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2011 Annual Report Conference on Electrical Insulation and Dielectric Phenomena最新文献

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Corona resistance of epoxy nanocomposites 环氧纳米复合材料的耐电晕性能
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232658
G. Iyer, R. Gorur, A. Krivda, V. H. Camara
Epoxy composites with micro, nano and micro + nano silica fillers have been evaluated for their resistance to corona using point plane electrodes. The experiments were conducted for 500 hours and the surface erosion was measured after every 100 hours using a surface profilometer. The results show significant improvement in corona resistance of micro+nanofilled samples and nanofilled samples when compared with the microfilled samples and unfilled materials respectively. The results emphasize the importance of good filler dispersion.
采用点平面电极对微、纳米和微+纳米二氧化硅填料的环氧复合材料的抗电晕性能进行了评价。实验进行500小时,每隔100小时使用表面轮廓仪测量表面侵蚀。结果表明:微+纳米填充样品和纳米填充样品的电晕电阻分别比微填充样品和未填充材料有显著提高;结果强调了填料良好分散的重要性。
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引用次数: 1
Effect of cumylalcohol in XLPE on space charge formation and electric breakdown under DC high electric field 交联聚乙烯中茴香醇对直流强电场下空间电荷形成和电击穿的影响
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232617
N. Hayashi, H. Suzuki, H. Miyake, Y. Tanaka, T. Maeno
For an insulation layer of a DC power transmission cable, space charge properties of various insulating materials have been investigated using pulsed electro acoustic (PEA) method. Especially, cross-linked polyethylene (XLPE), which has an improved heating resistance by forming a bridge between molecular chains of low density polyethylene (LDPE), is expected to be applied to the insulating layer of the cable. So, the insulating performance of XLPE under high DC stress is important. In the bulk of XLPE layer for power cables, there remain some chemical residues of crosslinking by-product such as acetophenone, α-methylstyrene, and cumylalcohol. Such residues are thought to affect the breakdown strength and space charge behavior in the insulating layer under dc high electric field. Therefore, we have examined the effect of each remaining chemical by-product in LDPE under dc high electric field. In this report, to investigate the effect of cumylalcohol, one of cross-linking by-product, on space charge formation and electric breakdown characteristics in XLPE, we tried to observe the space charge accumulation in XLPE with cumylalcohol under very high dc stress. As the results, it is found a curious and quite interesting space charge formation. In the material, an apparent backward flow of a negative packet-like charge against the electric field is observed. The performance of the packet-like charge is like a “Pororoca” in Amazon River. Furthermore, the relatively low dc breakdown strength was observed in the material. It seems to be a certain relationship between the “Pororoca” and the lower breakdown strength. In this report, the curious phenomena is mainly introduced.
针对直流输电电缆绝缘层,采用脉冲电声(PEA)方法研究了不同绝缘材料的空间电荷特性。特别是交联聚乙烯(XLPE),它通过在低密度聚乙烯(LDPE)分子链之间形成桥接而提高了耐热性,有望应用于电缆的绝缘层。因此,交联聚乙烯在高直流应力下的绝缘性能非常重要。在电力电缆用交联聚乙烯(XLPE)层中,大部分存在交联副产物苯乙酮、α-甲基苯乙烯、cumylalcohol等化学残留物。在直流强电场作用下,这些残馀会影响绝缘层的击穿强度和空间电荷行为。因此,我们研究了直流强电场作用下LDPE中各剩余化学副产物的影响。为了研究交联副产物cumyl醇对XLPE中空间电荷形成和电击穿特性的影响,我们尝试观察了在非常高的直流应力下,cumyl醇在XLPE中的空间电荷积累。结果发现了一种奇特而有趣的空间电荷形成。在材料中,观察到一个负的包状电荷对电场的明显反向流动。包式收费的表现就像亚马逊河上的“Pororoca”。此外,该材料的直流击穿强度相对较低。“Pororoca”与较低的击穿强度之间似乎存在一定的关系。在这篇报道中,主要介绍了一些奇怪的现象。
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引用次数: 14
High temperature aging of enameled copper wire — Relationships between chemical structure and electrical behavior 漆包线的高温老化。化学结构与电性能的关系
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232602
B. Petitgas, G. Seytre, O. Gain, G. Boiteux, I. Royaud, A. Serghei, A. Gimenez, A. Anton
This work presents the physico-chemical behavior of several enameled copper wires systems such as PolyEsterImide (PEI)/PolyAmideImide (PAI) or PAI based multi layers compared to PolyImide (PI) which remains the basic enamel material for high temperature applications. The structural, thermal and electrical properties of these systems have been investigated before and after aging in the 200°C-400°C temperature range by thermogravimetric analysis (TGA), ATR-FTIR microscopy, thermomechanical analysis (TMA) and dielectric relaxation spectroscopy (DRS). It has been particularly interesting to carry out physico-chemical analysis directly on enameled wires to improve the understanding of their thermal and electrical behaviour. Dielectric spectroscopy has indicated a loss of insulating properties during the thermal cycle especially for PEI-containing enamels whereas the properties of PI and PAI have been maintained. TGA and IR analyses have not only allowed confirming the PI and PAI high thermal performances, but have also given information on the thermal and chemical stability of PEI/PAI. Such investigations could be helpful for improving the enameled wire high temperature performances.
这项工作介绍了几种漆包铜线系统的物理化学行为,如聚酯酰亚胺(PEI)/聚酰胺酰亚胺(PAI)或基于PAI的多层,而聚酰亚胺(PI)仍然是高温应用的基本搪瓷材料。通过热重分析(TGA)、ATR-FTIR显微镜、热力学分析(TMA)和介电弛豫光谱(DRS)研究了这些体系在200°C-400°C温度范围内老化前后的结构、热学和电学性能。直接对漆包线进行物理化学分析以提高对其热学和电学行为的理解是特别有趣的。介电光谱表明,在热循环过程中,特别是对于含PI的搪瓷,绝缘性能会损失,而PI和PAI的性能却保持不变。热重分析和红外光谱分析不仅证实了PEI和PAI的高热性能,而且还提供了PEI/PAI的热稳定性和化学稳定性的信息。这些研究有助于提高漆包线的高温性能。
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引用次数: 16
Internal charging phenomena and change of electrical properties in electron beam irradiated insulating materials for spacecraft
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232612
K. Yagai, H. Miyake, Y. Tanaka, T. Takada
The purpose of our research work is to evaluate some electrical properties of electron beam irradiated insulating materials for spacecraft. The spacecraft like a communication or a broadcasting satellite flying in GEO (Geostationary Orbit) is always exposed to plasma and/or radioactive-rays such as α-, β-, and γ-rays. When the insulating materials, in which the spacecraft is wrapped to keep temperature in it stable, are irradiated by the high energy electron beam, sometimes an unexpected accident due to an electrostatic discharge occurs. The accident sometimes causes a serious mission error of spacecraft. However, it has not known how the irradiation affects to the electrical properties of the materials. In our previous research work, we especially focused on an internal charging phenomenon which must affect to the electrical properties of irradiated polymers for spacecraft such as Polyimide (PI) and Polytetrafluoroethylene (PTFE). Judging from the measurement results, it is found that an amount of negative charge accumulation in PTFE is much larger than that in PI. It seems that the charge accumulation in polymers including fluorine by irradiation of electron beam is larger than that in other polymeric materials. Furthermore, the accumulated charge in the polymer including fluorine remains for long time after irradiation. Such results indicate that the electrical properties are changed by the irradiation. Therefore, we tried to compare the charge accumulation properties between the irradiated and non-irradiated polymeric materials including fluorine. By applying dc stress to them, space charge accumulation processes in various irradiated materials are observed. From the results, it is found that the charge accumulation processes in irradiated materials are completely different from the non-irradiated materials.
本文的研究目的是评价航天器用电子束辐照绝缘材料的一些电学性能。在地球静止轨道上飞行的通信或广播卫星等航天器总是暴露在等离子体和/或放射性射线(如α-, β-和γ射线)下。当包裹航天器以保持其内部温度稳定的绝缘材料受到高能电子束照射时,有时会发生由于静电放电而导致的意外事故。这种事故有时会导致航天器的严重任务错误。然而,辐照对材料电性能的影响尚不清楚。在我们之前的研究工作中,我们特别关注了一种内部充电现象,这种现象会影响聚酰亚胺(PI)和聚四氟乙烯(PTFE)等航天器用辐照聚合物的电学性能。从测量结果来看,PTFE中的负电荷积累量远大于PI。电子束辐照下含氟聚合物的电荷积累似乎比其他聚合物大。此外,含氟聚合物中的累积电荷在辐照后可长时间保留。这些结果表明辐照改变了材料的电学性质。因此,我们试图比较辐照和未辐照的含氟高分子材料的电荷积累特性。通过对其施加直流应力,观察了不同辐照材料的空间电荷积累过程。结果表明,辐照材料中的电荷积累过程与未辐照材料完全不同。
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引用次数: 2
Design of a high voltage penetrator for high pressure and temperature laboratory testing 高压高温实验室测试用高压穿透器的设计
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232648
J. Aakervik, G. Berg, S. Hvidsten
High voltage apparatus and reliable power supply are of vital importance for subsea processing. The purpose of this work has been to develop a small high voltage penetrator for use with high pressure vessels in the laboratory. Such equipment can facilitate high voltage and current testing of models and materials at relevant subsea conditions. It is shown that the penetrator can withstand a hydrostatic differential pressure of 500 bars and 90°C for more than 6 months. The breakdown voltage of the penetrator is only limited by the model cable used in the design, making it attractive to use high voltage class cables. Sensitive partial discharge measurements of pressurized test objects can be implemented by using adapted oil-filled terminations.
高压设备和可靠的电源是海底处理的关键。这项工作的目的是开发一种用于实验室高压容器的小型高压穿透器。这种设备可以方便地在相关海底条件下对模型和材料进行高压和电流测试。结果表明,该穿甲弹可承受90℃、500 bar的静水压差6个月以上。穿透器的击穿电压仅受设计中使用的型号电缆的限制,因此使用高压级电缆具有吸引力。通过使用合适的充油终端,可以实现对受压试验对象的敏感局部放电测量。
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引用次数: 6
Researched on microstructure and density of sintered ZnO non-linear resistors 研究了烧结ZnO非线性电阻器的微观结构和密度
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232624
Chuntian Chen, Haifeng Xiao, J. Zou, Ru Wang, Hanfei Zhu, Xianyou Zhang
Systematic researched have been made of the grain growth and density of sintered ZnO-based systems containing one or more additive oxides of the type Bi2O3, MnO2, and CoO. These samples were characterized using such techniques as scanning electron microscopy. The influence of the nature and amount of additive oxides and sintering temperature at 950 to 1350°C is discussed in relation to microstructure, breakdown voltage and the density present.
对含有Bi2O3、MnO2和CoO等一种或多种氧化物的烧结zno基体系的晶粒生长和密度进行了系统的研究。这些样品用扫描电子显微镜等技术进行了表征。讨论了氧化物添加剂的性质和用量以及烧结温度(950 ~ 1350℃)对微观组织、击穿电压和密度的影响。
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引用次数: 0
Effect of gamma-ray irradiation on lateral charge motion on surface of laminated polymer insulating materials 射线辐照对层合聚合物绝缘材料表面横向电荷运动的影响
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232619
Y. Gao, B. Du, J. Cui, K. Wu
Polymer insulating materials installed in electronic and electrical devices have been used in space equipment and nuclear power station where the materials are exposed to high energetic radioactive rays. The molecular structure can be changed by radiation induced chemical reactions that possibly lead to the variation of characteristics of surface charge dynamics, which in turn influences the safe use of the devices. From the viewpoint of safety, it is essential to have a firm understanding of radiation effect on the surface charge behavior. This paper presents study aimed at clarifying gamma-ray irradiation effect on lateral charge decay on surface of epoxy resin. The samples were irradiated in air up to 100 kGy and then up to 1000 kGy with dosage rate of 10 kGy/h by using a 60Co gamma-source in advance of the test. Surface charge was introduced by corona charging and the decay behavior was examined with an electrostatic voltmeter. Isothermal surface potential decay was also performed to verify the lateral charge motion. Obtained results show that the lateral motion of charge is encouraged by the irradiation. It is suggested that the lateral charge decay is dependent upon the characteristics of localized surface states that are altered by the degradation reaction occurred within surface layer of ER.
高分子绝缘材料安装在电子和电气设备中,已用于空间设备和核电站,这些材料暴露在高能放射性射线中。辐射诱导的化学反应可以改变分子结构,从而可能导致表面电荷动力学特性的变化,从而影响器件的安全使用。从安全的角度出发,有必要对辐射对表面电荷行为的影响有一个确切的认识。本文旨在阐明伽马射线辐照对环氧树脂表面横向电荷衰变的影响。试验前用60Co γ源先在空气中照射100 kGy,然后再以10 kGy/h的剂量率照射1000 kGy。采用电晕充电法引入表面电荷,并用静电伏特计测试了其衰减行为。用等温表面电位衰减来验证电荷的横向运动。结果表明,辐照促进了电荷的横向运动。结果表明,横向电荷衰减取决于内质网表层发生的降解反应所改变的局部表面态的特征。
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引用次数: 1
Effect of irreversible electroporation on cancer cells 不可逆电穿孔对癌细胞的影响
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232622
R. Sundararajan, Ramya Rajendran, Sajan S. Shahid, D. Santosh, S. Radhakrishnan, K. Priyadarshan, S. Varsha, U. Kumar, R. Ramachandran, K. Sankaranarayanan
Cancer remains responsible for several million deaths each year, occurring worldwide. The conventional treatment strategies for cancer cause a plethora of side effects along with an exorbitant treatment cost per sitting. The focus now is on the development of new modalities of treatments which could minimize the side effects and prove to be an affordable treatment option to the patients. Usage of electrical pulses along with drugs - Electrochemotherapy (ECT) is a fast rising option for the treatment of chemo-refractive cancers. This has proven to be more efficient and effective than other existing methods of treatment and there is a growing evidence of research and clinical trials on the same. The major advantage that this mode of treatment offers is the massive reduction in the dosage of drug that is administered, thus significantly reducing the intensity of undesired side effects. The applied electrical pulses can be of two types - that for reversible and irreversible electroporation of cells. While reversible electroporation is primarily used as a means for delivery of molecules into the cell, irreversible electroporation is a mode which could be applied as such in the absence of a chemodrug to kill the cancerous cells. This would be of immense significance in the clinical scenario since it could be targeted treatment while totally eliminating the necessity of any chemodrug. In this paper we give a detailed report on the effect of such high voltage pulses on cancer cells. The variables tested out in the pulse parameters used include intensity of electric field applied, pulse duration, number of pulses and time interval between each train. The electric field applied is varied between 500V/cm to 2500V/cm with a pulse duration ranging from microseconds to milliseconds to keep the energy delivery constant. The effect of the parameters individually and effect of combination of all these parameters on the cells is studied and discussed in this paper. This study could be of clinical relevance in the translation of these findings to application at the patient-level.
癌症每年仍在全世界造成数百万人死亡。传统的癌症治疗策略会产生过多的副作用,而且每次的治疗费用也很高。现在的重点是开发新的治疗方式,以尽量减少副作用,并证明是患者负担得起的治疗选择。电脉冲与药物的结合使用——电化疗(ECT)是治疗化学屈光性癌症的一种快速发展的选择。事实证明,这种方法比其他现有的治疗方法更有效,而且有越来越多的证据表明,对这种方法进行了研究和临床试验。这种治疗方式的主要优点是大大减少了所施用药物的剂量,从而大大减少了不希望出现的副作用的强度。应用的电脉冲可以有两种类型-可逆和不可逆的细胞电穿孔。可逆电穿孔主要用于将分子传递到细胞中,而不可逆电穿孔是一种可以在没有化学药物杀死癌细胞的情况下应用的模式。这将在临床场景中具有巨大的意义,因为它可以作为靶向治疗,同时完全消除任何化疗药物的必要性。在本文中,我们详细报道了这种高压脉冲对癌细胞的影响。在脉冲参数中测试的变量包括施加的电场强度、脉冲持续时间、脉冲数和每列之间的时间间隔。施加的电场在500V/cm到2500V/cm之间变化,脉冲持续时间从微秒到毫秒不等,以保持能量传递恒定。本文研究和讨论了各参数的单独作用和各参数的组合作用对细胞的影响。本研究可能具有临床相关性,将这些发现转化为患者水平的应用。
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引用次数: 9
The dielectric permittivity of ceramic powders used in composite polymers 复合聚合物中陶瓷粉末的介电常数
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232756
C. V. Bouanga, S. Savoie, H. Couderc, M. Frechette, É. David
The aim of this study is to measure the complex dielectric constant over a wide range of frequencies for ceramic powders often used as additives in polymer composites. The dielectric responses of alumina and boron nitride powders are presented. The variation of the dielectric constant in the studied frequency range (10-1 Hz to 10 kHz) showed that there is absorption of the water on the surface of the powder. Therefore, different treatments were applied: heating at 100°C for 48 hours and under vacuum at room temperature. A significant change on the value of the permittivity at low frequency has been observed after treatment. By comparing the results obtained before and after treatment, the dielectric response of the powder measured under vacuum showed stability over the studied frequency range at room temperature. The measured values of the permittivity of the powder were used to estimate those of the bulk material using a mixing law. This situation is discussed.
本研究的目的是在广泛的频率范围内测量陶瓷粉末作为聚合物复合材料添加剂的复介电常数。介绍了氧化铝和氮化硼粉末的介电响应。在研究频率范围内(10-1 Hz ~ 10 kHz)介电常数的变化表明,粉末表面存在对水的吸收。因此,采用了不同的处理方法:在100°C下加热48小时和在室温下真空。经处理后,观察到低频时介电常数值有显著变化。通过对比处理前后的结果,真空下测得的粉末在室温下的介电响应在所研究的频率范围内是稳定的。利用粉末介电常数的测量值,利用混合定律来估计块状材料的介电常数。讨论了这种情况。
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引用次数: 5
Electric field analysis at the triple junction of a optimum profile disc type spacer in SF6 gas insulated system with abnormalities under DC voltages 直流电压异常情况下SF6气体绝缘系统最佳剖面圆盘式隔片三结处电场分析
Pub Date : 2011-10-01 DOI: 10.1109/CEIDP.2011.6232635
D. Chowdary, J. Amarnath
In Gas Insulated Systems the breakdown strength of SF6 gas is badly affected by locally enhanced electric fields due to protrusions and delamination. Metal insert electrodes, which are used in GIS, reduces stresses near the triple junctions with simultaneous rise in the stresses elsewhere along spacer surface. AC-GIS are in operation for a long time but there is a limited knowledge for DC application. In the case of DC-GIS, charges invariably accumulate over a period of time along the spacer surface. The electric field distribution around solid spacer is greatly altered by the accumulated surface charges. In this work, the electric field distribution with DC as applied voltage is studied at the triple junction for a cone type spacer with and without metal insert along with the effect of delamination and protrusions on the surface of the insulator. Finite Element Method (FEM), one of the proven numerical method, is used for computing the electric fields at various points under consideration.
在气体绝缘系统中,由于SF6气体的突出和分层引起的局部增强电场严重影响其击穿强度。在GIS中使用的金属插入电极可以减少三连接点附近的应力,同时在间隔器表面的其他地方增加应力。交流地理信息系统已经运行了很长时间,但人们对直流应用的了解有限。在DC-GIS的情况下,电荷总是在一段时间内沿着隔离器表面积累。固体间隔片周围的电场分布会因表面电荷的积累而发生很大的变化。本文研究了带和不带金属嵌件的锥形隔片在三结处的电场分布,以及绝缘子表面的分层和凸点的影响。有限元法是一种已得到验证的数值计算方法,用于计算各考虑点处的电场。
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引用次数: 6
期刊
2011 Annual Report Conference on Electrical Insulation and Dielectric Phenomena
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