keywords: Catalytic transesterification reactionbiodieselalternative fuelKOH/HY-type nano-catalystalternative nano silica AcknowledgmentsThe authors thankfully acknowledge scientific support of Department of Chemical Engineering and the Nanotechnology and Advanced Material Research Center, University of Technology-Iraq, Baghdad, Iraq.Disclosure statementNo potential conflict of interest was reported by the authors.Additional informationFundingThis research was funded by University of Technology Sydney through Strategic Research Support funding with grant number (324100.2200034).
摘要采用水热法制备了一种y型纳米沸石催化剂,以伊拉克砂土为原料,制备了一种低成本、易得的催化剂。对催化剂加装氢氧化钾前后进行了测试。采用不同粒径(75、600和1000 μm)的y -催化剂,在不同温度(40、50和60℃)和3 h反应时间的间歇式反应器中进行了实验。结果表明,在KOH不促进的情况下,提高反应温度和反应时间,转化率和产率均有所提高,分别达到55.56%和33.33%。然而,用10%的KOH分子促进催化剂后,转化率和产率显著提高。结果表明,生物柴油的最佳转化率和产率分别为86.67%和82.22%。反应温度为60℃,反应时间为2 h,催化剂粒径为75 μm, KOH浓度为10%。使用装载低百分比碱的多相催化剂有助于免除使用含有高百分比碱的均相催化剂。关键词:催化酯交换反应生物柴油替代燃料koh / hy型纳米催化剂替代纳米二氧化硅致谢作者感谢伊拉克理工大学化学工程系和纳米技术与先进材料研究中心的科学支持。披露声明作者未报告潜在的利益冲突。本研究由悉尼科技大学通过战略研究支持基金资助,资助号(324100.2200034)。
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引用次数: 0
Recent advancement in thermochemical conversion of biomass to biofuel 生物质热化学转化为生物燃料的最新进展
4区 工程技术 Q2 Environmental Science Pub Date : 2023-10-17 DOI: 10.1080/17597269.2023.2261788
Huei Yeong Lim, Nor Adilla Rashidi, Muhamad Farhan Haqeem Othman, Intan Syafiqah Ismail, Syazmi Zul Arif Hakimi Saadon, Bridgid Lai Fui Chin, Suzana Yusup, Mohammad Nurizat Rahman
AbstractBiofuel’s carbon neutrality possesses great potential in decarbonizing existing fossil fuels dependency. Biofuel can be produced from various low-cost and renewable wastes including agricultural residues and sewage sludge, through various methods like thermochemical and biological pathways, producing solid, liquid, or gaseous biofuels. Among the two, thermochemical methods offer significantly shorter reaction time and higher versatility toward feedstocks as compared to the biological route. Though, there are challenges caused by the biomass heterogeneity and low biofuel quality in thermochemical conversion methods. Hence, this review aims to discuss recent advancements of thermochemical conversion technologies of biomass to biofuel, including torrefaction, pyrolysis, transesterification, hydrothermal processing, and gasification. The challenges encountered in the thermochemical conversion methods are discussed and attempts made in resolving it are also reported. Furthermore, potentials of solid, liquid, and gaseous biofuels are also presented in terms of biomass resources availability, and applications in industry and transportation sectors. Overall, sustainable production and utilisation of biofuels are one highly potential alternative towards a net zero carbon future.Keywords: Biofuelbiomasscarbon neutralitythermochemical conversionwastes Competing interestThe authors declare no competing interest.Data availabilityNo datasets were generated or analysed during the current study.Disclosure statementNo potential conflict of interest was reported by the authors.Additional informationFundingThis work was supported by the Ministry of Higher Education, Malaysia under the HICoE research grant (cost centre: 015ME0-014).
摘要生物燃料的碳中性在减少对化石燃料的依赖方面具有巨大的潜力。生物燃料可以从各种低成本和可再生的废物中生产,包括农业残留物和污水污泥,通过各种方法,如热化学和生物途径,生产固体、液体或气体生物燃料。其中,与生物途径相比,热化学方法提供了明显更短的反应时间和更高的多功能性。然而,生物质的异质性和生物燃料的低质量给热化学转化方法带来了挑战。因此,本文综述了生物质转化为生物燃料的热化学转化技术的最新进展,包括焙烧、热解、酯交换、水热处理和气化。讨论了热化学转化方法中遇到的挑战,并报道了为解决这些挑战所作的尝试。此外,固体、液体和气体生物燃料的潜力也在生物质资源的可用性以及在工业和运输部门的应用方面进行了介绍。总体而言,生物燃料的可持续生产和利用是实现净零碳未来的一个极具潜力的替代方案。关键词:生物燃料生物质碳中性热化学转化废弃物竞争利益作者声明无竞争利益。数据可用性本研究未生成或分析任何数据集。披露声明作者未报告潜在的利益冲突。本研究由马来西亚高等教育部HICoE研究基金(成本中心:015ME0-014)资助。
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引用次数: 0
Kinetic evaluation of Pachira aquatica Aubl biomass slow pyrolysis towards to biochar production 水生松茸生物质缓慢热解制炭的动力学评价
4区 工程技术 Q2 Environmental Science Pub Date : 2023-10-16 DOI: 10.1080/17597269.2023.2269735
J. S. Nascimento, E. R. Camelo, M. S. Carvalho, C. F. Virgens
AbstractThe abrupt climate change, caused by the anthropogenic activities in the environment, intensified the search for sustainable sources of energy aiming reduce the dependence on fossil fuels. In this study, a multivariate study design was applied within a batch reactor system to determine the influence of process variables and kinetic parameters of slow pyrolysis of Pachira aquatica Aubl fruit peel towards biochar generation. The statistical evaluation of Box Behnken planning model was applied and showed good adjustment to the model establishing the model that describes the significant effect of variables behavior. The maximum biochar yield (41.22%) was observed were temperature (T) = 406 °C, heating rate β = 2 °C min−1, and residence time tR = 60 min, under nitrogen atmosphere. It is also observed that temperature was the most substantial influence on the process, followed by heating rate and the remaining process variables did not exhibit significant individual effects. The empirical model obtained was applied into mass change equation aiming calculate the activation energy (Ea)=77.10 kJ mol−1 and frequency factor (A0)= 6.28 × 1010 s−1. The low activation energy in maximum biochar yield region showed a great potential of Pachira aquatica Aubl fruit peel thermoconversion towards to biochar.Keywords: Biocharslow pyrolysiskineticsbiomassactivation energy AcknowledgmentsThe authors would like to thank Fundação de Amparo à Pesquisa do Estado da Bahia (FAPESB) for financing of the experimental pyrolysis unit (PLANT π/DCET-UNEB) through the agreement CNV.0076/2013, and Coordenação de aperfeicoamento de pessoal de nivel superior (CAPES) for financial support.Disclosure statementNo potential conflict of interest was reported by the authors.Data availability statementThe data that support the findings of this study are available from the corresponding author, Virgens, C.F., upon reasonable request.Additional informationFundingFapesb and Capes are prominent Brazilian fomentation agencies. Fapesb provided financial support through infrastructure grant CNV.0076/2013 (Project 10.13039/501100006181), while Capes generously awarded master’s scholarships to Juraci Nascimento and Mateus Carvalho.
摘要人类活动引起的气候突变加剧了人们对可持续能源的探索,以减少对化石燃料的依赖。本研究采用多变量研究设计,在间歇式反应器系统中确定了Pachira aquatica Aubl果皮缓慢热解的工艺变量和动力学参数对生物炭生成的影响。运用Box Behnken规划模型的统计评价,对模型进行了较好的调整,建立了描述变量行为显著效应的模型。在氮气气氛下,温度(T) = 406°C,升温速率β = 2°C min - 1,停留时间tR = 60 min,生物炭产率最高(41.22%)。温度对工艺的影响最大,其次是加热速率,其余工艺变量的个体影响不显著。将所得经验模型应用于质量变化方程,计算出活化能(Ea)=77.10 kJ mol−1,频率因子(A0)= 6.28 × 1010 s−1。最大产炭区活化能较低,显示了水果皮热转化为生物炭的巨大潜力。致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢致谢披露声明作者未报告潜在的利益冲突。数据可用性声明支持本研究结果的数据可根据合理要求从通讯作者Virgens, c.f.处获得。其他信息fundingfapesb和Capes是巴西著名的宣传机构。Fapesb通过基础设施赠款CNV.0076/2013(项目10.13039/501100006181)提供了财政支持,而Capes慷慨地向Juraci Nascimento和Mateus Carvalho颁发了硕士奖学金。
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引用次数: 0
Novel thermotolerant yeast suitable for industrial bioethanol production 适用于工业生物乙醇生产的新型耐热酵母
4区 工程技术 Q2 Environmental Science Pub Date : 2023-10-15 DOI: 10.1080/17597269.2023.2267850
Ifeanyi A. Ndubuisi, Chioma O. Amadi, Tochukwu N. Nwagu, Y. Murata, James C. Ogbonna
AbstractA thermotolerant yeast capable of converting 100 g/L glucose to 46 g/L ethanol was isolated. The isolate was identified as a strain of Pichia kudriavzevii based on sequences generated by amplifying the 18s ribosomal DNA and a blast search on the NCBI database. The strain could grow and produce ethanol from 30 °C to 45 °C with theoretical ethanol yield above 90% and an ethanol productivity of 2 g/L/h. The strain produced ethanol at acidic pH of 1.5 and 3 at 37 °C and 42 °C respectively. At 42 °C, the strain could tolerate up to 10% ethanol which further increased to 15% when the temperature was reduced to 37 °C. Pichia kudriavzevii LC671435 could utilize peanut and soybean meal as nitrogen sources for ethanol production in addition to its ability to produce ethanol from fructose with the same efficiency as glucose. P. kudriavzevii LC671435 produced 0.47, 0.45 and 0.40 g ethanol/g glucose from 100 g/L, 160 g/L and 200 g/L glucose respectively at 42 °C. When used for repeated batch ethanol production, P. kudriavzevii LC671435 produced above 46 g/L ethanol up to fifth batch at 37 °C and fourth batch at 42 °C. With its thermotolerant ability, this novel isolate has great prospects for industrial fermentation at high temperature without additional cooling costs.Keywords: BioethanolfermentationPichia kudriavzeviiyeastthermotolerance Disclosure statementNo potential conflict of interest was reported by the authors.
摘要:分离到一株能将100 g/L葡萄糖转化为46 g/L乙醇的耐热酵母。根据扩增18s核糖体DNA序列和NCBI数据库的blast检索结果,鉴定该分离物为毕赤酵母菌株。该菌株可在30 ~ 45℃条件下生长并产生乙醇,理论乙醇产率达90%以上,乙醇产量为2 g/L/h。菌株在37°C和42°C条件下分别在酸性pH为1.5和3时产生乙醇。在42°C时,菌株可以耐受高达10%的乙醇,当温度降低到37°C时,该菌株可以进一步增加到15%。Pichia kudriavzevii LC671435除了能够以与葡萄糖相同的效率从果糖中生产乙醇外,还可以利用花生和豆粕作为氮源生产乙醇。P. kudriavzevii LC671435在42℃下分别从100 g/L、160 g/L和200 g/L葡萄糖中产生0.47、0.45和0.40 g乙醇/g葡萄糖。当用于重复批量乙醇生产时,P. kudriavzevii LC671435在37°C和42°C下可生产46 g/L以上的乙醇至第五批。该分离物具有良好的耐热性,在不增加冷却成本的情况下进行高温工业发酵具有广阔的应用前景。关键词:生物乙醇发酵毕赤酵母耐热性披露声明作者未报告潜在利益冲突。
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