Pub Date : 2024-07-16DOI: 10.1186/s40712-024-00149-9
Johannes Meuchelböck, Carlo Peiffer, Lena Walter, Marcel Dippold, Peter Munro, Holger Ruckdäschel
This study explores how expanded thermoplastic polyurethane (ETPU) responds to temperature and compression at various temperatures. Dynamic mechanical thermal analysis (DMTA) was used to understand the temperature influence at small deformations. To investigate the deformation behavior at different compression stages we employed in-situ CT measurements and 3D strain mapping. Through quasi-static compression tests at temperatures from − 50 to 120 °C, we determined the influence of temperature on compression modulus, elastic stress, stress at 50% deformation, densification, and energy absorption. Remarkably, ETPU demonstrates robust recovery after compression, particularly within the − 50 to 60 °C temperature range. Subsequent compression tests show consistent or even slightly increased compression properties, such as a 10% increase in energy absorption for samples previously tested at − 40 °C, indicating that ETPU can withstand prior exposure to different temperatures.
本研究探讨了发泡热塑性聚氨酯(ETPU)在不同温度下对温度和压缩的反应。我们使用动态机械热分析(DMTA)来了解小变形时的温度影响。为了研究不同压缩阶段的变形行为,我们采用了原位 CT 测量和三维应变绘图。通过在 - 50 至 120 °C 温度范围内进行准静态压缩试验,我们确定了温度对压缩模量、弹性应力、50% 变形时的应力、致密化和能量吸收的影响。值得注意的是,ETPU 在压缩后表现出强劲的恢复能力,尤其是在 - 50 至 60 °C 的温度范围内。随后的压缩测试表明,ETPU 的压缩性能保持一致,甚至略有提高,例如之前在 - 40 °C 下测试的样品的能量吸收率提高了 10%,这表明 ETPU 可以承受之前暴露在不同温度下的情况。
{"title":"Influence of temperature on the compression properties of expanded thermoplastic polyurethane (ETPU)","authors":"Johannes Meuchelböck, Carlo Peiffer, Lena Walter, Marcel Dippold, Peter Munro, Holger Ruckdäschel","doi":"10.1186/s40712-024-00149-9","DOIUrl":"10.1186/s40712-024-00149-9","url":null,"abstract":"<div><p>This study explores how expanded thermoplastic polyurethane (ETPU) responds to temperature and compression at various temperatures. Dynamic mechanical thermal analysis (DMTA) was used to understand the temperature influence at small deformations. To investigate the deformation behavior at different compression stages we employed in-situ CT measurements and 3D strain mapping. Through quasi-static compression tests at temperatures from − 50 to 120 °C, we determined the influence of temperature on compression modulus, elastic stress, stress at 50% deformation, densification, and energy absorption. Remarkably, ETPU demonstrates robust recovery after compression, particularly within the − 50 to 60 °C temperature range. Subsequent compression tests show consistent or even slightly increased compression properties, such as a 10% increase in energy absorption for samples previously tested at − 40 °C, indicating that ETPU can withstand prior exposure to different temperatures.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00149-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141631106","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
To ascertain upon the ideal configuration of physico-mechanical qualities, efficient processing techniques, and network stability of the prepared bio-composite films in real-world applications, the polymeric materials shall be subjected to a careful manipulation. Such bio-composite films have outstanding combinations of biocompatibility and toxicity-associated safety qualities. Such research interventions will be beneficial for the packaging, pharmaceutical, and biomedical industries that wish to target and adopt them for commercial applications. In this article, three alternate organic acids, i.e., citric acid (CA), tartaric acid (TA), and malic acid (MA), are blended separately into polyvinyl alcohol (PVA)-starch (St)-glycerol (Gl) composite films and for the targeted purpose of enhanced crosslinking, plasticizing, and antibacterial capability of the polymer network. The organic acid-based bio-composite polymeric films were assessed in terms of swelling index (SI), in vitro degradation, tensile strength (TS), percentage elongation (%E), antibacterial activity, and cytotoxicity attributes. Among these, the MA-based PVA composite films outperformed the CA-based PVA composite film in terms of absorbency (SI 739.29%), mechanical strength (TS 4.88 MPa), and elasticity (%E 103.68%). Furthermore, following a 24-h incubation period, the MA-based films exhibited the highest proliferative effect of 215.59% for the HEK cells. In conclusion, the MA has been inferred to be the most relevant organic acid for the desired optimality of film composition, physical and biological properties, and cost.
为了确定制备的生物复合膜在实际应用中的物理机械质量、高效加工技术和网络稳定性的理想配置,必须对聚合物材料进行精心处理。这种生物复合薄膜具有出色的生物相容性和毒性相关安全性。这些研究措施将有利于包装、制药和生物医学行业将其作为商业应用的目标并加以采用。本文将柠檬酸(CA)、酒石酸(TA)和苹果酸(MA)这三种交替有机酸分别混入聚乙烯醇(PVA)-淀粉(St)-甘油(Gl)复合薄膜中,目的是增强聚合物网络的交联、塑化和抗菌能力。对有机酸基生物复合聚合物薄膜的溶胀指数(SI)、体外降解、拉伸强度(TS)、伸长率(%E)、抗菌活性和细胞毒性属性进行了评估。其中,基于 MA 的 PVA 复合薄膜在吸收性(SI 739.29%)、机械强度(TS 4.88 兆帕)和弹性(%E 103.68%)方面均优于基于 CA 的 PVA 复合薄膜。此外,在 24 小时的培养期后,基于 MA 的薄膜对 HEK 细胞的增殖效果最高,达到 215.59%。总之,MA 被推断为最适合实现薄膜成分、物理和生物特性以及成本最优化的有机酸。
{"title":"Comparative efficacy of citric acid/tartaric acid/malic acid additive-based polyvinyl alcohol-starch composite films","authors":"Aritra Das, Muktashree Saha, Manish Kumar Gupta, Latha Rangan, Ramagopal Uppaluri, Chandan Das","doi":"10.1186/s40712-024-00151-1","DOIUrl":"10.1186/s40712-024-00151-1","url":null,"abstract":"<div><p>To ascertain upon the ideal configuration of physico-mechanical qualities, efficient processing techniques, and network stability of the prepared bio-composite films in real-world applications, the polymeric materials shall be subjected to a careful manipulation. Such bio-composite films have outstanding combinations of biocompatibility and toxicity-associated safety qualities. Such research interventions will be beneficial for the packaging, pharmaceutical, and biomedical industries that wish to target and adopt them for commercial applications. In this article, three alternate organic acids, i.e., citric acid (CA), tartaric acid (TA), and malic acid (MA), are blended separately into polyvinyl alcohol (PVA)-starch (St)-glycerol (Gl) composite films and for the targeted purpose of enhanced crosslinking, plasticizing, and antibacterial capability of the polymer network. The organic acid-based bio-composite polymeric films were assessed in terms of swelling index (SI), in vitro degradation, tensile strength (TS), percentage elongation (%E), antibacterial activity, and cytotoxicity attributes. Among these, the MA-based PVA composite films outperformed the CA-based PVA composite film in terms of absorbency (SI 739.29%), mechanical strength (TS 4.88 MPa), and elasticity (%E 103.68%). Furthermore, following a 24-h incubation period, the MA-based films exhibited the highest proliferative effect of 215.59% for the HEK cells. In conclusion, the MA has been inferred to be the most relevant organic acid for the desired optimality of film composition, physical and biological properties, and cost.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00151-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141618158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-14DOI: 10.1186/s40712-024-00150-2
S. Santosh, M. Pavithran
On account of their unique shape memory effect (SME), pseudoelasticity, and biomedical applications, shape memory alloys (SMAs) have gained significant acceptance in the industrial trade and biomedical applications over the past few decades. Due to their affordable constituent parts and the availability of large-scale methods that are commonly employed for the manufacturing of stainless steels, Fe-based shape memory alloys offer benefits in commercial production, owing to their low cost compared to NiTi. The increasing insistence on stronger, lighter, and more functional materials paved the way for active materials. SMAs are a distinct grade of active materials. They exhibit attractive attributes like the potential to provide considerable recoverable strain while mechanical loading (superelasticity), shape recovery during heating (shape memory effect), and biocompatibility, which ultimately prove them to be one of the appropriate actuators for applications in the biomedical industry. This paper gives a review of the Martensitic transformation of some of the compositions of Fe-based SMAs, their potential to be used in civil structures as strengthening materials, their applications, and future research needs. This paper also focuses on the application of iron-based SMAs in different fields and the necessity to work on this SMA in the future since results show that Fe-based SMAs have shown good potential and can serve as an apt alternative to Ni-based shape memory alloys, which on the other hand has quite a lot of disadvantages, the key one being costly. Fe-based SMAs are comparatively lower in cost and have a greater scope to work with in the near future.
过去几十年来,形状记忆合金(SMA)凭借其独特的形状记忆效应(SME)、假弹性和生物医学应用,在工业贸易和生物医学应用中获得了广泛认可。与镍钛相比,铁基形状记忆合金的成本较低,因此在商业生产中具有优势。人们对强度更高、重量更轻、功能更强的材料的要求越来越高,这为活性材料的发展铺平了道路。SMA 是一种独特的活性材料。它们表现出极具吸引力的特性,如在机械加载(超弹性)、加热过程中的形状恢复(形状记忆效应)和生物兼容性过程中可提供相当大的可恢复应变,这些特性最终证明它们是生物医学行业应用的合适致动器之一。本文综述了一些铁基 SMA 成分的马氏体转变、它们在民用结构中用作增强材料的潜力、它们的应用以及未来的研究需求。本文还重点介绍了铁基 SMA 在不同领域的应用,以及未来对这种 SMA 进行研究的必要性,因为研究结果表明,铁基 SMA 具有良好的潜力,可以作为镍基形状记忆合金的理想替代品,而镍基形状记忆合金有很多缺点,其中最主要的是成本高昂。铁基 SMA 的成本相对较低,在不久的将来有更大的应用空间。
{"title":"Iron-based smart alloys for critical applications: a review on processing, properties, phase transformations, and current trends","authors":"S. Santosh, M. Pavithran","doi":"10.1186/s40712-024-00150-2","DOIUrl":"10.1186/s40712-024-00150-2","url":null,"abstract":"<div><p>On account of their unique shape memory effect (SME), pseudoelasticity, and biomedical applications, shape memory alloys (SMAs) have gained significant acceptance in the industrial trade and biomedical applications over the past few decades. Due to their affordable constituent parts and the availability of large-scale methods that are commonly employed for the manufacturing of stainless steels, Fe-based shape memory alloys offer benefits in commercial production, owing to their low cost compared to NiTi. The increasing insistence on stronger, lighter, and more functional materials paved the way for active materials. SMAs are a distinct grade of active materials. They exhibit attractive attributes like the potential to provide considerable recoverable strain while mechanical loading (superelasticity), shape recovery during heating (shape memory effect), and biocompatibility, which ultimately prove them to be one of the appropriate actuators for applications in the biomedical industry. This paper gives a review of the Martensitic transformation of some of the compositions of Fe-based SMAs, their potential to be used in civil structures as strengthening materials, their applications, and future research needs. This paper also focuses on the application of iron-based SMAs in different fields and the necessity to work on this SMA in the future since results show that Fe-based SMAs have shown good potential and can serve as an apt alternative to Ni-based shape memory alloys, which on the other hand has quite a lot of disadvantages, the key one being costly. Fe-based SMAs are comparatively lower in cost and have a greater scope to work with in the near future.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00150-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141618156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-11DOI: 10.1186/s40712-024-00152-0
Souha Aouini, Afrah Bardaoui, Ana M. Ferraria, Radhouane Chtourou, Diogo M. F. Santos
CuMn2O4 (CMO) thin films are produced using a simple hydrothermal method. The influence of reaction duration on the electrodes’ electrochemical performance is investigated. XRD data shows improved crystal structure after 24-h reaction time, with a crystallite size of 12.17 nm. Distinct vibrational peaks associated with Cu–O and Mn–O are observed in the ATR-FTIR spectra, corroborating the spinel formation after 24 h. XPS analysis shows a compositional shift over time, starting with copper hydroxide at 12 h, evolving into a mix of copper and manganese oxides, hydroxides, and oxyhydroxides by 18 h, and achieving the desired spinel composition by 24 h. Microscopic analysis reveals CMO is arranged as small sheet structures, with 4.95 ± 2.92 µm in length after 24-h reaction. The CMO24h electrode displays a maximum specific capacitance of 1187.50 Fg−1 at a scan rate of 1 mVs−1 in 1 M Na2SO4 electrolyte. The electrochemical performance of the synthesized CMO electrodes reveals a high potential for energy storage applications.
{"title":"CuMn2O4 spinel electrodes: effect of the hydrothermal treatment duration on electrochemical performance","authors":"Souha Aouini, Afrah Bardaoui, Ana M. Ferraria, Radhouane Chtourou, Diogo M. F. Santos","doi":"10.1186/s40712-024-00152-0","DOIUrl":"10.1186/s40712-024-00152-0","url":null,"abstract":"<div><p>CuMn<sub>2</sub>O<sub>4</sub> (CMO) thin films are produced using a simple hydrothermal method. The influence of reaction duration on the electrodes’ electrochemical performance is investigated. XRD data shows improved crystal structure after 24-h reaction time, with a crystallite size of 12.17 nm. Distinct vibrational peaks associated with Cu–O and Mn–O are observed in the ATR-FTIR spectra, corroborating the spinel formation after 24 h. XPS analysis shows a compositional shift over time, starting with copper hydroxide at 12 h, evolving into a mix of copper and manganese oxides, hydroxides, and oxyhydroxides by 18 h, and achieving the desired spinel composition by 24 h. Microscopic analysis reveals CMO is arranged as small sheet structures, with 4.95 ± 2.92 µm in length after 24-h reaction. The CMO<sub>24h</sub> electrode displays a maximum specific capacitance of 1187.50 Fg<sup>−1</sup> at a scan rate of 1 mVs<sup>−1</sup> in 1 M Na<sub>2</sub>SO<sub>4</sub> electrolyte. The electrochemical performance of the synthesized CMO electrodes reveals a high potential for energy storage applications.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00152-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141587070","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-08DOI: 10.1186/s40712-024-00145-z
Rahul Varma, Sugumar Vasudevan
Thin films reinforced with chitosan and cellulose nanocrystals (CNC) were produced using the casting process. In this study, the impact of plasticisers and sizing agents such as glycerol and polyvinyl alcohol (PVA) respectively on morphological, structural, thermal, and mechanical properties was investigated. The results showed the blends of CNC/PVA/glycerol gave better results when compared to films produced by blends of chitosan/PVA/glycerol films and chitosan/CNC/PVA/glycerol films. The UV spectroscopy showed 65% transmittance for chitosan/PVA/glycerol films, while the film of CNC/PVA/glycerol showed transmittance of 40%. The transmittance of chitosan/CNC/PVA/glycerol showed 75%. The films formed by the combination of CNC/PVA/glycerol showed better stress/strain properties than other films. The films of all combinations showed good thermal stability between the range of 350 and 450 °C. The morphological study using SEM revealed smooth texture for all the films. The study suggests that the films produced may be used for the food packaging applications due to its thermal stability and stress/strain properties.
采用浇铸工艺生产了壳聚糖和纤维素纳米晶体(CNC)增强薄膜。在这项研究中,研究了增塑剂和施胶剂(如甘油和聚乙烯醇(PVA))分别对形态、结构、热和机械性能的影响。结果表明,与壳聚糖/PVA/甘油薄膜和壳聚糖/CNC/PVA/甘油薄膜的混合物相比,CNC/PVA/甘油的混合物能产生更好的薄膜。紫外光谱显示,壳聚糖/PVA/甘油薄膜的透射率为 65%,而 CNC/PVA/ 甘油薄膜的透射率为 40%。壳聚糖/CNC/PVA/甘油的透射率为 75%。与其他薄膜相比,CNC/PVA/甘油组合形成的薄膜具有更好的应力/应变特性。所有组合的薄膜在 350 至 450 °C 范围内均表现出良好的热稳定性。使用 SEM 进行的形态研究显示,所有薄膜的纹理都很光滑。研究表明,由于其热稳定性和应力/应变特性,所生产的薄膜可用于食品包装应用。
{"title":"Synthesis of composite films using polymer blends of chitosan and cellulose nanocrystals from marine origin","authors":"Rahul Varma, Sugumar Vasudevan","doi":"10.1186/s40712-024-00145-z","DOIUrl":"10.1186/s40712-024-00145-z","url":null,"abstract":"<div><p>Thin films reinforced with chitosan and cellulose nanocrystals (CNC) were produced using the casting process. In this study, the impact of plasticisers and sizing agents such as glycerol and polyvinyl alcohol (PVA) respectively on morphological, structural, thermal, and mechanical properties was investigated. The results showed the blends of CNC/PVA/glycerol gave better results when compared to films produced by blends of chitosan/PVA/glycerol films and chitosan/CNC/PVA/glycerol films. The UV spectroscopy showed 65% transmittance for chitosan/PVA/glycerol films, while the film of CNC/PVA/glycerol showed transmittance of 40%. The transmittance of chitosan/CNC/PVA/glycerol showed 75%. The films formed by the combination of CNC/PVA/glycerol showed better stress/strain properties than other films. The films of all combinations showed good thermal stability between the range of 350 and 450 °C. The morphological study using SEM revealed smooth texture for all the films. The study suggests that the films produced may be used for the food packaging applications due to its thermal stability and stress/strain properties.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00145-z","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141561129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-02DOI: 10.1186/s40712-024-00144-0
Md Rizwan, Suhaib Ahmad Khan, M. Rizwan Khan, Asfar Ali Khan
The insulating oil serves the dual purpose of providing insulation and cooling within transformers. This investigation aims to explore the impact of various nanoparticles on the dielectric breakdown voltage (BDV) of dielectric oils. The study examines the effect of the concentration of magnetic nanoparticles on the dielectric breakdown voltage of insulating oils. Nanoparticles such as iron (II, III) oxide (Fe3O4), cobalt (II, III) oxide (CO3O4), and ferrous phosphide (Fe3P) were utilized to create nanofluids with carrier mediums consisting of mineral oil and synthetic ester oil. BDV determination was conducted using a VDE and S–S electrode system according to IEC 60156 standards. Nanofluid were prepared using a two-step method, and their concentrations ranged from 0.01 g/L, 0.02 g/L, and 0.04 g/L in base oils. Twelve iterations were conducted for each prepared nanofluid, and breakdown voltage measurements were recorded. The results indicate a noteworthy enhancement in the breakdown voltage of nanofluids. The statistical analysis was performed on the dielectric property of nanofluid samples for better breakdown accuracy. The maximum enhancement at specific nanoparticle concentrations was shown by each nanofluid. The results show that under the S–S electrode configuration, the greatest overall enhancement was observed for Fe3P in mineral oil, with an enhancement of 70.05%, and Fe3O4 in synthetic ester oil, with an enhancement of 46.29%.
{"title":"Experimental and statistical investigation on the dielectric breakdown of magneto nanofluids for power applications","authors":"Md Rizwan, Suhaib Ahmad Khan, M. Rizwan Khan, Asfar Ali Khan","doi":"10.1186/s40712-024-00144-0","DOIUrl":"10.1186/s40712-024-00144-0","url":null,"abstract":"<div><p>The insulating oil serves the dual purpose of providing insulation and cooling within transformers. This investigation aims to explore the impact of various nanoparticles on the dielectric breakdown voltage (BDV) of dielectric oils. The study examines the effect of the concentration of magnetic nanoparticles on the dielectric breakdown voltage of insulating oils. Nanoparticles such as iron (II, III) oxide (Fe<sub>3</sub>O<sub>4</sub>), cobalt (II, III) oxide (CO<sub>3</sub>O<sub>4</sub>), and ferrous phosphide (Fe<sub>3</sub>P) were utilized to create nanofluids with carrier mediums consisting of mineral oil and synthetic ester oil. BDV determination was conducted using a VDE and S–S electrode system according to IEC 60156 standards. Nanofluid were prepared using a two-step method, and their concentrations ranged from 0.01 g/L, 0.02 g/L, and 0.04 g/L in base oils. Twelve iterations were conducted for each prepared nanofluid, and breakdown voltage measurements were recorded. The results indicate a noteworthy enhancement in the breakdown voltage of nanofluids. The statistical analysis was performed on the dielectric property of nanofluid samples for better breakdown accuracy. The maximum enhancement at specific nanoparticle concentrations was shown by each nanofluid. The results show that under the S–S electrode configuration, the greatest overall enhancement was observed for Fe<sub>3</sub>P in mineral oil, with an enhancement of 70.05%, and Fe<sub>3</sub>O<sub>4</sub> in synthetic ester oil, with an enhancement of 46.29%.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00144-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141495489","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-26DOI: 10.1186/s40712-024-00146-y
Hamza Ghauri, Reza Tafreshi, Bilal Mansoor
Machine learning-driven automated replication micrographs analysis makes possible rapid and unbiased damage assessment of in-service steel components. Although micrographs captured by scanning electron microscopy (SEM) have been analyzed at depth using machine learning, there is no literature available on the technique being attempted on optical replication micrographs. This paper presents a machine-learning approach to segment and quantify carbide precipitates in thermally exposed HP40-Nb stainless-steel microstructures from batches of low-resolution optical images obtained by replication metallography. A dataset of nine micrographs was used to develop a random forest classification model to segment precipitates within the matrix (intragranular) and at grain boundaries (intergranular). The micrographs were preprocessed using background subtraction, denoising, and sharpening to improve quality. The method achieves high segmentation accuracy (91% intergranular, 97% intragranular) compared to human expert classification. Furthermore, segmented micrographs were quantified to obtain carbide size, shape, and density distribution. The correlations in the quantified data aligned with expected carbide evolution mechanisms. Results from this study are promising but necessitate validation of the method on a larger dataset representative of evolution of thermal degradation in steel, given that characterization of the evolution of microstructure components, such as precipitates, applies to broad applications across diverse alloy systems, particularly in extreme service.
{"title":"Toward automated microstructure characterization of stainless steels through machine learning-based analysis of replication micrographs","authors":"Hamza Ghauri, Reza Tafreshi, Bilal Mansoor","doi":"10.1186/s40712-024-00146-y","DOIUrl":"10.1186/s40712-024-00146-y","url":null,"abstract":"<div><p>Machine learning-driven automated replication micrographs analysis makes possible rapid and unbiased damage assessment of in-service steel components. Although micrographs captured by scanning electron microscopy (SEM) have been analyzed at depth using machine learning, there is no literature available on the technique being attempted on optical replication micrographs. This paper presents a machine-learning approach to segment and quantify carbide precipitates in thermally exposed HP40-Nb stainless-steel microstructures from batches of low-resolution optical images obtained by replication metallography. A dataset of nine micrographs was used to develop a random forest classification model to segment precipitates within the matrix (intragranular) and at grain boundaries (intergranular). The micrographs were preprocessed using background subtraction, denoising, and sharpening to improve quality. The method achieves high segmentation accuracy (91% intergranular, 97% intragranular) compared to human expert classification. Furthermore, segmented micrographs were quantified to obtain carbide size, shape, and density distribution. The correlations in the quantified data aligned with expected carbide evolution mechanisms. Results from this study are promising but necessitate validation of the method on a larger dataset representative of evolution of thermal degradation in steel, given that characterization of the evolution of microstructure components, such as precipitates, applies to broad applications across diverse alloy systems, particularly in extreme service.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00146-y","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141453561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-22DOI: 10.1186/s40712-024-00142-2
Oleg Gaidai, Alia Ashraf, Yu Cao, Jinlu Sheng, Yan Zhu, Zirui Liu
As the global agenda turns more towards the so-called challenge of climate change and lowering carbon emissions, research into green, renewable energy sources becoming nowadays more and more popular. Offshore wind power, produced by FOWTs (i.e., Floating Offshore Wind Turbines), is one such substitute. It is a significant industrial part of the contemporary offshore wind energy industry and produces clean, renewable electricity. Accurate operational lifetime assessment for FOWTs is an important technical safety issue, as environmental in situ loads can lead to fatigue damage as well as extreme structural dynamics, which can cause structural damage. In this study, in situ environmental hydro and aerodynamic environmental loads, that act on FOWT, given actual local sea conditions have been numerically assessed, using the FAST coupled nonlinear aero-hydro-servo-elastic software package. FAST combines aerodynamics and hydrodynamics models for FOWTs, control and electrical system dynamics models, along with structural dynamics models, enabling coupled nonlinear MC simulation in the real time. The FAST software tool enables analysis of a range of FOWT configurations, including 2- or 3-bladed horizontal-axis rotor, pitch and stall regulation, rigid and teetering hub, upwind and downwind rotors. FAST relies on advanced engineering models—derived from the fundamental laws, however with appropriate assumptions and simplifications, supplemented where applicable with experimental data. Recently developed Gaidai reliability lifetime assessment method, being well suitable for risks evaluation of a variety of sustainable energy systems, experiencing nonlinear, potentially extreme in situ environmental loads, throughout their designed service life. The main advantage of the advocated Gaidai risks evaluation methodology being its ability to tackle simultaneously a large number of dynamic systems' degrees of freedom, corresponding to the system's critical components.
{"title":"Lifetime assessment of semi-submersible wind turbines by Gaidai risk evaluation method","authors":"Oleg Gaidai, Alia Ashraf, Yu Cao, Jinlu Sheng, Yan Zhu, Zirui Liu","doi":"10.1186/s40712-024-00142-2","DOIUrl":"10.1186/s40712-024-00142-2","url":null,"abstract":"<div><p>As the global agenda turns more towards the so-called challenge of climate change and lowering carbon emissions, research into green, renewable energy sources becoming nowadays more and more popular. Offshore wind power, produced by FOWTs (i.e., Floating Offshore Wind Turbines), is one such substitute. It is a significant industrial part of the contemporary offshore wind energy industry and produces clean, renewable electricity. Accurate operational lifetime assessment for FOWTs is an important technical safety issue, as environmental in situ loads can lead to fatigue damage as well as extreme structural dynamics, which can cause structural damage. In this study, in situ environmental hydro and aerodynamic environmental loads, that act on FOWT, given actual local sea conditions have been numerically assessed, using the FAST coupled nonlinear aero-hydro-servo-elastic software package. FAST combines aerodynamics and hydrodynamics models for FOWTs, control and electrical system dynamics models, along with structural dynamics models, enabling coupled nonlinear MC simulation in the real time. The FAST software tool enables analysis of a range of FOWT configurations, including 2- or 3-bladed horizontal-axis rotor, pitch and stall regulation, rigid and teetering hub, upwind and downwind rotors. FAST relies on advanced engineering models—derived from the fundamental laws, however with appropriate assumptions and simplifications, supplemented where applicable with experimental data. Recently developed Gaidai reliability lifetime assessment method, being well suitable for risks evaluation of a variety of sustainable energy systems, experiencing nonlinear, potentially extreme in situ environmental loads, throughout their designed service life. The main advantage of the advocated Gaidai risks evaluation methodology being its ability to tackle simultaneously a large number of dynamic systems' degrees of freedom, corresponding to the system's critical components.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00142-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141444750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-22DOI: 10.1186/s40712-024-00147-x
Sai Ram Gajjala, Geoffrey A. Swift, Rasit Koc
La1-xCax(B1,B2,B3)O3 perovskite powders doped with calcium were synthesized and sintered. Calcium doping modified the A-site of the perovskite structure, while the B-site was composed of three cations in equal atomic amounts. Cations on the B-site included cobalt, chromium, iron, manganese, and nickel. Sintering temperature varied from 1200 to 1400 °C in air. Density measurements and microstructure imaging determined effect of composition on sintering. Electrical conductivity of sintered compacts was measured using the four-wire measurement method at temperatures of 300 to 900 °C in air. Electrical properties as a function of composition indicate the effect of calcium doping in combination with varied B-site substitution increases electrical conductivity and improves sintering.
合成并烧结了掺有钙的 La1-xCax(B1,B2,B3)O3 包晶粉末。钙掺杂改变了包晶结构的 A 位,而 B 位则由三种原子量相等的阳离子组成。B 位上的阳离子包括钴、铬、铁、锰和镍。烧结温度在 1200 至 1400 °C 的空气中变化。密度测定和微观结构成像确定了成分对烧结的影响。采用四线测量法测量了烧结压块在 300 至 900 ℃ 空气中的电导率。电性能与成分的函数关系表明,钙掺杂与不同的 B 位取代相结合可提高电导率并改善烧结。
{"title":"Sintering and electrical conductivity of calcium-doped three-cation perovskite materials","authors":"Sai Ram Gajjala, Geoffrey A. Swift, Rasit Koc","doi":"10.1186/s40712-024-00147-x","DOIUrl":"10.1186/s40712-024-00147-x","url":null,"abstract":"<div><p>La<sub>1-x</sub>Ca<sub>x</sub>(B1,B2,B3)O<sub>3</sub> perovskite powders doped with calcium were synthesized and sintered. Calcium doping modified the A-site of the perovskite structure, while the B-site was composed of three cations in equal atomic amounts. Cations on the B-site included cobalt, chromium, iron, manganese, and nickel. Sintering temperature varied from 1200 to 1400 °C in air. Density measurements and microstructure imaging determined effect of composition on sintering. Electrical conductivity of sintered compacts was measured using the four-wire measurement method at temperatures of 300 to 900 °C in air. Electrical properties as a function of composition indicate the effect of calcium doping in combination with varied B-site substitution increases electrical conductivity and improves sintering.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.4,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00147-x","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141444751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-17DOI: 10.1186/s40712-024-00143-1
B. Morhard, T. Lohner, K. Stahl
Enabling gears to withstand loss of lubrication in gearboxes without secondary oil supply systems can reduce weight and space demand and thus fuel consumption. This study investigates the potential of surface and material technologies on the loss of lubrication performance of gears. Thereby, superfinished, coated, and nitrided gears are compared to ground gears. Systematic experiments under loss of lubrication are performed at a back-to-back gear test rig with circumferential speeds of up to 20 m/s and Hertzian pressures in the pitch point of up to 1723 N/mm2. Torque loss, pinion bulk temperatures, and tooth flank surface are analyzed. The results show that surface and material technologies can greatly influence frictional behavior and damage initiation of gears operating under loss of lubrication. With the materials and conditions tested, superfinishing yields to accelerated rise of frictional losses and thus scuffing. Coatings lead to significantly enhanced service life under loss of lubrication by friction reduction and scuffing avoidance.
{"title":"Influence of surface and material technologies on the loss of lubrication performance of gears","authors":"B. Morhard, T. Lohner, K. Stahl","doi":"10.1186/s40712-024-00143-1","DOIUrl":"10.1186/s40712-024-00143-1","url":null,"abstract":"<div><p>Enabling gears to withstand loss of lubrication in gearboxes without secondary oil supply systems can reduce weight and space demand and thus fuel consumption. This study investigates the potential of surface and material technologies on the loss of lubrication performance of gears. Thereby, superfinished, coated, and nitrided gears are compared to ground gears. Systematic experiments under loss of lubrication are performed at a back-to-back gear test rig with circumferential speeds of up to 20 m/s and Hertzian pressures in the pitch point of up to 1723 N/mm<sup>2</sup>. Torque loss, pinion bulk temperatures, and tooth flank surface are analyzed. The results show that surface and material technologies can greatly influence frictional behavior and damage initiation of gears operating under loss of lubrication. With the materials and conditions tested, superfinishing yields to accelerated rise of frictional losses and thus scuffing. Coatings lead to significantly enhanced service life under loss of lubrication by friction reduction and scuffing avoidance.</p></div>","PeriodicalId":592,"journal":{"name":"International Journal of Mechanical and Materials Engineering","volume":"19 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://jmsg.springeropen.com/counter/pdf/10.1186/s40712-024-00143-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141334109","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}