首页 > 最新文献

Journal of Contemporary Physics (Armenian Academy of Sciences)最新文献

英文 中文
Multilayer Energy-Absorbing Substrate for Two-Layer Barriers with an External Ceramic Layer 带外部陶瓷层的多层双层屏障吸能衬底
IF 0.5 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1134/S1068337224700099
P. G. Petrosyan, L. N. Grigoryan

A new type of multilayer energy-absorbing substrate has been proposed, the layers of which are stuck together by an elastic glue. When the impactor collides with an obstacle, part of the kinetic energy of this impactor is spent on the displacement of separate layers of the substrate relative to each other, which increases the maximum velocity of penetration of the barrier. The dependence of the maximum velocity of penetration of the barrier on the displacement of the substrate layers, as well as the dependence of the energy spent on sliding layers on the area of the deformed part of the substrate, have been studied. It is shown that, at the same impact energy, the depth of deformation of the proposed substrate is 1.5 times less than that of substrates in which the sliding of layers is absent. The use of the proposed substrate in ceramic protective structures allows one to significantly reduce the surface density of the structure.

摘要 提出了一种新型的多层吸能基板,其各层通过弹性胶粘在一起。当撞击器与障碍物碰撞时,撞击器的部分动能用于使基材的不同层之间产生相对位移,从而提高了障碍物的最大穿透速度。我们研究了障碍物的最大穿透速度与基体各层位移的关系,以及滑动层所消耗的能量与基体变形部分面积的关系。结果表明,在相同的冲击能量下,拟议基底的变形深度是无滑动层基底的 1.5 倍。在陶瓷保护结构中使用拟议的基底,可以大大降低结构的表面密度。
{"title":"Multilayer Energy-Absorbing Substrate for Two-Layer Barriers with an External Ceramic Layer","authors":"P. G. Petrosyan,&nbsp;L. N. Grigoryan","doi":"10.1134/S1068337224700099","DOIUrl":"10.1134/S1068337224700099","url":null,"abstract":"<p>A new type of multilayer energy-absorbing substrate has been proposed, the layers of which are stuck together by an elastic glue. When the impactor collides with an obstacle, part of the kinetic energy of this impactor is spent on the displacement of separate layers of the substrate relative to each other, which increases the maximum velocity of penetration of the barrier. The dependence of the maximum velocity of penetration of the barrier on the displacement of the substrate layers, as well as the dependence of the energy spent on sliding layers on the area of the deformed part of the substrate, have been studied. It is shown that, at the same impact energy, the depth of deformation of the proposed substrate is 1.5 times less than that of substrates in which the sliding of layers is absent. The use of the proposed substrate in ceramic protective structures allows one to significantly reduce the surface density of the structure.</p>","PeriodicalId":623,"journal":{"name":"Journal of Contemporary Physics (Armenian Academy of Sciences)","volume":"59 1","pages":"79 - 84"},"PeriodicalIF":0.5,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142175750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Absorption and Fluorescence Characteristics of the Binding of Ethidium Bromide with Synthetic Single- and Double-Stranded Polyribonucleotides 溴化乙锭与合成单链和双链多核苷酸结合的吸收和荧光特性
IF 0.5 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1134/S1068337224700130
A. P. Antonyan, P. O. Vardevanyan, M. S. Mikaelyan, G. H. Kocharyan, G. H. Poghosyan, M. A. Parsadanyan

A comparative study of the complex formation of ethidium bromide (EtBr) and methylene blue (MB) with synthetic single-stranded (ss-) polynucleotides poly(rA) and poly(rU) was conducted. The absorption spectra of these ligands decreased upon interaction with ss-polynucleotides and poly(rA)-poly(rU) formed at their hybridization. In the case of the MB-polynucleotide complexes, the fluorescence intensity decreases, while in the case of EtBr, the fluorescence intensity increases along with the enhancement of concentrations of polynucleotides. Based on the fluorescence spectra analysis of the complexes EtBr with ss- and hybrid ds-polynucleotides, the binding curves in Scatchard coordinates were constructed (r/Cf and r), and the values of the binding parameters of polynucleotides determined, including the binding constant value K and the number of bases n (base pairs at hybridization) per binding site..

摘要 对溴化乙锭(EtBr)和亚甲基蓝(MB)与合成单链(ss-)多核苷酸聚(rA)和聚(rU)形成的复合物进行了比较研究。这些配体与ss-多核苷酸和杂交形成的聚(rA)-聚(rU)相互作用后,其吸收光谱降低。在甲基溴-多核苷酸复合物的情况下,荧光强度会降低,而在乙特溴的情况下,荧光强度会随着多核苷酸浓度的增加而增加。根据 EtBr 与ss-多核苷酸和杂合ds-多核苷酸复合物的荧光光谱分析,构建了 Scatchard 坐标下的结合曲线(r/Cf 和 r),并确定了多核苷酸的结合参数值,包括结合常数 K 值和每个结合位点的碱基数 n(杂交时的碱基对数)。
{"title":"Absorption and Fluorescence Characteristics of the Binding of Ethidium Bromide with Synthetic Single- and Double-Stranded Polyribonucleotides","authors":"A. P. Antonyan,&nbsp;P. O. Vardevanyan,&nbsp;M. S. Mikaelyan,&nbsp;G. H. Kocharyan,&nbsp;G. H. Poghosyan,&nbsp;M. A. Parsadanyan","doi":"10.1134/S1068337224700130","DOIUrl":"10.1134/S1068337224700130","url":null,"abstract":"<p>A comparative study of the complex formation of ethidium bromide (EtBr) and methylene blue (MB) with synthetic single-stranded (ss-) polynucleotides poly(rA) and poly(rU) was conducted. The absorption spectra of these ligands decreased upon interaction with ss-polynucleotides and poly(rA)-poly(rU) formed at their hybridization. In the case of the MB-polynucleotide complexes, the fluorescence intensity decreases, while in the case of EtBr, the fluorescence intensity increases along with the enhancement of concentrations of polynucleotides. Based on the fluorescence spectra analysis of the complexes EtBr with ss- and hybrid ds-polynucleotides, the binding curves in Scatchard coordinates were constructed (<i>r</i>/<i>C</i><sub>f</sub> and <i>r</i>), and the values of the binding parameters of polynucleotides determined, including the binding constant value <i>K</i> and the number of bases <i>n</i> (base pairs at hybridization) per binding site<i>.</i>.</p>","PeriodicalId":623,"journal":{"name":"Journal of Contemporary Physics (Armenian Academy of Sciences)","volume":"59 1","pages":"103 - 110"},"PeriodicalIF":0.5,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142175756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Features of Microwave Propagation Through a Two-Layer Metasurface Made of Conductive Rods 由导电棒构成的两层元表面的微波传播特性
IF 0.5 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1134/S1068337224700142
G. Ohanyan

In a two-layer meta surface consisting of periodically arranged rods, there is a strong dispersion of the transmission coefficient in the microwave region of the spectrum. The observed phenomenon is the result of the resonant interaction of the microwave with the rod, where a standing wave with axial symmetry is formed, as well as the effective electrical interaction between the rods of adjacent layers. The transmission coefficient curve found in the experiment has an acute peak, which allows the structure to be used as a bandpass filter. It was found that the resonant frequency shifts to the low-frequency region as the length of the rods, their diameter, and the distance between the layers increases, which opens up the possibilities of controlling the microwave.

摘要 在一个由周期性排列的棒组成的双层元表面中,光谱的微波区域存在很强的传输系数分散现象。观察到的这一现象是微波与棒的共振相互作用(形成轴对称驻波)以及相邻层的棒之间有效电相互作用的结果。实验中发现的传输系数曲线有一个尖锐的峰值,这使得该结构可以用作带通滤波器。实验发现,随着棒的长度、直径和层间距离的增加,谐振频率会向低频区移动,这为控制微波提供了可能。
{"title":"Features of Microwave Propagation Through a Two-Layer Metasurface Made of Conductive Rods","authors":"G. Ohanyan","doi":"10.1134/S1068337224700142","DOIUrl":"10.1134/S1068337224700142","url":null,"abstract":"<p>In a two-layer meta surface consisting of periodically arranged rods, there is a strong dispersion of the transmission coefficient in the microwave region of the spectrum. The observed phenomenon is the result of the resonant interaction of the microwave with the rod, where a standing wave with axial symmetry is formed, as well as the effective electrical interaction between the rods of adjacent layers. The transmission coefficient curve found in the experiment has an acute peak, which allows the structure to be used as a bandpass filter. It was found that the resonant frequency shifts to the low-frequency region as the length of the rods, their diameter, and the distance between the layers increases, which opens up the possibilities of controlling the microwave.</p>","PeriodicalId":623,"journal":{"name":"Journal of Contemporary Physics (Armenian Academy of Sciences)","volume":"59 1","pages":"111 - 114"},"PeriodicalIF":0.5,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142175757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Increase in the Resolution of Hard X-Ray Phase-Contrast Imaging in a Device Based on a Triple Laue-Case Interferometer 在基于三重 Laue-Case 干涉仪的设备中提高硬 X 射线相位对比成像的分辨率
IF 0.5 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1134/S1068337224700166
L. A. Haroutunyan

The possibility of increasing the resolution of X-ray phase-contrast imaging with a device based on a triple Laue-case interferometer is considered. To address one of the drawbacks of this scheme—the distortion of the interference pattern during diffraction of the object wave on the interferometer analyzer—it is proposed to replace the analyzer with two crystalline blocks of equal thickness. These blocks act as a diffraction lens, suppressing the mentioned distortions. Numerical simulations demonstrate that the low coherence of the initial radiation increases the quality of phase-contrast imaging using this method.

摘要 研究考虑了利用基于三重 Laue-case 干涉仪的装置提高 X 射线相位对比成像分辨率的可能性。为了解决该方案的一个缺点--干涉图案在物体波在干涉仪分析器上衍射时发生扭曲--建议用两个等厚的晶体块取代分析器。这些晶体块就像一个衍射透镜,可以抑制上述扭曲现象。数值模拟证明,使用这种方法,初始辐射的低相干性提高了相位对比成像的质量。
{"title":"Increase in the Resolution of Hard X-Ray Phase-Contrast Imaging in a Device Based on a Triple Laue-Case Interferometer","authors":"L. A. Haroutunyan","doi":"10.1134/S1068337224700166","DOIUrl":"10.1134/S1068337224700166","url":null,"abstract":"<p>The possibility of increasing the resolution of X-ray phase-contrast imaging with a device based on a triple Laue-case interferometer is considered. To address one of the drawbacks of this scheme—the distortion of the interference pattern during diffraction of the object wave on the interferometer analyzer—it is proposed to replace the analyzer with two crystalline blocks of equal thickness. These blocks act as a diffraction lens, suppressing the mentioned distortions. Numerical simulations demonstrate that the low coherence of the initial radiation increases the quality of phase-contrast imaging using this method.</p>","PeriodicalId":623,"journal":{"name":"Journal of Contemporary Physics (Armenian Academy of Sciences)","volume":"59 1","pages":"122 - 127"},"PeriodicalIF":0.5,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S1068337224700166.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142175626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Miscibility Gaps Analysis for BN–Si–C Ternary Material System BN-Si-C 三元材料体系的混溶性差距分析
IF 0.5 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1134/S1068337224700117
L. S. Yeranyan, A. V. Margaryan, K. M. Gambaryan

Cubic boron nitride (c-BN) is an ultrawide band gap, superhard material with significant potential for applications under extreme temperatures and pressures. Nevertheless, two major challenges hinder its practical utilization in technology: (i) the difficulty in producing high-quality c-BN films, and (ii) the challenge of effectively n- and p-doping its matrix. This theoretical study focuses on investigating the solubility limits of silicon (Si) and carbon (C) in the c-BN and wurtzite BN (WZ–BN) on the basis of the strictly regular solution approximation. These elements are key candidates as n-type dopants in BN, addressing a critical concern in the realization of c-BN based electronics. The calculated Gibbs free energies of binary mixtures within the temperature range of 800–3000 K indicate that the presence of unstable regions, and consequently, miscibility gaps, are a prevalent characteristic of this system. The analysis reveals that the immiscibility gap is influenced not only by temperature, but also by the crystallographic structure. The calculated results of Si solubility limit in BN–Si binary system are in a good agreement with the latest experimental results. The findings presented here are applicable to the fabrication of multicomponent bulk crystals, epitaxial thin films, and nanostructures based on BN–Si–C solid solutions.

摘要立方氮化硼(c-BN)是一种超宽带隙超硬材料,在极端温度和压力下具有巨大的应用潜力。然而,两大挑战阻碍了它在技术上的实际应用:(i) 难以生产出高质量的立方氮化硼薄膜;(ii) 难以有效地对其基体进行 n 掺杂和 p 掺杂。本理论研究的重点是在严格正则溶液近似的基础上,研究硅(Si)和碳(C)在c-BN和沃特兹BN(WZ-BN)中的溶解度极限。这些元素是 BN 中 n 型掺杂剂的关键候选元素,解决了实现基于 c-BN 的电子器件的关键问题。计算得出的二元混合物在 800-3000 K 温度范围内的吉布斯自由能表明,不稳定区域的存在以及由此产生的混溶隙是该体系的一个普遍特征。分析表明,不相溶间隙不仅受温度影响,还受晶体结构影响。BN-Si 二元体系中硅溶解度极限的计算结果与最新的实验结果非常吻合。本文的研究结果适用于基于 BN-Si-C 固溶体的多组分块状晶体、外延薄膜和纳米结构的制造。
{"title":"Miscibility Gaps Analysis for BN–Si–C Ternary Material System","authors":"L. S. Yeranyan,&nbsp;A. V. Margaryan,&nbsp;K. M. Gambaryan","doi":"10.1134/S1068337224700117","DOIUrl":"10.1134/S1068337224700117","url":null,"abstract":"<p>Cubic boron nitride (c-BN) is an ultrawide band gap, superhard material with significant potential for applications under extreme temperatures and pressures. Nevertheless, two major challenges hinder its practical utilization in technology: (<i>i</i>) the difficulty in producing high-quality c-BN films, and (<i>ii</i>) the challenge of effectively n- and p-doping its matrix. This theoretical study focuses on investigating the solubility limits of silicon (Si) and carbon (C) in the c-BN and wurtzite BN (WZ–BN) on the basis of the strictly regular solution approximation. These elements are key candidates as n-type dopants in BN, addressing a critical concern in the realization of <i>c</i>-BN based electronics. The calculated Gibbs free energies of binary mixtures within the temperature range of 800–3000 K indicate that the presence of unstable regions, and consequently, miscibility gaps, are a prevalent characteristic of this system. The analysis reveals that the immiscibility gap is influenced not only by temperature, but also by the crystallographic structure. The calculated results of Si solubility limit in BN–Si binary system are in a good agreement with the latest experimental results. The findings presented here are applicable to the fabrication of multicomponent bulk crystals, epitaxial thin films, and nanostructures based on BN–Si–C solid solutions.</p>","PeriodicalId":623,"journal":{"name":"Journal of Contemporary Physics (Armenian Academy of Sciences)","volume":"59 1","pages":"91 - 96"},"PeriodicalIF":0.5,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142175753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel Prediction Using TB-mBJ of Electronic Properties, Magnetic Exchange Couplings, and Half-Metallicity in CrCaSe Materials 利用 TB-mBJ 对 CrCaSe 材料的电子特性、磁交换耦合和半金属性进行新颖预测
IF 0.5 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1134/S1068337224700063
H. R. Sahraoui, B. Doumi, A. Mokaddem, D. Bensaid, M. Boutaleb, A. Tadjer, A. Yakoubi, A. Sayede

In this study, we have performed investigations on the structural stability, electronic band structures, magnetic exchange couplings, and half-metallic performance of CrxCa1– xSe materials using computational methods of density functional theory via GGA-WC, GGA-PBE and, TB-mBJ exchange-correlation potentials. The CrxCa1–xSe compounds are thermodynamically stable and synthesizable owing to their negative formation energies. The structural parameters of CrxCa1–xSe with GGA-WC and GGA-PBE approximations appear to be in excellent concordance compared to the experimental data and recent theoretical calculations. According to GGA-PBE and TB-mBJ calculations, the CrxCa1–xSe compounds revealed integral magnetic moments and a half-metallic behavior with better half-metallic gaps, and spin-polarization of 100%. The CrxCa1–xSe alloys appear to be better materials for use in spintronic devices.

摘要 在这项研究中,我们利用密度泛函理论的计算方法,通过 GGA-WC、GGA-PBE 和 TB-mBJ 交换相关势,对 CrxCa1- xSe 材料的结构稳定性、电子能带结构、磁交换耦合和半金属性能进行了研究。由于 CrxCa1-xSe 的负形成能,它们在热力学上是稳定和可合成的。用 GGA-WC 和 GGA-PBE 近似计算得出的 CrxCa1-xSe 结构参数与实验数据和最近的理论计算结果非常吻合。根据 GGA-PBE 和 TB-mBJ 计算,CrxCa1-xSe 化合物显示出积分磁矩和半金属行为,具有较好的半金属间隙和 100% 的自旋极化。CrxCa1-xSe 合金似乎是用于自旋电子器件的更好材料。
{"title":"Novel Prediction Using TB-mBJ of Electronic Properties, Magnetic Exchange Couplings, and Half-Metallicity in CrCaSe Materials","authors":"H. R. Sahraoui,&nbsp;B. Doumi,&nbsp;A. Mokaddem,&nbsp;D. Bensaid,&nbsp;M. Boutaleb,&nbsp;A. Tadjer,&nbsp;A. Yakoubi,&nbsp;A. Sayede","doi":"10.1134/S1068337224700063","DOIUrl":"10.1134/S1068337224700063","url":null,"abstract":"<p>In this study, we have performed investigations on the structural stability, electronic band structures, magnetic exchange couplings, and half-metallic performance of Cr<sub><i>x</i></sub>Ca<sub>1– <i>x</i></sub>Se materials using computational methods of density functional theory via GGA-WC, GGA-PBE and, TB-mBJ exchange-correlation potentials. The Cr<sub><i>x</i></sub>Ca<sub>1–<i>x</i></sub>Se compounds are thermodynamically stable and synthesizable owing to their negative formation energies. The structural parameters of Cr<sub><i>x</i></sub>Ca<sub>1–<i>x</i></sub>Se with GGA-WC and GGA-PBE approximations appear to be in excellent concordance compared to the experimental data and recent theoretical calculations. According to GGA-PBE and TB-mBJ calculations, the Cr<sub><i>x</i></sub>Ca<sub>1–<i>x</i></sub>Se compounds revealed integral magnetic moments and a half-metallic behavior with better half-metallic gaps, and spin-polarization of 100%. The Cr<sub><i>x</i></sub>Ca<sub>1–<i>x</i></sub>Se alloys appear to be better materials for use in spintronic devices.</p>","PeriodicalId":623,"journal":{"name":"Journal of Contemporary Physics (Armenian Academy of Sciences)","volume":"59 1","pages":"41 - 57"},"PeriodicalIF":0.5,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142175749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental Optimization, Design Synthesis, and Up-Conversion Luminescence Properties of Y4GeO8: Er3+/Yb3+ Red Phosphors Y4GeO8: Er3+/Yb3+ 红色荧光粉的实验优化、设计合成和上转换发光特性
IF 0.5 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1134/S1068337224700087
S. Y. Liu, D. Gao, L. Wang, W. B. Song, H. Yin, S. T. Wang, Y. Zhu

The Er3+/Yb3+ co-doped Y4GeO8 crystal powders were successfully synthesized using a high-temperature solid-phase method. The crystal structure of the obtained phosphors was confirmed to be pure Y4GeO8 through X-ray diffraction (XRD) analysis. A regression equation correlating Er3+/Yb3+ doping concentrations with luminescent intensity was established based on the optimized theoretical model derived from experimental design. The optimal concentrations of Er3+ and Yb3+ under 980 nm laser excitation were determined as 7.41 and 21.34%, respectively, while under 1550 nm laser excitation, the concentrations were 2.66 and 17.42%, respectively. The fluorescence emission spectra of the up-conversion samples were measured, revealing intense green and red emissions with peaks at 542, 546, and 654 nm under 980 nm excitation, and peaks at 546, 557, and 663 nm under 1550 nm excitation. These peaks correspond to transitions from 2H11/2 to 4I15/2, 4S3/2 to 4I15/2, and 4F9/2 to 4I15/2 energy levels. The relationship between up-conversion luminescence and laser operating current for the optimal samples under 980 nm and 1550 nm was investigated, uncovering that up-conversion luminescence occurs through both two-photon and three-photon processes. A detailed analysis and discussion of the up-conversion luminescence mechanisms were conducted. Furthermore, the relationship between up-conversion fluorescence and temperature for the optimal samples was studied, revealing excellent temperature-sensing characteristics under 980 nm and 1550 nm laser excitations. The calculated illumination region coordinates for the optimal samples under 980 nm and 1550 nm wavelength excitations were (0.5558, 0.4362) and (0.5256, 0.4687), respectively. The research highlights the potential of rare-earth ion-doped up-conversion luminescent materials for diverse anti-counterfeiting applications. In particular, the Y4GeO8: Yb3+/Er3+ phosphors, incorporating a dual-excitation mechanism, enhance the security of anti-counterfeiting strategies in multifaceted scenarios. The study underscores the promising developments in this field.

摘要 采用高温固相法成功合成了Er3+/Yb3+共掺杂Y4GeO8晶体粉末。通过 X 射线衍射(XRD)分析证实了所获得荧光粉的晶体结构为纯 Y4GeO8。根据实验设计得出的优化理论模型,建立了 Er3+/Yb3+ 掺杂浓度与发光强度的回归方程。在 980 nm 激光激发下,Er3+ 和 Yb3+ 的最佳浓度分别为 7.41% 和 21.34%;在 1550 nm 激光激发下,最佳浓度分别为 2.66% 和 17.42%。对上转换样品的荧光发射光谱进行了测量,结果显示,在 980 nm 激光激发下,绿色和红色发射强烈,峰值分别为 542、546 和 654 nm;在 1550 nm 激光激发下,峰值分别为 546、557 和 663 nm。这些峰值对应于 2H11/2 到 4I15/2、4S3/2 到 4I15/2 和 4F9/2 到 4I15/2 能级的跃迁。研究了 980 纳米和 1550 纳米波长下最佳样品的上转换发光与激光工作电流之间的关系,发现上转换发光是通过双光子和三光子过程发生的。对上转换发光机制进行了详细的分析和讨论。此外,还研究了最佳样品的上转换荧光与温度之间的关系,发现在 980 nm 和 1550 nm 激光激发下,上转换荧光具有出色的温度感应特性。在 980 nm 和 1550 nm 波长的激发下,最佳样品的照明区域坐标分别为 (0.5558, 0.4362) 和 (0.5256, 0.4687)。这项研究凸显了掺杂稀土离子的上转换发光材料在各种防伪应用中的潜力。尤其是 Y4GeO8:Yb3+/Er3+ 荧光粉,结合了双重激发机制,可在多方面提高防伪策略的安全性。这项研究强调了这一领域的发展前景。
{"title":"Experimental Optimization, Design Synthesis, and Up-Conversion Luminescence Properties of Y4GeO8: Er3+/Yb3+ Red Phosphors","authors":"S. Y. Liu,&nbsp;D. Gao,&nbsp;L. Wang,&nbsp;W. B. Song,&nbsp;H. Yin,&nbsp;S. T. Wang,&nbsp;Y. Zhu","doi":"10.1134/S1068337224700087","DOIUrl":"10.1134/S1068337224700087","url":null,"abstract":"<p>The Er<sup>3+</sup>/Yb<sup>3+</sup> co-doped Y<sub>4</sub>GeO<sub>8</sub> crystal powders were successfully synthesized using a high-temperature solid-phase method. The crystal structure of the obtained phosphors was confirmed to be pure Y<sub>4</sub>GeO<sub>8</sub> through X-ray diffraction (XRD) analysis. A regression equation correlating Er<sup>3+</sup>/Yb<sup>3+</sup> doping concentrations with luminescent intensity was established based on the optimized theoretical model derived from experimental design. The optimal concentrations of Er<sup>3+</sup> and Yb<sup>3+</sup> under 980 nm laser excitation were determined as 7.41 and 21.34%, respectively, while under 1550 nm laser excitation, the concentrations were 2.66 and 17.42%, respectively. The fluorescence emission spectra of the up-conversion samples were measured, revealing intense green and red emissions with peaks at 542, 546, and 654 nm under 980 nm excitation, and peaks at 546, 557, and 663 nm under 1550 nm excitation. These peaks correspond to transitions from <sup>2</sup>H<sub>11/2</sub> to <sup>4</sup>I<sub>15/2</sub>, <sup>4</sup>S<sub>3/2</sub> to <sup>4</sup>I<sub>15/2</sub>, and <sup>4</sup>F<sub>9/2</sub> to <sup>4</sup>I<sub>15/2</sub> energy levels. The relationship between up-conversion luminescence and laser operating current for the optimal samples under 980 nm and 1550 nm was investigated, uncovering that up-conversion luminescence occurs through both two-photon and three-photon processes. A detailed analysis and discussion of the up-conversion luminescence mechanisms were conducted. Furthermore, the relationship between up-conversion fluorescence and temperature for the optimal samples was studied, revealing excellent temperature-sensing characteristics under 980 nm and 1550 nm laser excitations. The calculated illumination region coordinates for the optimal samples under 980 nm and 1550 nm wavelength excitations were (0.5558, 0.4362) and (0.5256, 0.4687), respectively. The research highlights the potential of rare-earth ion-doped up-conversion luminescent materials for diverse anti-counterfeiting applications. In particular, the Y<sub>4</sub>GeO<sub>8</sub>: Yb<sup>3+</sup>/Er<sup>3+</sup> phosphors, incorporating a dual-excitation mechanism, enhance the security of anti-counterfeiting strategies in multifaceted scenarios. The study underscores the promising developments in this field.</p>","PeriodicalId":623,"journal":{"name":"Journal of Contemporary Physics (Armenian Academy of Sciences)","volume":"59 1","pages":"58 - 78"},"PeriodicalIF":0.5,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142175755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simple Extension of Kitaev Chain for ({{mathcal{Z}}_{3}}) Parafermions 针对 $${{mathcal{Z}}_{3}}$ Parafermions 的基塔耶夫链的简单扩展
IF 0.5 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1134/S1068337224700075
T. S. Hakobyan, R. H. Varosyan, G. H. Harutunyan

A simple quantum chain with a topological phase is constructed. It is formed by parafermions (quasiparticles obeying the fractional statistics) with angular parameter (theta = {{2pi } mathord{left/ {vphantom {{2pi } 3}} right. kern-0em} 3}). The model is derived from the one-dimensional spin model with topological order protected by the ({{mathcal{Z}}_{3}} times {{mathcal{Z}}_{3}}~) symmetry (generalized cluster model). Parafermionic zero modes arising at the chain boundaries, which remain stable because of the vacuum gap and topological order, are constructed and studied.

摘要 构建了一个具有拓扑相的简单量子链。它是由具有角参数(theta = {{2pi })的旁费米子(服从分数统计的准粒子)构成的。mathord{left/ {vphantom {{2pi }3}}right.kern-0em} 3})。该模型源于一维自旋模型,其拓扑阶次受到({{mathcal{Z}}_{3}} times {{mathcal{Z}}_{3}}~)对称性的保护(广义簇模型)。我们构建并研究了在链边界产生的副非米子零模,这些零模由于真空间隙和拓扑秩序而保持稳定。
{"title":"Simple Extension of Kitaev Chain for ({{mathcal{Z}}_{3}}) Parafermions","authors":"T. S. Hakobyan,&nbsp;R. H. Varosyan,&nbsp;G. H. Harutunyan","doi":"10.1134/S1068337224700075","DOIUrl":"10.1134/S1068337224700075","url":null,"abstract":"<p>A simple quantum chain with a topological phase is constructed. It is formed by parafermions (quasiparticles obeying the fractional statistics) with angular parameter <span>(theta = {{2pi } mathord{left/ {vphantom {{2pi } 3}} right. kern-0em} 3})</span>. The model is derived from the one-dimensional spin model with topological order protected by the <span>({{mathcal{Z}}_{3}} times {{mathcal{Z}}_{3}}~)</span> symmetry (generalized cluster model). Parafermionic zero modes arising at the chain boundaries, which remain stable because of the vacuum gap and topological order, are constructed and studied.</p>","PeriodicalId":623,"journal":{"name":"Journal of Contemporary Physics (Armenian Academy of Sciences)","volume":"59 1","pages":"28 - 35"},"PeriodicalIF":0.5,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142175748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optical and EPR Spectroscopy of Microwave-Modified Natural Zeolite Activated with Zinc Oxide and Silver 用氧化锌和银活化的微波修饰天然沸石的光学和 EPR 光谱分析
IF 0.5 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1134/S1068337224700129
N. R. Aghamalyan, H. T. Gyulasaryan, E. A. Kafadaryan, M. N. Nersisyan, A. A. Sargsyan, V. V. Baghramyan

Samples of natural zeolite from the Nor-Kokhb deposit (Armenia), activated with zinc oxide (30% ZnO) and silver (30% ZnO + 5% Ag), were studied during chemical and thermal treatment by microwave and traditional methods. It was previously shown that microwave processing is 3 times faster than the traditional method. The X-ray diffraction analysis shows the presence of zeolite in the form of clinoptilolite and zinc oxide in the studied samples. Based on the results of optical and EPR spectroscopy, the presence of Fe3+ ions in the framework and extra-framework positions of the zeolite of the studied samples was revealed. The study of diffuse reflectance spectra showed that in zeolite, which is a wide-gap material (with a band gap of 4.14 eV), the activation of 30% ZnO decreases the band gap to 3.38 eV, and with additional activation with a silver (30% ZnO + 5% Ag) the bandgap decreases to 3.31 eV. The photocatalytic activity of natural zeolite activated with zinc oxide (30% ZnO) and silver (30% ZnO + 5% Ag) was studied according to the decomposition reaction of methylene blue under UV irradiation.

摘要 研究了用氧化锌(30% ZnO)和银(30% ZnO + 5%Ag)活化的来自 Nor-Kokhb 矿床(亚美尼亚)的天然沸石样品,这些样品通过微波和传统方法进行化学和热处理。之前的研究表明,微波处理比传统方法快 3 倍。X 射线衍射分析表明,在所研究的样品中存在沸石(clinoptilolite)和氧化锌。根据光学和 EPR 光谱分析的结果,发现所研究样品的沸石框架和框架外位置存在 Fe3+ 离子。对漫反射光谱的研究表明,沸石是一种宽带隙材料(带隙为 4.14 eV),30% ZnO 的活化会使带隙减小到 3.38 eV,而额外的银活化(30% ZnO + 5%Ag)会使带隙减小到 3.31 eV。根据亚甲基蓝在紫外线照射下的分解反应,研究了用氧化锌(30% ZnO)和银(30% ZnO + 5%Ag)活化的天然沸石的光催化活性。
{"title":"Optical and EPR Spectroscopy of Microwave-Modified Natural Zeolite Activated with Zinc Oxide and Silver","authors":"N. R. Aghamalyan,&nbsp;H. T. Gyulasaryan,&nbsp;E. A. Kafadaryan,&nbsp;M. N. Nersisyan,&nbsp;A. A. Sargsyan,&nbsp;V. V. Baghramyan","doi":"10.1134/S1068337224700129","DOIUrl":"10.1134/S1068337224700129","url":null,"abstract":"<p>Samples of natural zeolite from the Nor-Kokhb deposit (Armenia), activated with zinc oxide (30% ZnO) and silver (30% ZnO + 5% Ag), were studied during chemical and thermal treatment by microwave and traditional methods. It was previously shown that microwave processing is 3 times faster than the traditional method. The X-ray diffraction analysis shows the presence of zeolite in the form of clinoptilolite and zinc oxide in the studied samples. Based on the results of optical and EPR spectroscopy, the presence of Fe<sup>3+</sup> ions in the framework and extra-framework positions of the zeolite of the studied samples was revealed. The study of diffuse reflectance spectra showed that in zeolite, which is a wide-gap material (with a band gap of 4.14 eV), the activation of 30% ZnO decreases the band gap to 3.38 eV, and with additional activation with a silver (30% ZnO + 5% Ag) the bandgap decreases to 3.31 eV. The photocatalytic activity of natural zeolite activated with zinc oxide (30% ZnO) and silver (30% ZnO + 5% Ag) was studied according to the decomposition reaction of methylene blue under UV irradiation.</p>","PeriodicalId":623,"journal":{"name":"Journal of Contemporary Physics (Armenian Academy of Sciences)","volume":"59 1","pages":"97 - 102"},"PeriodicalIF":0.5,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142175754","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of Magnetic Field on the Electron States in CdSe Nanoplatelets with Impurities 磁场对含杂质硒化镉纳米片中电子态的影响
IF 0.5 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1134/S1068337224700154
D. A. Baghdasaryan, A. A. Nahapetyan, V. A. Harutyunyan, H. A. Sarkisyan

In the presence of the axial magnetic field, the behavior of the electron in the colloidal CdSe nanoplatelet containing multi-impurity centers has been investigated. The two-dimensional Schrodinger equation with the effective potential of the interaction of electron and impurity centers, localized in the central plane of the nanoplatelet has been obtained. It has been shown that the magnetic field influence on the electron energy levels weakens with increasing the number of impurities.

摘要 在轴向磁场的作用下,研究了电子在含有多杂质中心的胶体碲化镉纳米微粒中的行为。得到了电子与杂质中心相互作用的有效势能的二维薛定谔方程,该势能位于纳米板的中心平面。研究表明,磁场对电子能级的影响随着杂质数量的增加而减弱。
{"title":"Influence of Magnetic Field on the Electron States in CdSe Nanoplatelets with Impurities","authors":"D. A. Baghdasaryan,&nbsp;A. A. Nahapetyan,&nbsp;V. A. Harutyunyan,&nbsp;H. A. Sarkisyan","doi":"10.1134/S1068337224700154","DOIUrl":"10.1134/S1068337224700154","url":null,"abstract":"<p>In the presence of the axial magnetic field, the behavior of the electron in the colloidal CdSe nanoplatelet containing multi-impurity centers has been investigated. The two-dimensional Schrodinger equation with the effective potential of the interaction of electron and impurity centers, localized in the central plane of the nanoplatelet has been obtained. It has been shown that the magnetic field influence on the electron energy levels weakens with increasing the number of impurities.</p>","PeriodicalId":623,"journal":{"name":"Journal of Contemporary Physics (Armenian Academy of Sciences)","volume":"59 1","pages":"115 - 121"},"PeriodicalIF":0.5,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142175758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Journal of Contemporary Physics (Armenian Academy of Sciences)
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1