Pub Date : 2024-09-19DOI: 10.1007/s13762-024-06047-z
M. R. Mehrian, M. M. Qelichi, H. Tahouri
Solar energy, recognized for its potential in direct conversion into electricity and heat, offers a sustainable energy source with minimal environmental impact. Despite Iran’s significant solar potential, the country’s reliance on fossil fuels has hindered the widespread adoption of solar energy. This study evaluates the relative potential of different regions in Iran for solar power plant development using a novel integration of Geographic Information Systems (GIS) and Fuzzy Inference Systems (FIS). The findings indicate that the most suitable regions for photovoltaic (PV) power plant construction are located in Isfahan, Khorasan-Razavi, and Kerman provinces, where over 70% of the highly suitable land is identified. Conversely, the northern provinces such as Gilan, Mazandaran, and Golestan show minimal suitability. The study’s outcomes provide critical insights for policymakers and stakeholders to optimize site selection for solar energy infrastructure, potentially increasing Iran’s renewable energy capacity significantly.
{"title":"Solar power plant site selection using fuzzy inference system: a case study in Iran","authors":"M. R. Mehrian, M. M. Qelichi, H. Tahouri","doi":"10.1007/s13762-024-06047-z","DOIUrl":"https://doi.org/10.1007/s13762-024-06047-z","url":null,"abstract":"<p>Solar energy, recognized for its potential in direct conversion into electricity and heat, offers a sustainable energy source with minimal environmental impact. Despite Iran’s significant solar potential, the country’s reliance on fossil fuels has hindered the widespread adoption of solar energy. This study evaluates the relative potential of different regions in Iran for solar power plant development using a novel integration of Geographic Information Systems (GIS) and Fuzzy Inference Systems (FIS). The findings indicate that the most suitable regions for photovoltaic (PV) power plant construction are located in Isfahan, Khorasan-Razavi, and Kerman provinces, where over 70% of the highly suitable land is identified. Conversely, the northern provinces such as Gilan, Mazandaran, and Golestan show minimal suitability. The study’s outcomes provide critical insights for policymakers and stakeholders to optimize site selection for solar energy infrastructure, potentially increasing Iran’s renewable energy capacity significantly.</p>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"25 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142258254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-18DOI: 10.1007/s13762-024-06050-4
Y. Zhu, H. Li
Agriculture (e.g., rice paddies) emissions have been considered one of the main sources contributing to the revived atmospheric methane (CH4) increase since 2007 while it remains debated. In this study, we synthesized available paddy field CH4 emissions from publications in a representative region of China. The results showed that CH4 emissions exhibited strong variation among the 416 samples. Compared to the period 2000–2009, CH4 emissions significantly (p < 0.01) increased during 2010–2018 and the average (252.17 kg ha-1) was 1.52 times higher than that in 2000–2009 (146.02 kg ha-1), which was consistent with the trend of atmospheric CH4 concentrations. CH4 emissions were significantly affected by both air temperature and water saving practices, however, this was not likely the reason for the increase after 2009. This study provides a quantitative estimate of regional CH4 emissions based on available data, although the connection with the revived atmospheric CH4 increase since 2007 remains uncertain.
{"title":"Methane emissions from rice paddies in the Yangtze River Delta region of China: synthesis of new estimates","authors":"Y. Zhu, H. Li","doi":"10.1007/s13762-024-06050-4","DOIUrl":"https://doi.org/10.1007/s13762-024-06050-4","url":null,"abstract":"<p>Agriculture (e.g., rice paddies) emissions have been considered one of the main sources contributing to the revived atmospheric methane (CH<sub>4</sub>) increase since 2007 while it remains debated. In this study, we synthesized available paddy field CH<sub>4</sub> emissions from publications in a representative region of China. The results showed that CH<sub>4</sub> emissions exhibited strong variation among the 416 samples. Compared to the period 2000–2009, CH<sub>4</sub> emissions significantly (<i>p</i> < 0.01) increased during 2010–2018 and the average (252.17 kg ha<sup>-1</sup>) was 1.52 times higher than that in 2000–2009 (146.02 kg ha<sup>-1</sup>), which was consistent with the trend of atmospheric CH<sub>4</sub> concentrations. CH<sub>4</sub> emissions were significantly affected by both air temperature and water saving practices, however, this was not likely the reason for the increase after 2009. This study provides a quantitative estimate of regional CH<sub>4</sub> emissions based on available data, although the connection with the revived atmospheric CH<sub>4</sub> increase since 2007 remains uncertain.</p>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"77 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-17DOI: 10.1007/s13762-024-05985-y
N. Marsidi, S. R. S. Abdullah, H. A. Hasan, A. R. Othman, J. Ahmad, N. I. Ismail
Suitable plant species required to initially facilitate a phytoremediation process for any pollutant should be established to avoid pollutant toxicity to plants leading to inefficient phytoremediation process. The goal of this study was to search for native plants (Pennisetum purpureum, Cyperus surinamensis and Phragmites karka) that can tolerate and survive in sludge containing total petroleum hydrocarbon. Each plant species was planted in pots at a density of three plants in each pot containing 3 kg petroleum sludge. As for plant control, each plant species was planted in garden soil. Control contaminant contained petroleum sludge without plants. All pots were watered in an alternate day to ensure constant humidity during the observation period. This study was performed in a greenhouse over a period of 15 days. At the end of the exposure period, all three and two plants of P. purpureum and C. surinamensis died, respectively, with dried stalk and leaf. While P. karka ended up with one dead plant. The survival percentages were 0%, 33.3% and 66.7% for P. purpureum, C. surinamensis and P. karka, respectively, at the end of 15-day exposure period. As a conclusion, P. karka achieved the highest plant survival in the phytoremediation process of hydrocarbon based on the number of withered plants resulting in P. karka as a promising candidate for phytoremediation agent.
应确定最初促进任何污染物的植物修复过程所需的合适植物物种,以避免污染物对植物的毒性导致植物修复过程效率低下。本研究的目的是寻找能够在含有总石油烃的污泥中耐受和存活的本地植物(Pennisetum purpureum、Cyperus surinamensis 和 Phragmites karka)。每种植物都被种植在花盆中,密度为每盆 3 株,内含 3 千克石油污泥。至于植物对照,每种植物都种植在花园土壤中。对照污染物包含石油污泥,不含植物。所有花盆均隔天浇水,以确保观察期间湿度恒定。这项研究在温室中进行,为期 15 天。在暴露期结束时,P. purpureum 和 C. surinamensis 分别有三株和两株植物死亡,茎叶干枯。而 P. karka 只有一株死亡。在 15 天的暴露期结束时,P. purpureum、C. surinamensis 和 P. karka 的存活率分别为 0%、33.3% 和 66.7%。总之,根据枯萎植株的数量,在碳氢化合物的植物修复过程中,P. karka 的存活率最高,因此 P. karka 有希望成为植物修复剂的候选者。
{"title":"Tolerance and survival of native plants exposed to petroleum hydrocarbon-containing sludge: First step in phytoremediation","authors":"N. Marsidi, S. R. S. Abdullah, H. A. Hasan, A. R. Othman, J. Ahmad, N. I. Ismail","doi":"10.1007/s13762-024-05985-y","DOIUrl":"https://doi.org/10.1007/s13762-024-05985-y","url":null,"abstract":"<p>Suitable plant species required to initially facilitate a phytoremediation process for any pollutant should be established to avoid pollutant toxicity to plants leading to inefficient phytoremediation process. The goal of this study was to search for native plants (<i>Pennisetum purpureum, Cyperus surinamensis</i> and <i>Phragmites karka</i>) that can tolerate and survive in sludge containing total petroleum hydrocarbon. Each plant species was planted in pots at a density of three plants in each pot containing 3 kg petroleum sludge. As for plant control, each plant species was planted in garden soil. Control contaminant contained petroleum sludge without plants. All pots were watered in an alternate day to ensure constant humidity during the observation period. This study was performed in a greenhouse over a period of 15 days. At the end of the exposure period, all three and two plants of <i>P. purpureum</i> and <i>C. surinamensis</i> died, respectively, with dried stalk and leaf. While <i>P. karka</i> ended up with one dead plant. The survival percentages were 0%, 33.3% and 66.7% for <i>P. purpureum</i>, <i>C. surinamensis</i> and <i>P. karka</i>, respectively, at the end of 15-day exposure period. As a conclusion, <i>P. karka</i> achieved the highest plant survival in the phytoremediation process of hydrocarbon based on the number of withered plants resulting in <i>P. karka</i> as a promising candidate for phytoremediation agent.</p>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"9 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142258257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-17DOI: 10.1007/s13762-024-06032-6
G. Kou, H. Dinçer, D. Pamucar, S. Yüksel, V. Simic
Blockchain-based waste management investments are key to increase the performance for achieving sustainable growth for both businesses and the country's economy. In this context, a new study should be conducted to identify the most important variables. Accordingly, the purpose of this study is to examine blockchain-based waste management investments via a novel model. The scope of this study is the smart cities that are defined as settlements that aim to improve the quality of life and ensure sustainability by using technology to manage and improve services. Firstly, artificial intelligence (AI) methodology is taken into consideration to compute the weights of the experts. Secondly, the weights of the criteria for blockchain-based waste management investments are computed. Finally, selected investment alternatives for smart cities are ranked with Vise Kriterijumska Optimizacija I Kompromisno Resenje (VIKOR) methodology. Additionally, a comparative analysis is also performed by technique for order preference by similarity (TOPSIS). In addition to this issue, a sensitivity analysis is also conducted with four different cases to check the coherency of the analysis results. The main contribution of this study is the calculation of the expert weights by AI. It is identified that participating in waste to energy schemes has the greatest significance. Similarly, optimizing the lifecycle management has also high weight. It is also defined that integration of physical and digital infrastructures is the most critical alternative. Moreover, urban innovativeness is another critical factor for this situation.
基于区块链的废物管理投资是提高企业和国家经济可持续增长绩效的关键。在此背景下,应开展一项新的研究,以确定最重要的变量。因此,本研究的目的是通过一个新颖的模型来研究基于区块链的废物管理投资。本研究的范围是智慧城市,其定义是旨在通过利用技术管理和改善服务来提高生活质量并确保可持续发展的住区。首先,采用人工智能(AI)方法计算专家权重。其次,计算基于区块链的废物管理投资标准的权重。最后,采用 Vise Kriterijumska Optimizacija I Kompromisno Resenje(VIKOR)方法对选定的智慧城市投资备选方案进行排序。此外,还采用相似性排序偏好技术(TOPSIS)进行了比较分析。此外,还对四种不同情况进行了敏感性分析,以检查分析结果的一致性。本研究的主要贡献在于通过人工智能计算专家权重。结果表明,参与废物变能源计划的意义最大。同样,优化生命周期管理的权重也很高。此外,整合物理和数字基础设施也是最重要的选择。此外,城市创新也是造成这种情况的另一个关键因素。
{"title":"Analyzing blockchain-based waste management investments in smart cities using quantum picture fuzzy rough modelling","authors":"G. Kou, H. Dinçer, D. Pamucar, S. Yüksel, V. Simic","doi":"10.1007/s13762-024-06032-6","DOIUrl":"https://doi.org/10.1007/s13762-024-06032-6","url":null,"abstract":"<p>Blockchain-based waste management investments are key to increase the performance for achieving sustainable growth for both businesses and the country's economy. In this context, a new study should be conducted to identify the most important variables. Accordingly, the purpose of this study is to examine blockchain-based waste management investments via a novel model. The scope of this study is the smart cities that are defined as settlements that aim to improve the quality of life and ensure sustainability by using technology to manage and improve services. Firstly, artificial intelligence (AI) methodology is taken into consideration to compute the weights of the experts. Secondly, the weights of the criteria for blockchain-based waste management investments are computed. Finally, selected investment alternatives for smart cities are ranked with Vise Kriterijumska Optimizacija I Kompromisno Resenje (VIKOR) methodology. Additionally, a comparative analysis is also performed by technique for order preference by similarity (TOPSIS). In addition to this issue, a sensitivity analysis is also conducted with four different cases to check the coherency of the analysis results. The main contribution of this study is the calculation of the expert weights by AI. It is identified that participating in waste to energy schemes has the greatest significance. Similarly, optimizing the lifecycle management has also high weight. It is also defined that integration of physical and digital infrastructures is the most critical alternative. Moreover, urban innovativeness is another critical factor for this situation.</p>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"40 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142258259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-16DOI: 10.1007/s13762-024-06038-0
F. S. Kawakubo, G. A. V. Mataveli, E. F. Justiniano, J. V. R. Guerrero, B. M. de Melo, E. R. dos Santos Júnior, R. S. S. Marinho, M. R. Martines, M. Fantin, J. C. Pedrassoli, R. G. Morato
The indiscriminate increase in impervious surface area, mainly associated with anthropogenic activities, is causing important environmental changes. Given the relevance of impervious surface area, this paper introduces an approach designed to map impervious areas. The proposed method was applied to the State of São Paulo, southern Brazil, using nighttime light imagery collected by the Visible Infrared Imaging Radiometer Suite Day–Night Band from the Suomi National Polar-orbiting Partnership satellite. Our hypothesis is that impervious surface area is primarily related to the presence of persistent nighttime light in space and time, and that its quantification basically depends on the brightness pattern emitted by the urban surface. Thus, brightness patterns extracted from monthly composites of nighttime light were associated with impervious surface area established through a random forest regression model. The results for the entire study area (248,000 km2) showed that the method was quite effective in predicting impervious surface area (R2 = 0.90, p < 0.001), although, on average, an underestimation deviation (~ 20%) occurred. Focusing on densely urbanized areas, on the other hand, an overestimation error was reported, mainly around downtown areas. Despite this error, graduated values of impervious surface area were found in intra-urban spaces, making it possible to characterize, consistently, differences in the land-use patterns.
不透水地表面积的肆意增加,主要与人类活动有关,正在造成重要的环境变化。鉴于不透水表面积的相关性,本文介绍了一种旨在绘制不透水区域地图的方法。所提议的方法被应用于巴西南部的圣保罗州,使用的是 Suomi 国家极轨伙伴关系卫星上的可见红外成像辐射计套件昼夜波段收集的夜间光线图像。我们的假设是,不透水表面积主要与空间和时间上是否存在持续的夜间光线有关,其量化基本上取决于城市表面发出的亮度模式。因此,通过随机森林回归模型,从夜间光线月度合成图中提取的亮度模式与不透水表面积建立了联系。整个研究区域(24.8 万平方公里)的结果表明,该方法在预测不透水表面积方面相当有效(R2 = 0.90,p < 0.001),尽管平均出现了低估偏差(约 20%)。另一方面,以城市化密集地区为重点,高估的误差主要出现在市中心地区。尽管存在这种误差,但在城市内部空间发现了不透水表面积的刻度值,从而可以一致地描述土地利用模式的差异。
{"title":"Extension and variability of impervious surface area revealed by nighttime light imagery","authors":"F. S. Kawakubo, G. A. V. Mataveli, E. F. Justiniano, J. V. R. Guerrero, B. M. de Melo, E. R. dos Santos Júnior, R. S. S. Marinho, M. R. Martines, M. Fantin, J. C. Pedrassoli, R. G. Morato","doi":"10.1007/s13762-024-06038-0","DOIUrl":"https://doi.org/10.1007/s13762-024-06038-0","url":null,"abstract":"<p>The indiscriminate increase in impervious surface area, mainly associated with anthropogenic activities, is causing important environmental changes. Given the relevance of impervious surface area, this paper introduces an approach designed to map impervious areas. The proposed method was applied to the State of São Paulo, southern Brazil, using nighttime light imagery collected by the Visible Infrared Imaging Radiometer Suite Day–Night Band from the Suomi National Polar-orbiting Partnership satellite. Our hypothesis is that impervious surface area is primarily related to the presence of persistent nighttime light in space and time, and that its quantification basically depends on the brightness pattern emitted by the urban surface. Thus, brightness patterns extracted from monthly composites of nighttime light were associated with impervious surface area established through a random forest regression model. The results for the entire study area (248,000 km<sup>2</sup>) showed that the method was quite effective in predicting impervious surface area (R<sup>2</sup> = 0.90, <i>p</i> < 0.001), although, on average, an underestimation deviation (~ 20%) occurred. Focusing on densely urbanized areas, on the other hand, an overestimation error was reported, mainly around downtown areas. Despite this error, graduated values of impervious surface area were found in intra-urban spaces, making it possible to characterize, consistently, differences in the land-use patterns.</p>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"41 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142269393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-16DOI: 10.1007/s13762-024-05960-7
H. Bahman, K. Gharanjig, E. Ghasemi, H. Kazemian, M. Hosseinnezhad, H. Gharanjig
A newly developed bio-hybrid material comprising luteolin as a bioactive dye and a Zinc-Aluminum layered double hydroxide as an adsorbent was synthesized using two distinct methods. In the first method, Zinc-Aluminum layered double hydroxide was initially produced using the co-precipitation technique. Subsequently, the bioactive luteolin was intercalated onto the synthesized layered double hydroxide through an ion exchange mechanism. Response surface methodology and analysis of variance studies were employed to design experiments leading to achieve optimized adsorption onto the Zinc-Aluminum layered double hydroxide, considering effective variables like pH, dye concentration, layered double hydroxide weight, and operating time. Under the optimized conditions, the maximum adsorption efficiency (94.2%) and adsorption capacity (47.11 mg g−1) were achieved. Kinetic studies indicated the pseudo-second order model characterized the luteolin adsorption, and the Langmuir model served as a suitable representation of the adsorption isotherm. In the second method, a co-precipitation approach was employed to simultaneously synthesize and intercalate luteolin onto layered double hydroxide with varying concentrations (5%, 15%, and 25%) under optimized conditions. The maximum adsorption efficiency and capacity reached 99.9% and 49.98 mg g−1, respectively. Analytical characterization confirmed successful luteolin adsorption and stabilization of the layered double hydroxide. Furthermore, sustained luteolin release over an extended period was observed which attributed to its incorporation within the layered double hydroxide structure. The study also investigated the antioxidant activity of luteolin on the synthesized complexes, providing a comprehensive exploration of the bio-hybrid structure, Luteolin-Zinc-Aluminum Layered Double Hydroxide, with potential biomedical applications.
{"title":"Synthesis and characterization of an eco-friendly nano-hybrid based on luteolin-loaded zinc-aluminum layered double hydroxide for biological applications","authors":"H. Bahman, K. Gharanjig, E. Ghasemi, H. Kazemian, M. Hosseinnezhad, H. Gharanjig","doi":"10.1007/s13762-024-05960-7","DOIUrl":"https://doi.org/10.1007/s13762-024-05960-7","url":null,"abstract":"<p>A newly developed bio-hybrid material comprising luteolin as a bioactive dye and a Zinc-Aluminum layered double hydroxide as an adsorbent was synthesized using two distinct methods. In the first method, Zinc-Aluminum layered double hydroxide was initially produced using the co-precipitation technique. Subsequently, the bioactive luteolin was intercalated onto the synthesized layered double hydroxide through an ion exchange mechanism. Response surface methodology and analysis of variance studies were employed to design experiments leading to achieve optimized adsorption onto the Zinc-Aluminum layered double hydroxide, considering effective variables like pH, dye concentration, layered double hydroxide weight, and operating time. Under the optimized conditions, the maximum adsorption efficiency (94.2%) and adsorption capacity (47.11 mg g<sup>−1</sup>) were achieved. Kinetic studies indicated the pseudo-second order model characterized the luteolin adsorption, and the Langmuir model served as a suitable representation of the adsorption isotherm. In the second method, a co-precipitation approach was employed to simultaneously synthesize and intercalate luteolin onto layered double hydroxide with varying concentrations (5%, 15%, and 25%) under optimized conditions. The maximum adsorption efficiency and capacity reached 99.9% and 49.98 mg g<sup>−1</sup>, respectively. Analytical characterization confirmed successful luteolin adsorption and stabilization of the layered double hydroxide. Furthermore, sustained luteolin release over an extended period was observed which attributed to its incorporation within the layered double hydroxide structure. The study also investigated the antioxidant activity of luteolin on the synthesized complexes, providing a comprehensive exploration of the bio-hybrid structure, Luteolin-Zinc-Aluminum Layered Double Hydroxide, with potential biomedical applications.</p>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"9 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142258255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-16DOI: 10.1007/s13762-024-06022-8
N. Kabaňová, Z. Tokárová
Benzimidazoles are important heterocyclic compounds that exhibit a wide range of pharmacological and biological properties. Among all, sensitivity to Lewis acids provide a possibility to act as a fluorescent detectors for senzing the cathions, radicals, highly reactive low-molecular species with hazardous effects to environment and human health. Herein, we present the design and synthesis of N-((1H-benzo[d]imidazol-2-yl)methyl)cinnamamide (I) for the detection of readily reactive thionyl chloride (SOCl2). Treatment of SOCl2 with a novel benzimidazole-based compound I is accompanied by immediate color change. Although the process is irreversible the change noticeable by eye is profitable for a simple and rapid protection against the SOCl2 exposure at amounts harmful for surroundings and body. In the context of environmental issue, the chemical reaction between the detector I and thionyl chloride is beneficial for the safe waste disposal. Thionyl chloride is recaptured in the structure of I throughout the reaction leading to a formation of stable compound II. Incorporation of residual traces of SOCl2 into the structure of organic-type detector I represents effective route to achieve non-reactive and non-damaging derivatives. Accordingly, the organic non-liquid waste is subsequently stored and disposed in a safe manner.
苯并咪唑是重要的杂环化合物,具有广泛的药理和生物学特性。其中,对路易斯酸的敏感性为荧光检测器提供了可能性,可用于检测对环境和人类健康有害的阴离子、自由基、高活性低分子物种。在此,我们介绍了 N-((1H-苯并[d]咪唑-2-基)甲基)肉桂酰胺 (I) 的设计与合成,用于检测易反应的亚硫酰氯 (SOCl2)。用新型苯并咪唑类化合物 I 处理 SOCl2 时,颜色会立即发生变化。虽然这一过程是不可逆的,但肉眼可察觉的变化有利于提供简单快速的保护,避免接触对周围环境和人体有害的 SOCl2。就环境问题而言,检测器 I 和亚硫酰氯之间的化学反应有利于废物的安全处理。在整个反应过程中,亚硫酰氯被重新吸收到 I 的结构中,形成稳定的化合物 II。将残留的微量 SOCl2 加入有机型检测器 I 的结构中,是实现无反应和无损害衍生物的有效途径。因此,有机非液体废物随后可以安全地储存和处理。
{"title":"Novel approach of thionyl chloride detection and disposal using a benzimidazole-based derivative: perspectives and proposals","authors":"N. Kabaňová, Z. Tokárová","doi":"10.1007/s13762-024-06022-8","DOIUrl":"https://doi.org/10.1007/s13762-024-06022-8","url":null,"abstract":"<p>Benzimidazoles are important heterocyclic compounds that exhibit a wide range of pharmacological and biological properties. Among all, sensitivity to Lewis acids provide a possibility to act as a fluorescent detectors for senzing the cathions, radicals, highly reactive low-molecular species with hazardous effects to environment and human health. Herein, we present the design and synthesis of <i>N</i>-((1<i>H</i>-benzo[<i>d</i>]imidazol-2-yl)methyl)cinnamamide (<i>I</i>) for the detection of readily reactive thionyl chloride (SOCl<sub>2</sub>). Treatment of SOCl<sub>2</sub> with a novel benzimidazole-based compound <i>I</i> is accompanied by immediate color change. Although the process is irreversible the change noticeable by eye is profitable for a simple and rapid protection against the SOCl<sub>2</sub> exposure at amounts harmful for surroundings and body. In the context of environmental issue, the chemical reaction between the detector <i>I</i> and thionyl chloride is beneficial for the safe waste disposal. Thionyl chloride is recaptured in the structure of <i>I</i> throughout the reaction leading to a formation of stable compound <i>II</i>. Incorporation of residual traces of SOCl<sub>2</sub> into the structure of organic-type detector <i>I</i> represents effective route to achieve non-reactive and non-damaging derivatives. Accordingly, the organic non-liquid waste is subsequently stored and disposed in a safe manner.</p>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"15 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142258258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-16DOI: 10.1007/s13762-024-06037-1
P. Praipipat, P. Ngamsurach, K. Bunchu, V. Lekwaree, P. Srirat, P. Chaiphumee, J. Noisri, T. Aeamsa-ard
The recycling fruit wastes of banana, pomelo, and mangosteen as biosorbents for eliminating methylene blue dye (MBD) were investigated in this study by synthesizing 3 materials of banana (Musa ABB cv. Kluai ‘Namwa’) powder beads (BPB), pomelo (Citrus maxima (Burm.f.) Merr) powder beads (PPB), and mangosteen (Garcinia mangostana Linn) powder beads (MPB) and characterizing with several techniques. Their MBD adsorption performances were examined by a series of batch experiments, desorption experiments, adsorption isotherms, kinetics, and thermodynamics studies. MPB had a higher specific surface area and pore volume than BPB and PPB, whereas its pore size was smaller than theirs. All materials had amorphous structures. BPB had rough surfaces, whereas PPB had coarse surfaces with layer structures. MPB had rough surfaces with irregular shapes. They consisted of carbon, oxygen, calcium, chloride, and sodium. The chemical functional groups of hydroxyl, methine, carbonyl, and ether were detected in all materials. The pHpzc of BPB, PPB, and MPB were 5.41, 5.00, and 5.05. MPB showed a higher MBD removal efficiency of 98.92% and adsorption capacity (qe) of 6.59 mg/g than BPB and PPB, and all materials could be reused for 3 cycles with the adsorption efficiency of more than 61%. Their adsorption patterns and mechanisms were described by Freundlich and pseudo-second-order kinetic models. BPB and MPB were endothermic processes, whereas PPB was an exothermic process.