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2015 2nd International Symposium on Physics and Technology of Sensors (ISPTS)最新文献

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Room temperature NH3 sensing properties of Co-B-PANI nanocomposite films Co-B-PANI纳米复合膜的室温NH3传感性能
Pub Date : 2015-03-07 DOI: 10.1109/ISPTS.2015.7220073
U. Patil, N. Ramgir, A. Debnath, D. K. Aswal, S. Gupta, S. Gupta, N. Patel, D. Kothari
In the present work, we report the room temperature NH3 sensing properties of Cobalt-boride nanoparticles intercalated polyaniline (Co-B-PANI) nanocomposite films. Polyaniline nanocomposite films (PNCF's) have been deposited at room temperatures by in-situ oxidative polymerization of aniline in the presence of Co-B nanoparticles. The PNCF exhibited a highly selective, sensitive and reversible response towards NH3. It exhibited an improved response and recovery times of 3 and 345 s, respectively towards 50 ppm of NH3. The response time in the case of PNCF was found to be better than that exhibited by pure PANI-sensor-films (7 and 400 s). Raman measurements performed before and after the exposure towards NH3 indicated a strong variation in the intensity of the peak corresponding to C=N/C-N+ stretching vibrations. Good sensitivity along with the improved response and recovery times indicated Co-B-PANI nanocomposite film to be suitable for room temperature ammonia sensing applications.
在本工作中,我们报道了硼化钴纳米颗粒嵌入聚苯胺(Co-B-PANI)纳米复合膜的室温NH3传感性能。采用苯胺原位氧化聚合的方法,在室温下制备了聚苯胺纳米复合膜。PNCF对NH3具有高度选择性、敏感性和可逆性。当NH3浓度为50 ppm时,其响应时间和恢复时间分别提高了3 s和345 s。PNCF的响应时间比纯聚苯胺传感器膜的响应时间(7秒和400秒)要好。暴露于NH3前后的拉曼测量表明,C=N/C-N+拉伸振动对应的峰值强度有很大变化。良好的灵敏度以及改进的响应和恢复时间表明Co-B-PANI纳米复合膜适合于室温氨传感应用。
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引用次数: 0
Effect of addition of surfactant on LPG sensing properties of nano tin oxide based thick film sensors 表面活性剂对纳米氧化锡基厚膜液化气传感器传感性能的影响
Pub Date : 2015-03-07 DOI: 10.1109/ISPTS.2015.7220102
A. Garje
Nanocrystalline tin oxide powder is synthesized using sol gel method. To observe the effect of addition of surfactant on particle size, Sodium Dodecyl Sulphate (SDS) is added during the synthesis. The particle is found to be ~ 8 nm using TEM. The synthesized nanophase tin oxide powder is used to fabricate thick film sensors using screen printing technique. The sensor performance is tested for 100 ppm of LPG. The role of surfactant is observed to be responsible for remarkable improvement in sensitivity for LPG by 5 times with low operating temperature of 110 °c. The optical and structural characterization of powder and film is done using UV-Vis, XRD, SEM; TEM. The repeatability, response and recovery time of the sensors is studied.
采用溶胶-凝胶法制备了纳米氧化锡粉体。为了观察表面活性剂的加入对颗粒大小的影响,在合成过程中加入十二烷基硫酸钠(SDS)。通过透射电镜分析,发现该粒子的粒径为~ 8 nm。采用丝网印刷技术将合成的纳米氧化锡粉末用于制作厚膜传感器。在100ppm的LPG中测试传感器的性能。在低工作温度为110℃时,表面活性剂的作用使LPG的灵敏度提高了5倍。采用UV-Vis、XRD、SEM对粉末和薄膜进行了光学和结构表征;TEM。研究了传感器的重复性、响应性和恢复时间。
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引用次数: 1
Calibration and optimization of a metamaterial sensor for hybrid fuel detection 混合燃料检测用超材料传感器的标定与优化
Pub Date : 2015-03-07 DOI: 10.1109/ISPTS.2015.7220124
Vaishali Rawat, Vihang Nadkarni, Sangeeta Kale, Sushant Hingane, S. Wani, C. Rajguru
Simple, compact, robust and handy device for chemical sensing using microstrip-based metamaterial Complementary-Split-Ring-Resonator (CSRR) is proposed. A pseudo-microfluidic channel is fabricated upon the CSRR pattern to form the sensor. Combination of two liquids namely, ethanol and petrol, and their varying combinations are sensed for hybrid fuel applications. Simulation and experimental results for shifts in resonance frequency and magnitude are discussed. The results of fluidic approach are seen to be repeatable.
提出了一种简单、紧凑、坚固、方便的基于微带的超材料互补劈环谐振器(CSRR)化学传感装置。在CSRR模式上制作了一个伪微流控通道来形成传感器。两种液体的组合,即乙醇和汽油,以及它们的不同组合被用于混合燃料的应用。讨论了共振频率和幅度变化的仿真和实验结果。流体方法的结果被认为是可重复的。
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引用次数: 9
Effect of Mn substitution on acetone and ammonia sensing in CoFe2O4 nanoparticles 锰取代对CoFe2O4纳米颗粒中丙酮和氨传感的影响
Pub Date : 2015-03-07 DOI: 10.1109/ISPTS.2015.7220123
S. Sarkar, M. Bhatnagar
Mn has substituted part of Fe in cobalt ferrite (CoFe2O4) and resultant material has been abbreviated as CFMO (CoFe1.7Mn0.3O4). Chemical co-precipitation route has been followed for synthesis. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive x-ray spectroscopy (EDX), I-V measurement were performed for sample characterization. The influence of Mn substitution was seen in lowering the operating temperature for both acetone and ammonia gas sensing with high response as well as very fast response and recovery timealong with temperature dependent selectivity.
在钴铁氧体(CoFe2O4)中,Mn取代了部分Fe,生成的材料简称为CFMO (CoFe1.7Mn0.3O4)。采用化学共沉淀法合成。采用x射线衍射(XRD)、扫描电镜(SEM)、能量色散x射线能谱(EDX)、I-V测量等方法对样品进行表征。Mn取代对丙酮气敏和氨气敏的影响是降低操作温度,具有高响应、快速响应和恢复时间以及温度依赖的选择性。
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引用次数: 0
Al2O3 modified ZnO composite thick film for ethanol gas sensing 乙醇气敏用Al2O3改性ZnO复合厚膜
Pub Date : 2015-03-07 DOI: 10.1109/ISPTS.2015.7220135
Sapana Rane, S. Gosavi, S. Awate, Govind Uamrji, S. Arbuj, S. Rane
The Al2O3 modified ZnO nanostructure with 1:9 ratio was synthesized at 500°C using solid-state reaction technique. The prepared nanostructure material was characterized with XRD and FE-SEM technique. XRD indicate the formation of wurtzite phase of ZnO. FE-SEM confirms the formation of hexagonal shaped rod like morphology. The sensing characteristic of the material was tested using ethanol gas.
采用固相反应技术,在500℃下合成了比例为1:9的Al2O3修饰ZnO纳米结构。采用XRD和FE-SEM对制备的纳米结构材料进行了表征。XRD表明ZnO形成纤锌矿相。FE-SEM证实了六角形棒状结构的形成。用乙醇气体测试了该材料的传感特性。
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引用次数: 1
Titanium dioxide nanotube based sensing platform for detection of mycobacterium tuberculosis volatile biomarkers methyl nicotinate and p-anisate 基于二氧化钛纳米管的结核分枝杆菌挥发性生物标志物烟酸甲酯和茴香酯检测平台
Pub Date : 2015-03-07 DOI: 10.1109/ISPTS.2015.7220147
Younghwan Kim, Jason Young, David C. Robinson, Greg Jones, M. Misra, S. Mohanty
This research presents a metal functionalized titanium dioxide (TiO2) nanotube based sensor developed for detection of volatile biomarkers (methyl p-anisate and methyl nicotinate) associated with tuberculosis (TB). In this work self-aligning TiO2 nanotubes were fabricated, and functionalized with cobalt for specific binding to the volatile biomarkers of interest. Mimics of the volatile biomarkers were dissolved in water at variable concentrations, and nitrogen gas was flowed through the biomarker solutions and delivered to the sensor. A potentiostatic scan was used to measure current across the device under constant potentials ranging from -1.0 volts to 1-volts methyl nicotinate and methyl p-anisate. The sensor response showed a 3 × 105 change in current for methyl nicotinate, and 7.61 × 106 change in current for methyl p-anisate when compared to baseline. The sensor also showed little response to five other VOCs (acetone, ethanol, methanol, benzene, and phenol) which suggest the sensor is functionalized to be specific for the target VOCs associated with TB. Results showed detection of the volatile biomarkers yield orders of magnitude change in current which is detected easily. The sensor is simple to operate, responds in minutes, and has potential applications in non-invasive diagnosis of TB and other diseases that have distinct volatile biomarkers.
本研究提出了一种基于金属功能化二氧化钛(TiO2)纳米管的传感器,用于检测与结核病(TB)相关的挥发性生物标志物(对茴香酸甲酯和烟酸甲酯)。在这项工作中,制备了自对准的TiO2纳米管,并与钴功能化,以特异性结合感兴趣的挥发性生物标志物。挥发性生物标记物的模拟物以不同浓度溶解在水中,氮气流经生物标记物溶液并输送到传感器。恒电位扫描用于测量在-1.0伏至1伏烟酸甲酯和对茴香酸甲酯的恒定电位下通过器件的电流。与基线相比,传感器响应显示烟酸甲酯电流变化3 × 105,对茴香甲酯电流变化7.61 × 106。该传感器对其他五种挥发性有机化合物(丙酮、乙醇、甲醇、苯和苯酚)也没有反应,这表明该传感器可以对与结核病相关的目标挥发性有机化合物进行特异性功能化。结果表明,挥发性生物标志物的检测产生数量级的电流变化,易于检测。该传感器操作简单,在几分钟内做出反应,在结核病和其他具有独特挥发性生物标志物的疾病的非侵入性诊断中具有潜在的应用前景。
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引用次数: 1
Spectroscopic and morphological studies of polyaniline (PANI) — Carbon nanotubes (CNTs) nanocomposite synthesized via dynamic, liquid-liquid interfacial polymerization process and its application as optical pH sensor 动态液-液界面聚合法制备聚苯胺(PANI) -碳纳米管(CNTs)纳米复合材料的光谱和形态学研究及其在光学pH传感器中的应用
Pub Date : 2015-03-07 DOI: 10.1109/ISPTS.2015.7220098
S. Thorat, M. Kulkarni, B. Kale
Herein, we report the development of highly water dispersible nanocomposite of conducting polyaniline and multiwalled carbon nanotubes (PANI-MWCNTs) via novel, `dynamic' or `stirred' liquid-liquid interfacial polymerization method using sulphonic acid as a dopant. MWCNTs were functionalized prior to their use and then dispersed in water. The nanocomposite was further subjected for physico-chemical characterization using spectroscopic (UV-Vis and FT-IR), FE-SEM analysis. The UV-VIS spectrum of the PANI-MWCNTs nanocomposite shows a free carrier tail with increasing absorption at higher wavelength. This confirms the presence of conducting emeraldine salt phase of the polyaniline and is further supported by FT-IR analysis. The FE-SEM images show that the thin layer of polyaniline is coated over the functionalized MWCNTs forming a `core-shell' like structure. The synthesized nanocomposite was found to be highly dispersible in water and shows beautiful colour change from dark green to blue with change in pH of the solution from 1 to 12 (i.e. from acidic to basic pH). The change in colour of the polyaniline-MWCNTs nanocomposite is mainly due to the pH dependent chemical transformation /change of thin layer of polyaniline.
在此,我们报告了采用新颖的“动态”或“搅拌”液-液界面聚合方法,以磺酸作为掺杂剂,开发了导电聚苯胺和多壁碳纳米管(PANI-MWCNTs)的高水分散纳米复合材料。MWCNTs在使用前被功能化,然后分散在水中。利用紫外可见光谱、红外光谱、FE-SEM等对纳米复合材料进行了理化表征。PANI-MWCNTs纳米复合材料的紫外可见光谱显示出自由载流子尾巴,在波长越高吸收越强。这证实了聚苯胺的导电绿绿盐相的存在,并得到了FT-IR分析的进一步支持。FE-SEM图像显示,聚苯胺薄层被包裹在功能化的MWCNTs上,形成“核壳”状结构。合成的纳米复合材料在水中具有高度的分散性,并且随着溶液pH值从1到12(即从酸性到碱性)的变化,呈现出从深绿色到蓝色的美丽颜色变化。聚苯胺- mwcnts纳米复合材料的颜色变化主要是由于聚苯胺薄层的pH依赖性化学转化/变化。
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引用次数: 1
Application of principal component analysis to the conductometric Cr1−xFexNbO4 (x = 0, 0.5, 1.0) thick films gas sensors 主成分分析在电导Cr1−xfennbo4 (x = 0,0.5, 1.0)厚膜气体传感器中的应用
Pub Date : 2015-03-07 DOI: 10.1109/ISPTS.2015.7220085
A. S. R. Murthy, K. I. Gnanasekar, V. Jayaraman, A. Umarji
The gas sensing characteristics of Cr1-xFexNbO4 (x = 0.0, 0.5, 1.0) towards different organic analytes and hydrogen were investigated at different operating temperatures. The slope of the retrace transient, a representative feature for desorption kinetics was considered for data exploration. 11 sensors with 12 samples were tested and the data obtained was processed using principal component analysis (PCA). The scores plot and loadings plot showed the possible differentiation of the cross sensitive analytes and redundancy of the sensor behaviour towards these analytes respectively.
研究了cr1 - xfennbo4 (x = 0.0, 0.5, 1.0)在不同工作温度下对不同有机分析物和氢气的气敏特性。在数据探索中,考虑了脱附动力学的一个代表性特征——回撤瞬态的斜率。对12个样品的11个传感器进行测试,所得数据采用主成分分析(PCA)进行处理。分数图和负载图分别显示了交叉敏感分析物的可能分化和对这些分析物的传感器行为的冗余。
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引用次数: 1
Simulation, fabrication and characterization of Dual-Gate MOSFET test structures 双栅MOSFET测试结构的模拟、制造与表征
Pub Date : 2015-03-07 DOI: 10.1109/ISPTS.2015.7220086
S. Sinha, R. Rathore, A. Sharma, R. Mukhiya, Ranjan Sharma, V. Khanna
Ion-Sensitive Field-Effect Transistor (ISFET) is a popular potentiometric chemical/bio-chemical sensor. However, due to charge screening, the sensitivity of the device is significantly reduced. A logarithmic dependence is exhibited between the charge present at the electrolyte-insulator interface and the charge mirrored in the conducting channel, which limits the sensitivity of an ideal conventional ISFET to 59.2 mV/pH, also known as the Nernstian limit. Using Dual-Gate effect in Silicon-on-Insulator (SOI) technology improves the sensitivity of ISFET. MOSFET test structures are generally fabricated along with ISFETs on the same wafer. In this paper, we have demonstrated the dual gate operation of a Near-Fully Depleted (NFD) SOI MOSFET, by simulating its behavior in SILVACO™ TCAD tool and validating it with the test results of fabricated NFDSOI MOSFET. It is observed that the threshold voltage and drain current of the transistor can be manipulated by applying a potential to the back gate.
离子敏感场效应晶体管(ISFET)是一种流行的电位化学/生化传感器。然而,由于电荷屏蔽,器件的灵敏度明显降低。电解质-绝缘体界面上的电荷与导电通道中反射的电荷呈对数依赖关系,这将理想的传统ISFET的灵敏度限制在59.2 mV/pH,也称为纳恩斯特极限。在绝缘体上硅(SOI)技术中引入双栅极效应,提高了ISFET的灵敏度。MOSFET测试结构通常与isfet一起在同一晶片上制造。在本文中,我们通过在SILVACO™TCAD工具中模拟近完全耗尽(NFD) SOI MOSFET的行为,并通过制造的NFDSOI MOSFET的测试结果验证了其双栅极操作。可以观察到,晶体管的阈值电压和漏极电流可以通过对后门施加电势来控制。
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引用次数: 3
Commercial H2s sensor based on SnO2:CuO thin films 基于SnO2:CuO薄膜的商用H2s传感器
Pub Date : 2015-03-07 DOI: 10.1109/ISPTS.2015.7220084
S. Ganapathi, N. Ramgir, N. Datta, Vivek Patnaik, Ankit Patel, M. Kaur, A. Debnath, R. Datta, T. K. Saha, D. K. Aswal, S. Gupta
In the present work, a commercial device for the detection of H2S using SnO2; CuO thin film as a sensing material has been demonstrated. A complete device consist of SnO2: CuO sensor thin film deposited on alumina substrate, teflon head in stainless steel housing containing the temperature control circuit with Pt-50 based heater and Pt-100 as reader, and a stand-alone monitor consisting of Data Acquisition & Control Board (DACB) and touch screen based human-machine interface (HMI) module. The monitor measures the change in resistance of sensor element on exposure to gas and displays the result in concentration (ppm). The monitor is also provided with a programmable alarm set point, touch switch to change between Normal/ Calibration Mode and provision to enter the historical logs like last sensor installation date, last sensor calibration date, last fault detail etc,.
在本工作中,一种利用SnO2检测H2S的商用装置;CuO薄膜作为传感材料已被证实。完整的设备由沉积在氧化铝基板上的SnO2: CuO传感器薄膜,不锈钢外壳内的铁氟龙头包含温度控制电路,基于Pt-50的加热器和Pt-100作为读取器,以及由数据采集与控制板(DACB)和基于触摸屏的人机界面(HMI)模块组成的独立监视器组成。监视器测量传感器元件在暴露于气体时的电阻变化,并以浓度(ppm)显示结果。监视器还提供可编程报警设定点,在正常/校准模式之间切换的触摸开关,并提供输入历史日志,如上次传感器安装日期,上次传感器校准日期,上次故障详细信息等。
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引用次数: 2
期刊
2015 2nd International Symposium on Physics and Technology of Sensors (ISPTS)
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