Pub Date : 2024-04-30DOI: 10.1007/s11947-024-03416-x
Alejandro Bermejo-López, Alba E. Illera, Rodrigo Melgosa, Sagrario Beltrán, M. Teresa Sanz
Lanthanides were tested (Ce3+, Er3+, and Yb3+) as catalysts to produce lactic acid (LA) from the monosaccharides present in corn stover (glucose, xylose, and arabinose) resulting in ytterbium being the most active. A MW-heated system led to similar LA yield as a conventionally heated pressurized system. The maximum value of LA yield was 40% at 240 °C after 20 min of isothermal treatment regardless the starting monosaccharides, which allowed to propose a similar LA production route based on the products profile determined along time for the three monosaccharides. Temperature and time determined the product profile, observing furfural degradation at severity factors higher than 3.5, while values higher than 5.5 were needed to observe LA degradation. By increasing temperature, catalyst solubility decreased, increasing its presence in the solid residue after treatment. Xylan conversion to LA was similar as for xylose, but lower yield was obtained from microcrystalline cellulose. Corn stover presented more amorphous regions leading to higher hydrolysis yields of its cellulose fraction.
测试了镧系元素(Ce3+、Er3+ 和 Yb3+)作为催化剂,利用玉米秸秆中的单糖(葡萄糖、木糖和阿拉伯糖)生产乳酸(LA),结果表明镱的活性最高。采用水力加热系统与传统的加压加热系统产生的乳酸产量相似。不管起始单糖如何,在 240 °C 等温处理 20 分钟后,LA 产率的最大值为 40%。温度和时间决定了产物曲线,在严重系数高于 3.5 时可观察到糠醛降解,而要观察到 LA 降解则需要高于 5.5 的值。温度升高,催化剂的溶解度降低,从而增加了催化剂在处理后固体残留物中的存在。木聚糖转化为 LA 的情况与木糖相似,但微晶纤维素的产量较低。玉米秸秆的无定形区域较多,因此其纤维素部分的水解产率较高。
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Pub Date : 2024-04-29DOI: 10.1007/s11947-024-03389-x
Xiaojia Guo, Shujin Liu, Lanyan Yang, Chaoguang Zhao, Liu Shi, Guangquan Xiong, Lang Chen, Sheng Chen, Wenjin Wu, Lan Wang
Controlled release of curcumin by a pH-sensitive carrier provides long-term preservation, which extends the shelf lives of fish. FTIR, XRD, 1H NMR, zeta potential, swelling ratio, and TG analyses indicated that a pH-sensitive starch-based carrier with a narrow pH-sensitivity range (pH 6–7) was fabricated from the carboxymethyl starch grafted with methacrylic acid and then cross-linked with β-cyclodextrin to achieve dual functionality. FTIR, XRD, and fluorescence spectroscopy revealed that the mechanism by which curcumin was encapsulated in the starch-based carriers involved hydrophobic interactions and intermolecular hydrogen bonding. The encapsulated curcumin showed improved stability, higher antioxidant activity, antibacterial activity, and biocompatibility. The pH, TVB-N, TVC, and drip loss tests confirmed that the use of the carrier-curcumin complex at a concentration of 10 mg/mL for the preservation of yellow catfish extended the shelf life for 2–4 days during cold storage and improved the storage quality of the resulting fillets. This work provides a dual functionality strategy for constructing a pH-sensitive starch-based carrier to deliver curcumin and offers a promising choice for fish preservation.