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Removal of heavy metals using lichen-derived activated carbons: adsorption studies, machine learning, and response surface methodology approaches 利用地衣活性炭去除重金属:吸附研究、机器学习和响应面方法学方法
IF 3.1 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-09 DOI: 10.1007/s13762-024-06001-z
H. Koyuncu, A. R. Kul, Ö. Akyavaşoğlu

Biomass-based activated carbons are promising as they are effective and low-cost for wastewater remediation. In this study, the removal of lead, copper, and zinc was investigated using activated carbons obtained from two different lichens. The performance of the 5th-order Response Surface methodology (RSM), Machine Learning (ML), and Artificial Neural Network (ANN) model based on Face-Centered Central Composite Design (FCCCD) was evaluated considering initial concentration, temperature, and time effects. The effectiveness of using ANN for accurate prediction in lead and copper removal and the superior performance of ML-based 5th-order RSM for zinc removal were demonstrated. Among the Langmuir, Freundlich, and Temkin isotherm models, the Freundlich model best described the adsorption processes, and the Langmuir maximum adsorption capacities were found to be 105.26 mg/g (Pb/AC-1), 59.52 mg/g (Cu/AC-1), and 53.19 mg/g (Cu/AC-2). Additionally, the pseudo-first-order, pseudo-second-order, and intra-particle diffusion models were examined, and it was found that the adsorption processes followed the pseudo-second-order kinetics and intra-particle diffusion played a significant role. The activation energies and ΔH0 values ​​less than 40 kJ/mol and ΔG0 values ​​below − 20 kJ/mol showed that the metals were adsorbed by physical mechanisms. The novelty of this study is that the 5th-order RSM model is applied to adsorption processes for the first time, and a multi-faceted approach is used to analyse adsorption processes, including machine learning and ANN, isotherm modeling, thermodynamic evaluation, kinetics analysis, and activation energy calculations.

基于生物质的活性炭在废水修复方面具有高效、低成本的特点,因此前景广阔。本研究使用从两种不同地衣中提取的活性碳对铅、铜和锌的去除进行了研究。考虑到初始浓度、温度和时间的影响,对基于面心中心复合设计(FCCCD)的五阶响应面方法(RSM)、机器学习(ML)和人工神经网络(ANN)模型的性能进行了评估。结果表明,使用 ANN 可以有效地准确预测铅和铜的去除率,而基于 ML 的五阶 RSM 则在锌去除率方面表现出色。在 Langmuir、Freundlich 和 Temkin 等温线模型中,Freundlich 模型最好地描述了吸附过程,Langmuir 最大吸附容量分别为 105.26 mg/g(Pb/AC-1)、59.52 mg/g(Cu/AC-1)和 53.19 mg/g(Cu/AC-2)。此外,还考察了伪一阶、伪二阶和颗粒内扩散模型,发现吸附过程遵循伪二阶动力学,颗粒内扩散起了重要作用。活化能和 ΔH0 值小于 40 kJ/mol,ΔG0 值小于 - 20 kJ/mol,这表明金属是通过物理机制被吸附的。本研究的新颖之处在于首次将五阶 RSM 模型应用于吸附过程,并采用机器学习和 ANN、等温线建模、热力学评估、动力学分析和活化能计算等多元方法来分析吸附过程。
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引用次数: 0
New methodology for improved bathymetry of coastal zones based on spaceborne spectroscopy 基于空间光谱学改进沿岸带水深测量的新方法
IF 3 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-09 DOI: 10.1007/s13762-024-06028-2
D. Karimi, M. Kabolizadeh, K. Rangzan, Z. Zaheri Abdehvand, F. Balouei

In-situ water depth measurement is a time-consuming and expensive process for large-scale and frequent monitoring. This underscores the need for alternative methods, such as those based on satellite imagery, which can offer a more efficient and cost-effective solution. This research explores the use of PRISMA hyperspectral images for bathymetry in Nayband Bay, South Iran. The proposed method, SSIP_PSO, includes image pan-sharpening, spectral and spatial information preservation, Particle Swarm Optimization for band ratio selection, and enhanced geometric correction. Among fusion methods tested, the Gram-Schmidt Transform proved most effective for pan-sharpening. The optimal band ratio, b4/b19, improved bathymetry accuracy, reducing root mean square error from 2.291 to 1.716. SSIP_PSO outperformed traditional methods and demonstrated the importance of preserving spatial information in bathymetry.

对于大规模和频繁的监测来说,现场水深测量是一个耗时且昂贵的过程。这就突出了对替代方法的需求,例如基于卫星图像的方法,它能提供更高效、更具成本效益的解决方案。本研究探讨了如何利用 PRISMA 高光谱图像来测量伊朗南部奈班德湾的水深。所提出的 SSIP_PSO 方法包括图像平移锐化、光谱和空间信息保存、选择波段比的粒子群优化以及增强几何校正。在测试的融合方法中,格拉姆-施密特变换被证明是最有效的平移锐化方法。最佳波段比 b4/b19 提高了测深精度,将均方根误差从 2.291 降至 1.716。SSIP_PSO 优于传统方法,证明了在水深测量中保留空间信息的重要性。
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引用次数: 0
Optimization of chlorine consumption in water distribution networks by using the new ant colony optimization (ACOR) algorithm 利用新型蚁群优化(ACOR)算法优化输水管网中的氯消耗量
IF 3 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-09 DOI: 10.1007/s13762-024-06008-6
M. H. Ahmadi, B. Mansoori, R. Aghamajidi

Chlorination by maintaining the injected chlorine concentration in the range between the minimum and maximum is among the most inexpensive and common disinfection methods in water distribution networks. The minimum concentration of residual chlorine must be observed to control the microbial quality of water. Besides, the maximum chlorine concentration must be observed to control problems related to water smell and taste and to prevent the production of toxic byproducts. This research has developed a model by combining the EPANET model and the ACOR optimization algorithm to optimize the chlorine injection program during the operation period. According to the results, the ACOR algorithm could be used to derive a suitable program for chlorine injection in the water distribution network such that the permissible constraints of chlorine are observed in the consumption nodes of the network and the consumption of chlorine is reduced to the least level in the network. The developed model was applied to determine an optimal chlorine injection program in a classical example (the Branford network), which was also of interest to some previous researchers. Using the optimal injection program obtained by the model, the chlorine concentration was set at an acceptable network level between the permissible range of 0.2–0.8 g/l. This output was more favorable than the response of other methods in terms of the total residual chlorine concentration, which was 5.8% and 4.7% lower in this method than the methods based on PSO and genetic algorithms, respectively. Moreover, a better convergence speed was obtained in this algorithm, and the number of calculation times of the objective function was 49.5 and 64.4 less than the methods based on PSO and genetic algorithms, respectively. Therefore, the ACOR algorithm can be used to derive the chlorine injection program to both comply with the permissible constraints of chlorine and reduce chlorine consumption to the minimum level.

将注入的氯浓度保持在最低和最高之间的范围内进行加氯消毒,是输水管网中最廉价、最常用的消毒方法之一。必须遵守最低余氯浓度,以控制水的微生物质量。此外,还必须遵守最大余氯浓度,以控制与水的气味和口感有关的问题,并防止产生有毒的副产品。本研究结合 EPANET 模型和 ACOR 优化算法建立了一个模型,以优化运行期间的投氯方案。结果表明,ACOR 算法可用于推导出合适的配水管网注氯方案,从而使管网消耗节点遵守氯的允许约束条件,并将管网中的氯消耗量降至最低水平。所开发的模型被用于确定一个经典案例(布兰福德供水网)中的最优注氯方案,这也是之前一些研究人员所感兴趣的。利用模型获得的最佳注氯程序,氯浓度被设定在 0.2-0.8 克/升的允许范围之间的可接受网络水平。就总余氯浓度而言,该输出结果比其他方法的响应更为有利,与基于 PSO 和遗传算法的方法相比,该方法的总余氯浓度分别降低了 5.8%和 4.7%。此外,该算法还获得了较好的收敛速度,目标函数的计算次数分别比基于 PSO 和遗传算法的方法少 49.5 和 64.4 次。因此,ACOR 算法可用于推导氯气注入方案,既能满足氯气允许约束条件,又能将氯气消耗量降至最低水平。
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引用次数: 0
Assessment of seven different global climate models for historical temperature and precipitation in Hatay, Türkiye 评估七种不同的全球气候模型对土耳其哈塔伊地区历史温度和降水量的影响
IF 3.1 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-09 DOI: 10.1007/s13762-024-06033-5
M. Ozbuldu, A. Irvem

Global climate models are important tools for estimating the possible future impacts of climate change and developing necessary adaptation strategies. This study assessed the suitability of global climate models for local climate projections in Hatay, Türkiye. Temperature and precipitation data from different Coupled Model Intercomparison Project Phase 6 climate models were compared with ground-based observations. For stations lacking historical data, multilayer perceptron artificial neural networks were used to generate data. These networks were trained with data from neighboring stations from 1980 to 2014. The most suitable global climate model was determined using a multi-criteria decision-making approach. As a result of the study, it was determined that the multilayer perceptron models effectively generated long-term temperature data with a normalized root mean square error of less than 0.50. Precipitation estimates, while less accurate, achieved reasonable accuracy with a normalized root mean square error of less than 0.70. The evaluation of global climate models revealed a tendency to underestimate minimum temperatures and overestimate maximum temperatures and precipitation. Specifically, the EC-EARTH3, CMCC-ESM2, and MPI-ESM1-2-HR models excelled in maximum temperature estimations; the CMCC-ESM2, GFDL-CM4, and TAIESM1 models were superior for minimum temperatures; and the EC-EARTH3, GFDL-CM4, and MPI-ESM1-2-HR models performed best for precipitation. The findings of this study will provide a framework for the assessment and selection of appropriate climate models for local regions and will help to develop targeted adaptation strategies.

全球气候模型是估算未来气候变化可能造成的影响和制定必要的适应战略的重要工具。本研究评估了全球气候模型对土耳其哈塔伊地区气候预测的适用性。将不同耦合模式相互比较项目第六阶段气候模式的温度和降水数据与地面观测数据进行了比较。对于缺乏历史数据的站点,则使用多层感知器人工神经网络生成数据。这些网络利用 1980 年至 2014 年邻近站点的数据进行训练。采用多标准决策方法确定了最合适的全球气候模型。研究结果表明,多层感知器模型能有效生成长期气温数据,归一化均方根误差小于 0.50。降水量估算虽然精度较低,但也达到了合理的精度,归一化均方根误差小于 0.70。对全球气候模式的评估显示,有低估最低气温、高估最高气温和降水量的趋势。具体来说,EC-EARTH3、CMCC-ESM2 和 MPI-ESM1-2-HR 模式在最高气温估计方面表现出色;CMCC-ESM2、GFDL-CM4 和 TAIESM1 模式在最低气温方面更胜一筹;EC-EARTH3、GFDL-CM4 和 MPI-ESM1-2-HR 模式在降水方面表现最佳。这项研究的结果将为评估和选择适合当地区域的气候模式提供一个框架,并有助于制定有针对性的适应战略。
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引用次数: 0
Insight of heavy metal contamination of soil in high background area: field investigation and laboratory test 高背景地区土壤重金属污染透视:实地调查与实验室测试
IF 3 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-09 DOI: 10.1007/s13762-024-06024-6
N. Xie, C. Kang, B. Z. Feng, B. Zhang

This paper utilizes field sampling and laboratory testing to identify potential sources of heavy metals, including rock, dust, rainfall, surface water, and groundwater, employing Pearson Correlation Coefficient—Principal Component—Sources Factors Analysis. A total of 33 surface and 22 profile soil samples were collected to investigate the migration characteristics and spatial distribution of heavy metals in the study area. Additionally, the paper discusses the comparison of soil heavy metal concentrations between sunny and shady slopes. The findings reveal that soil heavy metals in the study area primarily originate from weathering and downward migration deposition of parent rock, indicative of a geological high background area. Moreover, this has led to arsenic contamination in the soil, with an excess rate of 74.5%. It was observed that heavy metals tend to accumulate more on shady slopes than sunny slopes, with mercury and arsenic showing the most significant differences at 69.70% and 49.33% higher levels, respectively. The comprehensive impact index of agricultural soil was calculated at 53.25, indicating a sub-pollution level. Additionally, the study notes that with the increase in crop enrichment coefficient, the variation values of soil heavy metal concentrations decrease, with a correlation coefficient of 0.6077 between the two variables.

本文利用实地采样和实验室测试,采用皮尔逊相关系数-主要成分-来源因素分析法,确定重金属的潜在来源,包括岩石、灰尘、降雨、地表水和地下水。本文共采集了 33 个地表土壤样本和 22 个剖面土壤样本,以研究重金属在研究区域的迁移特征和空间分布。此外,论文还讨论了阳坡和阴坡土壤重金属浓度的比较。研究结果表明,研究区域的土壤重金属主要来源于母岩的风化和向下迁移沉积,表明该区域属于地质本底较高的区域。此外,这也导致了土壤中砷的污染,超标率高达 74.5%。据观察,重金属在阴坡的积累往往多于阳坡,其中汞和砷的含量差异最大,分别高出 69.70% 和 49.33%。经计算,农用土壤的综合影响指数为 53.25,表明处于亚污染水平。此外,研究还指出,随着农作物富集系数的增加,土壤重金属浓度的变化值也随之降低,两个变量之间的相关系数为 0.6077。
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引用次数: 0
Innovations in tannery wastewater management: a review of zero liquid discharge technology 制革废水管理创新:零液体排放技术综述
IF 3.1 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-09 DOI: 10.1007/s13762-024-05986-x
A. Pundir, M. S. Thakur, B. Goel, Radha, A. Kumar, S. Prakash, M. Thakur, M. Kumar

The tanning industry, a significant contributor to global leather production, faces critical challenges in wastewater management due to the hazardous pollutants generated during processing. Zero liquid discharge (ZLD) systems present a sustainable solution by efficiently treating and reusing wastewater while minimizing environmental impact. This study aims to explore the successful implementation of ZLD in the tannery industry, considering its economic and environmental benefits. Through a comprehensive review of literature and case studies, this research assesses the factors contributing to ZLD success, potential barriers to widespread adoption, and future advancements in technology. Methodologies include analyzing existing ZLD implementations, evaluating cost analyses, and investigating potential advancements in ZLD technologies. Results demonstrate that while ZLD offers significant advantages in water conservation, resource recovery, and environmental protection, challenges such as high installation costs and technical complexities hinder widespread adoption. Addressing these challenges requires concerted efforts from stakeholders, including tannery owners, regulatory bodies, and technology providers. Future directions suggest the need for ongoing research and development to enhance ZLD efficiency and cost-effectiveness. By embracing ZLD systems, tanneries can achieve sustainable wastewater management, conserve water resources, and meet environmental standards, thereby advancing towards an environmentally conscious and socially responsible business approach.

制革业是全球皮革生产的重要贡献者,由于加工过程中会产生有害污染物,该行业在废水管理方面面临严峻挑战。液体零排放(ZLD)系统通过有效处理和再利用废水,同时最大限度地减少对环境的影响,提供了一种可持续的解决方案。本研究旨在探讨在制革行业成功实施 ZLD 的情况,同时考虑其经济和环境效益。通过对文献和案例研究的全面回顾,本研究评估了促进 ZLD 成功的因素、广泛采用的潜在障碍以及未来的技术进步。研究方法包括分析现有的 ZLD 实施情况、评估成本分析以及调查 ZLD 技术的潜在进步。研究结果表明,虽然 ZLD 在节水、资源回收和环境保护方面具有显著优势,但高昂的安装成本和技术复杂性等挑战阻碍了其广泛应用。应对这些挑战需要包括制革厂主、监管机构和技术提供商在内的利益相关者共同努力。未来的发展方向表明,需要不断进行研究和开发,以提高 ZLD 的效率和成本效益。通过采用 ZLD 系统,制革厂可以实现可持续的废水管理,节约水资源,并达到环保标准,从而向具有环保意识和社会责任感的经营方式迈进。
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引用次数: 0
Fixed-bed adsorption for industrial wastewater purification: An in-depth review 用于工业废水净化的固定床吸附技术:深入评述
IF 3.1 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-09 DOI: 10.1007/s13762-024-06034-4
Prabu Rajandran, Nasratun Masngut, Nor Hasmaliana Abdul Manas, Nur Izyan Wan Azelee, Siti Fatimah Zaharah Mohd Fuzi, Mohamad Abd Hadi Bunyamin

The increasing discharge of industrial wastewater contaminated with hazardous pollutants requires innovative and efficient treatment technologies. This review addresses the potential of fixed-bed adsorption systems for the effective removal of a wide spectrum of contaminants from industrial effluent. It explains the basic principles, characteristics and mechanisms of fixed-bed adsorption systems and examines important factors affecting their performance. Through a comparative analysis of different adsorption models, the paper provides insights into the efficiency and applicability of these models in assessing the characteristics of adsorption system using breakthrough curves. The findings advocate for policy support to integrate fixed-bed adsorption technologies into existing wastewater management systems to improve environmental protection and public health.

受有害污染物污染的工业废水排放量不断增加,这就需要创新、高效的处理技术。本综述探讨了固定床吸附系统有效去除工业废水中各种污染物的潜力。它解释了固定床吸附系统的基本原理、特点和机制,并研究了影响其性能的重要因素。通过对不同吸附模型的比较分析,论文深入探讨了这些模型在利用突破曲线评估吸附系统特性时的效率和适用性。研究结果主张提供政策支持,将固定床吸附技术纳入现有的废水管理系统,以改善环境保护和公众健康。
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引用次数: 0
Investigation of biochemical and antioxidant system responses of sugarcane CP48-103 under drought stress induced by polyethylene glycol 聚乙二醇诱导干旱胁迫下甘蔗 CP48-103 的生化和抗氧化系统响应研究
IF 3 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-09 DOI: 10.1007/s13762-024-05981-2
K. Bavai, M. Kalahi, Z. Baghaeifar, A. Goldson-Barnaby

Sugarcane is an important crop globally as it is a primary source of sugar and is used in the production of a wide range of products such as food, biofuels, and renewable materials. In Iran, sugarcane is significant as it contributes to the country’s sugar production and supports its agricultural industry, providing employment and economic value to the region. In this study, the physiological changes of sugarcane plants under drought stress were investigated. After callus formation and transfer of the plants to a shoot culture medium, drought stress was applied at four levels: control, 0.4, 0.8, and 1.2 mM/L of polyethylene glycol in the MS culture medium. Changes in morphological characteristics, as well as biochemical properties including pigments, antioxidant enzyme activity, and non-enzymatic antioxidants of sugarcane plants under drought stress, were measured. Drought stress led to a decrease of about 34% in growth parameters and phenolic content increased by 1.43 times of sugarcane plants, proportional to the concentration of polyethylene glycol in the culture medium, while osmolytes and antioxidant enzymes such as catalase, superoxide dismutase, peroxidase, ascorbate peroxidase, glutathione reductase, and glutathione peroxidase, showed higher levels, indicating that one of their roles in sugarcane is responding to drought stress and neutralization of reactive oxygen species. These insights can inform the creation of drought-resistant crop varieties, supporting sustainable agriculture in regions prone to water scarcity. Moreover, they could pave the way for advancements in water conservation practices and help mitigate the impact of climate change on farming.

甘蔗是全球重要的农作物,因为它是糖的主要来源,可用于生产食品、生物燃料和可再生材料等多种产品。在伊朗,甘蔗具有重要意义,因为它有助于该国的蔗糖生产,支持其农业产业,为该地区提供就业和经济价值。本研究调查了甘蔗植物在干旱胁迫下的生理变化。在胼胝体形成并将植株转移到芽培养基后,在 MS 培养基中施加四种水平的干旱胁迫:对照、0.4、0.8 和 1.2 mM/L 的聚乙二醇。测量了干旱胁迫下甘蔗植株形态特征以及生化特性(包括色素、抗氧化酶活性和非酶抗氧化剂)的变化。干旱胁迫导致甘蔗植株的生长参数下降了约 34%,酚含量增加了 1.43 倍,与培养基中聚乙二醇的浓度成正比,而渗透溶质和抗氧化酶(如过氧化氢酶、超氧化物歧化酶、过氧化物酶、抗坏血酸过氧化物酶、谷胱甘肽还原酶和谷胱甘肽过氧化物酶)的含量较高,表明它们在甘蔗中的作用之一是应对干旱胁迫和中和活性氧。这些发现可以为培育抗旱作物品种提供信息,从而为缺水地区的可持续农业提供支持。此外,它们还能为节水实践的进步铺平道路,并有助于减轻气候变化对农业的影响。
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引用次数: 0
Effect of micelles-forming surfactant on performance of anaerobic digestion of synthetic municipal wastewater 形成胶束的表面活性剂对合成城市污水厌氧消化性能的影响
IF 3 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-09 DOI: 10.1007/s13762-024-06025-5
Z. Akbari, T. Tavallaiee, R. Ghiassi

Several papers have been published in the literature about the effect of surfactants on anaerobic digestion process and results have shown that surfactants had contradictory effect in different concentrations. To understand the reason of this contradictory effect, the surfactant behavior was studied during the anaerobic digestion process in this research. Firstly, laboratory-scale experiments were conducted using 200 cc reactors at mesophilic temperature to determine the optimum inoculum-substrate ratio and several parameters were measured such as chemical oxygen demand, total solids, volatile solids, pH, dissolved oxygen, electrical conductivity, total dissolved solids and alkalinity. Results have shown that optimum inoculum-substrate ratio was four. In the second part of this research, batch experiments were conducted with four Sodium Dodecyl Benzene Sulfonate concentrations namely 0, 100, 200, 400 under mesophilic condition lasted for 50 days. It was observed that a fundamental change in anaerobic digestion occurred at the surfactant concentration of 400 ppm in such a way that surfactant played the role of an obstacle in the anaerobic digestion. To study the effect of surfactant concentration on anaerobic digestion, electrical conductivity and turbidity of tab water and synthetic wastewater were plotted versus surfactant concentration. Results of these graphs showed that electrical conductivity of synthetic wastewater was raised sharply after critical micelle concentration unlike tab water due to the interaction between charged species in synthetic wastewater with formed micelles. In addition, at concentrations higher than 400 ppm, the number of produced micelles increased exponentially in synthetic wastewater. The inhibition of growth rate of microorganism could be attributing to the micelle-forming surfactant which induced curvature stress in cell membranes and led to disordering and then cell lysis.

已有多篇关于表面活性剂对厌氧消化过程的影响的文献发表,结果表明,表面活性剂在不同浓度下具有相互矛盾的效果。为了了解这种矛盾效应的原因,本研究对表面活性剂在厌氧消化过程中的行为进行了研究。首先,在中嗜酸温度下使用 200 毫升反应器进行了实验室规模的实验,以确定最佳接种物-底物比例,并测量了化学需氧量、总固体、挥发性固体、pH 值、溶解氧、电导率、总溶解固体和碱度等参数。结果表明,最佳接种物-基质比为 4。研究的第二部分是在嗜中性条件下,用 0、100、200、400 四种浓度的十二烷基苯磺酸钠进行了为期 50 天的批量实验。结果表明,表面活性剂浓度为 400 ppm 时,厌氧消化发生了根本变化,表面活性剂在厌氧消化过程中起到了阻碍作用。为了研究表面活性剂浓度对厌氧消化的影响,绘制了标签水和合成废水的电导率和浊度与表面活性剂浓度的关系图。这些图表的结果表明,由于合成废水中的带电物种与形成的胶束相互作用,合成废水的电导率在临界胶束浓度之后急剧上升,这一点与标签水不同。此外,当浓度高于 400 ppm 时,合成废水中产生的胶束数量呈指数增长。抑制微生物生长率的原因可能是形成胶束的表面活性剂引起了细胞膜的曲率应力,导致细胞膜紊乱,进而导致细胞溶解。
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引用次数: 0
Alkali-activated materials containing mine tailings and zeolite for seepage water treatment in a closed nickel mine 含有矿山尾矿和沸石的碱活性材料用于封闭镍矿的渗水处理
IF 3.1 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-09 DOI: 10.1007/s13762-024-06002-y
J. Laukkanen, H. Runtti, I. Lancellotti, T. Luukkonen, C. Leonelli, U. Lassi

In the present study, alkali-activated materials were assessed as adsorbents for mine water treatment. The composition of alkali-activated materials, involving mixtures of metakaolin, blast-furnace slag, mine tailings, and zeolite, was optimized based on their leaching behavior and adsorption performance. The most effective adsorbent contained solely blast furnace slag as an aluminosilicate precursor and was selected for a pilot-scale study at a closed nickel mine in Finland. In the pilot, seepage water from a gangue area with an influent flow rate of 0.5 m3/d was treated using a permeable reactive barrier set-up containing 10 kg of slag-based adsorbent prepared by a granulation-alkali activation process. During a one-week experiment, the adsorbent granules were capable of effectively uptaking Ni, Fe, and Mn from the seepage water; the removal percentages of Ni, Fe, and Mn were 82.4%, 81.6%, and 82.5%, respectively. The results indicated the feasibility of blast furnace slag-based adsorbents for toxic element removal in a potentially sustainable approach.

本研究将碱活性材料作为矿井水处理的吸附剂进行了评估。碱活性材料包括偏高岭土、高炉矿渣、矿山尾矿和沸石的混合物,根据其浸出行为和吸附性能对其成分进行了优化。最有效的吸附剂仅含有作为铝硅酸盐前体的高炉矿渣,并被选中在芬兰的一个封闭镍矿进行试验性研究。在试验过程中,使用了一种可渗透的反应屏障装置来处理矸石区的渗漏水,该装置的进水流量为 0.5 立方米/天,其中含有 10 千克通过造粒-碱活化工艺制备的矿渣吸附剂。在为期一周的实验中,吸附剂颗粒能够有效吸附渗出水中的镍、铁和锰;镍、铁和锰的去除率分别为 82.4%、81.6% 和 82.5%。研究结果表明,高炉矿渣吸附剂以潜在的可持续方式去除有毒元素是可行的。
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引用次数: 0
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