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2011 Annual Report Conference on Electrical Insulation and Dielectric Phenomena最新文献

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Electrochemical capacitances of carbon powder treated with dielectric barrier discharge 介质阻挡放电处理炭粉的电化学电容
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232608
D. Tashima, R. Hirakawa, T. Sakoda, M. Otsubo
Powdery activated carbons were treated using dielectric barrier discharge. In comparison with low pressure plasma, dielectric barrier discharge operated at atmospheric pressure can dramatically reduce the processing time and does not need vacuum equipment. In this study, electrochemical properties of Electric Double Layer Capacitors (EDLCs) made of oxygen plasma-treated powdery activated carbons were examined through Cyclic Voltammetry (CV), cole-cole plots and X-ray Photoelectron Spectroscopy (XPS). It was found that the specific capacitance of EDLCs could be improved by using oxygen plasma-treated activated carbon powder. A comparison of EDLCs using carbon powder treated for 15 S versus untreated EDLCs shows a 20% increase in specific capacitance, which indicates that the plasma treatment for EDLC's carbon powder are suitable for high-energy applications. The enhancement of capacitance was mainly attributed to an increase in the BET surface area of the carbon powder and the creation of phenolic hydroxyl groups on the surface of the carbon. The phenolic hydroxyl groups caused oxidation-reduction reactions, because oxygen was included in the operation gas. In addition, the phenolic hydroxyl groups improved the penetration of the electrolyte solution.
采用介质阻挡放电处理粉状活性炭。与低压等离子体相比,在常压下进行介质阻挡放电可以大大缩短处理时间,并且不需要真空设备。采用循环伏安法(CV)、cole-cole图和x射线光电子能谱法(XPS)研究了氧等离子体处理粉末活性炭制备的双电层电容器(edlc)的电化学性能。研究发现,氧等离子体处理的活性炭粉可以提高edlc的比电容。经过15 S碳粉处理的EDLC与未经处理的EDLC相比,比电容增加了20%,这表明等离子体处理的EDLC碳粉适用于高能应用。电容的增强主要是由于碳粉的BET表面积的增加和碳表面酚羟基的形成。酚羟基引起氧化还原反应,因为操作气体中含有氧气。此外,酚羟基提高了电解质溶液的渗透性。
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引用次数: 0
DC breakdown characteristic on LDPE/MgO nanocomposite influenced by DC prestress 直流预应力对LDPE/MgO纳米复合材料直流击穿特性的影响
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232664
Y. Murakami, S. Imazawa, M. Kurimoto, M. Nagao, Y. Inoue, C. Reddy, Y. Murata
To understand the space charge formation of low-density polyethylene (LDPE)/nano-sized magnesium oxide (MgO) nanocomposite materials, the breakdown strength and the space charge formation influenced by DC prestress were investigated. DC breakdown strength (Fb) of LDPE decreased with increase of DC prestress. A packet-like charge was observed under DC pre-stress. When the applied field turned to a ramp field from a constant field, the space charge decreased with incase of applied field. A packet-like charge, enhancing the local filed in bulk, might bring to many dissociated carrier. Therefore, it was considered that DC-Fb of LDPE decreased with increase of DC pre-stress field because bulk of LDPE became more conductive condition by generation of a packet like charge. On the other hand, DC-Fb of LDPE/MgO nanocomoposite increased with increase of DC pre-stress field. In case of MgO content of 1 phr, a packet-like charge was not observed under DC pre-stress field and a little positive space charge was formed in the bulk The positive charge decrease gradually with increase of ramp filed. When the MgO content was 5 phr, little space charge was observed under DC constant or ramp fields. The MgO nanofiller may trap the space charge, and the homo space charge in the vicinity of electrodes suppressed the carrier injection.
为了解低密度聚乙烯(LDPE)/纳米氧化镁(MgO)纳米复合材料的空间电荷形成,研究了直流预应力对材料击穿强度和空间电荷形成的影响。LDPE的直流击穿强度(Fb)随直流预应力的增大而减小。在直流预应力下,观察到包状电荷。当外加电场由恒定电场变为斜坡电场时,空间电荷随外加电场的增大而减小。一个包状电荷可以大量增强局部电场,从而产生许多解离的载流子。因此,可以认为LDPE的DC- fb随着直流预应力场的增大而减小,这是由于LDPE通过产生包状电荷而使大部分的LDPE变得更具有导电性。另一方面,LDPE/MgO纳米复合材料的DC- fb随直流预应力场的增大而增大。当MgO含量为1 phr时,在直流预应力场作用下未观察到包状电荷,在体中形成少量的正空间电荷,正电荷随着斜坡电场的增大而逐渐减少。当MgO含量为5 phr时,在直流常数场和斜坡场下几乎没有观察到空间电荷。MgO纳米填料可以捕获空间电荷,电极附近的homo空间电荷抑制载流子注入。
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引用次数: 2
Dielectric properties of colossal permittivity materials: An update 巨介电常数材料的介电特性:更新
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232754
C. Cheballah, Z. Valdez-Nava, L. Laudebat, T. Lebey, P. Bidan, S. Diaham, S. Guillemet-Fritsch
During the last ten years, a lot of interest has been devoted to the so-called colossal dielectric constant (CDC) material. The first materials exhibiting this behavior were the perovskyte-based ceramics based on the CaCu3Ti4O12 composition (CCTO). Relative dielectric permittivity can attain values up to (or even larger than) 105. Nevertheless, their losses are still high, the lower values ranging 10%, in a narrow frequency range, thus limiting their applications. Most work on this type of materials aims to reduce these losses and widen their useful frequency range. On the other hand, the underlying physical mechanisms responsible of the CDC are still under study. While the analysis of broadband impedance spectroscopy measurements leads most of the authors to propose an interfacial polarization mechanisms (at the electrodes or at internal barriers), there is a limited number of complementary electrical characterization techniques, for the moment, they comfort the proposed interfacial polarization mechanisms. In the present work, several characterization techniques like I-V, Sawyer-Tower (ST) measurements, and time-domain polarization are used to characterize these materials. One of our main results is the observation of a non-symmetrical response of these materials related to the direction of the polarization. These results are observed for both macroscopic level on bulk polycrystalline material and within individual grains of the same samples. These results do not fit current accepted models for polarization for CDC materials.
在过去的十年中,人们对所谓的巨介电常数(CDC)材料产生了浓厚的兴趣。首先表现出这种行为的材料是基于CaCu3Ti4O12成分(CCTO)的钙钛矿基陶瓷。相对介电常数可以达到(甚至大于)105。然而,在较窄的频率范围内,它们的损耗仍然很高,最低值为10%,从而限制了它们的应用。这类材料的大部分工作旨在减少这些损耗并扩大其有效频率范围。另一方面,疾病预防控制中心的基本物理机制仍在研究中。虽然对宽带阻抗谱测量的分析导致大多数作者提出界面极化机制(在电极或内部势垒处),但目前有有限数量的互补电表征技术,它们安慰了所提出的界面极化机制。在目前的工作中,一些表征技术,如I-V,索耶塔(ST)测量和时域极化被用来表征这些材料。我们的主要结果之一是观察到这些材料的非对称响应与极化方向有关。这些结果既可以在宏观水平上观察到块状多晶材料,也可以在同一样品的单个颗粒内观察到。这些结果不符合目前公认的CDC材料极化模型。
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引用次数: 4
Experienced gained from 132 kV EPDM composite insulators in a coastal environment 从132千伏EPDM复合绝缘子在沿海环境中获得经验
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232668
S. Rowland, A. Tzimas, M. Queen
A number of EPDM insulators have been taken from service on a 132 kV system after eight years in a harsh environment and have been examined. Fortuitously three different insulator designs are available and compared. Two of the insulators were installed in a vertical orientation and one in the horizontal. The insulators are characterized visually, electrically and for hydrophobicity. They have been found to be fit for purpose, but show extensive superficial ageing, in particular blackening, of the polymer surfaces. No severe degradation has been identified. In particular there is evidence of discharge activity around the prominent longitudinal mould lines on all the insulators.
一些EPDM绝缘子在恶劣环境中运行了8年后,已经从132千伏系统中取出并进行了检查。幸运的是,有三种不同的绝缘体设计可供比较。两个绝缘子安装在垂直方向,一个安装在水平方向。绝缘体具有视觉、电学和疏水性的特点。它们已经被发现适合使用,但显示出广泛的表面老化,特别是聚合物表面变黑。没有发现严重退化。特别是在所有绝缘子上突出的纵向模具线周围有放电活动的证据。
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引用次数: 0
Effect of epoxy coating on particle movement in SF6/N2 gas insulated Busduct 环氧涂层对SF6/N2气体绝缘管道中颗粒运动的影响
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232634
M. Rao, J. Amarnath
Due to an exceptional combination of physical and chemical properties, SF6 has become the only insulating gas used in gas insulated electric power transmission and distribution equipment. However, the fact that SF6 is one of the strongest man made greenhouse gases has promised a search for substitute gases with lower or no environmental impact. Thus, it is needed to develop the alternative dielectric gas or gas mixtures having better insulating characteristics and no greenhouse effect. The main issue concerning the practical use of such mixtures is their behavior in the presence of metallic particle contamination. In this paper particle movement is determined in epoxy coated gas insulated Busduct with SF6 and N2 gas mixtures as insulating medium. In the gas mixture, conducting particle material considered for study are Aluminium, Copper and Silver. The results have been analyzed and presented.
由于SF6特殊的物理和化学特性组合,SF6已成为气体绝缘输配电设备中唯一使用的绝缘气体。然而,SF6是最强的人造温室气体之一,这一事实使人们有希望寻找对环境影响较小或没有影响的替代气体。因此,需要开发绝缘性能更好、无温室效应的替代介质气体或混合气体。实际使用这种混合物的主要问题是它们在存在金属颗粒污染时的行为。本文以SF6和N2混合气体为绝缘介质,测定了环氧涂层气体绝缘管道中颗粒的运动。在气体混合物中,考虑研究的导电颗粒材料有铝、铜和银。对结果进行了分析和介绍。
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引用次数: 0
Impact of spacers regarding endwinding design of large rotating electrical machines 隔片对大型旋转电机端部设计的影响
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232713
M. Lerchbacher, D. Imamović, G. Lemesch, F. Ramsauer, M. Muhr
Today large rotating electrical machines are supposed to operate at optimised conditions and the highest degree of efficiency. Often the overall size of a generator has a significant impact on transport restrictions as well as cost efficiency. A key market requirement is a combination of high efficiency, very compact design and cost efficiency of acquisition and operation. One of the main elements to meet these demands is an optimised endwinding design of high voltage stator windings. A compact design requires among other things minimised distances between adjacent insulated bars or coils in the endwinding which consequently leads to a continuously increasing stress (thermal, electric) on spacers located in the endwinding area. Therefore the influence of spacers on the corona behaviour of air and hydrogen is the main focus for high voltage insulation stator winding design, especially in relation to the endwinding. The end winding area has to be designed in such a way that no corona activity can occur during the operation of the generator. On the one hand the distances between adjacent bars or coils should be as small as possible while on the other hand any corona activity should be avoided. In this paper the results of experimental investigations in air and hydrogen for electrode-spacer configurations are presented. Metallic electrodes were covered with standard insulation material which is used in generators. The test arrangement allowed changing the gas pressure whereas the gap distance between the electrodes was defined by the used spacer. To determine the corona inception and extinction voltage we used a conventional PD measurement system according to the IEC 60270 standard. Additionally for verification of our results we used acoustical (ultrasonic microphone) and optical (UV camera) PD detection systems. The purpose of this study was to determine the influence of spacers on partial discharge behaviour (corona inception and extinction voltage) of insulating systems used in endwinding areas. On the basis of gas physics and our previous studies we expected a decreasing corona inception and extinction voltage by increasing pressure and gap distance for spacer configurations. This is in comparison with configurations without spacers. In our experiments we were able to corroborate this. However, to formulate a conclusive relationship between the influences of spacers on PD inception level, further work needs to be done.
今天,大型旋转电机应该在优化的条件下运行,并具有最高的效率。通常,发电机的总体尺寸对运输限制和成本效率有重大影响。一个关键的市场需求是高效率,非常紧凑的设计和成本效益的采购和操作的组合。满足这些要求的主要因素之一是高压定子绕组的优化端绕组设计。紧凑的设计要求在相邻的绝缘棒或线圈之间的距离最小化,从而导致位于端绕区域的间隔片上的应力(热、电)不断增加。因此,隔离器对空气和氢气的电晕行为的影响是高压绝缘定子绕组设计的主要焦点,特别是与端绕组有关。末端绕组区域必须以这样一种方式设计,即在发电机运行期间不会发生电晕活动。一方面,相邻电棒或线圈之间的距离应尽可能小,另一方面,应避免任何电晕活动。本文介绍了在空气和氢气中电极-间隔层结构的实验研究结果。金属电极用发电机中使用的标准绝缘材料覆盖。测试安排允许改变气体压力,而电极之间的间隙距离由使用的垫片定义。为了确定电晕起始电压和消光电压,我们使用了符合IEC 60270标准的传统PD测量系统。此外,为了验证我们的结果,我们使用了声学(超声波麦克风)和光学(UV相机)PD检测系统。本研究的目的是确定隔离器对端绕区绝缘系统局部放电行为(电晕起始和消光电压)的影响。根据气体物理学和我们之前的研究,我们期望通过增加间隔配置的压力和间隙距离来降低电晕起始和消光电压。这是与没有间隔的配置相比较。我们在实验中证实了这一点。然而,为了确定间隔剂对PD起始水平的影响之间的结论性关系,还需要进一步的工作。
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引用次数: 0
UHF detection of PD in power transformers: The influence of disturbances 电力变压器中PD的超高频检测:干扰的影响
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232688
A. Cavallini, C. G. A. Ramos, G. Montanari, H. Saad, M. Tozzi
Ultra-high frequency partial discharge sensors are often deemed to be immune to disturbance, i.e., signals generated by partial discharge sources outside the transformer itself. In this paper, the above claim is investigated resorting to both computer simulations and experimental tests. The results indicate that corona from power lines in proximity of a transformer, or surface discharges on the surface of bushings can provide signals that are comparable with those generated by PD sources. These findings suggest that care must be taken when evaluating data coming from this type of sensors, as false alarms can be obtained.
超高频局部放电传感器通常被认为不受干扰,即由变压器本身以外的局部放电源产生的信号的影响。本文通过计算机模拟和实验测试对上述说法进行了研究。结果表明,靠近变压器的电晕或套管表面的表面放电可以提供与PD源产生的信号相当的信号。这些发现表明,在评估来自这类传感器的数据时必须小心,因为可能会产生假警报。
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引用次数: 5
Mechanical properties of polypropylene nano-composites: An investigation about the correlation with space charge measurements 聚丙烯纳米复合材料的力学性能:与空间电荷测量的相关性研究
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232748
F. Guastavino, E. Torello, G. Coletti, Z. Vuluga, D. Panaitescu, S. Iancu
Sets of nanostructured PP films have been prepared using various techniques and procedures. They have been subjected to mechanical tests (stress-strain curves and to impact strength tests) and have been subjected to electrical space charge tests by means of Pulse ElectroAcoustic techniques. Suitable analysis about the relevant correlations were performed and did produce results useful from the quality control point of view and interesting as regards the production process tuning.
采用各种技术和程序制备了纳米结构的PP薄膜。它们经过了机械试验(应力-应变曲线和冲击强度试验),并通过脉冲电声技术进行了空间电荷试验。对相关的相关性进行了适当的分析,从质量控制的角度来看,确实产生了有用的结果,并且在生产过程调整方面很有趣。
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引用次数: 0
Three-dimensional tree simulation considering interfaces with various angles of inclination to electric force line 考虑不同电力线倾角界面的三维树形仿真
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232772
Y. Ju, H. Uehara, K. Kudo
We previously carried out a three-dimensional (3D) tree simulation of a composite system with an interface perpendicular or parallel to the electric force line based on a dielectric breakdown model considering the growth probability. It was found that an interface perpendicular to the electric force line exhibits a positive barrier effect and that an interface parallel to the electric force line exhibits a negative barrier effect. In this study, we carried out a 3D tree simulation that considers interfaces having various angles of inclination to the electric force line, for which different barrier effects were observed. Furthermore, the simulated tree with interfaces having various angles of inclination either creeps on the barrier, penetrates the barrier or develops along the edge of the barrier.
我们之前基于介电击穿模型,考虑生长概率,对一个界面垂直或平行于电力线的复合材料系统进行了三维树形模拟。结果表明,垂直于电力线的界面具有正势垒效应,平行于电力线的界面具有负势垒效应。在这项研究中,我们进行了三维树形模拟,考虑了与电力线有不同倾角的界面,观察到不同的屏障效应。此外,具有不同倾角界面的模拟树或在屏障上爬行,或穿透屏障,或沿屏障边缘发育。
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引用次数: 2
Comparison between RF and electrical signals from the partial discharge activity of twisted pair cables at reduced pressures 减压双绞线电缆局部放电活动射频信号与电信号的比较
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232707
M. Given, R. Mason, M. Judd, P. McGlone, I. Timoshkin, M. Wilson
A pressure-controlled test facility has been set up that allows the PD behaviour of polymer insulated twisted pair samples exposed to 50 Hz AC voltages in the range of 0 to 10 kV to be characterised. Resulting PD activity is quantified using the methods defined in IEC standard 60270 and by using a simple monopole antenna to detect the RF signals excited inside the pressure vessel by the discharges. This paper gives the results of preliminary tests performed on samples of wire insulated with Ethylenetetraflourethylene, Silicon Rubber and Polyvinylchloride in the pressure range between 103 and 105 Pa in atmospheric air. The dependence of PD inception voltage on the environmental pressure is reported. Changes in the behaviour of the PD activity; the correlations between the RF and electrical measurements and the frequency components of the RF signals as the applied voltage and pressure are varied are characterised and discussed.
建立了一个压力控制测试设备,可以对暴露在0至10 kV范围内的50 Hz交流电压下的聚合物绝缘双绞线样品的PD行为进行表征。使用IEC标准60270中定义的方法和使用简单的单极天线来检测放电在压力容器内激发的射频信号,从而量化PD活度。本文给出了用乙烯四氟乙烯、硅橡胶和聚氯乙烯绝缘的电线样品在103 ~ 105pa大气压范围内的初步试验结果。本文报道了局部放电起始电压与环境压力的关系。PD活动行为的改变;描述和讨论了射频和电测量之间的相关性以及射频信号的频率成分随施加电压和压力的变化。
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引用次数: 2
期刊
2011 Annual Report Conference on Electrical Insulation and Dielectric Phenomena
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