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2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)最新文献

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Magnetic Properties of GaSb Quantum Dots Include Spin-Orbit Interaction GaSb量子点的磁性包括自旋轨道相互作用
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568519
O. Bauzha, S. Zagorodnyuk, B. Sus', Yuri Len
Quantitative numerical calculations of the effect of spin-orbit interaction on the magnetization and magnetic susceptibility of electrons to low-dimensional quantum dots were presented. The obtained characteristics demonstrate the irregular behavior in the region of ultralow temperatures. It is shown that the magnetization restraints at small magnetic fields are associated with the intersection of the energy levels of electrons, as a result of spin-orbit interaction. The calculations performed for GaSb quantum dots demonstrate the transformation of diamagnetic properties into paramagnetic ones, as well as the smoothing of the characteristics of magnetization and magnetic susceptibility with increasing temperature.
给出了自旋轨道相互作用对低维量子点磁化率和磁化率影响的定量数值计算。得到的特征表明,在超低温区域,合金具有不规则的行为。结果表明,由于自旋轨道相互作用,小磁场下的磁化约束与电子能级的交点有关。对GaSb量子点的计算表明,其抗磁性向顺磁性转变,磁化率和磁化率随温度的升高而趋于平滑。
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引用次数: 0
Optical Absorption in Core-Shell Quantum Antidot with Donor Impurity under Applied Magnetic Field 外加磁场下含给体杂质核壳量子反点的光吸收
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568536
V. Holovatsky, M. Chubrei, V. Ivanko
The influence of the magnetic field and off-central donor impurity on the energy spectrum and wave functions of an electron in the inverted core-shell QD are calculated. On this basis, the dependence of the binding energy and the absorption coefficient of electromagnetic waves by multilayer QD with an impurity on the magnetic field induction are investigated within the approximation of the effective mass and the rectangular potential profile of the nanosystem by the matrix method using the exact electron wave functions in nanosystem without perturbations.The linear, third-order nonlinear and total optical absorption coefficients (OACs) are calculated taking into account all possible intraband quantum transitions. The combined effect of donor position, magnetic field and core size on binding energies and optical absorption coefficients is observed. The results show that these effects cause significant changes on donor binding energy and optical absorption coefficient
计算了磁场和偏心给体杂质对倒转核壳量子点中电子能谱和波函数的影响。在此基础上,利用无扰动纳米体系中的精确电子波函数,用矩阵法研究了含杂质多层量子点的结合能和电磁波吸收系数对磁场感应强度的依赖关系。考虑了所有可能的带内量子跃迁,计算了线性、三阶非线性和全光吸收系数。观察到施主位置、磁场和核尺寸对结合能和光吸收系数的综合影响。结果表明,这些效应对施主结合能和光吸收系数产生了显著的影响
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引用次数: 0
Influence of Shell’s Organic Components on the Structure and Characteristics of Nanopores in Organic-Mineral Fertilizers 壳类有机组分对有机无机肥料纳米孔结构及特性的影响
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568553
A. Yanovska, S. Vakal, V. Vakal, V. Shkola, Tatiana Dychenko, A. Artyukhov
At this work the influence of biochar component addition to the shell surface on the characteristics of nanopores in the organic-mineral fertilizers. The nanoporous organic shell has good strength properties and is reliable attached to the core of the granule. The presence of biochar in the organic shell makes it possible to create a developed nanoporous structure due to a high specific surface area. The size and shape of nanopores allows for uniform penetration of moisture into the shell for its dissolution with subsequent introduction into the soil.
本文研究了在有机无机肥料壳表面添加生物炭组分对其纳米孔特性的影响。纳米多孔有机壳具有良好的强度性能,可可靠地附着在颗粒核上。生物炭在有机壳中的存在,由于具有较高的比表面积,使得创建发达的纳米孔结构成为可能。纳米孔的大小和形状允许水分均匀地渗透到外壳中,随后将其溶解到土壤中。
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引用次数: 3
Identifying Magnetic Phases in Additively Manufactured High-Entropy Alloy FeCoNiAlxMnx 增材制造高熵合金FeCoNiAlxMnx的磁相识别
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568591
Aleksander Larsen, A. Poulia, A. Azar, C. Bazioti, P. Carvalho, A. Gunnæs, B. Belle, S. Diplas, P. Mikheenko
High-Entropy Alloys are advanced technological materials composed of several (typically five) elements in nearly equal atomic concentration. By forming these alloys, previously unknown phase fields of multidimensional phase diagrams are explored. The large number of possible substitutions of constituent elements on crystal lattice sites justifies the dominant contribution of mixing entropy over enthalpy to the free energy reduction. This leads to the formation of phases, which otherwise could not be formed in alloys with fewer main alloying elements. Here we explore magnetic and compositional properties of a High-Entropy Alloy, namely FeCoNiAlx Mnx (0.05 ≤ x ≤ 3.08), composed of magnetic (Fe, Co, Ni) and non-magnetic elements (Al, Mn). By magnetic force microscopy of a selected area, it is observed that for intermediate to low Al and Mn contents, the alloy splits in two major crystallographic phases with different magnetic properties. Elemental maps of the same area were recorded with energy dispersive spectroscopy and scanning electron microscopy. Counterintuitively, it was found that the phase rich in non-magnetic Al has stronger magnetism than the phase rich in Fe. This work showcases possible applications of the here presented HEAs as soft magnetic materials in functional magnetic elements.
高熵合金是由原子浓度几乎相等的几种(通常是五种)元素组成的先进技术材料。通过形成这些合金,探索了以前未知的多维相图相场。晶格位置上大量可能的组成元素取代证明了混合熵比焓对自由能降低的主要贡献。这导致相的形成,否则在主要合金元素较少的合金中不可能形成相。本文研究了一种由磁性元素(Fe, Co, Ni)和非磁性元素(Al, Mn)组成的高熵合金FeCoNiAlx Mnx(0.05≤x≤3.08)的磁性和成分性能。通过选定区域的磁力显微镜观察,在中低Al和Mn含量的情况下,合金分裂为两个主要的具有不同磁性能的晶相。用能量色散光谱和扫描电镜记录了同一区域的元素图。与直觉相反,发现富非磁性Al的相比富Fe的相具有更强的磁性。本工作展示了HEAs作为软磁材料在功能磁性元件中的可能应用。
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引用次数: 1
Influence of Doping with Silver on Photocatalytic Properties of Tin Dioxide 银掺杂对二氧化锡光催化性能的影响
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568598
M. Samsonenko, S. Khalameida, V. Sydorchuk, O. Khyzhun, V. Starchevskyy, B. Charmas
Mechano- and sonochemical doping of precipitated SnO2 with silver have been studied. All obtained samples have been investigated using XRD, SEM and EDS, XPS, adsorption of nitrogen, TEM, UV-Vis spectroscopy. The doped samples have a developed porous structure, narrower band gap and stronger absorption of visible light and, as a consequence, high photocatalytic activity in the photodegradation of rhodamine B, safranin T and methyl orange under the action of visible light.
研究了沉淀氧化锡与银的机械化学和声化学掺杂。采用XRD、SEM、EDS、XPS、吸附氮、TEM、UV-Vis光谱对所得样品进行了表征。掺杂样品具有发达的多孔结构、更窄的带隙和更强的可见光吸收,因此在可见光作用下光降解罗丹明B、红花红T和甲基橙具有较高的光催化活性。
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引用次数: 0
Nickel-based Piezoresistive Sensors Obtained on Flexible Nanocellulose Substrate 基于柔性纳米纤维素基板的镍基压阻传感器
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568610
V. Koval, V. Barbash, M. Dusheyko, V. Lapshuda, O. Yashchenko, A. Naidonov
In the paper the biopolymer substrates were made from nanocellulose (NC), which is extracted from organosolvent reed cellulose using 2,2,6,6-tetramethylpiperidin-1-oxyl reagent (TEMPO). Nickel-based thin films were deposited on the surface of nanocellulose by RF magnetron sputtering. The peculiarities of surface morphology and chemical composition of inorganic material on the surface of biopolymer substrate were studied. Flexible strain sensors were obtained from nickel busbars on the surface of nanocellulose. The influence of overall sizes of nickel busbars on piezoresistive parameters of flexible sensors was established. It was determined that the maximum strain sensitivity is observed for a nickel busbar with a width of 1 mm, a thickness of 250 nm, a length of 15 mm and was 195,8⋆ 10-3 %. The magnitude of drift in time was 0,17 %/min. Obtained strain sensors were tested on mechanical strength depending on nickel busbar sizes. It was shown that the presence of nickel thin film increases the strength of strain sensors by 40%: from 13.8 MPa for pure nanocellulose to 19.5-19.6 MPa for nanocellulose with nickel thin films.
采用2,2,6,6-四甲基胡椒碱-1-氧试剂(TEMPO)从有机溶剂芦苇纤维素中提取纳米纤维素(NC),制备生物聚合物底物。采用射频磁控溅射技术在纳米纤维素表面沉积镍基薄膜。研究了生物聚合物衬底表面无机材料的表面形貌和化学组成的特性。利用纳米纤维素表面的镍母线制备了柔性应变传感器。建立了镍母线整体尺寸对柔性传感器压阻参数的影响。结果表明,对于宽度为1 mm,厚度为250 nm,长度为15 mm的镍母线,最大应变灵敏度为195,8 - 10- 3%。时间漂移幅度为0.17% /min。根据镍母线尺寸对得到的应变传感器进行机械强度测试。结果表明,镍薄膜的存在使应变传感器的强度提高了40%:从纯纳米纤维素的13.8 MPa提高到含镍薄膜的纳米纤维素的19.5-19.6 MPa。
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引用次数: 5
More on the Size Effects on the Optical Properties of the Metallic Nanotubes 尺寸对金属纳米管光学性能影响的进一步研究
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568567
Ya. V. Karandas, A. Korotun, I. Titov
The frequency dependencies for the diagonal components of the polarizability tensor of the metallic nanotubes have been obtained. The different approaches to the considering of the surface scattering of electrons have been analyzed. The calculations have been performed for the nanotubes Au, Ag, Cu, Al. It has been established that the location of the maximums of the polarizability and the scattering cross-section depend on the radius of the dielectric core and on the thickness of the metallic nanotube.
得到了金属纳米管极化张量对角线分量的频率依赖关系。分析了考虑电子表面散射的不同方法。对Au, Ag, Cu, Al纳米管进行了计算。结果表明,极化率和散射截面的最大值的位置取决于电介质核的半径和金属纳米管的厚度。
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引用次数: 0
Structure and Surface Properties of Magnetron Sputtered Tantalum Oxynitride Coatings for Biomedical Applications 生物医学用磁控溅射氧化氮化钽涂层的结构和表面性能
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568607
S. Yakovin, S. Dudin, A. Zykova, V. Safonov, T. Kuznetsova, G. Melnikova, A. Petrovskaya, S. A. Chizhik G, N. Donkov
Antimicrobial properties and thrombotic resistance of modern biomaterials depend on the composition and surface properties, such as roughness, topography and wettability. Tantalum oxynitrides demonstrate a wide range of modifications in the structure and elemental composition. Results show the effect of deposition conditions on the structure and surface properties of tantalum oxynitrides and further correlation with the biological response of TaON films in vitro tests.
现代生物材料的抗菌性能和抗血栓性取决于其组成和表面性能,如粗糙度、地形和润湿性。氧化氮化钽在结构和元素组成上表现出广泛的变化。结果表明,沉积条件对氧化氮化钽薄膜的结构和表面性能有影响,并与TaON薄膜的生物响应有进一步的相关性。
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引用次数: 0
SAXS and Raman Study of the Structural Evolution in Hemp Bast Fiber Derived Porous Carbon 麻韧皮纤维衍生多孔碳结构演化的SAXS和Raman研究
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568600
V. Kotsyubynsky, B. Rachiy, I. Budzulyak, V. Boychuk, S. Budzulyak, M. Hodlevska
The aim of this paper is the systematic study of the structural properties evolution of porous carbons derived from hemp bast fiber at the different carbonization temperatures with the next chemical activation procedure under the conditions of additional nitrogen doping and thermal treatment. The comparative analysis of SAXS and Raman spectroscopy data was done. The obtained materials have a turbostratic structure and consist of the ultrasmall graphitic fragments separated by amorphous carbon. It was determined that the carbonization temperature in a range of 800-1000°C causes sharp increase in micropores relative content after carbon treatment with nitric acid. The minimal lateral size of graphitic crystallites (of about 5.5 nm along (002) basal plane) is observed for nitrogen-doped carbon obtained at carbonization temperature of 800°C that corresponds to average aggregates size. The control of activated carbons structural properties allows to increase energy and power densities of electrochemical capacitors as well as to create the preconditions for composite electrode materials obtaining with predictable properties.
本文系统地研究了麻韧皮纤维制备的多孔炭在不同炭化温度下的结构性能演变,并在额外的氮掺杂和热处理条件下进行下一步化学活化。对SAXS和拉曼光谱数据进行了对比分析。所得材料具有涡层结构,由非晶碳分离的超小石墨碎片组成。结果表明,炭化温度在800 ~ 1000℃范围内,硝酸处理后微孔相对含量急剧增加。在800℃炭化温度下获得的氮掺杂碳的石墨晶体的最小横向尺寸(沿(002)基面约5.5 nm)与平均团聚体尺寸相对应。活性炭结构性能的控制可以提高电化学电容器的能量和功率密度,并为获得具有可预测性能的复合电极材料创造先决条件。
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引用次数: 2
Functional Properties of Fe-Ni-Co-Ti Nanocomposite under the Influence of Temperature and Mechanical Stress 温度和机械应力影响下Fe-Ni-Co-Ti纳米复合材料的功能特性
Pub Date : 2021-09-05 DOI: 10.1109/NAP51885.2021.9568542
A. Titenko, L. Demchenko, M. Babanli, Tymur Bykanov, Oleksii Titenko, S. Huseynov
The paper presents the functional properties of new Fe-Ni-Co-Ti shape memory nanocomposite, formed as a result of supersaturated solid solution aging. It was found that Fe-Ni-Co-Ti alloys in certain intervals exhibit unusual deformation and electrical effects when exposed to temperature and mechanical stresses. The reasons and factors that contribute to the achievement of large superelastic deformations and reactive stresses are analyzed. The appearance of differential thermo-emf (thermo-electromotive force) signals during the induction of martensitic transformation is studied experimentally. A correlation has been established between the temperature dependences of the differential thermo-emf and the electrical resistance of the studied alloy. Unique thermal power and the effect of deformation on electrical properties are able to compete with mechanical power drives, tools and signaling devices. Their uniqueness lies in the ability to reversibly restore the original shape and dimensions under thermal power loading conditions and, at the same time, perform useful work, signaling changes in external conditions. The formation of the required structure and functional properties is facilitated by the formation of a system of dispersed particles.
本文介绍了过饱和固溶时效形成的新型Fe-Ni-Co-Ti形状记忆纳米复合材料的功能性能。结果表明,Fe-Ni-Co-Ti合金在温度和机械应力作用下,在一定范围内表现出不同寻常的变形和电效应。分析了产生大超弹性变形和反应应力的原因和因素。实验研究了马氏体相变诱导过程中热电动势微分信号的出现。在热电动势差的温度依赖性和所研究合金的电阻之间建立了相关性。独特的热功率和变形对电性能的影响能够与机械动力驱动,工具和信号装置竞争。它们的独特之处在于能够在热负荷条件下可逆地恢复原始形状和尺寸,同时执行有用的工作,指示外部条件的变化。分散粒子体系的形成促进了所需结构和功能特性的形成。
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引用次数: 0
期刊
2021 IEEE 11th International Conference Nanomaterials: Applications & Properties (NAP)
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